ATE506335T1 - Verfahren zur herstellung von cyclohexylbenzol - Google Patents
Verfahren zur herstellung von cyclohexylbenzolInfo
- Publication number
- ATE506335T1 ATE506335T1 AT08797656T AT08797656T ATE506335T1 AT E506335 T1 ATE506335 T1 AT E506335T1 AT 08797656 T AT08797656 T AT 08797656T AT 08797656 T AT08797656 T AT 08797656T AT E506335 T1 ATE506335 T1 AT E506335T1
- Authority
- AT
- Austria
- Prior art keywords
- cyclohexylbenzene
- benzene
- hydrogen
- reaction zone
- catalyst system
- Prior art date
Links
- HHNHBFLGXIUXCM-GFCCVEGCSA-N cyclohexylbenzene Chemical compound [CH]1CCCC[C@@H]1C1=CC=CC=C1 HHNHBFLGXIUXCM-GFCCVEGCSA-N 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 238000002441 X-ray diffraction Methods 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000002808 molecular sieve Substances 0.000 abstract 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/74—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition with simultaneous hydrogenation
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/44—Palladium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/46—Ruthenium, rhodium, osmium or iridium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/755—Nickel
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
- C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
- C07C2529/74—Noble metals
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US97431207P | 2007-09-21 | 2007-09-21 | |
| PCT/US2008/072843 WO2009038900A1 (en) | 2007-09-21 | 2008-08-12 | Process for producing cyclohexylbenzene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE506335T1 true ATE506335T1 (de) | 2011-05-15 |
Family
ID=40032532
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT08797656T ATE506335T1 (de) | 2007-09-21 | 2008-08-12 | Verfahren zur herstellung von cyclohexylbenzol |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US7847128B2 (de) |
| EP (1) | EP2200955B1 (de) |
| JP (1) | JP5192546B2 (de) |
| KR (1) | KR101151978B1 (de) |
| CN (1) | CN101754940B (de) |
| AT (1) | ATE506335T1 (de) |
| DE (1) | DE602008006438D1 (de) |
| TW (1) | TWI465289B (de) |
| WO (1) | WO2009038900A1 (de) |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5529737B2 (ja) | 2007-08-15 | 2014-06-25 | エクソンモービル ケミカル パテンツ インコーポレイテッド | シクロヘキシルベンゼンの製造方法 |
| DE602008006438D1 (de) | 2007-09-21 | 2011-06-01 | Exxonmobil Chem Patents Inc | Verfahren zur herstellung von cyclohexylbenzol |
| EP2200954B1 (de) | 2007-09-21 | 2017-06-14 | ExxonMobil Chemical Patents Inc. | Verfahren zur herstellung von cyclohexylbenzol |
| US8084648B2 (en) | 2008-02-12 | 2011-12-27 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
| ES2573261T3 (es) | 2008-04-14 | 2016-06-06 | Exxonmobil Chemical Patents Inc. | Procedimiento para producir ciclohexilbenceno |
| WO2009134516A1 (en) | 2008-05-01 | 2009-11-05 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
| KR101254411B1 (ko) | 2008-07-28 | 2013-04-15 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | Ｅｍｍ-12를 이용하여 알킬방향족을 제조하는 방법 |
| WO2010014401A1 (en) | 2008-07-28 | 2010-02-04 | Exxonmobil Chemical Patents Inc. | Hydroalkylation of aromatic compounds using emm-13 |
| WO2010042273A1 (en) * | 2008-10-10 | 2010-04-15 | Exxonmobil Chemical Patents Inc. | Oxidation of hydrocarbons |
| SG173047A1 (en) * | 2009-02-26 | 2011-08-29 | Exxonmobil Chem Patents Inc | Process for producing cyclohexylbenzene |
| US8633343B2 (en) * | 2009-05-26 | 2014-01-21 | Exxonmobil Chemical Patents Inc. | Transalkylation of polycyclohexylbenzenes |
| IT1395594B1 (it) * | 2009-06-29 | 2012-10-16 | Polimeri Europa Spa | Processo per la preparazione di fenolo e cicloesanone |
| US8658834B2 (en) | 2010-02-12 | 2014-02-25 | Exxonmobil Chemical Patents Inc. | Hydrogenation process |
| WO2012025308A1 (en) | 2010-08-25 | 2012-03-01 | Exxonmobil Chemical Patents Inc. | Processes for the production of esters |
| WO2012036825A1 (en) * | 2010-09-14 | 2012-03-22 | Exxonmobil Chemical Patents Inc. | Oxidation of cyclohexylbenzene |
| US9169175B2 (en) * | 2010-09-14 | 2015-10-27 | Exxonmobil Chemical Patents Inc. | Cyclohexylbenzene compositions |
| US9545622B2 (en) | 2010-10-11 | 2017-01-17 | Exxonmobil Chemical Patents Inc. | Activation and use of hydroalkylation catalysts |
| WO2012082229A1 (en) | 2010-12-17 | 2012-06-21 | Exxonmobil Chemical Patents Inc. | Composition comprising cyclohexylbenzene and 1 - phenyl - 1 -methylcyclopentane and use thereof in oxidation processes |
| WO2012082232A1 (en) | 2010-12-17 | 2012-06-21 | Exxonmobil Chemical Patenst Inc. | Process for producing cycloalkylaromatic compounds |
| CN105418354A (zh) | 2010-12-21 | 2016-03-23 | 埃克森美孚化学专利公司 | 生产单环烷基取代的芳族化合物的方法 |
| EP2675772B1 (de) * | 2011-02-18 | 2015-09-16 | ExxonMobil Chemical Patents Inc. | Verfahren zur herstellung von cyclohexylbenzen |
| WO2013043271A1 (en) * | 2011-09-23 | 2013-03-28 | Exxonmobil Chemical Patents Inc. | Process for producing phenol |
| WO2013058882A1 (en) | 2011-10-17 | 2013-04-25 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
| US9458067B2 (en) | 2012-02-08 | 2016-10-04 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
| CN104136402B (zh) * | 2012-02-27 | 2015-12-09 | 埃克森美孚化学专利公司 | 加氢烷基化方法 |
| US9663417B2 (en) | 2013-03-14 | 2017-05-30 | Exxonmobil Chemical Patents Inc. | Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers |
| US9556087B2 (en) | 2013-03-14 | 2017-01-31 | Exxonmobil Chemical Patents Inc. | Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers |
| US9725377B2 (en) | 2013-03-14 | 2017-08-08 | Exxonmobil Chemical Patents Inc. | Hydroalkylation catalyst and process for use thereof |
| CN105102119B (zh) * | 2013-03-25 | 2019-12-06 | 埃克森美孚化学专利公司 | 用于制备烷基化芳族化合物的方法 |
| EP2978529A1 (de) | 2013-03-25 | 2016-02-03 | ExxonMobil Chemical Patents Inc. | Verfahren zur herstellung einer alkylierten aromatischen verbindung |
| EP3083538A2 (de) | 2013-12-20 | 2016-10-26 | ExxonMobil Chemical Patents Inc. | Verfahren zur herstellung von phenol und/oder cyclohexanon |
| CN105899477A (zh) | 2013-12-20 | 2016-08-24 | 埃克森美孚化学专利公司 | 环己基苯组合物 |
| CN105233861B (zh) * | 2014-07-11 | 2019-07-09 | 中国石油化工股份有限公司 | 环己基苯催化剂以及环己基苯的合成方法 |
| CN105233862B (zh) * | 2014-07-11 | 2018-10-23 | 中国石油化工股份有限公司 | 环己基苯催化剂及其制备方法 |
| CN105582989B (zh) * | 2014-10-24 | 2019-08-06 | 中国石油化工股份有限公司 | 环己基苯合成用催化剂 |
| TWI600640B (zh) * | 2015-03-31 | 2017-10-01 | 艾克頌美孚化學專利股份有限公司 | 轉烷化之環己基苯甲基及聯苯化合物 |
| CN112221521A (zh) * | 2016-01-27 | 2021-01-15 | 中国石油化工股份有限公司 | 一种催化剂、其制备方法及制备环己基苯的方法 |
| CN107303501B (zh) * | 2016-04-25 | 2020-02-21 | 中国石化扬子石油化工有限公司 | 金属/mcm-49催化剂及其在生产环己基苯中的应用 |
| CN107303500B (zh) * | 2016-04-25 | 2020-03-27 | 中国石化扬子石油化工有限公司 | 金属/h-mcm-22催化剂及其在生产环己基苯中的应用 |
| CN110563534B (zh) * | 2018-06-06 | 2022-04-05 | 中国石油化工股份有限公司 | 加氢烷基化合成环己基苯的方法 |
| CN110563543B (zh) * | 2018-06-06 | 2022-07-12 | 中国石油化工股份有限公司 | 合成环己基苯的方法 |
| CN114950542B (zh) * | 2022-06-02 | 2023-12-22 | 江苏扬农化工集团有限公司 | 一种双金属负载型分子筛催化剂及其制备方法和用途 |
Family Cites Families (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3412165A (en) * | 1967-02-15 | 1968-11-19 | Shell Oil Co | Phenylcyclohexane process |
| US3959381A (en) * | 1970-10-22 | 1976-05-25 | Texaco Inc. | Phenol and cyclohexanone manufacture |
| US3760018A (en) * | 1971-05-17 | 1973-09-18 | Texaco Inc | Hydroalkylation catalyst and process |
| US3760017A (en) * | 1971-05-17 | 1973-09-18 | Texaco Inc | Hydroalkylation catalyst and process |
| US3760019A (en) * | 1971-05-17 | 1973-09-18 | Texaco Inc | Hydroalkylation catalyst and process |
| JPS5432775B2 (de) * | 1971-10-08 | 1979-10-16 | ||
| JPS562049B2 (de) * | 1972-02-09 | 1981-01-17 | ||
| US3784618A (en) * | 1972-08-25 | 1974-01-08 | Texaco Inc | Hydroalkylation process |
| US3957687A (en) * | 1972-12-04 | 1976-05-18 | Texaco Inc. | Hydroalkylation catalyst and process |
| US3784617A (en) * | 1972-12-06 | 1974-01-08 | R Suggitt | Hydroalkylation of mononuclear aromatic hydrocarbons |
| US3839477A (en) * | 1972-12-06 | 1974-10-01 | Texaco Inc | Hydroalkylation process |
| US3864421A (en) * | 1973-05-07 | 1975-02-04 | Texaco Inc | Hydroalkylation of aromatic hydrocarbons |
| US4021490A (en) * | 1975-10-14 | 1977-05-03 | Phillips Petroleum Company | Process for production of phenol and cyclohexanone |
| JPS5262253A (en) * | 1975-11-14 | 1977-05-23 | Ube Ind Ltd | Production of cyclohexylbenzene |
| US4122125A (en) * | 1976-11-08 | 1978-10-24 | Phillips Petroleum Company | Hydroalkylation using multimetallic zeolite catalyst |
| US4206082A (en) * | 1976-11-08 | 1980-06-03 | Phillips Petroleum Company | Hydroalkylation process and a composition and process for producing said composition |
| AU509407B2 (en) * | 1976-12-20 | 1980-05-08 | The Standard Oil Company | Hydroalkylation of benzene and analogs |
| US4177165A (en) * | 1977-02-10 | 1979-12-04 | Phillips Petroleum Company | Hydroalkylation composition and process for producing said composition |
| US4094918A (en) * | 1977-02-10 | 1978-06-13 | Phillips Petroleum Company | Hydroalkylation process using multi-metallic zeolite catalyst |
| JPS591246B2 (ja) * | 1977-03-04 | 1984-01-11 | 宇部興産株式会社 | シクロヘキシルベンゼン類の製造方法 |
| US4152362A (en) * | 1978-01-03 | 1979-05-01 | Phillips Petroleum Company | Hydroalkylation using a rhenium, nickel, rare earth zeolite |
| US4268699A (en) * | 1978-07-21 | 1981-05-19 | Phillips Petroleum Company | Hydroalkylation using nickel-ruthenium catalyst on zeolite type support |
| US4219689A (en) * | 1978-09-08 | 1980-08-26 | Phillips Petroleum Company | Aromatic hydroalkylation catalyst using iridium on zeolites |
| US4447554A (en) * | 1980-05-29 | 1984-05-08 | Phillips Petroleum Company | Hydroalkylation catalyst and methods for producing and employing same |
| US4329531A (en) * | 1980-05-29 | 1982-05-11 | Phillips Petroleum Company | Hydroalkylation catalyst and methods for producing and employing same |
| DE3117135A1 (de) * | 1981-04-30 | 1982-11-18 | Bayer Ag, 5090 Leverkusen | Kristallines alumosilicat, verfahren zu dessen herstellung sowie dessen verwendung zur katalytischen umwandlung von methanol und/oder dimethylether in kohlenwasserstoffe |
| US4826667A (en) * | 1986-01-29 | 1989-05-02 | Chevron Research Company | Zeolite SSZ-25 |
| US4954325A (en) * | 1986-07-29 | 1990-09-04 | Mobil Oil Corp. | Composition of synthetic porous crystalline material, its synthesis and use |
| IT1205681B (it) | 1987-05-26 | 1989-03-31 | Eniricerche Spa | Materiale sintetico cristallino poroso contenente ossidi di silicio e boro |
| GB8809214D0 (en) * | 1988-04-19 | 1988-05-25 | Exxon Chemical Patents Inc | Reductive alkylation process |
| US4870217A (en) | 1988-10-24 | 1989-09-26 | Texaco Chemical Company | Method for production of phenol/acetone from cumene hydroperoxide |
| US5334795A (en) * | 1990-06-28 | 1994-08-02 | Mobil Oil Corp. | Production of ethylbenzene |
| US5190863A (en) * | 1990-06-29 | 1993-03-02 | Miles Inc. | Composition for determining the presence or concentration of D-β-hydroxybutyrate |
| US5250277A (en) * | 1991-01-11 | 1993-10-05 | Mobil Oil Corp. | Crystalline oxide material |
| US5146024A (en) * | 1991-05-20 | 1992-09-08 | Phillips Petroleum Company | Hydroalkylation of aromatic hydrocarbons |
| US5236575A (en) * | 1991-06-19 | 1993-08-17 | Mobil Oil Corp. | Synthetic porous crystalline mcm-49, its synthesis and use |
| JPH06271510A (ja) * | 1993-03-18 | 1994-09-27 | Chiyoda Corp | 炭酸エステルの製造方法 |
| US5362697A (en) | 1993-04-26 | 1994-11-08 | Mobil Oil Corp. | Synthetic layered MCM-56, its synthesis and use |
| US5488194A (en) | 1994-05-16 | 1996-01-30 | Mobil Oil Corp. | Selective production of para-dialkyl substituted benzenes and catalyst therefor |
| ES2124154B1 (es) | 1995-11-08 | 1999-12-01 | Univ Politecnica De Valencia C | Metodo de preparaciion y propiedades cataliticas de un solido microporoso con alta superficie externa. |
| ES2105982B1 (es) * | 1995-11-23 | 1998-07-01 | Consejo Superior Investigacion | Zeolita itq-1 |
| TW382146B (en) | 1998-06-19 | 2000-02-11 | United Microeletronics Corp | Semiconductor step-down voltage device having low power consumption |
| US6037513A (en) * | 1998-07-09 | 2000-03-14 | Mobil Oil Corporation | Hydroalkylation of aromatic hydrocarbons |
| US6489529B1 (en) * | 2000-01-24 | 2002-12-03 | Exxonmobil Oil Corporation | Production of monocycloalkyl aromatic compounds |
| US6506953B1 (en) * | 2000-01-24 | 2003-01-14 | Exxonmobil Oil Corporation | Hydroalkylation of aromatic hydrocarbons |
| DE10015874A1 (de) | 2000-03-30 | 2001-10-11 | Creavis Tech & Innovation Gmbh | Verfahren zur Herstellung von aromatischen Alkoholen insbesondere Phenol |
| US6936744B1 (en) * | 2000-07-19 | 2005-08-30 | Exxonmobil Chemical Patents, Inc. | Alkylaromatics production |
| JP2002102709A (ja) * | 2000-09-29 | 2002-04-09 | Showa Denko Kk | 酸化化合物製造用結晶性ｍｗｗ型チタノシリケート触媒、該触媒の製造方法、及び該触媒を用いた酸化化合物の製造方法 |
| JP4241068B2 (ja) * | 2002-03-07 | 2009-03-18 | 昭和電工株式会社 | Ｍｗｗ型ゼオライト物質の製造方法 |
| ES2246704B1 (es) | 2004-05-28 | 2007-06-16 | Universidad Politecnica De Valencia | Zeolita itq-30. |
| JP4457761B2 (ja) * | 2004-06-04 | 2010-04-28 | 宇部興産株式会社 | シクロヘキシルベンゼン製造用触媒及びシクロヘキシルベンゼンの製造方法 |
| US7959899B2 (en) * | 2006-07-28 | 2011-06-14 | Exxonmobil Chemical Patents Inc. | Molecular sieve composition (EMM-10-P), its method of making, and use for hydrocarbon conversions |
| US7842277B2 (en) * | 2006-07-28 | 2010-11-30 | Exxonmobil Chemical Patents Inc. | Molecular sieve composition, a method of making and a process of using the same |
| KR101044495B1 (ko) * | 2006-07-28 | 2011-06-27 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 분자체 조성물(ｅｍｍ-10), 이의 제조 방법, 및 탄화수소 전환에 있어서의 용도 |
| JP5529737B2 (ja) * | 2007-08-15 | 2014-06-25 | エクソンモービル ケミカル パテンツ インコーポレイテッド | シクロヘキシルベンゼンの製造方法 |
| DE602008006438D1 (de) | 2007-09-21 | 2011-06-01 | Exxonmobil Chem Patents Inc | Verfahren zur herstellung von cyclohexylbenzol |
-
2008
- 2008-08-12 DE DE602008006438T patent/DE602008006438D1/de active Active
- 2008-08-12 CN CN2008800250033A patent/CN101754940B/zh not_active Expired - Fee Related
- 2008-08-12 WO PCT/US2008/072843 patent/WO2009038900A1/en active Application Filing
- 2008-08-12 EP EP08797656A patent/EP2200955B1/de not_active Not-in-force
- 2008-08-12 US US12/663,303 patent/US7847128B2/en active Active
- 2008-08-12 AT AT08797656T patent/ATE506335T1/de not_active IP Right Cessation
- 2008-08-12 JP JP2010521924A patent/JP5192546B2/ja not_active Expired - Fee Related
- 2008-08-12 KR KR1020107006151A patent/KR101151978B1/ko not_active IP Right Cessation
- 2008-08-18 TW TW097131436A patent/TWI465289B/zh not_active IP Right Cessation
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2010
- 2010-10-14 US US12/904,215 patent/US7910779B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| DE602008006438D1 (de) | 2011-06-01 |
| WO2009038900A1 (en) | 2009-03-26 |
| EP2200955B1 (de) | 2011-04-20 |
| US7847128B2 (en) | 2010-12-07 |
| JP2010536862A (ja) | 2010-12-02 |
| US20110028762A1 (en) | 2011-02-03 |
| JP5192546B2 (ja) | 2013-05-08 |
| US7910779B2 (en) | 2011-03-22 |
| TWI465289B (zh) | 2014-12-21 |
| EP2200955A1 (de) | 2010-06-30 |
| KR20100044906A (ko) | 2010-04-30 |
| KR101151978B1 (ko) | 2012-06-01 |
| TW200922689A (en) | 2009-06-01 |
| CN101754940B (zh) | 2013-05-08 |
| CN101754940A (zh) | 2010-06-23 |
| US20100179351A1 (en) | 2010-07-15 |
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