DE602005009207D1 - Verfahren zur herstellung von phenol und methylethylketon - Google Patents
Verfahren zur herstellung von phenol und methylethylketonInfo
- Publication number
- DE602005009207D1 DE602005009207D1 DE602005009207T DE602005009207T DE602005009207D1 DE 602005009207 D1 DE602005009207 D1 DE 602005009207D1 DE 602005009207 T DE602005009207 T DE 602005009207T DE 602005009207 T DE602005009207 T DE 602005009207T DE 602005009207 D1 DE602005009207 D1 DE 602005009207D1
- Authority
- DE
- Germany
- Prior art keywords
- phenol
- produce
- preparation
- butylbenzene
- hydroperoxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
- C07C39/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with no unsaturation outside the aromatic ring
- C07C39/04—Phenol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
- C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
- C07C409/08—Compounds containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US60166104P | 2004-08-13 | 2004-08-13 | |
PCT/EP2005/008557 WO2006015826A1 (en) | 2004-08-13 | 2005-08-05 | Process for producing phenol and methyl ethyl ketone |
Publications (1)
Publication Number | Publication Date |
---|---|
DE602005009207D1 true DE602005009207D1 (de) | 2008-10-02 |
Family
ID=34956214
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE602005009207T Active DE602005009207D1 (de) | 2004-08-13 | 2005-08-05 | Verfahren zur herstellung von phenol und methylethylketon |
Country Status (10)
Country | Link |
---|---|
US (1) | US7799956B2 (de) |
EP (1) | EP1778605B1 (de) |
JP (1) | JP5051898B2 (de) |
KR (1) | KR101116523B1 (de) |
CN (1) | CN101006033B (de) |
AT (1) | ATE405535T1 (de) |
DE (1) | DE602005009207D1 (de) |
ES (1) | ES2313385T3 (de) |
TW (1) | TWI376361B (de) |
WO (1) | WO2006015826A1 (de) |
Families Citing this family (52)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW200744986A (en) * | 2006-02-14 | 2007-12-16 | Exxonmobil Chemical Patents Inc | Process for producing phenol and methyl ethyl ketone |
US7829062B2 (en) | 2006-02-14 | 2010-11-09 | Exxonmobil Chemical Patent Inc. | Method of preparing a molecular sieve composition |
WO2007093359A1 (en) * | 2006-02-14 | 2007-08-23 | Exxonmobil Chemical Patents Inc. | Process for producing sec-butylbenzene |
JP2009526789A (ja) * | 2006-02-14 | 2009-07-23 | エクソンモービル・ケミカル・パテンツ・インク | フェノールとメチルエチルケトンの製造方法 |
TW200744985A (en) * | 2006-02-14 | 2007-12-16 | Exxonmobil Chemical Patents Inc | Process for producing sec-butylbenzene |
KR100978980B1 (ko) | 2006-02-14 | 2010-08-30 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 엠씨엠-22계 분자체의 제조 방법 |
WO2007094938A1 (en) | 2006-02-14 | 2007-08-23 | Exxonmobil Chemical Patents Inc. | An mcm-22 family molecular sieve composition |
US7959899B2 (en) | 2006-07-28 | 2011-06-14 | Exxonmobil Chemical Patents Inc. | Molecular sieve composition (EMM-10-P), its method of making, and use for hydrocarbon conversions |
US7417003B2 (en) | 2006-12-29 | 2008-08-26 | Uop Llc | Solid acid catalyst and process for decomposition of cumene hydroperoxide |
WO2008097737A1 (en) * | 2007-02-09 | 2008-08-14 | Exxonmobil Chemical Patents Inc. A Corporation Of The State Of Delaware | Improved alkylaromatic production process |
TW200846312A (en) * | 2007-02-22 | 2008-12-01 | Exxonmobil Chem Patents Inc | Oxidation of sec-butylbenzene and production of phenol and methyl ethyl ketone |
WO2008101616A1 (en) * | 2007-02-22 | 2008-08-28 | Exxonmobil Chemical Patents Inc. | Production of alkylaromatic compounds |
TW200904789A (en) | 2007-04-19 | 2009-02-01 | Exxonmobil Chem Patents Inc | Process for oxidizing alkylaromatic compounds |
US7692046B2 (en) | 2007-06-21 | 2010-04-06 | Exxonmobil Chemical Patents Inc. | Heterogeneous arylalkyl oxidation promoter |
US8470289B2 (en) | 2007-07-16 | 2013-06-25 | Exxonmobil Chemical Patents Inc. | Manganese oxides and their use in the oxidation of alkanes |
US7985883B2 (en) | 2007-07-16 | 2011-07-26 | Exxonmobil Chemical Patents Inc. | Process for oxidizing alkylaromatic compounds |
WO2009024242A1 (en) | 2007-08-22 | 2009-02-26 | Exxonmobil Chemical Patents Inc. | Process for producing sec-butylbenzene |
US8487138B2 (en) | 2007-08-22 | 2013-07-16 | Exxonmobil Chemical Patents Inc. | Oxidation of hydrocarbons |
EP2098498A1 (de) * | 2008-03-04 | 2009-09-09 | ExxonMobil Chemical Patents Inc. | Selektive Oligomerisierung von Isobuten |
WO2009055216A2 (en) | 2007-10-26 | 2009-04-30 | Exxonmobil Chemical Patents Inc. | Method of preparing a molecular sieve composition |
CN101835746B (zh) | 2007-10-31 | 2016-07-13 | 埃克森美孚化学专利公司 | 烃的氧化 |
WO2009058531A1 (en) | 2007-10-31 | 2009-05-07 | Exxonmobil Chemical Patents Inc. | Oxidation of hydrocarbons |
JP5348803B2 (ja) | 2007-11-16 | 2013-11-20 | エクソンモービル・ケミカル・パテンツ・インク | 触媒再生方法 |
CN101925561B (zh) * | 2008-02-12 | 2014-04-16 | 埃克森美孚化学专利公司 | 制备环己基苯的方法 |
RU2509722C2 (ru) | 2008-07-28 | 2014-03-20 | Эксонмобил Кемикэл Пейтентс Инк. | Способ получения алкилароматических соединений с использованием емм-12 |
US8198496B2 (en) | 2008-07-28 | 2012-06-12 | Exxonmobil Chemical Patents Inc. | Process of making alkylaromatics using EMM-13 |
WO2010021795A1 (en) | 2008-07-28 | 2010-02-25 | Exxonmobil Chemical Patents Inc. | A novel molecular sieve composition emm-12, a method of making and a process of using the same |
KR101273039B1 (ko) | 2008-07-28 | 2013-06-10 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 신규한 분자체 조성물 emm-12, 이의 제조 방법 및 이를 사용하는 공정 |
JP2011525195A (ja) * | 2008-08-26 | 2011-09-15 | エクソンモービル・ケミカル・パテンツ・インク | アルキルベンゼンヒドロペルオキシドの製造方法 |
EP2352715A1 (de) | 2008-10-10 | 2011-08-10 | Exxonmobil Chemical Company | Verfahren zur herstellung von phenol |
WO2010042273A1 (en) | 2008-10-10 | 2010-04-15 | Exxonmobil Chemical Patents Inc. | Oxidation of hydrocarbons |
WO2010042268A1 (en) * | 2008-10-10 | 2010-04-15 | Exxonmobil Chemical Patents Inc. | Process for producing sec-butylbenzene |
WO2010042269A1 (en) | 2008-10-10 | 2010-04-15 | Exxonmobil Chemical Patents Inc. | Process for producing phenol and methyl ethyl ketone |
MY158652A (en) | 2008-12-15 | 2016-10-31 | Exxonmobil Chemical Patents Inc | Oxidation of alkylaromatic compounds |
US20100160704A1 (en) * | 2008-12-19 | 2010-06-24 | Robert Schmidt | Alkylation of aromatics with high activity catalyst |
WO2010098916A2 (en) | 2009-02-26 | 2010-09-02 | Exxonmobil Chemical Patents Inc. | Process for producing phenol |
CN102482211A (zh) | 2009-08-28 | 2012-05-30 | 埃克森美孚化学专利公司 | 烃的氧化 |
US8518847B2 (en) * | 2009-09-30 | 2013-08-27 | Uop Llc | Aromatic alkylation catalyst |
US9321710B2 (en) | 2010-01-25 | 2016-04-26 | Exxonmobil Chemical Patents Inc. | Process for producing phenol |
CN103097351B (zh) | 2010-09-14 | 2016-03-09 | 埃克森美孚化学专利公司 | 环己基苯的氧化方法 |
WO2012036824A1 (en) | 2010-09-14 | 2012-03-22 | Exxonmobil Chemical Patents Inc. | Oxidation of alkylbenzenes and cycloalkylbenzenes |
JP5793792B2 (ja) * | 2011-04-19 | 2015-10-14 | エクソンモービル ケミカル パテンツ インコーポレイテッド | フェノールの製造方法 |
US9388102B2 (en) | 2011-04-19 | 2016-07-12 | Exxonmobil Chemical Patents Inc. | Process for producing phenol |
WO2013052217A2 (en) | 2011-10-07 | 2013-04-11 | Exxonmobil Chemical Patents Inc. | Mixed metal oxide catalysts and use thereof |
CN103102240B (zh) * | 2011-11-14 | 2015-02-25 | 中国石油化工股份有限公司 | 一种仲丁基苯的合成方法 |
CN102826980B (zh) * | 2012-09-04 | 2014-10-15 | 华东理工大学 | 2,3-丁二醇气相脱水制备甲乙酮的方法 |
WO2014043478A1 (en) | 2012-09-17 | 2014-03-20 | Exxonmobil Chemical Patents Inc. | Process for producing phenol and/or cyclohexanone from cyclohexylbenzene |
US9272974B2 (en) | 2012-09-17 | 2016-03-01 | Exxonmobil Chemical Patents Inc. | Process for producing phenol and/or cyclohexanone from cyclohexylbenzene |
CN103739437B (zh) * | 2012-10-17 | 2015-10-21 | 中国石油化工股份有限公司 | 用于混合碳四和苯生产非苯芳烃的方法 |
EP3347331B1 (de) | 2015-09-07 | 2019-08-21 | SABIC Global Technologies B.V. | Verfahren zur herstellung von cumen und/oder sec-butylbenzol mit einem gemischten olefinstrom als alkylierungsmittel |
CN105251529B (zh) * | 2015-11-25 | 2017-09-12 | 广东工业大学 | 一种负载型催化剂及其制备方法与催化长链烷基酚的合成方法 |
CN109180437A (zh) | 2018-09-06 | 2019-01-11 | 常州大学 | 管式连续流反应器中过氧化氢异丙苯分解制备苯酚的方法 |
Family Cites Families (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2584103A (en) | 1949-07-16 | 1952-02-05 | Universal Oil Prod Co | Alkylation of aromatic hydrocarbons |
SU265349A1 (ru) | 1968-08-03 | 1976-10-05 | Институт Органической Химии Им.Н.Д. Зелинского | Способ получени втор-бутилбензола |
DE2300903A1 (de) * | 1972-01-10 | 1973-08-02 | Union Carbide Corp | Verfahren zur herstellung von butylbenzolhydroperoxid und dessen verwendung zur herstellung von phenol, acetophenon und methylaethylketon |
US3819735A (en) | 1972-02-04 | 1974-06-25 | Union Carbide Corp | Alkylation catalyst and process of alkylating benzene |
SU417405A1 (ru) | 1972-05-26 | 1974-02-28 | Я. И. Исаков, М. Миначев, Я. Т. Эйдус, А. Л. Лапидус , В. П. Калинин | Способ совместного получения этилбензола и вторичного бутилбензола |
US4051191A (en) | 1977-01-03 | 1977-09-27 | Uop Inc. | Solid phosphoric acid catalyzed alkylation of aromatic hydrocarbons |
SU1245564A1 (ru) | 1982-06-24 | 1986-07-23 | Ордена Трудового Красного Знамени Институт Нефтехимических Процессов Им.Ю.Г.Мамедалиева | Способ получени вторичного бутилбензола |
US4490565A (en) | 1983-05-06 | 1984-12-25 | Mobil Oil Corporation | Production of phenol |
US4490566A (en) | 1983-05-06 | 1984-12-25 | Mobil Oil Corporation | Production of phenol |
US4891458A (en) * | 1987-12-17 | 1990-01-02 | Innes Robert A | Liquid phase alkylation or transalkylation process using zeolite beta |
US4992606A (en) | 1988-10-06 | 1991-02-12 | Mobil Oil Corp. | Process for preparing short chain alkyl aromatic compounds |
JP2797609B2 (ja) * | 1989-04-25 | 1998-09-17 | 住友化学工業株式会社 | sec―ブチルベンゼンの製造方法 |
CA2015191A1 (en) * | 1989-04-25 | 1990-10-25 | Kazuhiro Yamauchi | Process for production of sec-butylbenzene |
JP2884820B2 (ja) * | 1990-09-10 | 1999-04-19 | 住友化学工業株式会社 | sec−ブチルベンゼンの製造法 |
US5236575A (en) | 1991-06-19 | 1993-08-17 | Mobil Oil Corp. | Synthetic porous crystalline mcm-49, its synthesis and use |
US5545788A (en) * | 1991-06-19 | 1996-08-13 | Mobil Oil Corporation | Process for the alkylation of benzene-rich reformate using MCM-49 |
US5183945A (en) | 1991-11-18 | 1993-02-02 | Exxon Research And Engineering Company | Catalytic production of aryl alkyl hydroperoxides by manganese complexes |
JPH05229972A (ja) * | 1991-12-26 | 1993-09-07 | Sumitomo Chem Co Ltd | フェノール及びメチルエチルケトンの製造方法 |
JP3225605B2 (ja) * | 1992-07-14 | 2001-11-05 | 住友化学工業株式会社 | フェノール及びメチルエチルケトンの製造方法 |
TW226011B (de) | 1991-12-26 | 1994-07-01 | Sumitomo Chemical Co | |
JP3089779B2 (ja) * | 1991-12-26 | 2000-09-18 | 住友化学工業株式会社 | フェノール及びメチルエチルケトンの製造方法 |
US5177283A (en) | 1992-02-03 | 1993-01-05 | Uop | Hydrocarbon conversion process |
JPH06256238A (ja) * | 1993-03-05 | 1994-09-13 | Sumitomo Chem Co Ltd | フェノール及びメチルエチルケトンの製造方法 |
JP3367056B2 (ja) * | 1992-07-07 | 2003-01-14 | 住友化学工業株式会社 | フェノール及びメチルエチルケトンの製造方法 |
US5362697A (en) | 1993-04-26 | 1994-11-08 | Mobil Oil Corp. | Synthetic layered MCM-56, its synthesis and use |
US5336820A (en) | 1993-08-11 | 1994-08-09 | Mobil Oil Corporation | Process for the alkylation of benzene-rich gasoline |
DE69517527T2 (de) * | 1994-08-03 | 2001-03-01 | Asahi Kasei Kogyo K.K., Osaka | METHODE ZUR ALKYLIERUNG VON AROMATISCHEN KOHLENWASSERSTOFFEN IN FLÜSSIGER PHASE MIT beta-ZEOLITEN |
US5504256A (en) | 1995-03-10 | 1996-04-02 | Exxon Research And Engineering Company | Catalytic production of aryl alkyl hydroperoxides by polynuclear transition metal aggregates (LAW229) |
US6162416A (en) | 1996-07-12 | 2000-12-19 | Uop Llc | Zeolite beta and its use in aromatic alkylation |
ES2173473T3 (es) * | 1996-08-20 | 2002-10-16 | Dow Chemical Co | Procedimiento de produccion de bencenos alquilados. |
AU743095B2 (en) | 1996-09-06 | 2002-01-17 | Exxonmobil Chemical Patents Inc | Alkylation process using zeolite beta |
US6051521A (en) | 1998-08-25 | 2000-04-18 | Mobil Oil Corporation | Method of producing an aromatics alkylation catalyst |
US6169215B1 (en) | 1999-03-25 | 2001-01-02 | Mobil Oil Corporation | Production of phenol |
US6169216B1 (en) | 1999-04-22 | 2001-01-02 | Mobil Oil Corporation | Production of phenol |
US6297406B1 (en) | 1999-08-03 | 2001-10-02 | Mobil Oil Corporation | Production of phenol |
DE19946888A1 (de) | 1999-09-30 | 2001-04-05 | Phenolchemie Gmbh & Co Kg | Verfahren zur Herstellung von Phenol, Aceton und Methylethylketon |
US6410804B1 (en) | 1999-12-21 | 2002-06-25 | Exxon Mobil Oil Corporation | Production of phenol using reactive distillation |
DE10015874A1 (de) | 2000-03-30 | 2001-10-11 | Creavis Tech & Innovation Gmbh | Verfahren zur Herstellung von aromatischen Alkoholen insbesondere Phenol |
JP2002282698A (ja) | 2001-03-29 | 2002-10-02 | Mitsui Chemicals Inc | 固体に担持したn−ヒドロキシフタルイミド触媒 |
-
2005
- 2005-07-04 TW TW094122566A patent/TWI376361B/zh not_active IP Right Cessation
- 2005-08-05 US US11/660,065 patent/US7799956B2/en not_active Expired - Fee Related
- 2005-08-05 AT AT05770053T patent/ATE405535T1/de not_active IP Right Cessation
- 2005-08-05 WO PCT/EP2005/008557 patent/WO2006015826A1/en active IP Right Grant
- 2005-08-05 EP EP05770053A patent/EP1778605B1/de not_active Not-in-force
- 2005-08-05 CN CN2005800275785A patent/CN101006033B/zh not_active Expired - Fee Related
- 2005-08-05 JP JP2007525234A patent/JP5051898B2/ja not_active Expired - Fee Related
- 2005-08-05 ES ES05770053T patent/ES2313385T3/es active Active
- 2005-08-05 DE DE602005009207T patent/DE602005009207D1/de active Active
- 2005-08-05 KR KR1020077005746A patent/KR101116523B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
TW200619180A (en) | 2006-06-16 |
CN101006033A (zh) | 2007-07-25 |
EP1778605B1 (de) | 2008-08-20 |
ES2313385T3 (es) | 2009-03-01 |
ATE405535T1 (de) | 2008-09-15 |
TWI376361B (en) | 2012-11-11 |
CN101006033B (zh) | 2011-10-12 |
US7799956B2 (en) | 2010-09-21 |
US20080086018A1 (en) | 2008-04-10 |
KR20070057173A (ko) | 2007-06-04 |
JP2008509178A (ja) | 2008-03-27 |
EP1778605A1 (de) | 2007-05-02 |
WO2006015826A1 (en) | 2006-02-16 |
JP5051898B2 (ja) | 2012-10-17 |
KR101116523B1 (ko) | 2012-02-28 |
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