BR112016025376A8 - método de preparação de um componente de catalisador para polimerização de olefina - Google Patents
método de preparação de um componente de catalisador para polimerização de olefinaInfo
- Publication number
- BR112016025376A8 BR112016025376A8 BR112016025376A BR112016025376A BR112016025376A8 BR 112016025376 A8 BR112016025376 A8 BR 112016025376A8 BR 112016025376 A BR112016025376 A BR 112016025376A BR 112016025376 A BR112016025376 A BR 112016025376A BR 112016025376 A8 BR112016025376 A8 BR 112016025376A8
- Authority
- BR
- Brazil
- Prior art keywords
- halogen
- catalyst component
- compound
- compounds
- preparing
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 6
- 238000006116 polymerization reaction Methods 0.000 title abstract 4
- 150000001336 alkenes Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 8
- 229910052736 halogen Inorganic materials 0.000 abstract 6
- 150000002367 halogens Chemical class 0.000 abstract 6
- -1 magnesium halide Chemical class 0.000 abstract 5
- 239000011777 magnesium Substances 0.000 abstract 3
- 229910052749 magnesium Inorganic materials 0.000 abstract 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- 239000004593 Epoxy Substances 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 239000012046 mixed solvent Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000002002 slurry Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
- C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/06—Catalyst characterized by its size
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
método de preparação de um componente de catalisador para polimerização de olefina. a presente invenção fornece um método de preparação de um componente de catalisador para polimerização de olefina que compreende primeiramente dissolver um haleto de magnésio anidro em um solvente misturado, que compreende um composto de titânio orgânico que contém oxigênio, um composto de epóxi orgânico, um composto que contém hidróxi e um solvente inerte, e não compreende um composto de fosfato, de modo a formar uma solução de haleto de magnésio; então, misturar a solução de haleto de magnésio com um composto de que contém halogênio para precipitar um sólido, de modo a obter o componente de catalisador, em que o composto de que contém halogênio compreende pelo menos um selecionado a partir de um grupo que consiste em compostos que contêm titânio e halogênio, compostos de hidrocarboneto orgânico halogenado, compostos de haleto de acila, compostos que contêm fósforo e halogênio, compostos que contêm boro e halogênio, compostos de alumínio orgânico halogenado e compostos que contêm silício e halogênio. o componente de catalisador preparado pela presente invenção tem melhor morfologia de partícula, e uma boa resposta ao hidrogênio e, desse modo, é favorável ao uso do catalisador em um dispositivo de processo de polimerização em gás ou em lama.
Applications Claiming Priority (13)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410177192.3A CN105085741B (zh) | 2014-04-29 | 2014-04-29 | 一种用于烯烃聚合的催化剂组分的制备方法 |
| CN201410176105.2A CN105085735B (zh) | 2014-04-29 | 2014-04-29 | 一种用于烯烃聚合的催化剂组分的制备方法 |
| CN201410177192.3 | 2014-04-29 | ||
| CN201410176229.0A CN105085740B (zh) | 2014-04-29 | 2014-04-29 | 一种用于烯烃聚合的催化剂组分的制备方法 |
| CN201410177228.8A CN105085743B (zh) | 2014-04-29 | 2014-04-29 | 一种用于烯烃聚合的催化剂组分的制备方法 |
| CN201410177203.8A CN105085742B (zh) | 2014-04-29 | 2014-04-29 | 一种用于烯烃聚合的催化剂组分的制备方法 |
| CN201410176179.6 | 2014-04-29 | ||
| CN201410176103.3A CN105085734B (zh) | 2014-04-29 | 2014-04-29 | 一种用于烯烃聚合的催化剂组分的制备方法 |
| CN201410176103.3 | 2014-04-29 | ||
| CN201410176229.0 | 2014-04-29 | ||
| CN201410176179.6A CN105085737B (zh) | 2014-04-29 | 2014-04-29 | 一种用于烯烃聚合的催化剂组分的制备方法 |
| CN201410177203.8 | 2014-04-29 | ||
| PCT/CN2015/077844 WO2015165405A1 (zh) | 2014-04-29 | 2015-04-29 | 一种用于烯烃聚合的催化剂组分的制备方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| BR112016025376A2 BR112016025376A2 (pt) | 2017-08-15 |
| BR112016025376A8 true BR112016025376A8 (pt) | 2021-05-04 |
| BR112016025376B1 BR112016025376B1 (pt) | 2021-11-30 |
Family
ID=54358185
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112016025376-0A BR112016025376B1 (pt) | 2014-04-29 | 2015-04-29 | Método de preparação de um componente de catalisador para polimerização de olefina |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US10174141B2 (pt) |
| EP (1) | EP3138856B1 (pt) |
| JP (1) | JP6706582B2 (pt) |
| KR (1) | KR102172790B1 (pt) |
| BR (1) | BR112016025376B1 (pt) |
| CA (1) | CA2947189C (pt) |
| MY (1) | MY187602A (pt) |
| PH (1) | PH12016502158A1 (pt) |
| RU (1) | RU2673609C2 (pt) |
| SG (1) | SG11201609010RA (pt) |
| WO (1) | WO2015165405A1 (pt) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2947186C (en) * | 2014-04-29 | 2023-01-10 | China Petroleum & Chemical Corporation | Magnesium halide solution, preparing method and use thereof |
| CN107880174B (zh) * | 2016-09-30 | 2020-06-09 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备与应用 |
| CN112707978B (zh) * | 2019-10-25 | 2023-05-12 | 中国石油化工股份有限公司 | 一种烯烃聚合用的镁基催化剂组分及其制备方法以及催化剂与应用 |
| CN112759685B (zh) * | 2019-11-01 | 2023-02-28 | 中国石油化工股份有限公司 | 用于乙烯聚合反应的催化剂组分及其制备方法、催化剂及其应用 |
| CN115397807B (zh) * | 2020-04-17 | 2024-08-13 | 帝斯曼知识产权资产管理有限公司 | 用于制备取代的烯胺化合物的方法 |
| KR102487346B1 (ko) * | 2020-12-04 | 2023-01-11 | 한화토탈에너지스 주식회사 | 초고분자량 폴리에틸렌의 분자량분포 조절을 위한 지글러-나타 촉매의 제조방법 |
| CN116041578A (zh) * | 2021-10-28 | 2023-05-02 | 中国石油化工股份有限公司 | 催化剂组分及其制备方法、催化剂体系及其应用 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5883006A (ja) * | 1981-11-13 | 1983-05-18 | Mitsui Petrochem Ind Ltd | オレフインの重合方法 |
| JPH06157658A (ja) | 1992-11-17 | 1994-06-07 | Chisso Corp | オレフィン重合用固体触媒成分の保存方法 |
| CN1169845C (zh) * | 2002-02-07 | 2004-10-06 | 中国石油化工股份有限公司 | 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用 |
| EP1947123B1 (en) * | 2005-10-31 | 2016-03-09 | China Petroleum & Chemical Corporation | Catalyst component for ethylene polymerization, preparation thereof and catalyst containing the same |
| RU2009102047A (ru) * | 2006-06-23 | 2010-07-27 | Базелль Полиолефин Италия С.Р.Л. (It) | Предшественники катализитора на основе хлоралкоголята магния |
| CN101407561B (zh) | 2008-11-28 | 2011-01-05 | 北京化工大学 | 烯烃聚合催化剂 |
| CN102020730B (zh) | 2009-09-10 | 2013-01-02 | 中国石油化工股份有限公司 | 一种用于乙烯聚合的催化剂组分和催化剂 |
| ES2472668T3 (es) * | 2009-08-21 | 2014-07-02 | China Petroleum & Chemical Corporation | Componente de catalizador para la polimerizaci�n de etileno, preparación del mismo y catalizador que comprende el componente de catalizador |
| SA3686B1 (ar) * | 2009-10-16 | 2014-10-22 | China Petroleum& Chemical Corp | مكون حفاز لبلمرة الأولفين وحفاز يشتمل عليه |
| CN101880342B (zh) | 2010-07-06 | 2012-10-17 | 中国石油天然气股份有限公司 | 一种烯烃聚合催化剂及其制备和应用 |
| US8501653B2 (en) | 2011-02-16 | 2013-08-06 | Fina Technology, Inc. | Heat-treated Ziegler-Natta catalysts for ethylene polymerization |
| CN102875707A (zh) | 2011-07-14 | 2013-01-16 | 中国石油化工股份有限公司 | 用于乙烯聚合或共聚合的催化剂组分的制备方法及其催化剂 |
| CN103044583B (zh) * | 2011-10-13 | 2015-10-28 | 中国石油化工股份有限公司 | 烯烃聚合物及其制备方法 |
| CN103087224B (zh) * | 2011-10-28 | 2015-03-11 | 中国石油化工股份有限公司 | 一种用于乙烯聚合反应的催化剂组分及其制备方法 |
| US20130109789A1 (en) | 2011-10-28 | 2013-05-02 | Sumitomo Chemical Company, Limited | Olefin polymerization catalyst, process for producing olefin polymer, polypropylene resin composition and article comprising the same |
| CN103059175B (zh) * | 2012-11-22 | 2014-11-26 | 中国科学院化学研究所 | 烯烃聚合固体催化剂组分及其制备方法 |
| CA2947186C (en) * | 2014-04-29 | 2023-01-10 | China Petroleum & Chemical Corporation | Magnesium halide solution, preparing method and use thereof |
-
2015
- 2015-04-29 JP JP2016565201A patent/JP6706582B2/ja active Active
- 2015-04-29 WO PCT/CN2015/077844 patent/WO2015165405A1/zh active Application Filing
- 2015-04-29 BR BR112016025376-0A patent/BR112016025376B1/pt active IP Right Grant
- 2015-04-29 US US15/307,209 patent/US10174141B2/en active Active
- 2015-04-29 CA CA2947189A patent/CA2947189C/en active Active
- 2015-04-29 SG SG11201609010RA patent/SG11201609010RA/en unknown
- 2015-04-29 RU RU2016146550A patent/RU2673609C2/ru active
- 2015-04-29 MY MYPI2016703972A patent/MY187602A/en unknown
- 2015-04-29 KR KR1020167033297A patent/KR102172790B1/ko active IP Right Grant
- 2015-04-29 EP EP15785255.9A patent/EP3138856B1/en active Active
-
2016
- 2016-10-28 PH PH12016502158A patent/PH12016502158A1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA2947189A1 (en) | 2015-11-05 |
| BR112016025376A2 (pt) | 2017-08-15 |
| SG11201609010RA (en) | 2016-12-29 |
| EP3138856A1 (en) | 2017-03-08 |
| EP3138856A4 (en) | 2017-12-27 |
| JP2017514946A (ja) | 2017-06-08 |
| EP3138856B1 (en) | 2020-11-04 |
| KR102172790B1 (ko) | 2020-11-02 |
| WO2015165405A1 (zh) | 2015-11-05 |
| CA2947189C (en) | 2022-08-30 |
| MY187602A (en) | 2021-10-01 |
| BR112016025376B1 (pt) | 2021-11-30 |
| RU2016146550A (ru) | 2018-05-30 |
| US20170051086A1 (en) | 2017-02-23 |
| KR20160149265A (ko) | 2016-12-27 |
| RU2673609C2 (ru) | 2018-11-29 |
| RU2016146550A3 (pt) | 2018-09-28 |
| US10174141B2 (en) | 2019-01-08 |
| PH12016502158A1 (en) | 2016-12-19 |
| JP6706582B2 (ja) | 2020-06-10 |
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