ATE405535T1 - Verfahren zur herstellung von phenol und methylethylketon - Google Patents

Verfahren zur herstellung von phenol und methylethylketon

Info

Publication number
ATE405535T1
ATE405535T1 AT05770053T AT05770053T ATE405535T1 AT E405535 T1 ATE405535 T1 AT E405535T1 AT 05770053 T AT05770053 T AT 05770053T AT 05770053 T AT05770053 T AT 05770053T AT E405535 T1 ATE405535 T1 AT E405535T1
Authority
AT
Austria
Prior art keywords
produce
producing phenol
butylbenzene
hydroperoxide
sec
Prior art date
Application number
AT05770053T
Other languages
English (en)
Inventor
Jane Cheng
John Buchanan
Doron Levin
Michael Steckel
Jihad Dakka
James Stokes
John Robbins
Jon Stanat
Charles Smith
Jose Santiesteban
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Application granted granted Critical
Publication of ATE405535T1 publication Critical patent/ATE405535T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/08Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/02Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with no unsaturation outside the aromatic ring
    • C07C39/04Phenol
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00Peroxy compounds
    • C07C409/02Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C07C409/08Compounds containing six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
AT05770053T 2004-08-13 2005-08-05 Verfahren zur herstellung von phenol und methylethylketon ATE405535T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US60166104P 2004-08-13 2004-08-13

Publications (1)

Publication Number Publication Date
ATE405535T1 true ATE405535T1 (de) 2008-09-15

Family

ID=34956214

Family Applications (1)

Application Number Title Priority Date Filing Date
AT05770053T ATE405535T1 (de) 2004-08-13 2005-08-05 Verfahren zur herstellung von phenol und methylethylketon

Country Status (10)

Country Link
US (1) US7799956B2 (de)
EP (1) EP1778605B1 (de)
JP (1) JP5051898B2 (de)
KR (1) KR101116523B1 (de)
CN (1) CN101006033B (de)
AT (1) ATE405535T1 (de)
DE (1) DE602005009207D1 (de)
ES (1) ES2313385T3 (de)
TW (1) TWI376361B (de)
WO (1) WO2006015826A1 (de)

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5537813B2 (ja) 2006-02-14 2014-07-02 エクソンモービル・ケミカル・パテンツ・インク Mcm−22型モレキュラーシーブの製造方法
TW200744986A (en) * 2006-02-14 2007-12-16 Exxonmobil Chemical Patents Inc Process for producing phenol and methyl ethyl ketone
WO2007094938A1 (en) 2006-02-14 2007-08-23 Exxonmobil Chemical Patents Inc. An mcm-22 family molecular sieve composition
TW200744985A (en) * 2006-02-14 2007-12-16 Exxonmobil Chemical Patents Inc Process for producing sec-butylbenzene
WO2007093359A1 (en) * 2006-02-14 2007-08-23 Exxonmobil Chemical Patents Inc. Process for producing sec-butylbenzene
CN102527428B (zh) 2006-02-14 2014-11-26 埃克森美孚化学专利公司 制备分子筛组合物的方法
US7834218B2 (en) * 2006-02-14 2010-11-16 Exxonmobil Chemical Patents Inc. Process for producing phenol and methyl ethyl ketone
US7959899B2 (en) 2006-07-28 2011-06-14 Exxonmobil Chemical Patents Inc. Molecular sieve composition (EMM-10-P), its method of making, and use for hydrocarbon conversions
US7417003B2 (en) 2006-12-29 2008-08-26 Uop Llc Solid acid catalyst and process for decomposition of cumene hydroperoxide
CA2675264C (en) * 2007-02-09 2013-04-02 Exxonmobil Chemical Patents Inc. Improved alkylaromatic production process
TW200846312A (en) * 2007-02-22 2008-12-01 Exxonmobil Chem Patents Inc Oxidation of sec-butylbenzene and production of phenol and methyl ethyl ketone
WO2008101616A1 (en) * 2007-02-22 2008-08-28 Exxonmobil Chemical Patents Inc. Production of alkylaromatic compounds
TW200904789A (en) 2007-04-19 2009-02-01 Exxonmobil Chem Patents Inc Process for oxidizing alkylaromatic compounds
US7692046B2 (en) 2007-06-21 2010-04-06 Exxonmobil Chemical Patents Inc. Heterogeneous arylalkyl oxidation promoter
CN101743222A (zh) * 2007-07-16 2010-06-16 埃克森美孚化学专利公司 氧化烷基芳族化合物的方法
US8470289B2 (en) 2007-07-16 2013-06-25 Exxonmobil Chemical Patents Inc. Manganese oxides and their use in the oxidation of alkanes
US8487138B2 (en) 2007-08-22 2013-07-16 Exxonmobil Chemical Patents Inc. Oxidation of hydrocarbons
KR20100044900A (ko) 2007-08-22 2010-04-30 엑손모빌 케미칼 패턴츠 인코포레이티드 2급 부틸벤젠의 제조 방법
US8398955B2 (en) 2007-10-26 2013-03-19 Exxonmobil Chemical Patents Inc. Method of preparing a molecular sieve composition
EP2098498A1 (de) * 2008-03-04 2009-09-09 ExxonMobil Chemical Patents Inc. Selektive Oligomerisierung von Isobuten
US8658835B2 (en) 2007-10-31 2014-02-25 Exxonmobil Chemical Patents Inc. Oxidation of hydrocarbons
US8658839B2 (en) 2007-10-31 2014-02-25 Exxonmobil Chemical Patents Inc. Oxidation of hydrocarbons
US8658836B2 (en) 2007-10-31 2014-02-25 Exxonmobil Chemical Patents Inc. Oxidation of hydrocarbons
WO2009067331A2 (en) 2007-11-16 2009-05-28 Exxonmobil Chemical Patents Inc. Catalyst regeneration process
ES2392015T3 (es) * 2008-02-12 2012-12-03 Exxonmobil Chemical Patents Inc. Procedimiento para producir ciclohexilbenceno
WO2010014405A1 (en) 2008-07-28 2010-02-04 Exxonmobil Chemical Patents Inc. Process of making alkylaromatics using emm-12
CA2729266C (en) 2008-07-28 2013-06-25 Exxonmobil Chemical Patents Inc. A novel molecular sieve composition emm-13, a method of making and a process of using the same
CN102112397B (zh) 2008-07-28 2016-12-21 埃克森美孚化学专利公司 一种新型分子筛组合物emm‑12、其制备方法和使用方法
ES2699702T3 (es) 2008-07-28 2019-02-12 Exxonmobil Chemical Patents Inc Procedimiento de preparación de compuestos alquilaromáticos usando EMM-13
JP2011525195A (ja) * 2008-08-26 2011-09-15 エクソンモービル・ケミカル・パテンツ・インク アルキルベンゼンヒドロペルオキシドの製造方法
CN102177120B (zh) 2008-10-10 2015-01-28 埃克森美孚化学专利公司 烃的氧化
CN102177126A (zh) 2008-10-10 2011-09-07 埃克森美孚化学专利公司 制备苯酚和甲乙酮的方法
CN102177110A (zh) * 2008-10-10 2011-09-07 埃克森美孚化学专利公司 用于生产仲丁基苯的方法
JP5486010B2 (ja) 2008-10-10 2014-05-07 エクソンモービル・ケミカル・パテンツ・インク フェノールの製造方法
CN102227405A (zh) 2008-12-15 2011-10-26 埃克森美孚化学专利公司 烷基芳族化合物的氧化
US20100160704A1 (en) * 2008-12-19 2010-06-24 Robert Schmidt Alkylation of aromatics with high activity catalyst
JP5817061B2 (ja) 2009-02-26 2015-11-18 エクソンモービル・ケミカル・パテンツ・インク フェノールの製造方法
US8518847B2 (en) * 2009-09-30 2013-08-27 Uop Llc Aromatic alkylation catalyst
US9321710B2 (en) 2010-01-25 2016-04-26 Exxonmobil Chemical Patents Inc. Process for producing phenol
WO2012036824A1 (en) 2010-09-14 2012-03-22 Exxonmobil Chemical Patents Inc. Oxidation of alkylbenzenes and cycloalkylbenzenes
EP2616436B1 (de) 2010-09-14 2018-05-30 ExxonMobil Chemical Patents Inc. Oxidation von cyclohexylbenzol
US9388102B2 (en) 2011-04-19 2016-07-12 Exxonmobil Chemical Patents Inc. Process for producing phenol
CN103492072B (zh) * 2011-04-19 2016-01-20 埃克森美孚化学专利公司 苯酚的制备方法
WO2013052217A2 (en) 2011-10-07 2013-04-11 Exxonmobil Chemical Patents Inc. Mixed metal oxide catalysts and use thereof
CN103102240B (zh) * 2011-11-14 2015-02-25 中国石油化工股份有限公司 一种仲丁基苯的合成方法
CN102826980B (zh) * 2012-09-04 2014-10-15 华东理工大学 2,3-丁二醇气相脱水制备甲乙酮的方法
US9272974B2 (en) 2012-09-17 2016-03-01 Exxonmobil Chemical Patents Inc. Process for producing phenol and/or cyclohexanone from cyclohexylbenzene
EP2895443A1 (de) 2012-09-17 2015-07-22 ExxonMobil Chemical Patents Inc. Verfahren zur herstellung von phenol und/oder cyclohexanon aus cyclohexylbenzol
CN103739437B (zh) * 2012-10-17 2015-10-21 中国石油化工股份有限公司 用于混合碳四和苯生产非苯芳烃的方法
WO2017042088A1 (en) 2015-09-07 2017-03-16 Sabic Global Technologies B.V. Process for producing cumene and/or sec-butylbenzene using a mixed olefins stream as alkylation agent
CN105251529B (zh) * 2015-11-25 2017-09-12 广东工业大学 一种负载型催化剂及其制备方法与催化长链烷基酚的合成方法
CN109180437A (zh) 2018-09-06 2019-01-11 常州大学 管式连续流反应器中过氧化氢异丙苯分解制备苯酚的方法

Family Cites Families (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2584103A (en) * 1949-07-16 1952-02-05 Universal Oil Prod Co Alkylation of aromatic hydrocarbons
SU265349A1 (ru) 1968-08-03 1976-10-05 Институт Органической Химии Им.Н.Д. Зелинского Способ получени втор-бутилбензола
DE2300903A1 (de) * 1972-01-10 1973-08-02 Union Carbide Corp Verfahren zur herstellung von butylbenzolhydroperoxid und dessen verwendung zur herstellung von phenol, acetophenon und methylaethylketon
US3819735A (en) * 1972-02-04 1974-06-25 Union Carbide Corp Alkylation catalyst and process of alkylating benzene
SU417405A1 (ru) 1972-05-26 1974-02-28 Я. И. Исаков, М. Миначев, Я. Т. Эйдус, А. Л. Лапидус , В. П. Калинин Способ совместного получения этилбензола и вторичного бутилбензола
US4051191A (en) * 1977-01-03 1977-09-27 Uop Inc. Solid phosphoric acid catalyzed alkylation of aromatic hydrocarbons
SU1245564A1 (ru) 1982-06-24 1986-07-23 Ордена Трудового Красного Знамени Институт Нефтехимических Процессов Им.Ю.Г.Мамедалиева Способ получени вторичного бутилбензола
US4490565A (en) * 1983-05-06 1984-12-25 Mobil Oil Corporation Production of phenol
US4490566A (en) * 1983-05-06 1984-12-25 Mobil Oil Corporation Production of phenol
US4891458A (en) * 1987-12-17 1990-01-02 Innes Robert A Liquid phase alkylation or transalkylation process using zeolite beta
US4992606A (en) * 1988-10-06 1991-02-12 Mobil Oil Corp. Process for preparing short chain alkyl aromatic compounds
JP2797609B2 (ja) * 1989-04-25 1998-09-17 住友化学工業株式会社 sec―ブチルベンゼンの製造方法
CA2015191A1 (en) * 1989-04-25 1990-10-25 Kazuhiro Yamauchi Process for production of sec-butylbenzene
JP2884820B2 (ja) * 1990-09-10 1999-04-19 住友化学工業株式会社 sec−ブチルベンゼンの製造法
US5236575A (en) * 1991-06-19 1993-08-17 Mobil Oil Corp. Synthetic porous crystalline mcm-49, its synthesis and use
US5545788A (en) * 1991-06-19 1996-08-13 Mobil Oil Corporation Process for the alkylation of benzene-rich reformate using MCM-49
US5183945A (en) * 1991-11-18 1993-02-02 Exxon Research And Engineering Company Catalytic production of aryl alkyl hydroperoxides by manganese complexes
JP3225605B2 (ja) * 1992-07-14 2001-11-05 住友化学工業株式会社 フェノール及びメチルエチルケトンの製造方法
JP3089779B2 (ja) * 1991-12-26 2000-09-18 住友化学工業株式会社 フェノール及びメチルエチルケトンの製造方法
JPH05229972A (ja) * 1991-12-26 1993-09-07 Sumitomo Chem Co Ltd フェノール及びメチルエチルケトンの製造方法
TW226011B (de) * 1991-12-26 1994-07-01 Sumitomo Chemical Co
US5177283A (en) * 1992-02-03 1993-01-05 Uop Hydrocarbon conversion process
JPH06256238A (ja) * 1993-03-05 1994-09-13 Sumitomo Chem Co Ltd フェノール及びメチルエチルケトンの製造方法
JP3367056B2 (ja) * 1992-07-07 2003-01-14 住友化学工業株式会社 フェノール及びメチルエチルケトンの製造方法
US5362697A (en) * 1993-04-26 1994-11-08 Mobil Oil Corp. Synthetic layered MCM-56, its synthesis and use
US5336820A (en) * 1993-08-11 1994-08-09 Mobil Oil Corporation Process for the alkylation of benzene-rich gasoline
WO1996004225A1 (en) * 1994-08-03 1996-02-15 Asahi Kasei Kogyo Kabushiki Kaisha METHOD OF LIQUID-PHASE ALKYLATION OF AROMATIC HYDROCARBON BY USING β-ZEOLITE
US5504256A (en) * 1995-03-10 1996-04-02 Exxon Research And Engineering Company Catalytic production of aryl alkyl hydroperoxides by polynuclear transition metal aggregates (LAW229)
US6162416A (en) * 1996-07-12 2000-12-19 Uop Llc Zeolite beta and its use in aromatic alkylation
JP2000516248A (ja) * 1996-08-20 2000-12-05 ザ ダウ ケミカル カンパニー アルキル化ベンゼンの製造方法
DE69705958T2 (de) * 1996-09-06 2002-04-04 Exxon Chemical Patents Inc Alkylierungsverfahren in dem zeolith beta verwendet wird
US6051521A (en) * 1998-08-25 2000-04-18 Mobil Oil Corporation Method of producing an aromatics alkylation catalyst
US6169215B1 (en) * 1999-03-25 2001-01-02 Mobil Oil Corporation Production of phenol
US6169216B1 (en) * 1999-04-22 2001-01-02 Mobil Oil Corporation Production of phenol
US6297406B1 (en) * 1999-08-03 2001-10-02 Mobil Oil Corporation Production of phenol
DE19946888A1 (de) 1999-09-30 2001-04-05 Phenolchemie Gmbh & Co Kg Verfahren zur Herstellung von Phenol, Aceton und Methylethylketon
US6410804B1 (en) * 1999-12-21 2002-06-25 Exxon Mobil Oil Corporation Production of phenol using reactive distillation
DE10015874A1 (de) * 2000-03-30 2001-10-11 Creavis Tech & Innovation Gmbh Verfahren zur Herstellung von aromatischen Alkoholen insbesondere Phenol
JP2002282698A (ja) 2001-03-29 2002-10-02 Mitsui Chemicals Inc 固体に担持したn−ヒドロキシフタルイミド触媒

Also Published As

Publication number Publication date
CN101006033B (zh) 2011-10-12
WO2006015826A1 (en) 2006-02-16
EP1778605A1 (de) 2007-05-02
ES2313385T3 (es) 2009-03-01
TWI376361B (en) 2012-11-11
US7799956B2 (en) 2010-09-21
DE602005009207D1 (de) 2008-10-02
EP1778605B1 (de) 2008-08-20
KR101116523B1 (ko) 2012-02-28
CN101006033A (zh) 2007-07-25
KR20070057173A (ko) 2007-06-04
JP5051898B2 (ja) 2012-10-17
TW200619180A (en) 2006-06-16
JP2008509178A (ja) 2008-03-27
US20080086018A1 (en) 2008-04-10

Similar Documents

Publication Publication Date Title
ATE405535T1 (de) Verfahren zur herstellung von phenol und methylethylketon
ATE455741T1 (de) Verfahren zur herstellung von sek.-butylbenzol
ATE510808T1 (de) Verfahren zur herstellung von sec-butylbenzol
BR9813760A (pt) Processo para a sìntese de 1,3-dióis
ATE523479T1 (de) Verfahren zur herstellung von cyclohexylbenzen
DE60223921D1 (de) Verfahren zur selektiven herstellung von meta-diisopropylbenzol
DE69511256T2 (de) Verfahren zur herstellung von phenol und seinen derivaten
TWI365180B (en) Alkylaromatics production
ATE479646T1 (de) Verfahren zur herstellung von phenol und methylethylketon
BR9306794A (pt) Uso de zeólito beta contendo titánio como catalisador zeólito beta contendo titánio e processo para a produção de ácido adípico
BRPI0414092A (pt) processo para a produção de hidrocarbonetos de cadeia ramificada de metanol e/ou éter de dimetila
ATE330925T1 (de) Verfahren zur herstellung von phenol und aceton durch zersetzung von cumolhydroperoxyd
DE69902783T2 (de) Stabilisierte, wässrige phenolharz-bindemittel für mineralwolle und verfahren zur herstellung von mineralwolleprodukten
TW200616939A (en) Production of bisphenol-a
DE60328036D1 (de) Verfahren zur alkylierung von aromatischen verbindungen
DE602004010013D1 (de) Presslinge aus aromatischem Polycarbonatharz für Lichtleiterplatte, Lichtleiterplatte, Verfahren zur Herstellung einer Lichtleiterplatte und Oberflächenlichtquelle welche diese benutzt.
ATE381525T1 (de) Verfahren zur herstellung von alkylaromatischen verbindungen
DE60100719D1 (de) Kontinuierliche Hydrierung von aromatischen Nitroverbindungen unter Verwendung eines Katalysators mit geringem Gehalt an Aluminium
BR0010837B1 (pt) processo para tratar uma composição compreendendo trimetilolalcano bis-monolinear formal.
WO2010042269A8 (en) Process for producing phenol and methyl ethyl ketone
ATE258153T1 (de) Verfahren zur katalytischen hydroxylierung von aromatischen verbindungen
EA200900932A1 (ru) Композиция катализатора цеолит-каолин
ATE459590T1 (de) Verfahren zur herstellung von 1,1,1-tris(4- hydroxyphenyl)alkanen
DE60127192D1 (de) Katalysatoren für die Herstellung von Olefinen durch oxidative Dehydrierung
ES2139418T3 (es) Procedimiento para la purificacion de dialdehido o-ftalico.

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties