WO2015032851A3 - Silicon-bridged pillared silicate compounds and process for their production - Google Patents

Silicon-bridged pillared silicate compounds and process for their production Download PDF

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Publication number
WO2015032851A3
WO2015032851A3 PCT/EP2014/068822 EP2014068822W WO2015032851A3 WO 2015032851 A3 WO2015032851 A3 WO 2015032851A3 EP 2014068822 W EP2014068822 W EP 2014068822W WO 2015032851 A3 WO2015032851 A3 WO 2015032851A3
Authority
WO
WIPO (PCT)
Prior art keywords
silicon
silicate
pillared
bridged
production
Prior art date
Application number
PCT/EP2014/068822
Other languages
French (fr)
Other versions
WO2015032851A2 (en
Inventor
Mathias Feyen
Roger Ruetz
Ulrich Müller
Manuela Gaab
Xinhe Bao
Weiping Zhang
Dirk De Vos
Ralf Weiss
Hermann Gies
Takashi Tatsumi
Feng-Shou Xiao
Yokoi TOSHIYUKI
Bilge Yilmaz
Trees De Baerdemaeker
Original Assignee
Basf Se
Tokyo Institute Of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se, Tokyo Institute Of Technology filed Critical Basf Se
Publication of WO2015032851A2 publication Critical patent/WO2015032851A2/en
Publication of WO2015032851A3 publication Critical patent/WO2015032851A3/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/035—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/049—Pillared clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5409—Particle size related information expressed by specific surface values
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Structural Engineering (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

The present invention relates to a process for the preparation of a pillared silicate compound comprising a layered silicate structure and bridging silicon atoms located between adjacent silicate layers of the silicate structure, wherein said bridging silicon atoms form at least one covalent bond to each of the adjacent silicate layers, said process comprising (1) providing one or more layered silicates; (2) adding said one or more layered silicates to a solvent system, wherein the resulting mixture has a pH of 5 or less; and (3) subjecting the mixture obtained in step (2) to solvothermal conditions; wherein no silicon-containing compound according to formula (I) R4-mSi[-(SiR2)n-R]m (I) is used at any point of the process up to and including step (3), wherein m is 1, 2, 3, or 4, and n is an integer greater than or equal to 0, wherein when n is equal to 0, one or more residues R are leaving groups, and wherein none of the residues R contains Si, as well as to a pillared silicate compound per se, preferably as obtained and/or obtainable according to the inventive process as well as to the use of the inventive compounds. A further process is disclosed wherein a sulfur oxoacid is present in step (2), and wherein a silicon-containing compound may or may not be used.
PCT/EP2014/068822 2013-09-06 2014-09-04 Silicon-bridged pillared silicate compounds and process for their production WO2015032851A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN2013083045 2013-09-06
CNPCT/CN2013/083045 2013-09-06

Publications (2)

Publication Number Publication Date
WO2015032851A2 WO2015032851A2 (en) 2015-03-12
WO2015032851A3 true WO2015032851A3 (en) 2015-06-04

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Family Applications (1)

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016128917A1 (en) 2015-02-12 2016-08-18 Basf Se Process for the preparation of a dealuminated zeolitic material having the bea framework structure
MX2017014148A (en) 2015-05-04 2018-03-15 Basf Se Process for the preparation of melonal.
MX2018000606A (en) 2015-07-15 2018-05-28 Basf Se Process for preparing an arylpropene.
CN105536864B (en) * 2016-01-13 2018-05-04 太原理工大学 The preparation method of ZSM-5/EU-1 composite molecular screens with core shell structure feature
CN110577239B (en) * 2019-09-03 2020-08-04 华北电力大学 Method for preparing two-dimensional metal oxide nanosheet by utilizing interlayer confinement strategy

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5980849A (en) * 1996-09-09 1999-11-09 Kabushiki Kaisha Toyota Chuo Kenkyusho Mesopore material, laminar silicic acid, and method of manufacturing mesopore material and laminar silicic acid
JP2008137857A (en) * 2006-12-03 2008-06-19 National Institute Of Advanced Industrial & Technology Method for producing high silica nanoporous body by acid-treating crystalline layered silicate at high temperature, and the high silica nanoporous body
US20110319250A1 (en) * 2009-03-03 2011-12-29 Tokyo Institute Of Technology Process For The Preparation Of Pillared Silicates
US20120004332A1 (en) * 2010-07-02 2012-01-05 Tokyo Institute Of Technology Metal-Bridged Pillared Silicate Compounds And Process For Their Production

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5980849A (en) * 1996-09-09 1999-11-09 Kabushiki Kaisha Toyota Chuo Kenkyusho Mesopore material, laminar silicic acid, and method of manufacturing mesopore material and laminar silicic acid
JP2008137857A (en) * 2006-12-03 2008-06-19 National Institute Of Advanced Industrial & Technology Method for producing high silica nanoporous body by acid-treating crystalline layered silicate at high temperature, and the high silica nanoporous body
US20110319250A1 (en) * 2009-03-03 2011-12-29 Tokyo Institute Of Technology Process For The Preparation Of Pillared Silicates
US20120004332A1 (en) * 2010-07-02 2012-01-05 Tokyo Institute Of Technology Metal-Bridged Pillared Silicate Compounds And Process For Their Production

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
FENG-SHOU XIAO ET AL: "Interlayer-Expanded Microporous Titanosilicate Catalysts with Functionalized Hydroxyl Groups", CHEMCATCHEM, vol. 3, no. 9, 11 July 2011 (2011-07-11), pages 1442 - 1446, XP055155851, ISSN: 1867-3880, DOI: 10.1002/cctc.201100144 *
HERMANN GIES ET AL: "Interlayer Expansion of the Hydrous Layer Silicate RUB-36 to a Functionalized, Microporous Framework Silicate: Crystal Structure Analysis and Physical and Chemical Characterization", CHEMISTRY OF MATERIALS, vol. 24, no. 8, 24 April 2012 (2012-04-24), pages 1536 - 1545, XP055153244, ISSN: 0897-4756, DOI: 10.1021/cm300525u *
TAKUJI IKEDA ET AL: "Structure Analysis of Si-Atom Pillared Lamellar Silicates Having Micropore Structure by Powder X-ray Diffraction", JOURNAL OF PHYSICAL CHEMISTRY C, vol. 114, no. 8, 4 March 2010 (2010-03-04), pages 3466 - 3476, XP055153252, ISSN: 1932-7447, DOI: 10.1021/jp912026n *

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