EA201500781A1 - Способ получения компонента катализатора полимеризации олефинов - Google Patents

Способ получения компонента катализатора полимеризации олефинов

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Publication number
EA201500781A1
EA201500781A1 EA201500781A EA201500781A EA201500781A1 EA 201500781 A1 EA201500781 A1 EA 201500781A1 EA 201500781 A EA201500781 A EA 201500781A EA 201500781 A EA201500781 A EA 201500781A EA 201500781 A1 EA201500781 A1 EA 201500781A1
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EA
Eurasian Patent Office
Prior art keywords
reaction product
intermediate reaction
compound
olefin polymerization
diester
Prior art date
Application number
EA201500781A
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English (en)
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EA025272B1 (ru
Inventor
Мансур Тафтаф
Джайпракаш Брийлал Сайнани
Владимир Александрович Захаров
Геннадий Дмитриевич Букатов
Махендрабхай Патель Вималькумар
Сергей Андреевич Сергеев
Мартин Александр Зёйдевелд
Аурора Александра Батинас-Гёртс
Original Assignee
Сауди Бейсик Индастриз Корпорейшн
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Publication of EA201500781A1 publication Critical patent/EA201500781A1/ru
Publication of EA025272B1 publication Critical patent/EA025272B1/ru

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/17—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/18—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/23—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/64—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings
    • C07C233/67—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/68—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/69—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6546—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof organo-magnesium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Настоящее изобретение относится к способу получения компонента катализатора полимеризации олефина, включающему стадии: i) введения соединения RMgX, где Rпредставляет собой ароматическую, алифатическую или циклоалифатическую группу, содержащую вплоть до 20 атомов углерода, X представляет собой галогенид, a z находится в диапазоне от более чем 0 до менее чем 2, в контакт с алкокси- или арилоксисодержащим силановым соединением для получения первого промежуточного продукта реакции; ii) введения первого промежуточного продукта реакции в контакт по меньшей мере с одним активирующим соединением, выбираемым из группы, образованной донорами электронов и соединениями, описывающимися формулами M(OR)(OR), где М может представлять собой Ti, Zr, Hf, Al или Si, и M(OR)(R), где М представляет собой Si, каждый из Rи Rнезависимо представляет собой алкильную, алкенильную или арильную группу, v представляет собой валентность М, при этом v составляет либо 3, либо 4, и w является меньшим, чем v, для получения второго промежуточного продукта реакции; и iii) введения второго промежуточного продукта реакции в контакт с галогенсодержащим соединением Ti, сложным моноэфиром в качестве активатора, простым 1,3-диэфиром в качестве внутреннего донора электронов и необязательно сложным диэфиром в качестве дополнительного внутреннего донора электронов.
EA201500781A 2013-01-31 2014-01-28 Способ получения компонента катализатора полимеризации олефинов EA025272B1 (ru)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
EP13000481 2013-01-31
EP13000492 2013-01-31
EP13199147 2013-12-20
EP13199160 2013-12-20
US201461927034P 2014-01-14 2014-01-14
US201461927029P 2014-01-14 2014-01-14
PCT/EP2014/051610 WO2014118165A1 (en) 2013-01-31 2014-01-28 Process for preparing a catalyst component for polymerization of olefins

Publications (2)

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EA201500781A1 true EA201500781A1 (ru) 2016-01-29
EA025272B1 EA025272B1 (ru) 2016-12-30

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EA201500781A EA025272B1 (ru) 2013-01-31 2014-01-28 Способ получения компонента катализатора полимеризации олефинов
EA201500779A EA026624B1 (ru) 2013-01-31 2014-01-28 Каталитическая композиция для полимеризации олефинов

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US (3) US9663596B2 (ru)
EP (2) EP2951214B1 (ru)
KR (2) KR102123473B1 (ru)
CN (2) CN104981487B (ru)
BR (2) BR112015018202B1 (ru)
EA (2) EA025272B1 (ru)
WO (2) WO2014118165A1 (ru)

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Publication number Publication date
EP2951214B1 (en) 2019-01-23
EA201500779A1 (ru) 2015-12-30
KR20150113107A (ko) 2015-10-07
US20170129974A1 (en) 2017-05-11
KR20150113108A (ko) 2015-10-07
EP2951215A1 (en) 2015-12-09
CN104981488A (zh) 2015-10-14
US10106632B2 (en) 2018-10-23
US9663596B2 (en) 2017-05-30
BR112015018202A2 (pt) 2017-07-18
KR102123473B1 (ko) 2020-06-17
WO2014118165A1 (en) 2014-08-07
CN104981487A (zh) 2015-10-14
EA025272B1 (ru) 2016-12-30
CN104981488B (zh) 2017-10-03
CN104981487B (zh) 2017-03-08
US20150368381A1 (en) 2015-12-24
KR102123471B1 (ko) 2020-06-17
BR112015018202B1 (pt) 2020-12-22
BR112015017749B1 (pt) 2021-01-12
EA026624B1 (ru) 2017-04-28
EP2951214A1 (en) 2015-12-09
BR112015017749A2 (pt) 2017-07-11
US9587051B2 (en) 2017-03-07
US20150353656A1 (en) 2015-12-10
WO2014118164A1 (en) 2014-08-07
EP2951215B1 (en) 2018-10-10

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