CL2016000919A1 - Método para preparar un portador esférico de un catalizador para la polimerización de olefinas; portador esférico; proceso para preparar una composición solida; composición solida; componente catalizador; método para preparar un componente catalizador; catalizador para la polimerización de olefinas; uso del catalizador; y método para la polimerización de olefina(s). - Google Patents

Método para preparar un portador esférico de un catalizador para la polimerización de olefinas; portador esférico; proceso para preparar una composición solida; composición solida; componente catalizador; método para preparar un componente catalizador; catalizador para la polimerización de olefinas; uso del catalizador; y método para la polimerización de olefina(s).

Info

Publication number
CL2016000919A1
CL2016000919A1 CL2016000919A CL2016000919A CL2016000919A1 CL 2016000919 A1 CL2016000919 A1 CL 2016000919A1 CL 2016000919 A CL2016000919 A CL 2016000919A CL 2016000919 A CL2016000919 A CL 2016000919A CL 2016000919 A1 CL2016000919 A1 CL 2016000919A1
Authority
CL
Chile
Prior art keywords
catalyst
polymerization
olefins
solid composition
preparing
Prior art date
Application number
CL2016000919A
Other languages
English (en)
Inventor
Weili Li
Xianzhi Xia
Yuexiang Liu
Yongtai Ling
Jin Zhao
Jigui Zhang
Futang Gao
Ping Gao
Yang Tan
Renqi Peng
Zhihui Zhang
Jie Lin
Ruilin Duan
Changyou Ma
Original Assignee
China Petroleum & Chem Corp
Beijing Res Inst Chemical Ind China Petroleum & Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN201310491641.7A external-priority patent/CN104558283B/zh
Priority claimed from CN201310491648.9A external-priority patent/CN104558284B/zh
Priority claimed from CN201310491393.6A external-priority patent/CN104558281B/zh
Application filed by China Petroleum & Chem Corp, Beijing Res Inst Chemical Ind China Petroleum & Chemical Corp filed Critical China Petroleum & Chem Corp
Publication of CL2016000919A1 publication Critical patent/CL2016000919A1/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00—Post-polymerisation treatments
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyethers (AREA)
  • Polymerization Catalysts (AREA)

Abstract

método para preparar un portador esférico de un catalizador para Ia polimerización de olefinas, que comprende hacer reaccionar al menos los siguientes componentes: (a) un haluro de magnesio, (b) un compuesto orgánico que contiene hidrógeno activo, y (c) un epóxido, en presencia de al menos un estabilizador de dispersión polimérico, para precipitar directamente un producto sólido particulado; portador esférico; proceso para preparar una composicion solida; composicion solida; y componente catalizador pare Ia polimerizacion de olefinas.
CL2016000919A 2013-10-18 2016-04-18 Método para preparar un portador esférico de un catalizador para la polimerización de olefinas; portador esférico; proceso para preparar una composición solida; composición solida; componente catalizador; método para preparar un componente catalizador; catalizador para la polimerización de olefinas; uso del catalizador; y método para la polimerización de olefina(s). CL2016000919A1 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN201310491641.7A CN104558283B (zh) 2013-10-18 2013-10-18 一种固体组合物及其制备方法和应用
CN201310491648.9A CN104558284B (zh) 2013-10-18 2013-10-18 用于烯烃聚合的催化剂组分及其制备方法和用于烯烃聚合的催化剂与应用
CN201310491393.6A CN104558281B (zh) 2013-10-18 2013-10-18 一种用于烯烃聚合催化剂的球形载体及其制备方法

Publications (1)

Publication Number Publication Date
CL2016000919A1 true CL2016000919A1 (es) 2016-11-11

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CL2016000919A CL2016000919A1 (es) 2013-10-18 2016-04-18 Método para preparar un portador esférico de un catalizador para la polimerización de olefinas; portador esférico; proceso para preparar una composición solida; composición solida; componente catalizador; método para preparar un componente catalizador; catalizador para la polimerización de olefinas; uso del catalizador; y método para la polimerización de olefina(s).

Country Status (12)

Country Link
US (1) US9951157B2 (es)
EP (1) EP3059263B1 (es)
JP (1) JP6397908B2 (es)
KR (1) KR102019727B1 (es)
BR (1) BR112016008605B1 (es)
CL (1) CL2016000919A1 (es)
MY (1) MY172451A (es)
RU (1) RU2668082C2 (es)
SA (1) SA516370961B1 (es)
SG (1) SG11201603004RA (es)
TW (1) TWI650335B (es)
WO (1) WO2015055136A1 (es)

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CN110938163A (zh) * 2018-09-25 2020-03-31 中国石油化工股份有限公司 用于烯烃聚合的催化剂体系和预聚合催化剂组合物及它们的应用
CN110938160B (zh) * 2018-09-25 2022-05-24 中国石油化工股份有限公司 用于烯烃聚合的催化剂体系和预聚合催化剂组合物及它们的应用
CN111057168B (zh) * 2018-10-16 2022-07-12 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂及其制备方法和应用
JP7479361B2 (ja) 2018-10-19 2024-05-08 中国石油化工股▲ふん▼有限公司 オレフィン重合用触媒成分、触媒及びその応用
CN111072797B (zh) * 2018-10-19 2021-07-02 中国石油化工股份有限公司 烯烃聚合催化剂球形载体及其制备方法和催化剂组分与催化剂及应用
CN111072809B (zh) * 2018-10-19 2022-05-24 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分和催化剂及其应用与烯烃聚合方法
CN110628393B (zh) * 2019-10-14 2021-02-02 北京工业大学 交联型聚氧乙烯醚制备相变潜热材料的方法
KR102342077B1 (ko) * 2019-12-24 2021-12-21 한화토탈 주식회사 에틸렌 중합용 촉매의 제조 방법
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JP2016540065A (ja) 2016-12-22
US9951157B2 (en) 2018-04-24
KR20160073986A (ko) 2016-06-27
EP3059263A1 (en) 2016-08-24
RU2668082C2 (ru) 2018-09-27
SG11201603004RA (en) 2016-05-30
MY172451A (en) 2019-11-26
RU2016118406A (ru) 2017-11-23
US20160251457A1 (en) 2016-09-01
RU2016118406A3 (es) 2018-04-26
EP3059263A4 (en) 2017-06-07
TWI650335B (zh) 2019-02-11
SA516370961B1 (ar) 2018-11-11
WO2015055136A1 (zh) 2015-04-23
BR112016008605B1 (pt) 2021-01-19
JP6397908B2 (ja) 2018-09-26
EP3059263B1 (en) 2021-07-21
TW201522399A (zh) 2015-06-16
KR102019727B1 (ko) 2019-09-09

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