BR112015018202A2 - processo para preparar um componente catalisador para a polimerização de olefinas - Google Patents

processo para preparar um componente catalisador para a polimerização de olefinas

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Publication number
BR112015018202A2
BR112015018202A2 BR112015018202A BR112015018202A BR112015018202A2 BR 112015018202 A2 BR112015018202 A2 BR 112015018202A2 BR 112015018202 A BR112015018202 A BR 112015018202A BR 112015018202 A BR112015018202 A BR 112015018202A BR 112015018202 A2 BR112015018202 A2 BR 112015018202A2
Authority
BR
Brazil
Prior art keywords
reaction product
preparing
intermediate reaction
catalyst component
contacting
Prior art date
Application number
BR112015018202A
Other languages
English (en)
Other versions
BR112015018202B1 (pt
Inventor
Alexandra Batinas-Geurts Aurora
Dimitrievich Bukatov Gennadii
Brijlal Sainani Jaiprakash
Patel Vimalkumar Mahendrabhai
Taftaf Mansour
Alexander Zuideveld Martin
Andreevich Sergeev Sergei
Aleksandrovich Zakharov Vladimir
Original Assignee
Saudi Basic Ind Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Basic Ind Corp filed Critical Saudi Basic Ind Corp
Publication of BR112015018202A2 publication Critical patent/BR112015018202A2/pt
Publication of BR112015018202B1 publication Critical patent/BR112015018202B1/pt

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/17—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/18—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/23—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/64—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings
    • C07C233/67—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/68—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/69—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6546—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof organo-magnesium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

resumo patente de invenção: "processo para preparar um componente catalisador para a polimerização de olefinas". a presente invenção refere-se a um processo para preparar um componente catalisador para a polimerização de uma olefina que compreende as etapas de: i) contatar um composto r9zmgx2-z em que r9 é um grupo aromático, alifático ou cicloalifático que contém até 20 átomos de carbono, x é um haleto e z está em uma faixa maior do que 0 e menor do que 2, com um composto de silano que contém alcóxi ou arilóxi para gerar um primeiro produto de reação intermediário; ii) contatar o primeiro produto de reação intermediário com pelo menos um composto de ativação selecionado a partir do grupo formado por doadores de elétrons e compostos de fórmula m(or10)v-w(or11)w, em que m pode ser ti, zr, hf, al ou si e m(or10)v-w(r11)w, em que m é si, cada um dentre r10 e r11, independentemente, representa um grupo alquila, alquenila ou arila, v é a valência de m, sendo que v é 3 ou 4 e w é menor do que v, para gerar um segundo produto de reação intermediário; e iii) contatar o segundo produto de reação intermediário com um composto de ti que contém halogênio, um monoéster como agente de ativação, um 1,3-diéter como um doador de elétrons interno e, opcionalmente, um diéster como um doador de elétrons interno adicional.
BR112015018202-0A 2013-01-31 2014-01-28 componente catalisador, seu processo de preparação, seu uso, sistema de catalisador e processo para produzir uma poliolefina BR112015018202B1 (pt)

Applications Claiming Priority (12)

Application Number Priority Date Filing Date Title
EP13000492.2 2013-01-31
EP13000481 2013-01-31
EP13000492 2013-01-31
EP13199147.3 2013-12-20
EP13199147 2013-12-20
EP13199160.6 2013-12-20
EP13199160 2013-12-20
US201461927029P 2014-01-14 2014-01-14
US201461927034P 2014-01-14 2014-01-14
US61/927,029 2014-01-14
US61/927,034 2014-01-14
PCT/EP2014/051610 WO2014118165A1 (en) 2013-01-31 2014-01-28 Process for preparing a catalyst component for polymerization of olefins

Publications (2)

Publication Number Publication Date
BR112015018202A2 true BR112015018202A2 (pt) 2017-07-18
BR112015018202B1 BR112015018202B1 (pt) 2020-12-22

Family

ID=51261483

Family Applications (2)

Application Number Title Priority Date Filing Date
BR112015018202-0A BR112015018202B1 (pt) 2013-01-31 2014-01-28 componente catalisador, seu processo de preparação, seu uso, sistema de catalisador e processo para produzir uma poliolefina
BR112015017749-2A BR112015017749B1 (pt) 2013-01-31 2014-01-28 composição de catalisador para a polimerização de olefinas, seu processo para a preparação e seu uso, sistema de catalisador e processo de produção de uma poliolefina

Family Applications After (1)

Application Number Title Priority Date Filing Date
BR112015017749-2A BR112015017749B1 (pt) 2013-01-31 2014-01-28 composição de catalisador para a polimerização de olefinas, seu processo para a preparação e seu uso, sistema de catalisador e processo de produção de uma poliolefina

Country Status (7)

Country Link
US (3) US9663596B2 (pt)
EP (2) EP2951215B1 (pt)
KR (2) KR102123473B1 (pt)
CN (2) CN104981488B (pt)
BR (2) BR112015018202B1 (pt)
EA (2) EA026624B1 (pt)
WO (2) WO2014118165A1 (pt)

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EA026624B1 (ru) 2013-01-31 2017-04-28 Сауди Бейсик Индастриз Корпорейшн Каталитическая композиция для полимеризации олефинов
WO2015091982A1 (en) 2013-12-20 2015-06-25 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
EA032114B1 (ru) 2013-12-20 2019-04-30 Сауди Бейсик Индастриз Корпорейшн Каталитическая система для полимеризации олефинов
US10000591B2 (en) 2013-12-20 2018-06-19 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin
EA033164B1 (ru) 2013-12-20 2019-09-30 Сауди Бейсик Индастриз Корпорейшн Каталитическая система для полимеризации олефина
KR20160102018A (ko) 2013-12-20 2016-08-26 사우디 베이식 인더스트리즈 코포레이션 올레핀 중합용 전구 촉매
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Also Published As

Publication number Publication date
US20150368381A1 (en) 2015-12-24
EP2951215A1 (en) 2015-12-09
US20150353656A1 (en) 2015-12-10
KR20150113108A (ko) 2015-10-07
KR102123471B1 (ko) 2020-06-17
EA201500779A1 (ru) 2015-12-30
EA201500781A1 (ru) 2016-01-29
BR112015018202B1 (pt) 2020-12-22
BR112015017749A2 (pt) 2017-07-11
EP2951215B1 (en) 2018-10-10
CN104981488A (zh) 2015-10-14
EA025272B1 (ru) 2016-12-30
BR112015017749B1 (pt) 2021-01-12
EA026624B1 (ru) 2017-04-28
WO2014118165A1 (en) 2014-08-07
KR102123473B1 (ko) 2020-06-17
US10106632B2 (en) 2018-10-23
US20170129974A1 (en) 2017-05-11
EP2951214B1 (en) 2019-01-23
CN104981487B (zh) 2017-03-08
US9587051B2 (en) 2017-03-07
EP2951214A1 (en) 2015-12-09
WO2014118164A1 (en) 2014-08-07
KR20150113107A (ko) 2015-10-07
CN104981487A (zh) 2015-10-14
CN104981488B (zh) 2017-10-03
US9663596B2 (en) 2017-05-30

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