BRPI0912920B1 - Processo de polimerização e copolímero de impacto de propileno - Google Patents
Processo de polimerização e copolímero de impacto de propileno Download PDFInfo
- Publication number
- BRPI0912920B1 BRPI0912920B1 BRPI0912920-0A BRPI0912920A BRPI0912920B1 BR PI0912920 B1 BRPI0912920 B1 BR PI0912920B1 BR PI0912920 A BRPI0912920 A BR PI0912920A BR PI0912920 B1 BRPI0912920 B1 BR PI0912920B1
- Authority
- BR
- Brazil
- Prior art keywords
- propylene
- polymerization
- impact copolymer
- fact
- weight
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1809—Controlling processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1872—Details of the fluidised bed reactor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2400/00—Characteristics for processes of polymerization
- C08F2400/02—Control or adjustment of polymerization parameters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethylene-propylene or ethylene-propylene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/02—Ziegler natta catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Materials Engineering (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| USPCT/US2008/007388 | 2008-08-21 | ||
| PCT/US2008/073882 WO2009029487A1 (en) | 2007-08-24 | 2008-08-21 | Self-limiting catalyst system with controlled aluminum rto sca ratio and method |
| US12/390,897 | 2009-02-23 | ||
| US12/390,897 US8067510B2 (en) | 2007-08-24 | 2009-02-23 | High melt flow propylene impact copolymer and method |
| PCT/US2009/034881 WO2010082943A1 (en) | 2008-08-21 | 2009-02-23 | High melt flow propylene impact copolymer and method |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| BRPI0912920A2 BRPI0912920A2 (pt) | 2015-10-06 |
| BRPI0912920A8 BRPI0912920A8 (pt) | 2017-09-19 |
| BRPI0912920B1 true BRPI0912920B1 (pt) | 2019-07-09 |
Family
ID=40756183
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0912920-0A BRPI0912920B1 (pt) | 2008-08-21 | 2009-02-23 | Processo de polimerização e copolímero de impacto de propileno |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US8779058B2 (https=) |
| EP (1) | EP2315790B1 (https=) |
| JP (1) | JP5474069B2 (https=) |
| KR (2) | KR101686253B1 (https=) |
| CN (1) | CN102203140B (https=) |
| BR (1) | BRPI0912920B1 (https=) |
| ES (1) | ES2674584T3 (https=) |
| MX (1) | MX2011001972A (https=) |
| PL (1) | PL2315790T3 (https=) |
| RU (1) | RU2487897C2 (https=) |
| WO (1) | WO2010082943A1 (https=) |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101848946B (zh) | 2007-08-24 | 2013-06-12 | 陶氏环球技术有限责任公司 | 气相聚合方法 |
| US7893003B2 (en) * | 2007-08-24 | 2011-02-22 | Dow Global Technologies Inc. | Catalyst composition with mixed selectivity control agent and method |
| EP2315790B1 (en) * | 2008-08-21 | 2018-04-25 | W.R. Grace & CO. - CONN. | High melt flow propylene impact copolymer and method |
| PL2373702T3 (pl) | 2008-12-31 | 2018-07-31 | W.R. Grace & Co.-Conn. | Kompozycja prekatalizatora z wewnętrznym donorem w postaci podstawionego aromatycznego diestru 1,2-fenylenowego oraz sposób |
| JP5731988B2 (ja) * | 2008-12-31 | 2015-06-10 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | プロピレン系ポリマー、物品およびその製造プロセス |
| EP2516489B1 (en) * | 2009-12-21 | 2014-07-02 | W.R. Grace & CO. - CONN. | Gas-phase polymerization process having multiple flow regimes |
| CN102884093B (zh) * | 2010-01-22 | 2014-03-12 | 中国石油化工股份有限公司 | 一种具有高熔体强度的丙烯均聚物及其制备方法 |
| CN101845171A (zh) * | 2010-04-20 | 2010-09-29 | 广州呈和科技有限公司 | 聚丙烯增刚成核剂组合物 |
| US20120116029A1 (en) * | 2010-11-08 | 2012-05-10 | Van Egmond Jan W | Method for polymerizing polypropylene |
| MX2013007356A (es) | 2010-12-21 | 2014-01-23 | Dow Global Technologies Llc | Proceso para producir polimeros basados en propileno con alto indice de fluidez y productos preparados a partir de los mismos. |
| KR20130131406A (ko) * | 2010-12-27 | 2013-12-03 | 다우 코닝 코포레이션 | 경화성 실리케이트-실록산 혼합된 매트릭스 멤브레인 조성물 |
| KR101928316B1 (ko) * | 2011-01-19 | 2018-12-12 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 올레핀 중합용 고체 촉매 성분 및 그러한 촉매 |
| CN103403088B (zh) | 2011-03-10 | 2016-02-10 | 巴塞尔聚烯烃意大利有限责任公司 | 聚烯烃基容器 |
| EP2607384A1 (en) | 2011-12-21 | 2013-06-26 | Basell Poliolefine Italia S.r.l. | Catalyst system for the polymerization of olefins |
| DE102013221849B4 (de) * | 2012-10-30 | 2021-07-29 | Beijing Research Institute Of Chemical Industry, China Petroleum & Chemical Corporation | Verfahren zur Herstellung eines Propylenpolymers |
| US9096729B2 (en) | 2013-02-06 | 2015-08-04 | Exxonmobil Chemical Patents Inc. | Polymerization activators for supported Ziegler-Natta catalysts |
| WO2014123668A1 (en) * | 2013-02-06 | 2014-08-14 | Exxonmobil Chemical Patents Inc. | Polymerization activators for supported ziegler-natta catalysts |
| ES2651456T3 (es) | 2013-08-14 | 2018-01-26 | Borealis Ag | Composición de propileno con mejor resistencia al impacto a baja temperatura |
| MX2016001705A (es) | 2013-08-21 | 2016-05-18 | Borealis Ag | Composicion de poliolefina de alto flujo con alta rigidez y tenacidad. |
| MX2016001930A (es) | 2013-08-21 | 2016-05-26 | Borealis Ag | Composicion de poliolefina de alto flujo con alta rigidez y tenacidad. |
| PT2853563T (pt) | 2013-09-27 | 2016-07-14 | Borealis Ag | Filmes adequados para processamento de bopp a partir de polímeros com xs elevada e tm elevado |
| ES2568615T3 (es) | 2013-10-11 | 2016-05-03 | Borealis Ag | Película para etiquetas orientada en la dirección de la máquina |
| ES2661108T3 (es) | 2013-10-24 | 2018-03-27 | Borealis Ag | Homopolímero de polipropileno de bajo punto de fusión con alto contenido de regioerrores y alto peso molecular |
| EP2865713B1 (en) | 2013-10-24 | 2016-04-20 | Borealis AG | Blow molded article based on bimodal random copolymer |
| EP3063185B9 (en) | 2013-10-29 | 2017-11-15 | Borealis AG | Solid single site catalysts with high polymerisation activity |
| EP3068809B1 (en) * | 2013-11-15 | 2021-03-03 | W.R. Grace & CO. - CONN. | Propylene-based polymer with reduced high-molecular weight portion |
| RU2731442C2 (ru) * | 2013-11-21 | 2020-09-02 | У.Р. Грейс Энд Ко.-Конн | Получение полимеров на основе пропилена с высоким содержанием сомономера |
| MX366147B (es) | 2013-11-22 | 2019-06-28 | Borealis Ag | Homopolimero de propileno de baja emision. |
| MX368147B (es) * | 2013-11-22 | 2019-09-20 | Borealis Ag | Homopolímero de propileno de baja emisión con alto flujo de masa fundida. |
| PL3074429T3 (pl) * | 2013-11-26 | 2024-07-08 | W.R. Grace & Co. - Conn. | Wytwarzanie udarowych kopolimerów propylenu i wyrobów |
| CN105764936B (zh) * | 2013-11-27 | 2018-05-11 | 格雷斯公司 | 主催化剂颗粒及抗冲共聚物的聚合方法 |
| WO2015082379A1 (en) | 2013-12-04 | 2015-06-11 | Borealis Ag | Phthalate-free pp homopolymers for meltblown fibers |
| CN105980457B (zh) | 2013-12-18 | 2019-03-22 | 博里利斯股份公司 | 具有改善的刚性/韧性平衡的bopp膜 |
| US10465025B2 (en) | 2014-01-15 | 2019-11-05 | Exxonmobil Chemical Patents Inc. | Low comonomer propylene-based impact copolymers |
| CN105899599B (zh) | 2014-01-15 | 2018-10-02 | 埃克森美孚化学专利公司 | 基于丙烯的抗冲共聚物 |
| EP3094660B1 (en) | 2014-01-17 | 2018-12-19 | Borealis AG | Process for preparing propylene/1-butene copolymers |
| US10100186B2 (en) | 2014-02-06 | 2018-10-16 | Borealis Ag | Soft and transparent impact copolymers |
| WO2015117958A1 (en) | 2014-02-06 | 2015-08-13 | Borealis Ag | Soft copolymers with high impact strength |
| EP2907841A1 (en) | 2014-02-14 | 2015-08-19 | Borealis AG | Polypropylene composite |
| ES2659731T3 (es) | 2014-05-20 | 2018-03-19 | Borealis Ag | Composición de polipropileno para aplicaciones en interiores de automóviles |
| CN107406539B (zh) * | 2015-03-25 | 2020-04-07 | 巴塞尔聚烯烃股份有限公司 | 连续气相聚合方法 |
| BR112017026534B1 (pt) | 2015-06-12 | 2021-12-07 | Sabic Global Technologies B.V. | Copolímero de propileno heterofásico, seu processo para a fabricação e uso, artigo que o compreende |
| WO2018025864A1 (ja) * | 2016-08-03 | 2018-02-08 | 住友化学株式会社 | ヘテロファジックプロピレン重合材料の製造方法 |
| KR102763007B1 (ko) * | 2016-08-30 | 2025-02-04 | 더블유.알. 그레이스 앤드 컴파니 -씨오엔엔. | 저회분 함량의 폴리올레핀들 및 그 제조방법 |
| US10920053B2 (en) | 2017-10-16 | 2021-02-16 | Exxonmobil Chemical Patents Inc. | Propylene impact copolymer blends with improved gloss |
| EP3710531B1 (en) * | 2017-11-13 | 2023-05-24 | Basell Poliolefine Italia S.r.l. | Compositions obtained from recycled polyolefins |
| WO2019094216A1 (en) * | 2017-11-13 | 2019-05-16 | W.R. Grace & Co.-Conn. | Catalyst components for propylene polymerization |
| CN109776955A (zh) * | 2018-12-18 | 2019-05-21 | 东华能源(宁波)新材料有限公司 | 一种采用氢调法制备聚丙烯材料的方法 |
| WO2020170046A1 (en) * | 2019-02-19 | 2020-08-27 | Braskem S.A. | No break polypropylene impact copolymers with melt flow rate higher than 90 g/10 min |
| KR102933619B1 (ko) * | 2019-03-15 | 2026-03-03 | 더블유.알. 그레이스 앤드 캄파니-콘. | 미분이 없이 올레핀 중합체를 제조하기 위한 촉매 시스템 |
| US12187880B2 (en) | 2019-04-05 | 2025-01-07 | W.R. Grace & Co.-Conn | Polypropylene polymer composition having high stiffness properties |
| KR102605269B1 (ko) * | 2019-12-09 | 2023-11-23 | 한화솔루션 주식회사 | 기상 중합에 의한 올레핀계 중합체의 제조방법 |
| EP4127055B1 (en) * | 2020-03-30 | 2025-09-17 | Basell Poliolefine Italia S.r.l. | Propylene polymer composition |
| EP4182363A2 (en) * | 2020-07-17 | 2023-05-24 | ExxonMobil Chemical Patents Inc. | Polymers with low levels of volatile organic compounds and methods of making such polymers |
| CA3191501A1 (en) * | 2020-09-09 | 2022-03-17 | W. R. Grace & Co.-Conn. | Polypropylene polymer having ultra-high melt flow rate |
| WO2022072825A1 (en) * | 2020-10-02 | 2022-04-07 | W.R. Grace & Co.-Conn | Monomodal polypropylene random copolymer with high impact strength |
| KR20230091125A (ko) * | 2020-10-23 | 2023-06-22 | 더블유.알. 그레이스 앤드 캄파니-콘. | Voc 함량이 감소한 충격 저항성 폴리프로필렌 중합체 조성물 |
| CN112521539B (zh) * | 2020-11-02 | 2024-06-28 | 中煤陕西能源化工集团有限公司 | 通过调整粉料粒径分布提高粒料产量的方法及粒料生产系统 |
| CN113248637B (zh) * | 2021-04-20 | 2022-07-26 | 国家能源集团宁夏煤业有限责任公司 | 外给电子体化合物、烯烃聚合催化剂及其应用以及聚烯烃及其制备方法 |
| CN113214416B (zh) * | 2021-04-20 | 2022-07-26 | 国家能源集团宁夏煤业有限责任公司 | 组合外给电子体、烯烃聚合催化剂及其应用以及聚烯烃及其制备方法 |
| KR20240076546A (ko) | 2022-11-22 | 2024-05-30 | 한화토탈에너지스 주식회사 | 공중합성이 개선된 프로필렌계 공중합체의 제조방법 |
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-
2009
- 2009-02-23 EP EP09789477.8A patent/EP2315790B1/en active Active
- 2009-02-23 MX MX2011001972A patent/MX2011001972A/es active IP Right Grant
- 2009-02-23 PL PL09789477T patent/PL2315790T3/pl unknown
- 2009-02-23 KR KR1020117006269A patent/KR101686253B1/ko active Active
- 2009-02-23 RU RU2011110521/04A patent/RU2487897C2/ru active
- 2009-02-23 ES ES09789477.8T patent/ES2674584T3/es active Active
- 2009-02-23 BR BRPI0912920-0A patent/BRPI0912920B1/pt active IP Right Grant
- 2009-02-23 US US13/059,490 patent/US8779058B2/en active Active
- 2009-02-23 WO PCT/US2009/034881 patent/WO2010082943A1/en not_active Ceased
- 2009-02-23 CN CN200980141797.4A patent/CN102203140B/zh active Active
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Also Published As
| Publication number | Publication date |
|---|---|
| PL2315790T3 (pl) | 2018-08-31 |
| RU2011110521A (ru) | 2012-09-27 |
| ES2674584T3 (es) | 2018-07-02 |
| RU2487897C2 (ru) | 2013-07-20 |
| KR20110048053A (ko) | 2011-05-09 |
| WO2010082943A8 (en) | 2011-07-14 |
| CN102203140B (zh) | 2014-07-02 |
| JP5474069B2 (ja) | 2014-04-16 |
| US8779058B2 (en) | 2014-07-15 |
| US20120130018A1 (en) | 2012-05-24 |
| US8067510B2 (en) | 2011-11-29 |
| KR101686253B1 (ko) | 2016-12-13 |
| JP2012500320A (ja) | 2012-01-05 |
| WO2010082943A1 (en) | 2010-07-22 |
| KR20160017096A (ko) | 2016-02-15 |
| MX2011001972A (es) | 2011-08-12 |
| BRPI0912920A8 (pt) | 2017-09-19 |
| BRPI0912920A2 (pt) | 2015-10-06 |
| EP2315790B1 (en) | 2018-04-25 |
| EP2315790A1 (en) | 2011-05-04 |
| US20090209706A1 (en) | 2009-08-20 |
| CN102203140A (zh) | 2011-09-28 |
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