CN103313847A - 包含dint作为增塑剂的聚合物-组合物 - Google Patents
包含dint作为增塑剂的聚合物-组合物 Download PDFInfo
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- CN103313847A CN103313847A CN2011800658538A CN201180065853A CN103313847A CN 103313847 A CN103313847 A CN 103313847A CN 2011800658538 A CN2011800658538 A CN 2011800658538A CN 201180065853 A CN201180065853 A CN 201180065853A CN 103313847 A CN103313847 A CN 103313847A
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- plastisol
- ester
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C—CHEMISTRY; METALLURGY
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Abstract
Description
增塑溶胶配方 (实施例 2) | 1** | 2* | 3* | 4** | 5* |
Vestolit B 7021 –Ultra | 100 | 100 | 100 | 100 | 100 |
VESTINOL® 9 | 50 | ||||
实施例1.1中的对苯二甲酸二(壬酯) | 50 | ||||
实施例1.3中的对苯二甲酸二(壬酯) | 50 | ||||
实施例1.6中的对苯二甲酸二(壬酯) | 50 | ||||
实施例1.7中的对苯二甲酸二(壬酯) | 50 | ||||
Drapex 39 | 3 | 3 | 3 | 3 | 3 |
Mark CZ 149 | 2 | 2 | 2 | 2 | 2 |
实施例2中的增塑溶胶配方 | 1** | 2* | 3* | 4** | 5* |
在剪切速率 = 100/s下的剪切粘度 [Pa*s] | 6.4 | 8.7 | 12.1 | n.bb. | 13.7 |
在剪切速率= 10/s下的剪切粘度[Pa*s] | 3.25 | 3.25 | 5 | n.bb. | 6 |
在剪切速率= 1/s下的剪切粘度 [Pa*s] | 3.1 | 2.34 | 3 | n.bb. | 3.2 |
在剪切速率= 0.1/s下的剪切粘度 [Pa*s] | 4.05 | 2.74 | 3.3 | n.bb. | 3.4 |
根据实施例2的增塑溶胶配方 | 1** | 2* | 3* | 4** | 5* |
肖氏A | 80 | 86 | 91 | 92 | 90 |
肖氏D | 25 | 30 | 35 | 38 | 36 |
评估 | 含义 |
1 | 极好(不可看出扩散或迁移;在表面上没有任何成膜)。 |
3 | 良好 – 满意(不可看出明显扩散或迁移;在表面上微小成膜)。 |
5 | 有缺陷(清楚的迁移迹象;“油腻”触感;形成微滴;由于渗出造成浑浊)。 |
增塑溶胶配方(根据实施例2) | 1** | 2* | 3* | 4** | 5* |
不透明度 [-] | 10.8 | 10.7 | 10.9 | n.bb. | 11.2 |
黄度值 [-] | 8.9 | 9.1 | 9.4 | n.bb. | 9.7 |
24小时后的渗泌行为的评估 | 1 | 1 | 1 | 5 | 1 |
4周后的渗泌行为的评估 | 1 | 3 | 3 | 5 | 3 |
配方: | 1** | 2** | 3* | 4* | 5* | 6* |
Vestolit B 7021 – Ultra | 100 | 100 | 100 | 100 | 100 | 100 |
Vestinol 9 | 50 | |||||
实施例1.1中的对苯二甲酸二(壬酯) | 50 | 40 | 40 | 40 | 40 | |
Eastman DBT | 10 | |||||
Vestinol INB | 10 | |||||
Citrofol B II | 10 | |||||
Santicizer 9201 | 10 | |||||
Drapex 39 | 3 | 3 | 3 | 3 | 3 | 3 |
Mark CZ 149 | 2 | 2 | 2 | 2 | 2 | 2 |
根据实施例6的增塑溶胶配方 | 1** | 2** | 3* | 4* | 5* | 6* |
达到增塑溶胶粘度1000 Pa*s的温度 [℃] | 87 | 121 | 97 | 107 | 99 | 95 |
达到增塑溶胶粘度10 000 Pa*s的温度[℃] | 102 | 137 | 122 | 127 | 125 | 120 |
最大增塑溶胶粘度[Pa*s] | 27 700 | 16 000 | 22 200 | 15 800 | 17 200 | 21 800 |
达到最大增塑溶胶粘度时的温度 [℃] | 137 | 147 | 139 | 134 | 142 | 142 |
根据实施例6的增塑溶胶配方 | 1** | 2** | 3* | 4* | 5* | 6* |
肖氏A | 80 | 89 | 83 | 83 | 84 | 86 |
肖氏D | 27 | 32 | 28 | 28 | 28 | 29 |
根据实施例6的增塑溶胶配方 | 1** | 2** | 3* | 4* | 5* | 6* |
不透明度 [-] | 10.4 | 10.7 | 10.8 | 11 | 10.5 | 11.3 |
制成后的黄度值 [-] | 9 | 9 | 9 | 9 | 8.8 | 9 |
在10 min. @ 200℃后的黄度值 | 41 | 18 | 14 | 12 | 14 | 22.6 |
24小时后的渗泌行为的评估 | 1 | 1 | 1 | 1 | 1 | 1 |
4周后的渗泌行为的评估 | 1 | 3 | 1 | 3 | 1 | 1 |
7天储存时间 @ 30℃后的吸水率 [质量%] | + 1.2 | + 1.2 | + 1.1 | + 1.2 | + 0.6 | - 1.2 |
在30℃水中储存7天造成的质量损失 [质量%] | + 0.1 | + 0.1 | - 0.1 | 0 | - 0.5 | - 2.3 |
配方: | 1** | 2** | 3* | 4* | 5* | 6* | 7* | 8* |
P 1430 K70 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 |
Vestinol 9 | 65 | |||||||
根据实施例1.1的对苯二甲酸二(壬酯) | 75 | 50 | 50 | 50 | 50 | 45 | 35 | |
Eastman DBT | 20 | 20 | 30 | |||||
Santicizer 9201 | 20 | |||||||
Vestinol INB | 20 | |||||||
Citrofol B II | 20 | |||||||
Calcilit 6G | 15 | 15 | 15 | 15 | 15 | 15 | 15 | 15 |
Kronos 2220 | 3 | 3 | 3 | 3 | 3 | 3 | 3 | 3 |
Drapex 39 | 3 | 3 | 3 | 3 | 3 | 3 | 3 | 3 |
Mark BZ 561 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 |
根据实施例11的增塑溶胶配方 | 1** | 2** | 3* | 4* | 5* | 6* | 7* | 8* |
达到增塑溶胶粘度1000 Pa*s所需的温度 [℃] | 93 | 134 | 112 | 107 | 120 | 115 | 101 | 82 |
达到增塑溶胶粘度10 000 Pa*s所需的温度[℃] | 125 | - | 134 | 132 | - | 136 | 130 | 120 |
最大增塑溶胶粘度[Pa*s] | 17 300 | 6800 | 11 200 | 11 700 | 9800 | 11 400 | 13 200 | 16 000 |
达到最大增塑溶胶粘度时的温度 [℃] | 140 | 151 | 139 | 138 | 144 | 142 | 139 | 132 |
根据实施例11的增塑溶胶配方 | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 |
肖氏A | 72 | 71 | 67 | 72 | 70 | 70 | 72 | 69 |
肖氏D | 19 | 18 | 17 | 18 | 17 | 17 | 18 | 17 |
Claims (15)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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DE102010061871.3 | 2010-11-24 | ||
DE102010061871A DE102010061871A1 (de) | 2010-11-24 | 2010-11-24 | Polymer-Zusammensetzung enthaltend DINT als Weichmacher |
PCT/EP2011/069013 WO2012069278A1 (de) | 2010-11-24 | 2011-10-28 | Polymer-zusammensetzung enthaltend dint als weichmacher |
Publications (2)
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CN103313847A true CN103313847A (zh) | 2013-09-18 |
CN103313847B CN103313847B (zh) | 2016-02-10 |
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CN201180065853.8A Expired - Fee Related CN103313847B (zh) | 2010-11-24 | 2011-10-28 | 包含dint作为增塑剂的聚合物-组合物 |
Country Status (11)
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US (1) | US20130317152A1 (zh) |
EP (1) | EP2643156A1 (zh) |
JP (1) | JP2013543917A (zh) |
KR (1) | KR20140005908A (zh) |
CN (1) | CN103313847B (zh) |
CA (1) | CA2817282C (zh) |
DE (1) | DE102010061871A1 (zh) |
MX (1) | MX2013005591A (zh) |
MY (1) | MY165653A (zh) |
SG (1) | SG190298A1 (zh) |
WO (1) | WO2012069278A1 (zh) |
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KR20220094806A (ko) * | 2020-12-29 | 2022-07-06 | 한화솔루션 주식회사 | 가소제 조성물 |
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CN106661269A (zh) * | 2014-07-08 | 2017-05-10 | 巴斯夫欧洲公司 | 包含脂族二羧酸酯及对苯二甲酸二烷基酯的增塑剂组合物 |
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Also Published As
Publication number | Publication date |
---|---|
MY165653A (en) | 2018-04-18 |
JP2013543917A (ja) | 2013-12-09 |
EP2643156A1 (de) | 2013-10-02 |
SG190298A1 (en) | 2013-06-28 |
WO2012069278A1 (de) | 2012-05-31 |
MX2013005591A (es) | 2013-06-12 |
CA2817282A1 (en) | 2012-05-31 |
RU2013128409A (ru) | 2015-01-20 |
US20130317152A1 (en) | 2013-11-28 |
CA2817282C (en) | 2019-07-23 |
DE102010061871A1 (de) | 2012-05-24 |
CN103313847B (zh) | 2016-02-10 |
KR20140005908A (ko) | 2014-01-15 |
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