CA2447644C - Preparation of olefin polymerisation catalyst component - Google Patents
Preparation of olefin polymerisation catalyst component Download PDFInfo
- Publication number
- CA2447644C CA2447644C CA002447644A CA2447644A CA2447644C CA 2447644 C CA2447644 C CA 2447644C CA 002447644 A CA002447644 A CA 002447644A CA 2447644 A CA2447644 A CA 2447644A CA 2447644 C CA2447644 C CA 2447644C
- Authority
- CA
- Canada
- Prior art keywords
- process according
- metal
- particles
- magnesium
- complex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 63
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 12
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims abstract description 11
- 238000002360 preparation method Methods 0.000 title claims description 17
- 238000000034 method Methods 0.000 claims abstract description 52
- 239000000839 emulsion Substances 0.000 claims abstract description 27
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 11
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 150000004696 coordination complex Chemical class 0.000 claims abstract description 3
- 150000003623 transition metal compounds Chemical class 0.000 claims abstract 2
- 239000011777 magnesium Substances 0.000 claims description 50
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 46
- 239000002245 particle Substances 0.000 claims description 41
- 229910052751 metal Inorganic materials 0.000 claims description 38
- 239000002184 metal Substances 0.000 claims description 38
- 229910052749 magnesium Inorganic materials 0.000 claims description 30
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 15
- 239000012429 reaction media Substances 0.000 claims description 13
- 238000005406 washing Methods 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 11
- 150000003624 transition metals Chemical class 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 9
- 239000003381 stabilizer Substances 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- 239000002243 precursor Substances 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical group OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 150000002736 metal compounds Chemical class 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 4
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 150000004820 halides Chemical class 0.000 claims description 3
- 238000011065 in-situ storage Methods 0.000 claims description 3
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- 229910003074 TiCl4 Inorganic materials 0.000 claims description 2
- 125000005234 alkyl aluminium group Chemical group 0.000 claims description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical group CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 150000002009 diols Chemical class 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 238000007711 solidification Methods 0.000 claims description 2
- 230000008023 solidification Effects 0.000 claims description 2
- -1 transition metal olefin Chemical class 0.000 abstract description 34
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 235000001055 magnesium Nutrition 0.000 description 29
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 24
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 16
- 239000000047 product Substances 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 238000009826 distribution Methods 0.000 description 10
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 8
- 239000007795 chemical reaction product Substances 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 7
- 238000001556 precipitation Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 4
- FYXKZNLBZKRYSS-UHFFFAOYSA-N benzene-1,2-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=CC=C1C(Cl)=O FYXKZNLBZKRYSS-UHFFFAOYSA-N 0.000 description 4
- 238000010924 continuous production Methods 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 4
- 150000002681 magnesium compounds Chemical class 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 238000007873 sieving Methods 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 2
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 2
- WOFPPJOZXUTRAU-UHFFFAOYSA-N 2-Ethyl-1-hexanol Natural products CCCCC(O)CCC WOFPPJOZXUTRAU-UHFFFAOYSA-N 0.000 description 2
- CETWDUZRCINIHU-UHFFFAOYSA-N 2-heptanol Chemical compound CCCCCC(C)O CETWDUZRCINIHU-UHFFFAOYSA-N 0.000 description 2
- YVBCULSIZWMTFY-UHFFFAOYSA-N 4-Heptanol Natural products CCCC(O)CCC YVBCULSIZWMTFY-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 150000001555 benzenes Chemical class 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 2
- 229960001701 chloroform Drugs 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 239000000543 intermediate Substances 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- KXDANLFHGCWFRQ-UHFFFAOYSA-N magnesium;butane;octane Chemical compound [Mg+2].CCC[CH2-].CCCCCCC[CH2-] KXDANLFHGCWFRQ-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
- SJWFXCIHNDVPSH-UHFFFAOYSA-N octan-2-ol Chemical compound CCCCCCC(C)O SJWFXCIHNDVPSH-UHFFFAOYSA-N 0.000 description 2
- AQIXEPGDORPWBJ-UHFFFAOYSA-N pentan-3-ol Chemical compound CCC(O)CC AQIXEPGDORPWBJ-UHFFFAOYSA-N 0.000 description 2
- IVDFJHOHABJVEH-UHFFFAOYSA-N pinacol Chemical compound CC(C)(O)C(C)(C)O IVDFJHOHABJVEH-UHFFFAOYSA-N 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- NBRKLOOSMBRFMH-UHFFFAOYSA-N tert-butyl chloride Chemical compound CC(C)(C)Cl NBRKLOOSMBRFMH-UHFFFAOYSA-N 0.000 description 2
- 125000006528 (C2-C6) alkyl group Chemical group 0.000 description 1
- AVGQTJUPLKNPQP-UHFFFAOYSA-N 1,1,1-trichloropropane Chemical compound CCC(Cl)(Cl)Cl AVGQTJUPLKNPQP-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- OHVLMTFVQDZYHP-UHFFFAOYSA-N 1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-2-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]ethanone Chemical compound N1N=NC=2CN(CCC=21)C(CN1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)=O OHVLMTFVQDZYHP-UHFFFAOYSA-N 0.000 description 1
- 239000005968 1-Decanol Substances 0.000 description 1
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N 1-Tetradecanol Natural products CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 1
- BAYAKMPRFGNNFW-UHFFFAOYSA-N 2,4-dimethylpentan-3-ol Chemical compound CC(C)C(O)C(C)C BAYAKMPRFGNNFW-UHFFFAOYSA-N 0.000 description 1
- JJZZVQICFJITMO-UHFFFAOYSA-N 2,7-dimethyloctan-2-ol Chemical compound CC(C)CCCCC(C)(C)O JJZZVQICFJITMO-UHFFFAOYSA-N 0.000 description 1
- IOPYVZVNUXHZCP-UHFFFAOYSA-N 2-(3-ethyloctan-3-yloxycarbonyl)benzoic acid Chemical compound CCCCCC(CC)(CC)OC(=O)C1=CC=CC=C1C(O)=O IOPYVZVNUXHZCP-UHFFFAOYSA-N 0.000 description 1
- MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 description 1
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 1
- GBZJVZOWESVSMX-UHFFFAOYSA-N CCCCCCCC[Mg]OCCCC Chemical compound CCCCCCCC[Mg]OCCCC GBZJVZOWESVSMX-UHFFFAOYSA-N 0.000 description 1
- DMVNHJNKGGFAEB-UHFFFAOYSA-N CCCCC[Mg]CCCC Chemical compound CCCCC[Mg]CCCC DMVNHJNKGGFAEB-UHFFFAOYSA-N 0.000 description 1
- UNCRKDFOOFDWDK-UHFFFAOYSA-N CCCCC[Mg]CCCCC Chemical compound CCCCC[Mg]CCCCC UNCRKDFOOFDWDK-UHFFFAOYSA-N 0.000 description 1
- HEYWGIVDJPKIAQ-UHFFFAOYSA-N CCCCO[Mg]CC Chemical compound CCCCO[Mg]CC HEYWGIVDJPKIAQ-UHFFFAOYSA-N 0.000 description 1
- MVECFARLYQAUNR-UHFFFAOYSA-N CCCC[Mg]CC Chemical compound CCCC[Mg]CC MVECFARLYQAUNR-UHFFFAOYSA-N 0.000 description 1
- IWCXHHNYQNVTHS-UHFFFAOYSA-N CCCC[Mg]CCC Chemical compound CCCC[Mg]CCC IWCXHHNYQNVTHS-UHFFFAOYSA-N 0.000 description 1
- ABXKXVWOKXSBNR-UHFFFAOYSA-N CCC[Mg]CCC Chemical compound CCC[Mg]CCC ABXKXVWOKXSBNR-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- HXQPUEQDBSPXTE-UHFFFAOYSA-N Diisobutylcarbinol Chemical compound CC(C)CC(O)CC(C)C HXQPUEQDBSPXTE-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000004791 alkyl magnesium halides Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229950005499 carbon tetrachloride Drugs 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 150000004796 dialkyl magnesium compounds Chemical class 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 229940052308 general anesthetics halogenated hydrocarbons Drugs 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- VHHHONWQHHHLTI-UHFFFAOYSA-N hexachloroethane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)Cl VHHHONWQHHHLTI-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- QTBFPMKWQKYFLR-UHFFFAOYSA-N isobutyl chloride Chemical compound CC(C)CCl QTBFPMKWQKYFLR-UHFFFAOYSA-N 0.000 description 1
- 229960004592 isopropanol Drugs 0.000 description 1
- 235000011147 magnesium chloride Nutrition 0.000 description 1
- KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
- KMYFNYFIPIGQQZ-UHFFFAOYSA-N magnesium;octane Chemical compound [Mg+2].CCCCCCC[CH2-].CCCCCCC[CH2-] KMYFNYFIPIGQQZ-UHFFFAOYSA-N 0.000 description 1
- JYVLIDXNZAXMDK-UHFFFAOYSA-N methyl propyl carbinol Natural products CCCC(C)O JYVLIDXNZAXMDK-UHFFFAOYSA-N 0.000 description 1
- FCBBRODPXVPZAH-UHFFFAOYSA-N nonan-5-ol Chemical compound CCCCC(O)CCCC FCBBRODPXVPZAH-UHFFFAOYSA-N 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000013110 organic ligand Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- BNIXVQGCZULYKV-UHFFFAOYSA-N pentachloroethane Chemical compound ClC(Cl)C(Cl)(Cl)Cl BNIXVQGCZULYKV-UHFFFAOYSA-N 0.000 description 1
- REIUXOLGHVXAEO-UHFFFAOYSA-N pentadecan-1-ol Chemical compound CCCCCCCCCCCCCCCO REIUXOLGHVXAEO-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000010076 replication Effects 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/06—Catalyst characterized by its size
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01115000.0 | 2001-06-20 | ||
| EP01115000A EP1273595B8 (en) | 2001-06-20 | 2001-06-20 | Preparation of olefin polymerisation catalyst component |
| PCT/EP2002/006720 WO2003000757A1 (en) | 2001-06-20 | 2002-06-18 | Preparation of olefin polymerisation catalyst component |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2447644A1 CA2447644A1 (en) | 2003-01-03 |
| CA2447644C true CA2447644C (en) | 2009-09-15 |
Family
ID=8177772
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002447644A Expired - Lifetime CA2447644C (en) | 2001-06-20 | 2002-06-18 | Preparation of olefin polymerisation catalyst component |
| CA2447592A Expired - Fee Related CA2447592C (en) | 2001-06-20 | 2002-06-18 | Ziegler-natta catalyst and methods for preparing the same |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2447592A Expired - Fee Related CA2447592C (en) | 2001-06-20 | 2002-06-18 | Ziegler-natta catalyst and methods for preparing the same |
Country Status (15)
| Country | Link |
|---|---|
| US (3) | US7902108B2 (enExample) |
| EP (3) | EP1273595B8 (enExample) |
| JP (2) | JP2004530765A (enExample) |
| KR (2) | KR100852432B1 (enExample) |
| CN (3) | CN1247625C (enExample) |
| AT (1) | ATE328912T1 (enExample) |
| AU (2) | AU2002325246B2 (enExample) |
| BR (2) | BR0210400B1 (enExample) |
| CA (2) | CA2447644C (enExample) |
| DE (1) | DE60120389T2 (enExample) |
| ES (2) | ES2266053T3 (enExample) |
| HU (1) | HUP0400335A2 (enExample) |
| PL (1) | PL202988B1 (enExample) |
| PT (1) | PT1273595E (enExample) |
| WO (3) | WO2003000757A1 (enExample) |
Families Citing this family (264)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1323747A1 (en) * | 2001-12-19 | 2003-07-02 | Borealis Technology Oy | Production of olefin polymerisation catalysts |
| EP1375528A1 (en) * | 2002-06-18 | 2004-01-02 | Borealis Polymers Oy | Method for the preparation of olefin polymerisation catalysts |
| EP1403292B1 (en) * | 2002-09-30 | 2016-04-13 | Borealis Polymers Oy | Process for preparing an olefin polymerisation catalyst component with improved high temperature activity |
| EP1484345A1 (en) * | 2003-06-06 | 2004-12-08 | Borealis Technology Oy | Process for the production of polypropylene using a Ziegler-Natta catalyst |
| EP1489110B1 (en) | 2003-06-20 | 2012-01-18 | Borealis Polymers Oy | Method for preparing an olefin polymerisation catalyst composition |
| EP1544218A1 (en) | 2003-12-19 | 2005-06-22 | Borealis Technology Oy | Process for producing olefin polymers |
| US6962889B2 (en) | 2004-01-28 | 2005-11-08 | Engelhard Corporation | Spherical catalyst for olefin polymerization |
| US7135531B2 (en) | 2004-01-28 | 2006-11-14 | Basf Catalysts Llc | Spherical catalyst for olefin polymerization |
| EP1598379A1 (en) * | 2004-05-18 | 2005-11-23 | Borealis Technology OY | Process for producing polypropylene film |
| EP1598377A1 (en) * | 2004-05-21 | 2005-11-23 | Borealis Polymers Oy | Process for producing heterophasic alpha-olefin polymers |
| ES2309445T3 (es) | 2004-12-17 | 2008-12-16 | Borealis Technology Oy | Proceso para la polimerizacion de olefinas en presencia de un catalizador de polimerizacion de las mismas. |
| ATE514485T1 (de) | 2004-12-31 | 2011-07-15 | Borealis Tech Oy | Verfahren zur herstellung eines festen olefinpolymerisationskatalysators |
| ATE407970T1 (de) | 2005-01-14 | 2008-09-15 | Borealis Polymers Oy | Heterophasische polymerzusammensetzung und verfahren zu ihrer herstellung |
| EP1717269A1 (en) | 2005-04-28 | 2006-11-02 | Borealis Technology Oy | Alpha-olefin homo-or copolymer compositions |
| ES2588577T3 (es) | 2005-12-30 | 2016-11-03 | Borealis Technology Oy | Partículas de catalizador |
| ES2594859T3 (es) * | 2006-05-31 | 2016-12-23 | Borealis Technology Oy | Catalizador con componente de Al-alcoxilo |
| EP1862479A1 (en) | 2006-05-31 | 2007-12-05 | Borealis Technology Oy | Olefin polymerisation catalyst |
| EP1862480B1 (en) * | 2006-05-31 | 2016-07-27 | Borealis Technology Oy | Process for preparing an olefin polymerisation catalyst component with improved high temperature activity |
| DE602006004987D1 (de) | 2006-07-10 | 2009-03-12 | Borealis Tech Oy | Elektrischer Isolierfilm |
| EP1886806B1 (en) | 2006-07-10 | 2010-11-10 | Borealis Technology Oy | Biaxially oriented polypropylene film |
| US20080051535A1 (en) * | 2006-08-23 | 2008-02-28 | Fina Technology, Inc. | Promoter system for polymerization processes and polymers formed therefrom |
| EP1900764B1 (en) | 2006-08-25 | 2009-04-01 | Borealis Technology Oy | Polypropylene foam |
| EP1892264A1 (en) | 2006-08-25 | 2008-02-27 | Borealis Technology Oy | Extrusion coated substrate |
| EP1903579B1 (en) | 2006-09-25 | 2010-03-24 | Borealis Technology Oy | Coaxial cable |
| EP1939227B1 (en) * | 2006-12-28 | 2013-10-30 | Borealis Technology Oy | Catalyst preparation with phosphorous compound |
| ATE424424T1 (de) | 2006-12-28 | 2009-03-15 | Borealis Tech Oy | Verfahren zur herstellung von verzweigtem polypropylen |
| EP2014714A1 (en) | 2007-07-11 | 2009-01-14 | Borealis Technology Oy | Heterophasic polyolefin composition |
| EP2030996A1 (en) | 2007-08-31 | 2009-03-04 | Borealis Technology Oy | Polyolefin compositions having improved optical and mechanical properties |
| ATE528324T1 (de) * | 2007-11-30 | 2011-10-15 | Borealis Tech Oy | Katalysator mit niedriger oberfläche |
| PL2065087T3 (pl) * | 2007-11-30 | 2012-06-29 | Borealis Tech Oy | Sposób wytwarzania statystycznych kopolimerów propylenu |
| ES2377204T3 (es) | 2007-11-30 | 2012-03-23 | Borealis Technology Oy | Proceso para la fabricación de copolímero de propileno heterofásico |
| US7638585B2 (en) | 2008-05-13 | 2009-12-29 | Basf Catalysts, Llc | Catalyst flow |
| US8003559B2 (en) | 2008-05-13 | 2011-08-23 | Basf Corporation | Internal donor for olefin polymerization catalysts |
| ES2393382T3 (es) | 2008-06-26 | 2012-12-20 | Borealis Ag | Preparación de catalizador usando H2 |
| EP2147939A1 (en) | 2008-07-22 | 2010-01-27 | Borealis AG | Polypropylene composition with improved optics for film and moulding applications |
| US8003558B2 (en) | 2008-07-29 | 2011-08-23 | Basf Corporation | Internal donor for olefin polymerization catalysts |
| EP2174965B1 (en) | 2008-10-08 | 2013-05-29 | Borealis AG | Preparation of propylene copolymer with dynamically operated reactor |
| ATE535554T1 (de) | 2008-10-08 | 2011-12-15 | Borealis Ag | Verfahren zur herstellung von sehr steifem polyproylen |
| CN102264827B (zh) | 2008-12-29 | 2013-11-27 | 北欧化工公司 | 抗应力致白性得以改进的改性柔性聚丙烯电缆层 |
| EP2216347A1 (en) | 2009-01-30 | 2010-08-11 | Borealis AG | A method of catalyst transitions in olefin polymerizations |
| ATE529450T1 (de) | 2009-02-25 | 2011-11-15 | Borealis Ag | Multimodales polymer aus propylen, zusammensetzung damit und verfahren zur herstellung davon |
| EP2226327A1 (en) | 2009-03-02 | 2010-09-08 | Borealis AG | Preparation of an olefin polymerization catalyst component |
| CN102365325B (zh) | 2009-04-09 | 2015-04-22 | 北欧化工公司 | 热塑性聚烯烃组合物 |
| EP2251361B1 (en) * | 2009-05-04 | 2013-10-02 | Borealis AG | Preparation of precipitated ZN PP catalysts with internal pore structure using nanoparticles |
| US9587043B2 (en) | 2009-11-11 | 2017-03-07 | Borealis Ag | Polymer composition and a power cable comprising the polymer composition |
| JP5739442B2 (ja) | 2009-11-11 | 2015-06-24 | ボレアリス エージー | ケーブルおよびその製造法 |
| CN102666602B (zh) | 2009-11-11 | 2015-11-25 | 博瑞立斯有限公司 | 具有有利的电性能的可交联的聚合物组合物和电缆 |
| WO2011057926A1 (en) | 2009-11-11 | 2011-05-19 | Borealis Ag | A polymer composition comprising a polyolefin produced in a high pressure process, a high pressure process and an article |
| EP2330135B1 (en) | 2009-12-02 | 2012-11-07 | Borealis AG | Process for producing polyolefins |
| KR102094653B1 (ko) | 2010-03-17 | 2020-03-30 | 보레알리스 아게 | 유리한 전기적 특성을 갖는 와이어 및 케이블 용도의 중합체 조성물 |
| CA2792990C (en) | 2010-03-17 | 2019-05-14 | Borealis Ag | Polyethylene polymer composition and power cable with improved electrical properties |
| EP2399943A1 (en) | 2010-06-28 | 2011-12-28 | Borealis AG | Process for producing polyethylene |
| ES2541701T3 (es) | 2010-07-13 | 2015-07-23 | Borealis Ag | Componente de catalizador |
| EP2415790B1 (en) | 2010-07-13 | 2014-09-24 | Borealis AG | Catalyst component |
| CN102453170B (zh) * | 2010-10-19 | 2013-02-27 | 中国石油化工股份有限公司 | 烯烃聚合的催化剂组份、制备方法及应用 |
| US9068025B2 (en) | 2010-08-19 | 2015-06-30 | China Petroleum & Chemical Corporation | Catalyst component for polymerization of olefin and preparation method |
| CN102372801B (zh) * | 2010-08-19 | 2013-05-01 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组分及其制备方法 |
| CN102372803B (zh) * | 2010-08-19 | 2013-03-27 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备方法 |
| CN102372802B (zh) * | 2010-08-19 | 2013-03-27 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组分及其制备方法 |
| CN102453171B (zh) * | 2010-10-19 | 2013-07-03 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组分及其制备方法 |
| ES2397547T3 (es) | 2010-08-27 | 2013-03-07 | Borealis Ag | Composición de polipropileno rígido con excelente alargamiento de rotura |
| ES2750266T3 (es) | 2010-11-03 | 2020-03-25 | Borealis Ag | Una composición de polímero y un cable de alimentación que comprende la composición de polímero |
| US8227370B2 (en) | 2010-11-10 | 2012-07-24 | Basf Corporation | High activity catalyst component for olefin polymerization and method of using the same |
| EP2452976A1 (en) | 2010-11-12 | 2012-05-16 | Borealis AG | Heterophasic propylene copolymers with improved stiffness/impact/flowability balance |
| EP2452956A1 (en) | 2010-11-12 | 2012-05-16 | Borealis AG | Improved process for polymerising propylene |
| EP2452959B1 (en) | 2010-11-12 | 2015-01-21 | Borealis AG | Process for producing propylene random copolymers and their use |
| EP2452960B1 (en) | 2010-11-12 | 2015-01-07 | Borealis AG | Process for preparing propylene polymers with an ultra high melt flow rate |
| EP2452920A1 (en) | 2010-11-12 | 2012-05-16 | Borealis AG | A method for recovering transition metal tetrahalide and hydrocarbons from a waste stream |
| EP2452975A1 (en) | 2010-11-12 | 2012-05-16 | Borealis AG | Soft heterophasic propylene copolymers |
| EP2452957A1 (en) | 2010-11-12 | 2012-05-16 | Borealis AG | Improved process for producing heterophasic propylene copolymers |
| HUE051319T2 (hu) | 2011-03-02 | 2021-03-01 | Borealis Ag | Nagy átmenõteljesítményû reaktoregység olefinek polimerizálására |
| HUE052511T2 (hu) | 2011-03-02 | 2021-05-28 | Borealis Ag | Eljárás polimerek elõállítására |
| EP2508562B1 (en) | 2011-03-28 | 2018-06-13 | Borealis AG | Polypropylene composition for extrusion blown molded bottles |
| CN103476805B (zh) | 2011-04-18 | 2017-03-29 | 巴塞尔聚烯烃意大利有限责任公司 | 二氯化镁‑醇加合物及由其获得的催化剂组分 |
| US8685879B2 (en) * | 2011-04-29 | 2014-04-01 | Basf Corporation | Emulsion process for improved large spherical polypropylene catalysts |
| RU2613330C2 (ru) | 2011-05-04 | 2017-03-16 | Бореалис Аг | Полимерная композиция для электротехнических устройств |
| US9978478B2 (en) | 2011-05-04 | 2018-05-22 | Borealis Ag | Polymer composition for electrical devices |
| CA2834812A1 (en) | 2011-05-04 | 2012-11-08 | Borealis Ag | Polymer composition for electrical devices |
| EP2521137B1 (en) | 2011-05-04 | 2014-12-17 | Borealis AG | Polymer composition for electrical and communication devices |
| ES2462165T3 (es) | 2011-05-23 | 2014-05-22 | Borealis Ag | Copolímero aleatorio de propileno con alta rigidez y baja turbidez |
| EP2535372B1 (en) | 2011-06-15 | 2016-09-14 | Borealis AG | In-situ reactor blend of a Ziegler-Natta catalysed, nucleated polypropylene and a metallocene catalysed polypropylene |
| EP2565221B2 (en) | 2011-08-30 | 2018-08-08 | Borealis AG | Process for the manufacture of a capacitor film |
| KR101627442B1 (ko) | 2011-08-30 | 2016-06-03 | 보레알리스 아게 | 폴리프로필렌을 포함하는 전력 케이블 |
| ES2488415T3 (es) | 2011-10-28 | 2014-08-27 | Borealis Ag | Composición blanda de polipropileno de alta fluidez |
| JP5976832B2 (ja) | 2011-11-21 | 2016-08-24 | ビーエーエスエフ コーポレーション | オレフィン重合のための触媒系、固体触媒成分及び重合方法 |
| WO2013079457A1 (en) | 2011-11-29 | 2013-06-06 | Borealis Ag | Blow molding material |
| US8765626B2 (en) | 2011-11-30 | 2014-07-01 | Basf Corporation | Internal donor structure for olefin polymerization catalysts and methods of making and using same |
| EP2610273B1 (en) * | 2011-12-30 | 2018-02-07 | Borealis AG | Catalyst component |
| EP2610270B1 (en) | 2011-12-30 | 2015-10-07 | Borealis AG | Catalyst component |
| EP2610272B1 (en) | 2011-12-30 | 2017-05-10 | Borealis AG | Catalyst component |
| ES2727405T3 (es) | 2011-12-30 | 2019-10-16 | Borealis Ag | Preparación de catalizadores de ZN PP libres de ftalato |
| EP2617741B1 (en) | 2012-01-18 | 2016-01-13 | Borealis AG | Process for polymerizing olefin polymers in the presence of a catalyst system and a method of controlling the process |
| ES2796856T3 (es) | 2012-08-29 | 2020-11-30 | Borealis Ag | Conjunto de reactor y procedimiento para la polimerización de olefinas |
| KR101677737B1 (ko) | 2012-09-24 | 2016-11-18 | 인디언 오일 코퍼레이션 리미티드 | 고체의 유기금속 화합물, 이의 제조방법 및 이의 용도 |
| US9890229B2 (en) | 2012-09-24 | 2018-02-13 | Indian Oil Corporation Limited | Precursor for catalyst, process for preparing the same and its use thereof |
| EP2711073B1 (en) | 2012-09-24 | 2018-11-21 | Borealis AG | Storage and transportation of a catalyst for a production of olefin polymers |
| EP2719725B1 (en) | 2012-10-11 | 2018-12-05 | Abu Dhabi Polymers Company Limited (Borouge) | Nucleated polypropylene composition for containers |
| EP2917247B1 (en) * | 2012-11-08 | 2023-12-20 | Reliance Industries Limited | Modified ziegler natta catalyst for propylene polymerization |
| ES2615499T3 (es) | 2012-12-21 | 2017-06-07 | Borealis Ag | Procedimiento para la producción de un procatalizador de Ziegler-Natta para la polimerización de etileno |
| EP2745927A1 (en) | 2012-12-21 | 2014-06-25 | Borealis AG | Fluidized bed reactor with internal moving bed reaction unit |
| ES2653868T3 (es) | 2012-12-21 | 2018-02-09 | Borealis Ag | Procatalizador de Ziegler Natta soportado para la polimerización de etileno |
| EP2745926A1 (en) | 2012-12-21 | 2014-06-25 | Borealis AG | Gas phase polymerization and reactor assembly comprising a fluidized bed reactor and an external moving bed reactor |
| EP2749580B1 (en) | 2012-12-28 | 2016-09-14 | Borealis AG | Process for producing copolymers of propylene |
| CN104031184B (zh) * | 2013-03-06 | 2016-05-11 | 中国石油天然气股份有限公司 | 一种乙烯聚合或共聚合的固体钛催化剂及其制备和应用 |
| US8933180B2 (en) | 2013-03-14 | 2015-01-13 | Basf Corporation | Internal and external donor compounds for olefin polymerization catalysts IV |
| US9284392B2 (en) | 2013-03-15 | 2016-03-15 | Basf Corporation | Mixed internal donor structures for 1-olefin polymerization catalysts |
| ES2632593T3 (es) | 2013-04-22 | 2017-09-14 | Borealis Ag | Procedimiento de dos fases de producción de composiciones de polipropileno |
| ES2628082T3 (es) | 2013-04-22 | 2017-08-01 | Borealis Ag | Procedimiento con múltiples etapas para producir composiciones de polipropileno resistentes a baja temperatura |
| EP3235832B1 (en) | 2013-04-22 | 2018-06-20 | Borealis AG | Polypropylene compositions |
| ES2646195T3 (es) | 2013-05-29 | 2017-12-12 | Abu Dhabi Polymers Co. Ltd (Borouge) Llc. | Polipropileno bimodal para películas hechas por colada o una película metalizada en donde el polipropileno comprende dos fracciones que difieren en el contenido de comonómeros |
| CN104277145B (zh) * | 2013-07-01 | 2016-05-25 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组份、其制备方法及应用 |
| CN105636967B (zh) | 2013-08-12 | 2018-09-28 | 沙特基础工业公司 | 用于烯烃聚合的催化剂体系 |
| CN105452364B (zh) | 2013-08-14 | 2018-05-11 | 博里利斯股份公司 | 低温下具有改进的耐冲击性的丙烯组合物 |
| CA2919171A1 (en) | 2013-08-21 | 2015-02-26 | Borealis Ag | High flow polyolefin composition with high stiffness and toughness |
| US9777142B2 (en) | 2013-08-21 | 2017-10-03 | Borealis Ag | High flow polyolefin composition with high stiffness and toughness |
| PT2853563T (pt) | 2013-09-27 | 2016-07-14 | Borealis Ag | Filmes adequados para processamento de bopp a partir de polímeros com xs elevada e tm elevado |
| EP2853562A1 (en) | 2013-09-27 | 2015-04-01 | Borealis AG | Two-stage process for producing polypropylene compositions |
| ES2568615T3 (es) | 2013-10-11 | 2016-05-03 | Borealis Ag | Película para etiquetas orientada en la dirección de la máquina |
| ES2661108T3 (es) | 2013-10-24 | 2018-03-27 | Borealis Ag | Homopolímero de polipropileno de bajo punto de fusión con alto contenido de regioerrores y alto peso molecular |
| EP2865713B1 (en) | 2013-10-24 | 2016-04-20 | Borealis AG | Blow molded article based on bimodal random copolymer |
| CN105722869B (zh) | 2013-10-29 | 2017-09-12 | 北欧化工公司 | 具有高聚合活性的固体单点催化剂 |
| EP2868375A1 (en) | 2013-10-31 | 2015-05-06 | Borealis AG | A method for producing an olefin polymerization catalyst |
| WO2015075088A1 (en) | 2013-11-22 | 2015-05-28 | Borealis Ag | Low emission propylene homopolymer with high melt flow |
| BR112016011829B1 (pt) | 2013-12-04 | 2022-01-18 | Borealis Ag | Composição de polipropileno, fibra e trama soprada em fusão, artigo e uso da composição de polipropileno |
| WO2015091839A1 (en) | 2013-12-18 | 2015-06-25 | Borealis Ag | Bopp film with improved stiffness/toughness balance |
| CN105940022B (zh) | 2013-12-20 | 2018-07-31 | 沙特基础工业公司 | 用于烯烃聚合的催化剂体系 |
| WO2015091940A1 (en) | 2013-12-20 | 2015-06-25 | Saudi Basic Industries Corporation | Catalyst system for polymerisation of an olefin |
| WO2015091983A1 (en) | 2013-12-20 | 2015-06-25 | Saudi Basic Industries Corporation | Catalyst system for polymerization of an olefin |
| EP3083822B1 (en) | 2013-12-20 | 2021-09-08 | Saudi Basic Industries Corporation | Heterophasic propylene copolymer |
| EP3083717B1 (en) | 2013-12-20 | 2019-08-28 | Saudi Basic Industries Corporation | Catalyst system for polymerization of an olefin |
| EP3083722B1 (en) | 2013-12-20 | 2021-11-10 | Saudi Basic Industries Corporation | Catalyst system for polymerisation of an olefin |
| WO2015091151A1 (en) | 2013-12-20 | 2015-06-25 | Saudi Basic Industries Corporation | Polyolefin composition |
| EP3083723B1 (en) | 2013-12-20 | 2022-01-19 | Saudi Basic Industries Corporation | Catalyst system for polymerisation of an olefin |
| CN105829438A (zh) | 2013-12-31 | 2016-08-03 | 博里利斯股份公司 | 制备丙烯三聚物的方法 |
| WO2015107020A1 (en) | 2014-01-17 | 2015-07-23 | Borealis Ag | Process for preparing propylene/1-butene copolymers |
| ES2767498T3 (es) | 2014-02-06 | 2020-06-17 | Borealis Ag | Copolímeros de impacto transparentes y suaves |
| US10100185B2 (en) | 2014-02-06 | 2018-10-16 | Borealis Ag | Soft copolymers with high impact strength |
| EP2907841A1 (en) | 2014-02-14 | 2015-08-19 | Borealis AG | Polypropylene composite |
| TWI554402B (zh) | 2014-05-12 | 2016-10-21 | 柏列利斯股份公司 | 用於層元件之聚丙烯組成物 |
| ES2659731T3 (es) | 2014-05-20 | 2018-03-19 | Borealis Ag | Composición de polipropileno para aplicaciones en interiores de automóviles |
| US10160816B2 (en) | 2014-06-02 | 2018-12-25 | Sabic Global Technologies B.V. | Procatalyst for polymerization of olefins |
| WO2015185489A1 (en) | 2014-06-02 | 2015-12-10 | Sabic Global Technologies B.V. | Procatalyst for polymerization of olefins |
| ES2929284T3 (es) | 2014-06-27 | 2022-11-28 | Borealis Ag | Proceso mejorado para preparar un componente catalizador de polimerización de olefinas en partículas |
| EP2960256B1 (en) | 2014-06-27 | 2018-04-25 | Borealis AG | Catalyst component for the preparation of nucleated polyolefins |
| EP2966099B1 (en) | 2014-07-08 | 2020-03-11 | Indian Oil Corporation Limited | Particle size distribution control through internal donor in ziegler-natta catalyst |
| US9663595B2 (en) | 2014-08-05 | 2017-05-30 | W. R. Grace & Co. —Conn. | Solid catalyst components for olefin polymerization and methods of making and using the same |
| US9738736B2 (en) | 2014-08-12 | 2017-08-22 | W. R. Grace & Co.-Conn | Combined internal donor system for Ziegler-Natta polyolefin catalysts and methods of making and using same |
| EP2995631A1 (en) | 2014-09-12 | 2016-03-16 | Borealis AG | Process for producing graft copolymers on polyolefin backbone |
| US9714302B2 (en) | 2014-10-10 | 2017-07-25 | W. R. Grace & Co.—Conn. | Process for preparing spherical polymerization catalyst components for use in olefin polymerizations |
| EP3212710B2 (en) | 2014-10-27 | 2023-12-27 | Borealis AG | Polymer composition for cable applications with advantageous electrical properties |
| EP3018156B1 (en) | 2014-11-05 | 2023-03-22 | Borealis AG | Branched polypropylene for foam applications |
| EP3023450B1 (en) | 2014-11-21 | 2017-07-19 | Borealis AG | Process for producing pellets of soft copolymers |
| ES2790649T3 (es) | 2014-12-08 | 2020-10-28 | Borealis Ag | Procedimiento para producir gránulos de copolímeros de propileno |
| EP3040364B1 (en) | 2014-12-30 | 2017-06-14 | Abu Dhabi Polymers Company Limited (Borouge) L.L.C. | Polypropylene compound with improved optical property and gel level |
| US9637575B2 (en) | 2014-12-31 | 2017-05-02 | W. R. Grace & Co. -Conn. | Catalyst system, olefin polymerization catalyst components comprising at least an internal electron donor compound, and methods of making and using the same |
| BR112017026534B1 (pt) | 2015-06-12 | 2021-12-07 | Sabic Global Technologies B.V. | Copolímero de propileno heterofásico, seu processo para a fabricação e uso, artigo que o compreende |
| WO2017001479A1 (en) | 2015-06-30 | 2017-01-05 | Borealis Ag | Process for preparing propylene polymer compositions |
| US10851191B2 (en) | 2015-06-30 | 2020-12-01 | Borealis Ag | Process for preparing propylene polymer compositions |
| ES2961331T3 (es) | 2015-07-16 | 2024-03-11 | Borealis Ag | Componente catalítico |
| EP3124567A1 (en) | 2015-07-30 | 2017-02-01 | Borealis AG | Polypropylene based hot-melt adhesive composition |
| CA2993466C (en) | 2015-07-30 | 2018-07-24 | Borealis Ag | Polypropylene composition with improved hot-tack force |
| US10696756B2 (en) | 2015-08-07 | 2020-06-30 | Sabic Global Technologies B.V. | Process for the polymerization of olefins |
| WO2017025330A1 (en) | 2015-08-07 | 2017-02-16 | Sabic Global Technologies B.V. | Process for the polymerization of olefins |
| EP3331923B1 (en) | 2015-08-07 | 2021-02-17 | SABIC Global Technologies B.V. | Process for the polymerization of olefins |
| US10611864B2 (en) | 2015-09-22 | 2020-04-07 | Sabic Global Technologies B.V. | Synthesis of substituted amidobenzoate compounds, the compounds obtained and the use thereof as phthalate free internal electron donor for polymerization of olefins |
| EP3147324B1 (en) | 2015-09-28 | 2018-09-26 | Borealis AG | Polypropylene pipes with improved pressure resistance |
| BR112018006475B1 (pt) | 2015-10-21 | 2022-03-15 | Borealis Ag | Composição de polipropileno ramificado de cadeia longa, processos para produzir uma composição de polipropileno ramificado de cadeia longa, para produzir um artigo e uma espuma, artigo, espuma ou um artigo espumado, e, uso de uma composição de polipropileno ramificado de cadeia longa |
| AU2016345511B2 (en) | 2015-10-28 | 2019-07-11 | Borealis Ag | Polypropylene composition for a layer element |
| EP3178853B1 (en) | 2015-12-07 | 2018-07-25 | Borealis AG | Process for polymerising alpha-olefin monomers |
| EP3181625A1 (en) | 2015-12-18 | 2017-06-21 | SABIC Global Technologies B.V. | Composition comprising heterophasic propylene copolymer |
| EP3187512A1 (en) | 2015-12-31 | 2017-07-05 | Borealis AG | Process for preparing propylene copolymer compositions |
| WO2017157484A1 (en) | 2016-03-14 | 2017-09-21 | Borealis Ag | Polypropylene composition comprising flame retardant |
| EP3243622B1 (en) | 2016-05-13 | 2020-09-09 | Borealis AG | Process for hydraulic conveying of polyolefin pellets |
| WO2018011165A1 (en) | 2016-07-12 | 2018-01-18 | Borealis Ag | Solid catalyst for the preparation of nucleated polyolefins |
| EP3281973A1 (en) | 2016-08-11 | 2018-02-14 | Borealis AG | Polypropylene composition with flame retardant activity |
| US11384166B2 (en) | 2016-09-08 | 2022-07-12 | Sabic Global Technologies B.V. | Process of preparing polyolefin with the discontinuous addition of a thermal runaway reducing agent |
| WO2018046395A1 (en) | 2016-09-08 | 2018-03-15 | Sabic Global Technologies B.V. | Process of preparing polyolefin with the discontinuous addition of a thermal runaway reducing agent |
| EA038511B9 (ru) | 2016-09-29 | 2021-10-01 | Сабик Глоубл Текнолоджиз Б.В. | Прокатализатор для полимеризации олефинов |
| WO2018060406A1 (en) | 2016-09-29 | 2018-04-05 | Sabic Global Technologies B.V. | Procatalyst for polymerization of olefins |
| MX2019003759A (es) | 2016-11-09 | 2019-07-04 | Borealis Ag | Composicion de polipropileno. |
| CN110198963B (zh) | 2016-12-12 | 2022-06-24 | Sabic环球技术有限责任公司 | 制造低排放异相聚丙烯的方法 |
| WO2018108928A1 (en) | 2016-12-12 | 2018-06-21 | Sabic Global Technologies B.V. | Heterophasic propylene copolymer |
| EP3551695B1 (en) | 2016-12-12 | 2023-09-06 | SABIC Global Technologies B.V. | Pellet comprising thermoplastic polymer sheath surrounding glass filaments having reduced emissions |
| CN110248968B (zh) | 2016-12-12 | 2022-05-27 | Sabic环球技术有限责任公司 | 制造低排放均聚物或无规聚丙烯的方法 |
| EP3333222A1 (en) | 2016-12-12 | 2018-06-13 | SABIC Global Technologies B.V. | Composition comprising heterophasic propylene copolymer |
| WO2018141672A1 (en) | 2017-02-01 | 2018-08-09 | Borealis Ag | Article comprising a layer element |
| US11186653B2 (en) | 2017-03-17 | 2021-11-30 | Sabic Global Technologies B.V. | Process of making polyolefins |
| EP3395377A1 (en) | 2017-04-28 | 2018-10-31 | Borealis AG | Soft polypropylene composition with improved properties |
| EP3625055B1 (en) | 2017-05-19 | 2023-10-25 | Abu Dhabi Polymers Co. Ltd (Borouge) Llc. | Propylene random copolymer composition with reduced sealing initiation temperature |
| RU2734641C1 (ru) | 2017-07-14 | 2020-10-21 | Бореалис Аг | Полипропиленовая композиция |
| EP3447088B1 (en) | 2017-08-21 | 2019-11-13 | Borealis AG | Polypropylene composition |
| PT3456776T (pt) | 2017-09-13 | 2020-03-09 | Borealis Ag | Composição de polipropileno |
| KR20200030609A (ko) | 2017-09-20 | 2020-03-20 | 보레알리스 아게 | 폴리프로필렌 조성물 |
| DK3473674T3 (da) | 2017-10-19 | 2022-06-20 | Abu Dhabi Polymers Co Ltd Borouge Llc | Polypropylensammensætning |
| EP3700943A1 (en) | 2017-10-24 | 2020-09-02 | Borealis AG | Catalysts |
| WO2019122016A1 (en) | 2017-12-21 | 2019-06-27 | Borealis Ag | Process for the preparation of solid catalyst |
| JP7249349B2 (ja) | 2017-12-27 | 2023-03-30 | ボレアリス エージー | チーグラー・ナッタ触媒及びその調製 |
| EP3732209A1 (en) | 2017-12-28 | 2020-11-04 | Borealis AG | Catalyst and preparation thereof |
| KR20200083636A (ko) | 2018-01-05 | 2020-07-08 | 보레알리스 아게 | 개선된 밀봉 거동을 갖는 폴리프로필렌 조성물 |
| CN108247055B (zh) | 2018-02-12 | 2019-01-29 | 成都优材科技有限公司 | 牙科附着体的数字化一体化成型方法 |
| PT3553096T (pt) | 2018-04-10 | 2020-06-05 | Borealis Ag | Composição de polipropileno |
| CN111868115A (zh) | 2018-04-10 | 2020-10-30 | 北欧化工公司 | 聚丙烯组合物 |
| US20210171749A1 (en) | 2018-05-18 | 2021-06-10 | Abu Dhabi Polymers Co. Ltd (Borouge) Llc. | Improving rheological properties of thermoplastic polyolefin compositions |
| EP3804119A2 (en) | 2018-05-28 | 2021-04-14 | Borealis AG | Devices for a photovoltaic (pv) module |
| EP3608364A1 (en) | 2018-08-06 | 2020-02-12 | Borealis AG | Multimodal propylene random copolymer based composition suitable as hot melt adhesive composition |
| US20210277290A1 (en) | 2018-08-06 | 2021-09-09 | Borealis Ag | Propylene random copolymer based hot melt adhesive composition |
| EP3620486B1 (en) | 2018-09-06 | 2020-11-18 | Borealis AG | Polypropylene based composition with improved paintability |
| EP3856794A1 (en) | 2018-09-28 | 2021-08-04 | Borealis AG | A multi-stage process for producing a c2 to c8 olefin polymer composition |
| US12258465B2 (en) | 2018-10-31 | 2025-03-25 | Borealis Ag | Polyethylene composition for high pressure resistant pipes with improved homogeneity |
| EP3647645A1 (en) | 2018-10-31 | 2020-05-06 | Borealis AG | Polyethylene composition for high pressure resistant pipes |
| US20210403691A1 (en) | 2018-11-19 | 2021-12-30 | Sabic Global Technologies B.V. | Food packaging comprising a polymer composition and use of said polymer composition for manufacturing of food packaging |
| ES2986685T3 (es) | 2018-11-30 | 2024-11-12 | Borealis Ag | Proceso de lavado |
| WO2020127859A1 (en) | 2018-12-21 | 2020-06-25 | Borealis Ag | Catalyst and preparation thereof |
| EP3670547B1 (en) | 2018-12-21 | 2023-06-07 | Borealis AG | Polypropylene composition for film sealing layer |
| JP7283203B2 (ja) | 2019-04-25 | 2023-05-30 | 住友化学株式会社 | プロピレン重合体の製造方法 |
| CN110283261B (zh) * | 2019-06-28 | 2021-08-03 | 上海化工研究院有限公司 | 一种烯烃聚合催化剂的主体组分及其制备方法 |
| WO2021004728A1 (en) | 2019-07-05 | 2021-01-14 | Borealis Ag | Soft propylene copolymer composition |
| ES2975494T3 (es) | 2019-07-05 | 2024-07-08 | Borealis Ag | Composición de copolímero de propileno blando |
| EP4021975B1 (en) | 2019-08-27 | 2024-04-10 | SABIC Global Technologies, B.V. | Heterophasic propylene copolymer composition |
| EP4025642A1 (en) | 2019-09-06 | 2022-07-13 | SABIC Global Technologies B.V. | Healthcare article comprising a random propylene-ethylene copolymer |
| EP4103648A1 (en) | 2020-02-14 | 2022-12-21 | SABIC Global Technologies B.V. | Film comprising heterophasic propylene copolymer composition |
| EP3650495A3 (en) | 2020-02-14 | 2020-05-27 | SABIC Global Technologies B.V. | Film comprising heterophasic propylene copolymer composition |
| EP3650494A3 (en) | 2020-02-14 | 2020-05-27 | SABIC Global Technologies B.V. | Matte film comprising heterophasic propylene copolymer composition |
| EP3875503B1 (en) | 2020-03-02 | 2025-10-08 | Borealis GmbH | Catalyst and preparation thereof |
| KR20220158252A (ko) | 2020-03-27 | 2022-11-30 | 사빅 글로벌 테크놀러지스 비.브이. | 저온에서 개선된 충격 강도를 갖는 폴리머 조성물 |
| JP7539785B2 (ja) | 2020-03-31 | 2024-08-26 | 住友化学株式会社 | オレフィン重合用固体触媒成分 |
| EP3912810B1 (en) | 2020-05-18 | 2022-08-10 | Borealis AG | Polypropylene composition |
| MY208978A (en) | 2020-05-25 | 2025-06-14 | Borealis Ag | Layer element suitable as integrated backsheet for a bifacial photovoltaic module |
| EP3915782B1 (en) | 2020-05-25 | 2024-07-17 | Borealis AG | Layer element suitable as integrated backsheet element of a photovoltaic module |
| MX2023006101A (es) | 2020-11-27 | 2023-06-06 | Borealis Ag | Sistema de alimentacion de catalizador. |
| WO2022122444A1 (en) | 2020-12-11 | 2022-06-16 | Borealis Ag | Semiconductive polypropylene composition |
| EP4314152B1 (en) | 2021-03-25 | 2025-03-19 | Borealis AG | Polypropylene composition for cable insulation |
| CN117043256A (zh) | 2021-03-25 | 2023-11-10 | 北欧化工公司 | 用于电缆绝缘材料的聚丙烯组合物 |
| EP4144435A1 (en) | 2021-09-01 | 2023-03-08 | Borealis AG | Gas phase polymerization process with improved gas recycling |
| EP4155324A3 (en) | 2021-09-22 | 2023-05-03 | Sumitomo Chemical Company, Limited | Method for producing solid catalyst component for olefin polymerization, method for producing catalyst for olefin polymerization, and method for producing olefin polymer |
| WO2023062108A1 (en) | 2021-10-14 | 2023-04-20 | Borealis Ag | Process for forming a ziegler-natta catalyst component |
| US20250101152A1 (en) | 2021-12-09 | 2025-03-27 | Sabic Global Technologies B.V. | Catalyst system for polymerization of an olefin |
| EP4453090A1 (en) | 2021-12-21 | 2024-10-30 | SABIC Global Technologies B.V. | High impact polypropylene composition |
| JP2023103559A (ja) | 2022-01-14 | 2023-07-27 | 住友化学株式会社 | ヘテロファジックプロピレン重合材料およびオレフィン重合体 |
| CN118871526A (zh) | 2022-03-14 | 2024-10-29 | Sabic环球技术有限责任公司 | 注塑成型方法 |
| US20250179281A1 (en) | 2022-03-14 | 2025-06-05 | Sabic Global Technologies B.V. | Heterophasic propylene copolymer composition |
| CN119183458A (zh) | 2022-05-13 | 2024-12-24 | Sabic环球技术有限责任公司 | 具有低的己烷提取物的多相聚丙烯组合物 |
| EP4522666A1 (en) | 2022-05-13 | 2025-03-19 | SABIC Global Technologies B.V. | Heterophasic polypropylene composition with low shrinkage |
| WO2023217945A1 (en) | 2022-05-13 | 2023-11-16 | Sabic Global Technologies B.V. | Heterophasic polypropylene composition with low emission |
| US20250382394A1 (en) | 2022-07-05 | 2025-12-18 | Sabic Global Technologies B.V. | Catalyst system for polymerization of an olefin |
| WO2024068578A1 (en) | 2022-09-28 | 2024-04-04 | Borealis Ag | Polypropylene composition for cable insulation |
| KR20250068767A (ko) | 2022-09-28 | 2025-05-16 | 보레알리스 아게 | 케이블 절연재용 폴리프로필렌 조성물 |
| KR20250073329A (ko) | 2022-09-28 | 2025-05-27 | 보레알리스 아게 | 케이블 절연재용 폴리프로필렌 조성물 |
| US20250263545A1 (en) | 2022-09-28 | 2025-08-21 | Borealis Ag | Polypropylene composition for cable insulation |
| CN119948098A (zh) | 2022-09-28 | 2025-05-06 | 博里利斯股份公司 | 用于电缆绝缘的聚丙烯组合物 |
| EP4389783A1 (en) | 2022-12-20 | 2024-06-26 | Borealis AG | Catalyst transition process |
| EP4389776A1 (en) | 2022-12-20 | 2024-06-26 | Borealis AG | Process |
| JP2024119514A (ja) | 2023-02-22 | 2024-09-03 | 住友化学株式会社 | 酸化防止剤混合液の保管方法 |
| EP4421149A3 (en) | 2023-02-22 | 2024-11-06 | Sumitomo Chemical Company, Limited | Method of storing antioxidant mixture |
| US20240301100A1 (en) | 2023-02-22 | 2024-09-12 | Sumitomo Chemical Company, Limited | Method for producing heterophasic propylene polymerization material and method for producing olefin polymer |
| WO2024223777A1 (en) | 2023-04-26 | 2024-10-31 | Borealis Ag | Layer element suitable as integrated backsheet for a bifacial photovoltaic module |
| WO2024223775A1 (en) | 2023-04-26 | 2024-10-31 | Borealis Ag | Layer element suitable as integrated backsheet for a bifacial photovoltaic module |
| WO2024240540A1 (en) | 2023-05-23 | 2024-11-28 | Borealis Ag | Process for producing pellets of polyolefins, and pellets so produced |
| EP4477679A1 (en) | 2023-06-13 | 2024-12-18 | Borealis AG | Prepolymerised ziegler-natta catalysts |
| US20250109218A1 (en) | 2023-09-29 | 2025-04-03 | Formosa Plastics Corporation, U.S.A. | Method for preparing catalyst component for polymerization of polyolefin without the use of internal electron donors |
| WO2025068333A1 (en) | 2023-09-28 | 2025-04-03 | Borealis Ag | Semiconductive polypropylene composition |
| US20250115687A1 (en) | 2023-10-06 | 2025-04-10 | Formosa Plastics Corporation, U.S.A. | Production method for solid catalyst component for polymerizing olefins, and catalyst for polymerizaing olefins |
| WO2025125458A1 (en) | 2023-12-12 | 2025-06-19 | Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. | Modified polyethylene having improved hydrostatic pressure resistance and slow crack growth resistance |
| EP4644436A1 (en) | 2024-05-03 | 2025-11-05 | Borealis GmbH | Heterophasic propylene-ethylene copolymer having excellent stiffness-impact strength balance, optical properties and stress whitening performance |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2534698A (en) * | 1944-11-29 | 1950-12-19 | Standard Oil Dev Co | Polymerization of olefins in fluorinated diluent |
| YU35844B (en) * | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
| JPS6037804B2 (ja) * | 1979-04-11 | 1985-08-28 | 三井化学株式会社 | オレフイン重合触媒用担体の製法 |
| JPS58127706A (ja) * | 1982-01-23 | 1983-07-29 | Mitsubishi Petrochem Co Ltd | オレフイン重合用触媒担体 |
| US4399055A (en) * | 1981-05-01 | 1983-08-16 | Mitsubishi Petrochemical Company Limited | Carrier of catalyst and catalyst component composed of the carrier, for polymerization of olefins, as well as processes for production thereof |
| IT1169291B (it) * | 1981-12-24 | 1987-05-27 | Montedison Spa | Componenti di catalizzatori per la polimerizzazione dell'etilene e sue miscele con olefine ed i soui catalizzatori da essi ottenuti |
| IT1169292B (it) | 1981-12-24 | 1987-05-27 | Montedison Spa | Componenti di catalizzatori per la polimerizzazione delle alfa olefine e i catalizzatori da essi ottenuti |
| IT1151627B (it) * | 1982-06-10 | 1986-12-24 | Anic Spa | Procedimento per la preparazione di copolimeri dell'etilene con basso valore delle densita' |
| EP0258089B1 (en) | 1986-07-31 | 1990-10-24 | Montedison S.p.A. | Process for preparing solid components of catalysts, or precursors of such components, in the form of microspheroidal particles, suitable for the preparation of ethylene polymers |
| IT1213474B (it) * | 1986-07-31 | 1989-12-20 | Montedison Spa | Procedimento per preparare componenti solidi di catalizzatori, o precursori di tali componenti, in forma di particellmicrosferoidali per la polimerizzazione delle alfa-olefine. |
| DE3765351D1 (de) * | 1986-07-31 | 1990-11-08 | Montedison Spa | Verfahren zur polymerisierung von alpha-olefinen oder ihrer mischungen mit aethylen unter anwendung eines mikrosphaeroidalen, teilchenfoermigen, festen katalysatorbestandteils oder eines deren vorlaeufer enthaltenden katalysators. |
| IT1203330B (it) * | 1987-02-06 | 1989-02-15 | Enichem Base Spa | Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine |
| US4741453A (en) * | 1987-06-22 | 1988-05-03 | International Precision Components Corporation | Container and closure with fastening means |
| FR2654431B1 (fr) * | 1989-11-16 | 1993-07-23 | Atochem | Support de catalyseur pour la polymerisation des olefines - procede de fabrication du support et catalyseur obtenu a partir de ce support. |
| FR2658498B1 (fr) * | 1990-02-19 | 1992-05-15 | Atochem | Particules de chlorure de magnesium a structure tronc conique, composante catalytique supportee sur ces particules, polyolefines obtenues a partir de cette composante catalytique, procedes de fabrication de ces produits. |
| US5094735A (en) | 1990-06-14 | 1992-03-10 | The Mitchell-Bate Company | Plating workstation support |
| IT1251785B (it) * | 1991-07-12 | 1995-05-26 | Enichem Polimeri | Procedimento per la preparazione di un componente solido di catalizzatore per la (co)polimerizzazione di etilene |
| DZ1626A1 (fr) * | 1991-10-09 | 2002-02-17 | Enichem Polimeri | Catalyseurs pour la polymérisation d'oléfines. |
| IT1262934B (it) | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| FI942949A0 (fi) | 1994-06-20 | 1994-06-20 | Borealis Polymers Oy | Prokatalysator foer producering av etenpolymerer och foerfarande foer framstaellning daerav |
| JP3471099B2 (ja) | 1994-11-25 | 2003-11-25 | 昭和電工株式会社 | オレフィン重合用触媒担体の製造方法 |
| US5955396A (en) | 1995-10-17 | 1999-09-21 | Bp Amoco Corporation | Morphology-controlled olefin polymerization catalyst formed from an emulsion |
| DE19545444A1 (de) * | 1995-12-06 | 1997-06-12 | Du Pont | Alkoxide mit Erdalkalien und Titan, Zirkon und/oder Hafnium, deren Herstellung und Verwendung |
| ES2213898T3 (es) | 1997-03-29 | 2004-09-01 | Basell Poliolefine Italia S.P.A. | Aductos de dicloruro de magnesio/alcohol, procedimiento para su preparacion y componentes catalizadores obtenidos a partir de estos. |
| US6420499B1 (en) | 1997-12-23 | 2002-07-16 | Borealis Technology Oy | Catalyst component comprising magnesium, titanium, a halogen and an election donor, its preparation and use |
| FI981717L (fi) | 1998-08-07 | 2000-02-08 | Borealis As | Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonorin, sen valmistus ja käyttö |
| FI981718A7 (fi) | 1998-08-07 | 2000-02-08 | Borealis As | Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektrodonorin, sen valmistus ja käyttö |
| GB0001914D0 (en) | 2000-01-27 | 2000-03-22 | Borealis Polymers Oy | Catalyst |
-
2001
- 2001-06-20 DE DE60120389T patent/DE60120389T2/de not_active Expired - Lifetime
- 2001-06-20 PT PT01115000T patent/PT1273595E/pt unknown
- 2001-06-20 EP EP01115000A patent/EP1273595B8/en not_active Expired - Lifetime
- 2001-06-20 AT AT01115000T patent/ATE328912T1/de not_active IP Right Cessation
- 2001-06-20 ES ES01115000T patent/ES2266053T3/es not_active Expired - Lifetime
-
2002
- 2002-06-18 US US10/481,313 patent/US7902108B2/en not_active Expired - Lifetime
- 2002-06-18 BR BRPI0210400-8A patent/BR0210400B1/pt not_active IP Right Cessation
- 2002-06-18 ES ES02760186.3T patent/ES2545763T3/es not_active Expired - Lifetime
- 2002-06-18 KR KR1020037016474A patent/KR100852432B1/ko not_active Expired - Lifetime
- 2002-06-18 EP EP02754701A patent/EP1397401A1/en not_active Withdrawn
- 2002-06-18 CN CNB02812281XA patent/CN1247625C/zh not_active Expired - Fee Related
- 2002-06-18 CA CA002447644A patent/CA2447644C/en not_active Expired - Lifetime
- 2002-06-18 WO PCT/EP2002/006720 patent/WO2003000757A1/en not_active Ceased
- 2002-06-18 AU AU2002325246A patent/AU2002325246B2/en not_active Ceased
- 2002-06-18 JP JP2003507157A patent/JP2004530765A/ja not_active Withdrawn
- 2002-06-18 BR BRPI0210403-2A patent/BR0210403B1/pt not_active IP Right Cessation
- 2002-06-18 WO PCT/EP2002/006716 patent/WO2003000755A2/en not_active Ceased
- 2002-06-18 CN CNB028125509A patent/CN1252098C/zh not_active Expired - Lifetime
- 2002-06-18 US US10/481,312 patent/US7271119B2/en not_active Expired - Fee Related
- 2002-06-18 KR KR1020037016475A patent/KR100796361B1/ko not_active Expired - Fee Related
- 2002-06-18 US US10/481,314 patent/US20040242407A1/en not_active Abandoned
- 2002-06-18 WO PCT/EP2002/006713 patent/WO2003000754A1/en not_active Ceased
- 2002-06-18 CA CA2447592A patent/CA2447592C/en not_active Expired - Fee Related
- 2002-06-18 PL PL366583A patent/PL202988B1/pl unknown
- 2002-06-18 CN CNB028124456A patent/CN1308355C/zh not_active Expired - Lifetime
- 2002-06-18 AU AU2002325838A patent/AU2002325838B2/en not_active Ceased
- 2002-06-18 HU HU0400335A patent/HUP0400335A2/hu unknown
- 2002-06-18 EP EP02760186.3A patent/EP1397395B1/en not_active Expired - Lifetime
-
2010
- 2010-02-05 JP JP2010024841A patent/JP5300757B2/ja not_active Expired - Fee Related
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2447644C (en) | Preparation of olefin polymerisation catalyst component | |
| AU2002325246A1 (en) | Preparation of olefin polymerisation catalyst component | |
| US7659223B2 (en) | Process for preparing an olefin polymerization catalyst component with improved high temperature activity | |
| US7256150B2 (en) | Preparation of olefin polymerization catalyst component | |
| EP1862481B1 (en) | Catalyst with al-alkoxy component | |
| US20100056359A1 (en) | Process for preparing an olefin polymerisation catalyst component with improved high temperature activity | |
| WO2007137849A1 (en) | Olefin polymerisation catalyst | |
| US20100216957A1 (en) | Catalyst preparation with phosphorous compound | |
| US8592536B2 (en) | Catalyst preparation using H2 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKEX | Expiry |
Effective date: 20220620 |