MX2016015768A - Procatalizador para la polimerizacion de olefinas. - Google Patents

Procatalizador para la polimerizacion de olefinas.

Info

Publication number
MX2016015768A
MX2016015768A MX2016015768A MX2016015768A MX2016015768A MX 2016015768 A MX2016015768 A MX 2016015768A MX 2016015768 A MX2016015768 A MX 2016015768A MX 2016015768 A MX2016015768 A MX 2016015768A MX 2016015768 A MX2016015768 A MX 2016015768A
Authority
MX
Mexico
Prior art keywords
procatalyst
polymerization
present
aralkyl
alkenyl
Prior art date
Application number
MX2016015768A
Other languages
English (en)
Inventor
Brijlal Sainani Jaiprakash
Taftaf Mansour
Aleksandrovich Zakharov Vladimir
Dimitrievich Bukatov Gennadii
Andreevich Sergeev Sergei
Alexander Zuideveld Martin
Alexandra Batinas-Geurts Aurora
Abdullah AL-BAHILY Khalid
Shirish Shrikant Abhyankar
AL-HUMAIDAN Osamah
Original Assignee
Sabic Global Technologies Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sabic Global Technologies Bv filed Critical Sabic Global Technologies Bv
Publication of MX2016015768A publication Critical patent/MX2016015768A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
    • C08F4/6565—Pretreating with metals or metal-containing compounds with silicon or compounds thereof and magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15—Isotactic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

La presente invención se refiere a un procatalizador que comprende el compuesto representado por la fórmula A como un donante interno de electrones, (ver Fórmula) en donde: R81, R82, R83, R84, R85, y R86 son iguales o diferentes y se seleccionan cada uno independientemente del grupo que consiste de hidrógeno o un grupo hidrocarbilo lineal, ramificado o cíclico, seleccionado de grupos alquilo, alquenilo, arilo, aralquilo, o alquilarilo, y una o más combinaciones de los mismos, preferiblemente que tienen de 1 a 20 átomos de carbono; R87 es un hidrógeno o un grupo hidrocarbilo lineal, ramificado o cíclico, seleccionado de entre grupos alquilo, alquenilo, arilo, aralquilo, alcoxicarbonilo o alquilarilo, y una o más combinaciones de los mismos, preferiblemente que tienen de 1 a 20 átomos de carbono; cada grupo R80 es independientemente un grupo hidrocarbilo lineal, ramificado o cíclico, seleccionado de grupos alquilo, alquenilo, arilo, aralquilo, o alquilarilo, y una o más combinaciones de los mismos, preferiblemente que tienen de 1 a 30 átomos de carbono; N es un átomo de nitrógeno; O es un átomo de oxígeno; y C es un átomo de carbono. La presente invención también se refiere a un procedimiento para preparar dicho procatalizador de polimerización y a un sistema catalizador de polimerización que comprende dicho procatalizador, un cocatalizador y opcionalmente un donante externo de electrones. Además, la presente invención se refiere a una poliolefina que puede ser obtenida mediante el procedimiento de acuerdo con la presente invención y al uso del compuesto de fórmula A como un donante interno de electrones en catalizadores para la polimerización de olefinas.
MX2016015768A 2014-06-02 2015-06-01 Procatalizador para la polimerizacion de olefinas. MX2016015768A (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP14170831 2014-06-02
US201462057260P 2014-09-30 2014-09-30
EP15161408 2015-03-27
US201562163744P 2015-05-19 2015-05-19
PCT/EP2015/062117 WO2015185489A1 (en) 2014-06-02 2015-06-01 Procatalyst for polymerization of olefins

Publications (1)

Publication Number Publication Date
MX2016015768A true MX2016015768A (es) 2017-04-10

Family

ID=54766192

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016015768A MX2016015768A (es) 2014-06-02 2015-06-01 Procatalizador para la polimerizacion de olefinas.

Country Status (8)

Country Link
US (1) US10005859B2 (es)
EP (1) EP3149056B1 (es)
KR (1) KR20170015386A (es)
CN (1) CN106471018B (es)
BR (1) BR112016026938A8 (es)
EA (1) EA036725B1 (es)
MX (1) MX2016015768A (es)
WO (1) WO2015185489A1 (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108349873B (zh) * 2015-09-22 2022-12-23 Sabic环球技术有限责任公司 取代的酰胺基苯甲酸酯化合物的合成及其作为不含邻苯二甲酸酯的内给电子体的用途
WO2017093132A1 (en) * 2015-12-02 2017-06-08 Sabic Global Technologies B.V. Process for preparing a procatalyst for polymerization of olefins
CN108495874B (zh) * 2015-12-02 2021-01-15 Sabic环球技术有限责任公司 用于烯烃聚合的主催化剂
US10836847B2 (en) 2015-12-02 2020-11-17 Sabic Global Technologies B.V. Procatalyst for polymerization of olefins
EP3519457B1 (en) 2016-09-29 2024-06-12 SABIC Global Technologies B.V. Process to prepare procatalyst for polymerization of olefins
WO2018059955A1 (en) 2016-09-29 2018-04-05 Sabic Global Technologies B.V. Process to prepare procatalyst for polymerization of olefins
US10882929B2 (en) 2016-09-29 2021-01-05 Sabic Global Technologies B.V. Procatalyst for polymerization of olefins
CN109843944B (zh) * 2016-09-29 2022-02-22 Sabic环球技术有限责任公司 用于制备用于烯烃聚合的主催化剂的方法
WO2018059750A1 (en) 2016-09-29 2018-04-05 Sabic Global Technologies B.V. Process to prepare procatalyst for polymerization of olefins
EP3519459B1 (en) 2016-09-29 2023-10-11 SABIC Global Technologies B.V. Procatalyst for polymerization of olefins
WO2018069379A1 (en) 2016-10-12 2018-04-19 Sabic Global Technologies B.V. Process to prepare a solid support for a procatalyst suitable for polymerization of olefins
CN109890850A (zh) * 2016-10-12 2019-06-14 Sabic环球技术有限责任公司 制备适用于烯烃聚合的主催化剂的固体载体的方法
EP3596136A1 (en) 2017-03-17 2020-01-22 SABIC Global Technologies B.V. Process for the polymerization of a polyolefin
WO2020060499A1 (en) * 2018-09-18 2020-03-26 Ptt Exploration And Production Public Company Limited Catalyst system for producing cyclic carbonates and method related thereto
CN114728276A (zh) 2019-11-22 2022-07-08 Sabic环球技术有限责任公司 制备烯烃聚合所用主催化剂的方法

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IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
CA1141093A (en) 1979-05-17 1983-02-08 Brian L. Goodall Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions
IT1190681B (it) 1982-02-12 1988-02-24 Montedison Spa Componenti e catalizzatori per la polimerizzazione di olefine
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JP3786138B2 (ja) 2002-08-19 2006-06-14 宇部興産株式会社 α−オレフィンの重合又は共重合に用いられるα−オレフィンの重合又は共重合用触媒、その触媒成分及びその触媒を用いたα−オレフィンの重合方法
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Also Published As

Publication number Publication date
EA201692461A1 (ru) 2017-05-31
KR20170015386A (ko) 2017-02-08
WO2015185489A1 (en) 2015-12-10
EP3149056B1 (en) 2019-02-27
EP3149056A1 (en) 2017-04-05
CN106471018B (zh) 2019-09-17
EA036725B1 (ru) 2020-12-11
CN106471018A (zh) 2017-03-01
US20170198071A1 (en) 2017-07-13
US10005859B2 (en) 2018-06-26
BR112016026938A8 (pt) 2021-05-04

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