AU2003300566B2 - Phenolic antioxidants in crystalline form - Google Patents

Phenolic antioxidants in crystalline form Download PDF

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Publication number
AU2003300566B2
AU2003300566B2 AU2003300566A AU2003300566A AU2003300566B2 AU 2003300566 B2 AU2003300566 B2 AU 2003300566B2 AU 2003300566 A AU2003300566 A AU 2003300566A AU 2003300566 A AU2003300566 A AU 2003300566A AU 2003300566 B2 AU2003300566 B2 AU 2003300566B2
Authority
AU
Australia
Prior art keywords
butyl
bis
tert
polyoxyethylene
sorbitan
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU2003300566A
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English (en)
Other versions
AU2003300566A1 (en
Inventor
Christian Guckel
Daniel Rehm
Johannes Schafter
Paul Adriaan Van Der Schaaf
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of AU2003300566A1 publication Critical patent/AU2003300566A1/en
Assigned to BASF SE reassignment BASF SE Request for Assignment Assignors: CIBA SPECIALTY CHEMICALS HOLDING INC.
Application granted granted Critical
Publication of AU2003300566B2 publication Critical patent/AU2003300566B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/22—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/22—Separation; Purification; Stabilisation; Use of additives
    • C07C231/24—Separation; Purification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
    • C07C69/732—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids of unsaturated hydroxy carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/20—Carboxylic acid amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/005—Additives being defined by their particle size in general

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)
AU2003300566A 2002-11-26 2003-11-17 Phenolic antioxidants in crystalline form Ceased AU2003300566B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP02406023 2002-11-26
EP02406023.8 2002-11-26
PCT/EP2003/050838 WO2004048312A1 (en) 2002-11-26 2003-11-17 Phenolic antioxidants in crystalline form

Publications (2)

Publication Number Publication Date
AU2003300566A1 AU2003300566A1 (en) 2004-06-18
AU2003300566B2 true AU2003300566B2 (en) 2010-01-21

Family

ID=32338231

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2003300566A Ceased AU2003300566B2 (en) 2002-11-26 2003-11-17 Phenolic antioxidants in crystalline form

Country Status (11)

Country Link
US (1) US7262319B2 (enExample)
EP (1) EP1575895A1 (enExample)
JP (1) JP2006507337A (enExample)
KR (1) KR20050085019A (enExample)
CN (1) CN100448838C (enExample)
AU (1) AU2003300566B2 (enExample)
BR (1) BR0316567A (enExample)
MY (1) MY136146A (enExample)
RU (1) RU2362764C2 (enExample)
TW (1) TWI308145B (enExample)
WO (1) WO2004048312A1 (enExample)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006014605A2 (en) * 2004-07-23 2006-02-09 Polnox Corporation Anti-oxidant macromonomers and polymers and methods of making and using the same
JP2008508231A (ja) 2004-07-27 2008-03-21 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド フェノール系抗酸化剤の固体粒子を調製する方法
US7902317B2 (en) 2004-12-03 2011-03-08 Polnox Corporation Synthesis of aniline and phenol-based antioxidant macromonomers and corresponding polymers
WO2006091705A2 (en) 2005-02-22 2006-08-31 Polnox Corporation Nitrogen and hindered phenol containing dual functional macromolecular antioxidants: synthesis , performances and applications
US7705185B2 (en) 2005-03-25 2010-04-27 Polnox Corporation Alkylated and polymeric macromolecular antioxidants and methods of making and using the same
EP1966293A1 (en) 2005-10-27 2008-09-10 Polnox Corporation Stabilized polyolefin compositions
WO2007050985A2 (en) 2005-10-27 2007-05-03 Polnox Corporation Macromolecular antioxidants based on stξrically hindered phenolic phosphites
US20070161522A1 (en) 2005-12-02 2007-07-12 Cholli Ashok L Lubricant oil compositions
WO2008005358A2 (en) 2006-07-06 2008-01-10 Polnox Corporation Novel macromolecular antioxidants comprising differing antioxidant moieties: structures, methods of making and using the same
US7767853B2 (en) 2006-10-20 2010-08-03 Polnox Corporation Antioxidants and methods of making and using the same
WO2008055832A2 (en) * 2006-11-09 2008-05-15 Ciba Holding Inc. Process using liquid phenolic antioxidants
KR101211231B1 (ko) * 2008-08-21 2012-12-11 주식회사 엘지화학 산화방지제 유성 분산액과 이의 제조방법 및 이로부터 제조된 염화비닐계 수지 중합체
JP5330904B2 (ja) * 2009-06-12 2013-10-30 住友化学株式会社 粒状物質の製造方法
BR112013023637B1 (pt) * 2011-03-14 2020-12-15 Dow Global Technologies Llc Composição e artigo
JP5542289B2 (ja) * 2012-01-23 2014-07-09 トヨタ自動車株式会社 オイル添加物およびオイルフィルター
US10294423B2 (en) 2013-11-22 2019-05-21 Polnox Corporation Macromolecular antioxidants based on dual type moiety per molecule: structures, methods of making and using the same
US20180251695A1 (en) 2017-03-01 2018-09-06 Polnox Corporation Macromolecular Corrosion (McIn) Inhibitors: Structures, Methods Of Making And Using The Same
EP3609861A1 (en) 2017-04-10 2020-02-19 Basf Se Low volatile organic anti-oxidation stabilisers for polymeric systems, their production and use
CN107417528A (zh) * 2017-05-02 2017-12-01 沈阳化工大学 一种抗氧剂1076在甲醇溶剂中得到针状晶形结晶的方法
CN111495312B (zh) * 2020-05-22 2023-07-28 河南心连心化学工业集团股份有限公司 一种草酰胺合成装置以及合成方法
KR102771644B1 (ko) * 2022-06-21 2025-02-26 금호석유화학 주식회사 산화방지제의 제조방법

Family Cites Families (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3644482A (en) * 1961-10-30 1972-02-22 Geigy Ag J R (4-hydroxy-5-alkylphenyl) alkanoic acid esters of polyols
GB1123505A (en) * 1966-01-10 1968-08-14 Sankyo Co Method for the production of microcrystals of chloramphenicol
US3666809A (en) * 1969-10-08 1972-05-30 Mitsubishi Chem Ind Method for the production of acrylamide crystals
US3867414A (en) * 1969-12-04 1975-02-18 Yamanouchi Pharma Co Ltd Process for the preparation of suspensions of microcrystals of chloramphenicol palmitate
AT303971B (de) * 1969-12-04 1972-12-27 Yamanouchi Pharma Co Ltd Verfahren zur Herstellung einer Suspension von Chloramphenicol-palmitat in mikrokristalliner Form
JPS6013018B2 (ja) * 1980-04-01 1985-04-04 三井化学株式会社 新規な結晶構造を有するテトラキス〔３−（３，５−ジ−ｔ−ブチル−４−ヒドロキシフエニル）プロピオニルオキシメチル〕メタン
JPS6013017B2 (ja) * 1980-01-14 1985-04-04 三井化学株式会社 テトラキス〔３−（３，５−ジ−ｔ−ブチル−４−ヒドロキシフエニル）プロピオニルオキシメチル〕メタンの製造方法
US4405807A (en) * 1980-01-14 1983-09-20 Mitsui Petrochemical Industries, Ltd. Tetrakis[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionyloxymethyl]methane having a novel crystal structure and process for production thereof
JPS57197245A (en) * 1981-05-28 1982-12-03 Mitsui Petrochem Ind Ltd Tetrakis(3-(3,5-dibutyl-4-hydroxyphenyl) propionyloxymethyl)methane
JPS5974182A (ja) * 1982-10-20 1984-04-26 Sumitomo Chem Co Ltd 複合酸化防止剤の球状製品の製造法
JPS6063274A (ja) * 1983-09-16 1985-04-11 Mitsui Toatsu Chem Inc 酸化防止剤分散液
JPH0689171B2 (ja) * 1984-03-07 1994-11-09 三井東圧化学株式会社 酸化防止剤分散液の製造方法
DE3673055D1 (de) * 1985-05-02 1990-09-06 Ciba Geigy Ag Verfahren zum stabilisieren von kugelfoermig polymerisierten polyolefinen.
US4683326A (en) * 1985-07-19 1987-07-28 Ciba-Geigy Corporation Solvent-free crystallization of pentaerythritol tetrakis-[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate] and the novel alpha-crystalline form thereof
JPH0657676B2 (ja) * 1986-04-30 1994-08-03 ムサシノガイギ−株式会社 独立粒子状β晶テトラキス〔３−（３，５−ジ−ｔ−ブチル−４−ヒドロキシフエニル）プロピオニルオキシメチル〕メタンおよびその製造方法
JPS63159315A (ja) * 1986-12-22 1988-07-02 Yuutoku Yakuhin Kogyo Kk パツプ剤
EP0366808B1 (en) * 1988-03-31 1994-06-15 Yoshitomi Pharmaceutical Industries, Ltd. Method of crystallization and purification for obtaining stable crystalls of tetrakis 3-(3,5-di-tertiary-butyl-4-hydroxyphenyl)propionyloxymethyl- methane on an industrial scale
JPH075518B2 (ja) * 1988-03-31 1995-01-25 吉富製薬株式会社 テトラキス〔３―（３，５―ジ第３級ブチル―４―ヒドロキシフェニル）プロピオニルオキシメチル〕メタンのβ晶の晶出精製方法
US4847585A (en) 1988-05-20 1989-07-11 Mosebach Manufacturing Company Center ventilated resistor grid
JP2736265B2 (ja) * 1989-06-08 1998-04-02 吉富製薬株式会社 粉体特性の優れたα晶テトラキス〔３―（３，５―ジ―ｔ―ブチル―４―ヒドロキシフェニル）プロピオニルオキシメチル〕メタンの製造法
JPH085844B2 (ja) * 1989-06-08 1996-01-24 吉富製薬株式会社 流動性の優れたα晶テトラキス〔３―（３，５―ジ―ｔ―ブチル―４―ヒドロキシフェニル）プロピオニルオキシメチル〕メタンおよびその製造方法
US5204022A (en) * 1989-08-11 1993-04-20 Eastman Kodak Company Solid-form additive systems dispersible in aqueous media
JP2819163B2 (ja) * 1989-08-25 1998-10-30 旭電化工業株式会社 ラテックス用酸化防止剤分散液
JPH03146563A (ja) * 1989-11-01 1991-06-21 Adeka Argus Chem Co Ltd ラテックス用酸化防止剤分散液
JP3024802B2 (ja) * 1991-02-04 2000-03-27 ポリプラスチックス株式会社 ポリアセタール樹脂着色組成物
JPH05271516A (ja) * 1992-03-26 1993-10-19 Polyplastics Co ポリオキシメチレン組成物
CA2092952A1 (en) * 1992-03-31 1993-10-01 Pak S. Leung Dispersions of polymer additives in fatty acid esters
JPH0625430A (ja) * 1992-07-09 1994-02-01 Yoshitomi Pharmaceut Ind Ltd 有機材料の安定化処理法
JP3215728B2 (ja) * 1992-10-15 2001-10-09 旭電化工業株式会社 テトラキス〔３−（３，５−ジ第三ブチル−４−ヒドロキシフェニル）プロピオニルオキシメチル〕メタンの製造方法
DE19523115A1 (de) * 1995-06-26 1997-01-02 Hoechst Ag Dispersionspulver mit erhöhter Selbstentzündungstemperatur
GB9624615D0 (en) * 1996-11-26 1997-01-15 Zeneca Ltd Chrystallisation process
AU7043298A (en) * 1997-04-15 1998-11-11 Ciba Specialty Chemicals Holding Inc. Preparation of low-dust stabilisers
FR2775903B1 (fr) * 1998-03-12 2001-06-08 Lhd Lab Hygiene Dietetique Masse hydrocolloide a absorption accrue des les premieres heures d'utilisation

Also Published As

Publication number Publication date
TWI308145B (en) 2009-04-01
RU2005120164A (ru) 2006-04-27
MY136146A (en) 2008-08-29
WO2004048312A1 (en) 2004-06-10
US20060189820A1 (en) 2006-08-24
EP1575895A1 (en) 2005-09-21
CN1717385A (zh) 2006-01-04
AU2003300566A1 (en) 2004-06-18
RU2362764C2 (ru) 2009-07-27
CN100448838C (zh) 2009-01-07
JP2006507337A (ja) 2006-03-02
US7262319B2 (en) 2007-08-28
KR20050085019A (ko) 2005-08-29
TW200415234A (en) 2004-08-16
BR0316567A (pt) 2005-10-04

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Legal Events

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PC1 Assignment before grant (sect. 113)

Owner name: BASF SE

Free format text: FORMER APPLICANT(S): CIBA SPECIALTY CHEMICALS HOLDING INC.

FGA Letters patent sealed or granted (standard patent)
MK14 Patent ceased section 143(a) (annual fees not paid) or expired