CN104505523B - 一种铂基催化剂/石墨烯复合材料及其制备方法 - Google Patents
一种铂基催化剂/石墨烯复合材料及其制备方法 Download PDFInfo
- Publication number
- CN104505523B CN104505523B CN201510014578.7A CN201510014578A CN104505523B CN 104505523 B CN104505523 B CN 104505523B CN 201510014578 A CN201510014578 A CN 201510014578A CN 104505523 B CN104505523 B CN 104505523B
- Authority
- CN
- China
- Prior art keywords
- graphene
- catalyst
- based catalyst
- platinum
- platinum based
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 title claims abstract description 119
- 239000003054 catalyst Substances 0.000 title claims abstract description 85
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 51
- 229910052697 platinum Inorganic materials 0.000 title claims abstract description 41
- 239000002131 composite material Substances 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 12
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 6
- 239000010439 graphite Substances 0.000 claims abstract description 6
- 239000011268 mixed slurry Substances 0.000 claims abstract description 4
- 238000001914 filtration Methods 0.000 claims abstract description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 14
- 239000000243 solution Substances 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 239000000956 alloy Substances 0.000 claims description 8
- 229910045601 alloy Inorganic materials 0.000 claims description 8
- 239000003960 organic solvent Substances 0.000 claims description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 238000001291 vacuum drying Methods 0.000 claims description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- 239000011259 mixed solution Substances 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 2
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 2
- 230000003197 catalytic effect Effects 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- 150000004767 nitrides Chemical class 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- IVDFJHOHABJVEH-UHFFFAOYSA-N pinacol Chemical compound CC(C)(O)C(C)(C)O IVDFJHOHABJVEH-UHFFFAOYSA-N 0.000 claims description 2
- 238000002407 reforming Methods 0.000 claims description 2
- 210000002966 serum Anatomy 0.000 claims description 2
- 238000002604 ultrasonography Methods 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims 1
- 239000003610 charcoal Substances 0.000 claims 1
- 239000002023 wood Substances 0.000 claims 1
- 239000008367 deionised water Substances 0.000 abstract description 5
- 229910021641 deionized water Inorganic materials 0.000 abstract description 5
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 238000009792 diffusion process Methods 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- 239000000376 reactant Substances 0.000 abstract description 2
- 238000012546 transfer Methods 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract description 2
- 238000004090 dissolution Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 238000005303 weighing Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 4
- 239000004809 Teflon Substances 0.000 description 4
- 229920006362 Teflon® Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- -1 Ni and Pt Poly- Chemical class 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical compound B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 description 1
- 206010057855 Hypotelorism of orbit Diseases 0.000 description 1
- 229910002849 PtRu Inorganic materials 0.000 description 1
- 229910009848 Ti4O7 Inorganic materials 0.000 description 1
- 229910033181 TiB2 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 208000036142 Viral infection Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000002484 cyclic voltammetry Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000005087 graphitization Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002082 metal nanoparticle Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000013528 metallic particle Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/921—Alloys or mixtures with metallic elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8892—Impregnation or coating of the catalyst layer, e.g. by an ionomer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510014578.7A CN104505523B (zh) | 2015-01-13 | 2015-01-13 | 一种铂基催化剂/石墨烯复合材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510014578.7A CN104505523B (zh) | 2015-01-13 | 2015-01-13 | 一种铂基催化剂/石墨烯复合材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104505523A CN104505523A (zh) | 2015-04-08 |
CN104505523B true CN104505523B (zh) | 2017-01-04 |
Family
ID=52947258
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510014578.7A Active CN104505523B (zh) | 2015-01-13 | 2015-01-13 | 一种铂基催化剂/石墨烯复合材料及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104505523B (zh) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105322192B (zh) * | 2015-10-26 | 2017-12-01 | 华南理工大学 | 一种载Pt石墨烯中空微球催化剂及其制备方法与应用 |
CN105390707A (zh) * | 2015-11-30 | 2016-03-09 | 许昌学院 | 一种Pt/石墨烯复合物电极材料的合成方法 |
CN107275646B (zh) * | 2017-06-16 | 2020-03-10 | 福州大学 | 一种核壳结构的质子交换膜燃料电池催化剂及其制备方法 |
CN109950566A (zh) * | 2019-04-15 | 2019-06-28 | 南京大学 | 一种基于表面功能增强的高性能氧还原催化剂及其制法 |
CN110013881B (zh) * | 2019-04-30 | 2021-10-15 | 哈尔滨工业大学 | 原子级分散的金属与氮共掺杂碳基氧还原反应催化剂的制备方法 |
CN112366329A (zh) * | 2020-11-20 | 2021-02-12 | 新疆大学 | 一种三维煤基石墨烯负载铂催化剂的制备方法 |
CN112701308A (zh) * | 2020-12-29 | 2021-04-23 | 华南理工大学 | 一种具有高耐久性能燃料电池催化剂的制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101752572A (zh) * | 2010-01-28 | 2010-06-23 | 哈尔滨工业大学 | 提高直接醇类燃料电池催化剂稳定性的方法 |
CN104258848A (zh) * | 2014-10-08 | 2015-01-07 | 青岛大学 | 一种Pt/三维石墨烯复合催化剂的制备方法及其应用 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007172887A (ja) * | 2005-12-19 | 2007-07-05 | Equos Research Co Ltd | 燃料電池用担持触媒、燃料電池用反応層、燃料電池、及び燃料電池用担持触媒の製造方法。 |
-
2015
- 2015-01-13 CN CN201510014578.7A patent/CN104505523B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101752572A (zh) * | 2010-01-28 | 2010-06-23 | 哈尔滨工业大学 | 提高直接醇类燃料电池催化剂稳定性的方法 |
CN104258848A (zh) * | 2014-10-08 | 2015-01-07 | 青岛大学 | 一种Pt/三维石墨烯复合催化剂的制备方法及其应用 |
Non-Patent Citations (1)
Title |
---|
A newly-designed sandwich-structured graphene-Pt-graphene catalyst with improved electrocatalytic performance for fuel cells;Lei Zhao等;《Journal of Materials Chemistry A》;20150106(第3期);第5313-5320页 * |
Also Published As
Publication number | Publication date |
---|---|
CN104505523A (zh) | 2015-04-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104505523B (zh) | 一种铂基催化剂/石墨烯复合材料及其制备方法 | |
CN105170169B (zh) | 一种氮掺杂石墨烯‑铁基纳米颗粒复合型催化剂及其制备方法 | |
CN106861740B (zh) | 氮掺杂有序分级介孔碳催化剂的制备及其碳催化剂和应用 | |
CN103143378B (zh) | 一种燃料电池阴极非贵金属氧还原电催化剂的制备方法 | |
CN103050715B (zh) | 一种钯铜锡三元合金纳米催化剂的制备方法 | |
CN108923050B (zh) | 一种高催化性能的核壳碳纳米结构电催化剂及其制备方法 | |
CN109817998A (zh) | 一种S掺杂碳材料负载Pt复合催化剂及其制备方法和应用 | |
CN104549407A (zh) | 一种铂基/氮掺杂碳量子点-碳纳米管催化剂的制备方法 | |
CN103394350B (zh) | 一种钛钨氧化物包覆碳纳米管载铂电催化剂的制备方法 | |
CN102891326A (zh) | 氮掺杂中空碳球负载的钯基催化剂及其制备方法和应用该催化剂的乙醇燃料电池 | |
CN103915633B (zh) | 一种复合碳纤维载金属催化剂及其制备方法和应用 | |
CN104667953A (zh) | 一种氮掺杂石墨炔、制备方法及其用途 | |
CN104289249A (zh) | 一种可用于聚合物燃料电池阴极催化剂的Fe、N共掺杂多孔碳纳米纤维的制备方法 | |
CN106268798A (zh) | 用于甲酸氧化的Pd/WO3‑RGO催化剂及其制备方法 | |
Fang et al. | Preparation, characterization and catalytic performance of a novel Pt/SiC | |
CN102728397A (zh) | 一种碳化硅负载金属纳米粒子催化剂的制备方法 | |
CN104525185A (zh) | 一种碳基复合物燃料电池阴极氧还原催化剂及其制备方法 | |
CN111477887A (zh) | 一种Co3O4负载空心碳微球的复合氧还原催化剂及其制法 | |
CN108878910A (zh) | 一种质子交换膜燃料电池用负载型高分散铂合金催化剂的制备方法 | |
CN105977500A (zh) | 一种掺氮碳/石墨烯/氧化锰复合材料的制备方法及其应用于氧的电催化还原 | |
CN108281675A (zh) | 一种空心球形氮化碳包裹铜基燃料电池催化剂及制备方法 | |
CN101826623B (zh) | 一种质子交换膜燃料电池Pt-Ru/C催化剂的制备方法 | |
CN104241664B (zh) | 一种用于燃料电池氧还原反应的PtM/M’-PPy-C电催化剂及其制备方法 | |
CN104148071A (zh) | 一种多孔高活性非贵金属催化剂的制备及其应用 | |
CN102806106A (zh) | 一种碳载金属聚吡咯类氧还原催化剂的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20230113 Address after: No. 131, Haihe Road, Hebi Economic and Technological Development Zone, Henan 458000 Patentee after: HEBI NXE ELECTRONICS CO.,LTD. Address before: 150000 No. 92, West Da Zhi street, Nangang District, Harbin, Heilongjiang. Patentee before: HARBIN INSTITUTE OF TECHNOLOGY |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20230327 Address after: Room 1101, Unit 1, Building 3, Left Bank, Industrial University, No. 73, Wendao Street, Harbin, Heilongjiang Province, 150000 Patentee after: Wang Zhenbo Address before: No. 131, Haihe Road, Hebi Economic and Technological Development Zone, Henan 458000 Patentee before: HEBI NXE ELECTRONICS CO.,LTD. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20230414 Address after: 201100 building 41, No. 398, Heqing Road, Minhang District, Shanghai Patentee after: Haizhuojian New Energy Materials (Shanghai) Co.,Ltd. Address before: Room 1101, Unit 1, Building 3, Left Bank, Industrial University, No. 73, Wendao Street, Harbin, Heilongjiang Province, 150000 Patentee before: Wang Zhenbo |
|
TR01 | Transfer of patent right |