CN103906768A - 使用反应性乳化剂的乳液聚合方法、由此得到的水系聚合物分散液和聚合物薄膜 - Google Patents

使用反应性乳化剂的乳液聚合方法、由此得到的水系聚合物分散液和聚合物薄膜 Download PDF

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Publication number
CN103906768A
CN103906768A CN201280049309.9A CN201280049309A CN103906768A CN 103906768 A CN103906768 A CN 103906768A CN 201280049309 A CN201280049309 A CN 201280049309A CN 103906768 A CN103906768 A CN 103906768A
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monomer
reactive emulsifier
group
molecule
polymer
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小笠原亚沙子
桥本贺之
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DKS Co Ltd
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Dai Ichi Kogyo Seiyaku Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/38—Esters containing sulfur
    • C08F220/382—Esters containing sulfur and containing oxygen, e.g. 2-sulfoethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/103—Esters of polyhydric alcohols or polyhydric phenols of trialcohols, e.g. trimethylolpropane tri(meth)acrylate

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201280049309.9A 2011-10-07 2012-09-19 使用反应性乳化剂的乳液聚合方法、由此得到的水系聚合物分散液和聚合物薄膜 Pending CN103906768A (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP2011223108 2011-10-07
JP2011-223108 2011-10-07
JP2012-172562 2012-08-03
JP2012172562 2012-08-03
PCT/JP2012/005946 WO2013051205A1 (ja) 2011-10-07 2012-09-19 反応性乳化剤を用いた乳化重合方法、それにより得られる水系ポリマーディスパージョン及びポリマーフィルム

Publications (1)

Publication Number Publication Date
CN103906768A true CN103906768A (zh) 2014-07-02

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CN201280049309.9A Pending CN103906768A (zh) 2011-10-07 2012-09-19 使用反应性乳化剂的乳液聚合方法、由此得到的水系聚合物分散液和聚合物薄膜

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US (1) US20140249272A1 (cg-RX-API-DMAC7.html)
EP (1) EP2765142A4 (cg-RX-API-DMAC7.html)
JP (1) JPWO2013051205A1 (cg-RX-API-DMAC7.html)
KR (1) KR20140068136A (cg-RX-API-DMAC7.html)
CN (1) CN103906768A (cg-RX-API-DMAC7.html)
IN (1) IN2014CN03315A (cg-RX-API-DMAC7.html)
TW (1) TW201331233A (cg-RX-API-DMAC7.html)
WO (1) WO2013051205A1 (cg-RX-API-DMAC7.html)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105713145A (zh) * 2014-12-19 2016-06-29 赢创德固赛有限公司 包含乙二醇二(甲基)丙烯酸酯化合物的用于封装薄膜的共交联剂体系
CN107474236A (zh) * 2017-07-07 2017-12-15 联泓(江苏)新材料研究院有限公司 一种反应性乳化剂、其制备方法和应用
CN109890495A (zh) * 2016-09-29 2019-06-14 第一工业制药株式会社 表面活性剂组合物
CN110191904A (zh) * 2016-11-23 2019-08-30 巴斯夫欧洲公司 粘合剂组合物及其制备和使用方法
CN113831530A (zh) * 2021-08-13 2021-12-24 温州医科大学 一种反应性乳化剂及其制备方法和制备的纳米微球
CN114195936A (zh) * 2021-12-19 2022-03-18 江苏三瑞生物技术有限公司 一种丙烯基乳化剂的制备方法
CN114213582A (zh) * 2022-02-21 2022-03-22 河南博源新材料有限公司 一种多位点支化阴离子型聚丙烯酰胺及其用途
CN115850568A (zh) * 2022-12-16 2023-03-28 嘉宝莉化工集团股份有限公司 一种生物基羟基聚丙烯酸酯乳液及其制备方法和应用

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CN104011088A (zh) * 2011-12-20 2014-08-27 第一工业制药株式会社 乳液聚合用乳化剂以及使用其的乳液聚合方法
CN104418974B (zh) * 2013-09-11 2016-08-17 中国石油化工股份有限公司 一种聚丙烯酰胺乳液的制备方法
KR101722818B1 (ko) 2013-11-18 2017-04-03 주식회사 엘지화학 카르본산 변성 니트릴계 공중합체 라텍스 조성물, 이의 제조방법 및 이를 포함하는 딥 성형용 라텍스 조성물
CN106998678B (zh) * 2014-12-09 2021-02-26 巴斯夫欧洲公司 农药和含有可共聚表面活性剂的聚合物颗粒的水分散体
KR101875999B1 (ko) * 2015-10-23 2018-08-02 주식회사 엘지화학 열안정성이 우수한 난연 열가소성 수지 조성물, 이의 제조방법 및 이로부터 제조된 성형품
KR102674581B1 (ko) * 2016-06-15 2024-06-13 주식회사 엘지생활건강 열 안정성이 우수한 유화용 조성물 및 이를 이용한 유화중합 방법
WO2020185513A1 (en) * 2019-03-08 2020-09-17 Stepan Company Reactive surfactants
PL3962986T3 (pl) * 2019-05-03 2025-03-31 Specialty Operations France Polimeryzowalne surfaktanty o odporności na wybielanie wodą i sposoby zastosowania
JP6808798B1 (ja) * 2019-09-30 2021-01-06 第一工業製薬株式会社 界面活性剤組成物、樹脂水分散体の製造方法、塗料及び粘着剤
KR102822966B1 (ko) * 2020-06-29 2025-06-18 주식회사 엘지화학 아크릴계 에멀젼 점착제 조성물의 제조 방법
WO2022019241A1 (ja) * 2020-07-22 2022-01-27 ダイキン工業株式会社 含フッ素エラストマー水性分散液の製造方法および含フッ素エラストマー水性分散液
CN117700601A (zh) * 2023-12-06 2024-03-15 江苏三木化工股份有限公司 一种高光泽高硬度丙烯酸乳液及其制备方法
CN117866146B (zh) * 2023-12-29 2024-10-01 黄山联固新材料科技有限公司 一种水性高光工业漆乳液及其制备方法
JP7611451B1 (ja) * 2024-08-14 2025-01-09 第一工業製薬株式会社 樹脂水分散体及びその製造方法、並びに塗料及び粘着剤

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105713145B (zh) * 2014-12-19 2020-10-09 赢创运营有限公司 包含乙二醇二(甲基)丙烯酸酯化合物的用于封装薄膜的共交联剂体系
CN105713145A (zh) * 2014-12-19 2016-06-29 赢创德固赛有限公司 包含乙二醇二(甲基)丙烯酸酯化合物的用于封装薄膜的共交联剂体系
CN109890495A (zh) * 2016-09-29 2019-06-14 第一工业制药株式会社 表面活性剂组合物
CN109890495B (zh) * 2016-09-29 2021-04-20 第一工业制药株式会社 表面活性剂组合物
CN110191904B (zh) * 2016-11-23 2023-06-30 巴斯夫欧洲公司 粘合剂组合物及其制备和使用方法
CN110191904A (zh) * 2016-11-23 2019-08-30 巴斯夫欧洲公司 粘合剂组合物及其制备和使用方法
US11505636B2 (en) 2016-11-23 2022-11-22 Basf Se Binder compositions and methods of preparing and using the same
CN116769111A (zh) * 2016-11-23 2023-09-19 巴斯夫欧洲公司 粘合剂组合物及其制备和使用方法
CN107474236B (zh) * 2017-07-07 2021-03-16 联泓(江苏)新材料研究院有限公司 一种反应性乳化剂、其制备方法和应用
CN107474236A (zh) * 2017-07-07 2017-12-15 联泓(江苏)新材料研究院有限公司 一种反应性乳化剂、其制备方法和应用
CN113831530A (zh) * 2021-08-13 2021-12-24 温州医科大学 一种反应性乳化剂及其制备方法和制备的纳米微球
CN113831530B (zh) * 2021-08-13 2023-07-07 温州医科大学 一种反应性乳化剂及其制备方法和制备的纳米微球
CN114195936A (zh) * 2021-12-19 2022-03-18 江苏三瑞生物技术有限公司 一种丙烯基乳化剂的制备方法
CN114195936B (zh) * 2021-12-19 2023-08-15 江苏三瑞生物技术有限公司 一种丙烯基乳化剂的制备方法
CN114213582A (zh) * 2022-02-21 2022-03-22 河南博源新材料有限公司 一种多位点支化阴离子型聚丙烯酰胺及其用途
CN115850568A (zh) * 2022-12-16 2023-03-28 嘉宝莉化工集团股份有限公司 一种生物基羟基聚丙烯酸酯乳液及其制备方法和应用

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