MX2010005266A - Composicion catalizadora y proceso para oligomerizacion de etileno. - Google Patents

Composicion catalizadora y proceso para oligomerizacion de etileno.

Info

Publication number
MX2010005266A
MX2010005266A MX2010005266A MX2010005266A MX2010005266A MX 2010005266 A MX2010005266 A MX 2010005266A MX 2010005266 A MX2010005266 A MX 2010005266A MX 2010005266 A MX2010005266 A MX 2010005266A MX 2010005266 A MX2010005266 A MX 2010005266A
Authority
MX
Mexico
Prior art keywords
oligomerization
ethylene
catalyst composition
r1r2p
catalyst
Prior art date
Application number
MX2010005266A
Other languages
English (en)
Inventor
Fuad Mosa
Anton Wellenhofer
Peter M Fritz
Heinz Boelt
Anina Woehl
Wolfgang Mueller
Florian Winkler
Uwe Rosenthal
Bernd H Mueller
Marko Hapke
Normen Peulecke
Mohammed Hassan Al-Hazmi
Vugar Aliyev
Original Assignee
Linde Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Linde Ag filed Critical Linde Ag
Publication of MX2010005266A publication Critical patent/MX2010005266A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B01J31/188—Amide derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

La presente invención se refiere a una composición catalizadora que comprende: (a) un complejo de cromo(ll) de doble núcleo; (b) un ligando de la estructura general (A) R1R2P-N(R3)-P(R4)-N(R5)-H o (A) R1R2P-N(R3)-P(R4)-N(R5)-PR6R7, en donde R1, R2, R3, R4, R5, R6 y R7 se seleccionan independientemente de halógeno, amino, trimetilsililo, alquilo de 1 a 10 átomos de carbono, arilo y arilo sustituido, en donde la unidad PNPN o PNPNP es opcionalmente parte de un sistema de anillo; y (c) un activador o co-catalizador, así como a un proceso para la oligomerización de etileno.
MX2010005266A 2007-11-28 2008-11-05 Composicion catalizadora y proceso para oligomerizacion de etileno. MX2010005266A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07023013 2007-11-28
PCT/EP2008/009305 WO2009068157A1 (en) 2007-11-28 2008-11-05 Catalyst composition and process for oligomerization of ethylene

Publications (1)

Publication Number Publication Date
MX2010005266A true MX2010005266A (es) 2010-06-02

Family

ID=39402871

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2010005266A MX2010005266A (es) 2007-11-28 2008-11-05 Composicion catalizadora y proceso para oligomerizacion de etileno.

Country Status (13)

Country Link
US (1) US8778827B2 (es)
EP (1) EP2219784B1 (es)
JP (1) JP5462179B2 (es)
KR (1) KR101445431B1 (es)
CN (1) CN101855015B (es)
BR (1) BRPI0819904B1 (es)
CA (1) CA2703021C (es)
ES (1) ES2397303T3 (es)
MX (1) MX2010005266A (es)
MY (1) MY150515A (es)
RU (1) RU2467797C2 (es)
TW (1) TWI440503B (es)
WO (1) WO2009068157A1 (es)

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EP2354113A1 (en) 2010-02-04 2011-08-10 Linde AG Method for deactivation of a catalyst
EP2489431B1 (en) 2011-02-16 2013-05-01 Linde AG Method for preparing a catalyst composition for oligomerization of ethylene and respective catalyst composition pre-formation unit
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KR101757835B1 (ko) 2015-06-12 2017-07-13 주식회사 엘지화학 리간드 화합물, 유기 크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법
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CN107899614B (zh) * 2017-11-20 2020-05-26 常州大学 一种双核占吨桥连胺基-吡啶镍催化剂及其制备方法和应用
CN113242764B (zh) * 2018-11-12 2023-10-20 沙特基础全球技术有限公司 用于铬辅助乙烯低聚工艺中生产1-辛烯的配体
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CN114409495A (zh) * 2020-10-28 2022-04-29 中国石油天然气股份有限公司 一种乙烯四聚的方法
WO2024047612A1 (en) 2022-09-02 2024-03-07 Sabic Global Technologies B.V. Methods for producing 1-hexene

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Also Published As

Publication number Publication date
JP5462179B2 (ja) 2014-04-02
WO2009068157A1 (en) 2009-06-04
CA2703021A1 (en) 2009-06-04
BRPI0819904B1 (pt) 2018-02-06
KR20100088665A (ko) 2010-08-10
RU2010126183A (ru) 2012-01-10
CN101855015A (zh) 2010-10-06
KR101445431B1 (ko) 2014-09-26
JP2011504799A (ja) 2011-02-17
TWI440503B (zh) 2014-06-11
EP2219784B1 (en) 2012-10-24
EP2219784A1 (en) 2010-08-25
CA2703021C (en) 2015-01-20
US8778827B2 (en) 2014-07-15
RU2467797C2 (ru) 2012-11-27
US20100298618A1 (en) 2010-11-25
TW200942327A (en) 2009-10-16
ES2397303T3 (es) 2013-03-06
BRPI0819904A2 (pt) 2015-09-15
CN101855015B (zh) 2013-07-17
MY150515A (en) 2014-01-30

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