MX2016001079A - Composicion catalizadora y proceso para la oligomerizacion de etileno. - Google Patents

Composicion catalizadora y proceso para la oligomerizacion de etileno.

Info

Publication number
MX2016001079A
MX2016001079A MX2016001079A MX2016001079A MX2016001079A MX 2016001079 A MX2016001079 A MX 2016001079A MX 2016001079 A MX2016001079 A MX 2016001079A MX 2016001079 A MX2016001079 A MX 2016001079A MX 2016001079 A MX2016001079 A MX 2016001079A
Authority
MX
Mexico
Prior art keywords
catalyst composition
r1r2p
oligomerization
ethylene
ring system
Prior art date
Application number
MX2016001079A
Other languages
English (en)
Inventor
Uwe Rosenthal
Normen Peulecke
Marco Harff
Mohammed H Al-Hazmi
Abdullah Al-Qahtani
Anina Woehl
Andreas Meiswinkle
Heinz Boelt
Bernd H Mueller
Wolfgang Mueller
Original Assignee
Linde Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Linde Ag filed Critical Linde Ag
Publication of MX2016001079A publication Critical patent/MX2016001079A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1885—Ligands comprising two different formal oxidation states of phosphorus in one at least bidentate ligand, e.g. phosphite/phosphinite
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Una composición catalizadora que incluye: (a) un compuesto de cromo; (b) un ligando de la estructura general (A) R1R2P-N (R3)-P (R4) -NR5R6 o (B) R1R2P-N (R3)-p (XR7) R8 o R1R2P-N(R3)-P(XR7)2, con X = O o S, en donde R1, R2, R3, R4, R5, R6, R7 y R8 son independientemente alquilo C1-C10, arilo C6-C20, cicloalquilo C3-C10, aralquilo, alquilarilo o trialquilsililo o cualquier derivado cíclico de (A) y (B), en donde al menos uno de los átomos de P o de N de la unidad PNPN o de la unidad PNP es un miembro del sistema de anillo, estando formado el sistema de anillo por uno o más compuestos constituyentes de las estructuras (A) o (B) por sustitución; y (c) un activador o un co-catalizador; y un proceso para tri- y/o tetramerización.
MX2016001079A 2013-07-29 2014-07-28 Composicion catalizadora y proceso para la oligomerizacion de etileno. MX2016001079A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13178362.3A EP2832445A1 (en) 2013-07-29 2013-07-29 Catalyst composition and process for oligomerization of ethylene
US201462008237P 2014-06-05 2014-06-05
PCT/IB2014/063485 WO2015015402A2 (en) 2013-07-29 2014-07-28 Catalyst composition and process for oligomerization of ethylene

Publications (1)

Publication Number Publication Date
MX2016001079A true MX2016001079A (es) 2016-04-25

Family

ID=48874924

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016001079A MX2016001079A (es) 2013-07-29 2014-07-28 Composicion catalizadora y proceso para la oligomerizacion de etileno.

Country Status (13)

Country Link
US (4) US9561500B2 (es)
EP (1) EP2832445A1 (es)
JP (1) JP6175192B2 (es)
KR (1) KR102268302B1 (es)
CN (2) CN108295900A (es)
BR (1) BR112016001705A2 (es)
CA (1) CA2916919C (es)
MX (1) MX2016001079A (es)
MY (1) MY172628A (es)
RU (1) RU2647863C2 (es)
SG (1) SG11201510819VA (es)
TW (1) TWI561305B (es)
WO (1) WO2015015402A2 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2832445A1 (en) 2013-07-29 2015-02-04 Linde AG Catalyst composition and process for oligomerization of ethylene
KR101679515B1 (ko) 2015-02-12 2016-11-24 주식회사 엘지화학 올리고머화 촉매계의 제조방법 및 이에 의해 제조된 올리고머화 촉매계
KR102545533B1 (ko) * 2016-05-27 2023-06-21 에스케이이노베이션 주식회사 올리고머화 촉매 및 이를 이용한 에틸렌 올리고머의 제조방법
WO2018012997A1 (en) 2016-07-15 2018-01-18 Public Joint Stock Company "Sibur Holding" Method of oligomerization of olefins
KR101880810B1 (ko) * 2016-09-21 2018-07-23 롯데케미칼 주식회사 올레핀 올리고머 제조방법
US11511265B2 (en) 2018-11-12 2022-11-29 Sabic Global Technologies B.V. Ligands for production of 1-octene in chromium assisted ethylene oligomerization process
CN113260457B (zh) * 2018-11-12 2024-04-02 沙特基础全球技术有限公司 用于铬辅助乙烯低聚工艺中生产1-己烯的配体
CN111889142B (zh) * 2020-07-23 2023-02-07 天津科技大学 一种乙烯选择性齐聚的催化剂体系、反应方法及其应用
CN112473741B (zh) * 2020-10-22 2023-09-01 杭州小菱科技有限公司 一种乙烯齐聚催化剂体系及其制备方法与用途
KR20240124384A (ko) 2021-12-23 2024-08-16 사빅 글로벌 테크놀러지스 비.브이. 올리고머화 반응을 위한 촉매 조성물

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0016895D0 (en) * 2000-07-11 2000-08-30 Bp Chem Int Ltd Olefin oligomerisation
CN1308269C (zh) 2001-12-20 2007-04-04 Sasol技术股份有限公司 使用铬基催化剂的烯烃三聚和寡聚
US7297832B2 (en) * 2002-12-20 2007-11-20 Sasol Technology (Pty) Limited Tetramerization of olefins
US7525009B2 (en) * 2002-12-20 2009-04-28 Sasol Technology (Pty) Limited Trimerisation of olefins
BRPI0317510B1 (pt) * 2002-12-20 2020-01-07 Sasol Technology ( Pty) Ltd Processo de tetramerização de olefinas e sistema catalisador
JP2006511625A (ja) * 2002-12-20 2006-04-06 サソル テクノロジー （ピーティーワイ） リミテッド オレフィンの四量体化
US7323611B2 (en) * 2005-06-28 2008-01-29 Sumitomo Chemical Company Limited Process for producing olefin oligomer
CN100443178C (zh) 2006-03-10 2008-12-17 中国石油天然气股份有限公司 一种乙烯低聚的催化剂组合物及其应用
CN101600723A (zh) * 2006-12-22 2009-12-09 国际壳牌研究有限公司 用于烯烃单体催化低聚的配体及其催化剂体系
US8637721B2 (en) * 2007-07-11 2014-01-28 Saudi Basic Industries Corporation Catalyst composition and process for di-, tri- and/or tetramerization of ethylene
ES2367133T3 (es) * 2008-04-04 2011-10-28 Saudi Basic Industries Corporation Catalizador para la oligomerización de etileno, procedimiento para la preparación del mismo y procedimiento de oligomerización que usa el mismo.
ES2371218T3 (es) 2009-04-09 2011-12-28 Saudi Basic Industries Corporation Composición de catalizador y procedimiento para la oligomerización de etileno.
EP2489431B1 (en) * 2011-02-16 2013-05-01 Linde AG Method for preparing a catalyst composition for oligomerization of ethylene and respective catalyst composition pre-formation unit
CA2765429C (en) * 2012-01-25 2019-12-31 Nova Chemicals Corporation P-n-p ligand
EP2832445A1 (en) 2013-07-29 2015-02-04 Linde AG Catalyst composition and process for oligomerization of ethylene

Also Published As

Publication number Publication date
EP2832445A1 (en) 2015-02-04
RU2016104650A (ru) 2017-08-31
TW201519949A (zh) 2015-06-01
US10265690B2 (en) 2019-04-23
MY172628A (en) 2019-12-06
SG11201510819VA (en) 2016-02-26
JP2016529098A (ja) 2016-09-23
US20170128925A1 (en) 2017-05-11
CN105408019B (zh) 2019-06-28
CA2916919C (en) 2018-05-01
RU2647863C2 (ru) 2018-03-21
CN105408019A (zh) 2016-03-16
US20190210011A1 (en) 2019-07-11
KR102268302B1 (ko) 2021-06-23
US20220241764A1 (en) 2022-08-04
JP6175192B2 (ja) 2017-08-02
WO2015015402A2 (en) 2015-02-05
WO2015015402A3 (en) 2015-07-16
BR112016001705A2 (pt) 2017-09-19
US20160167033A1 (en) 2016-06-16
US9561500B2 (en) 2017-02-07
TWI561305B (en) 2016-12-11
CN108295900A (zh) 2018-07-20
KR20160037181A (ko) 2016-04-05
CA2916919A1 (en) 2015-02-05

Similar Documents

Publication Publication Date Title
MX2016001079A (es) Composicion catalizadora y proceso para la oligomerizacion de etileno.
MX2016015768A (es) Procatalizador para la polimerizacion de olefinas.
MY148675A (en) Catalyst composition and process for di-, tri-and/or tetramerization of ethylene
EA201692489A1 (ru) Прокатализатор полимеризации олефинов, содержащий сложный моноэфир и амидобензоатный внутренний донор
IN2014DN10763A (es)
EA201500781A1 (ru) Способ получения компонента катализатора полимеризации олефинов
MY178722A (en) Catalyst component for olefin polymerization, preparation method thereof, and catalyst comprising same
MY189858A (en) Producing polyolefin products with improved stiffness, toughness, and processability
MX2010005266A (es) Composicion catalizadora y proceso para oligomerizacion de etileno.
MY172451A (en) Spherical carriers for olefin polymerization catalyst, catalyst components, catalyst, and preparation methods therefor
MX2016008059A (es) Composicion catalizadora para polimerizacion de olefinas.
EA201990936A1 (ru) Способ получения (со)полимеров сопряженных диенов в присутствии каталитической системы, содержащей пиридильный комплекс железа (iii)
BR112019005082A2 (pt) catalisadores de polimerização bimodal
EA201691031A1 (ru) Синтез макроциклического трипептида, ингибирующего hcv ns3
BR112019005191A2 (pt) catalisadores de polimerização
MX2016015210A (es) Proceso para la dimerizacion de olefinas activadas.
MY173996A (en) Oligomerisation of ethylene to mixtures of 1-hexene and 1-octene
MX2017000799A (es) Composicion de catalizador y proceso para la oligomerizacion de etileno para producir 1-hexeno y/o 1-octeno.
EA201691268A1 (ru) Каталитическая система для полимеризации олефинов
BR112016002870A2 (pt) sistema catalisador para polimerização de uma olefina
BR112018069252A2 (pt) sistemas catalisadores de polimerização de olefina e métodos de uso dos mesmos
EA201990812A1 (ru) Прокатализатор для полимеризации олефинов
BR112015027981A2 (pt) Complexo de metal, processo para produzir o complexo de metal, composto, processo para a fabricação de um composto, sistema de catalisador e processo para a preparação de um polímero polimerizando-se pelo menos um monômero olefínico
BR112018068879A2 (pt) catalisador de polimerização de olefina
BR112016012971A2 (pt) Complexo de metal-ligante, catalisador e processo para preparar uma poliolefina

Legal Events

Date Code Title Description
FG Grant or registration