BRPI0719764A8 - Métodos para carbonizar e ativar material carbonáceo, e para preparar carbono ativado, forno ativado, processos para preparar um produto de carbono ativado, para preparar um produto particulado carbonizado, e para produzir glóbulos sólidos discretos de material polimérico, e, aparelho para formar glóbulos sólidos discretos de material polimérico - Google Patents
Métodos para carbonizar e ativar material carbonáceo, e para preparar carbono ativado, forno ativado, processos para preparar um produto de carbono ativado, para preparar um produto particulado carbonizado, e para produzir glóbulos sólidos discretos de material polimérico, e, aparelho para formar glóbulos sólidos discretos de material poliméricoInfo
- Publication number
- BRPI0719764A8 BRPI0719764A8 BRPI0719764A BRPI0719764A BRPI0719764A8 BR PI0719764 A8 BRPI0719764 A8 BR PI0719764A8 BR PI0719764 A BRPI0719764 A BR PI0719764A BR PI0719764 A BRPI0719764 A BR PI0719764A BR PI0719764 A8 BRPI0719764 A8 BR PI0719764A8
- Authority
- BR
- Brazil
- Prior art keywords
- preparing
- globules
- polymeric material
- activated carbon
- carbonizing
- Prior art date
Links
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
- F27B7/14—Rotary-drum furnaces, i.e. horizontal or slightly inclined with means for agitating or moving the charge
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
- F27B7/14—Rotary-drum furnaces, i.e. horizontal or slightly inclined with means for agitating or moving the charge
- F27B7/16—Rotary-drum furnaces, i.e. horizontal or slightly inclined with means for agitating or moving the charge the means being fixed relatively to the drum, e.g. composite means
- F27B7/167—Rotary-drum furnaces, i.e. horizontal or slightly inclined with means for agitating or moving the charge the means being fixed relatively to the drum, e.g. composite means the means comprising partitions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/30—Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/30—Active carbon
- C01B32/312—Preparation
- C01B32/318—Preparation characterised by the starting materials
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/30—Active carbon
- C01B32/312—Preparation
- C01B32/336—Preparation characterised by gaseous activating agents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/30—Active carbon
- C01B32/312—Preparation
- C01B32/342—Preparation characterised by non-gaseous activating agents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/30—Active carbon
- C01B32/39—Apparatus for the preparation thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B47/00—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
- C10B47/28—Other processes
- C10B47/30—Other processes in rotary ovens or retorts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/07—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/12—Applying additives during coking
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
- F27B7/14—Rotary-drum furnaces, i.e. horizontal or slightly inclined with means for agitating or moving the charge
- F27B7/16—Rotary-drum furnaces, i.e. horizontal or slightly inclined with means for agitating or moving the charge the means being fixed relatively to the drum, e.g. composite means
- F27B7/161—Rotary-drum furnaces, i.e. horizontal or slightly inclined with means for agitating or moving the charge the means being fixed relatively to the drum, e.g. composite means the means comprising projections jutting out from the wall
- F27B7/162—Rotary-drum furnaces, i.e. horizontal or slightly inclined with means for agitating or moving the charge the means being fixed relatively to the drum, e.g. composite means the means comprising projections jutting out from the wall the projections consisting of separate lifting elements, e.g. lifting shovels
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B9/00—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
- F27B9/30—Details, accessories, or equipment peculiar to furnaces of these types
- F27B9/36—Arrangements of heating devices
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Carbon And Carbon Compounds (AREA)
- Polymerisation Methods In General (AREA)
Abstract
MÉTODOS PARA CARBONIZAR E ATIVAR MATERIAL CARBONÁCEO, E PARA PREPARAR CARBONO ATIVADO, FORNO ROTATIVO, PROCESSOS PARA PREPARAR UM PRODUTO DE CARBONO ATIVADO, PARA PREPARAR UM PRODUTO PARTICULADO CARBONIZADO, E PARA PRODUZIR GLÓBULOS SÓLIDOS DISCRETOS DE MATERIAL POLIMÉRICO, E, APARELHO PARA FORMAR GLÓBULOS SÓLIDOS DISCRETOS DE MATERIAL POLIMÉRICO. É fornecido um método para carbonizar e ativar material carbonáceo, compreendendo alimentar o material em um forno rotativo externamente ignizado mantido em temperaturas de carbonização e ativação, o forno tendo uma inclinação em declive para avançar o material à medida que ele gira, o forno tendo uma atmosfera substancialmente livre de oxigênio formada por uma contra-corrente de vapor ou dióxido de carbono, e barragens anulares estando posicionadas em intervalos ao longo do forno para controlar o avanço do material. Pode ser adicionalmente fornecido um forno rotativo externamente ignizado para carbonizar e ativar material carbonáceo tendo um corpo rotativo oco que tem uma inclinação em declive na direção de sua extremidade de descarga, e que está munido em intervalos ao longo de seu comprimento com barragens anulares para controlar o avanço do material carbonáceo. Em modalidades, também é fornecido um processo para produzir glóbulos sólidos discretos de material polimérico e.g. glóbulos de resina fenólica tendo uma estrutura mesoporosa, que pode ser útil como matéria-prima para o processo de carbonização/ativação acima mencionado ou que pode ter outra utilidade e.g. como resinas trocadoras de íons. O processo pode produzir glóbulos de resina em uma escala industrial sem agregados de resina se desenvolvendo em grande velocidade e interrompendo a produção. O processo compreende as etapas de: (a) combinar uma corrente de um precursor líquido polimerizável e.g. um novolac ou uma hexamina como agente reticulante dissolvido em um primeiro líquido orgânico polar e.g. etileno-glicol com uma corrente de meio de suspensão líquido que é um segundo líquido não-polar com o qual o precursor líquido é substancial ou completamente imiscível e.g. óleo de transformador contendo um óleo secante; (b) misturar a corrente combinada para dispersar o precursor líquido polimerizável como gotículas no meio de suspensão e.g. usando um misturador estático em-linha; (c) permitir que as gotículas se polimerizem em um fluxo laminar do meio de suspensão de modo que formem glóbulos sólidos discretos que não podem ser aglomerar; e (d) recuperar os glóbulos do meio de suspensão. Também é fornecido um aparelho para formar glóbulos sólidos discretos de material polimérico, dito aparelho compreendendo: uma primeira linha para transportar uma corrente de um precursor líquido polimerizável; uma segunda linha para transportar uma corrente de um meio de dispersão com o qual o precursor líquido polimerizável é substancial ou completamente imiscível; um misturador em-linha para receber um fluxo combinado das primeira e segunda linhas e para dispersar o precursor líquido polimerizável como gotículas no meio de dispersão; uma coluna de polimerização vertical configurada para receber o meio de dispersão com as gotículas dispersadas no mesmo e para permitir que o precursor líquido polimerizável polimerize enquanto desce pela coluna em um fluxo descendente do meio de polimerização; e um vaso na base da coluna para receber o fluxo descendente de meio de dispersão e coletar glóbulos sólidos polimerizados.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0619973A GB0619973D0 (en) | 2006-10-09 | 2006-10-09 | Process and apparatus |
GB0619973.1 | 2006-10-09 | ||
GBGB0710003.5A GB0710003D0 (en) | 2007-05-24 | 2007-05-24 | Process and apparatus |
GB0710003.5 | 2007-05-24 | ||
PCT/GB2007/003755 WO2008043982A2 (en) | 2006-10-09 | 2007-10-04 | Carbonising and/or activating carbonaceous material |
Publications (2)
Publication Number | Publication Date |
---|---|
BRPI0719764A2 BRPI0719764A2 (pt) | 2014-01-28 |
BRPI0719764A8 true BRPI0719764A8 (pt) | 2017-10-31 |
Family
ID=38959684
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0719764A BRPI0719764A8 (pt) | 2006-10-09 | 2007-10-04 | Métodos para carbonizar e ativar material carbonáceo, e para preparar carbono ativado, forno ativado, processos para preparar um produto de carbono ativado, para preparar um produto particulado carbonizado, e para produzir glóbulos sólidos discretos de material polimérico, e, aparelho para formar glóbulos sólidos discretos de material polimérico |
Country Status (10)
Country | Link |
---|---|
US (1) | US8501142B2 (pt) |
EP (1) | EP2074059A2 (pt) |
JP (1) | JP5371765B2 (pt) |
KR (1) | KR101431855B1 (pt) |
CN (1) | CN101918308B (pt) |
AR (1) | AR063181A1 (pt) |
BR (1) | BRPI0719764A8 (pt) |
CA (1) | CA2660883C (pt) |
RU (1) | RU2478573C2 (pt) |
WO (1) | WO2008043982A2 (pt) |
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2007
- 2007-10-04 CA CA2660883A patent/CA2660883C/en not_active Expired - Fee Related
- 2007-10-04 US US12/444,840 patent/US8501142B2/en active Active
- 2007-10-04 KR KR1020097009576A patent/KR101431855B1/ko active IP Right Grant
- 2007-10-04 JP JP2009531894A patent/JP5371765B2/ja not_active Expired - Fee Related
- 2007-10-04 BR BRPI0719764A patent/BRPI0719764A8/pt not_active IP Right Cessation
- 2007-10-04 EP EP07824011A patent/EP2074059A2/en not_active Withdrawn
- 2007-10-04 WO PCT/GB2007/003755 patent/WO2008043982A2/en active Application Filing
- 2007-10-04 RU RU2009117383/04A patent/RU2478573C2/ru not_active IP Right Cessation
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Also Published As
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KR20090074230A (ko) | 2009-07-06 |
KR101431855B1 (ko) | 2014-08-25 |
EP2074059A2 (en) | 2009-07-01 |
BRPI0719764A2 (pt) | 2014-01-28 |
RU2478573C2 (ru) | 2013-04-10 |
CA2660883A1 (en) | 2008-04-17 |
CN101918308B (zh) | 2014-09-24 |
US8501142B2 (en) | 2013-08-06 |
AR063181A1 (es) | 2008-12-30 |
WO2008043982A3 (en) | 2010-03-18 |
WO2008043982A2 (en) | 2008-04-17 |
US20100098615A1 (en) | 2010-04-22 |
RU2009117383A (ru) | 2010-11-20 |
JP2010510947A (ja) | 2010-04-08 |
CA2660883C (en) | 2014-12-09 |
JP5371765B2 (ja) | 2013-12-18 |
CN101918308A (zh) | 2010-12-15 |
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