ATE242176T1 - Aluminiumoxidsol, verfahren zu dessen herstellung,verfahren zur herstellung eines aluminiumoxidteils unter verwendung derselben und daraus hergestellte katalysator auf basis von aluminiumoxid - Google Patents
Aluminiumoxidsol, verfahren zu dessen herstellung,verfahren zur herstellung eines aluminiumoxidteils unter verwendung derselben und daraus hergestellte katalysator auf basis von aluminiumoxidInfo
- Publication number
- ATE242176T1 ATE242176T1 AT97903661T AT97903661T ATE242176T1 AT E242176 T1 ATE242176 T1 AT E242176T1 AT 97903661 T AT97903661 T AT 97903661T AT 97903661 T AT97903661 T AT 97903661T AT E242176 T1 ATE242176 T1 AT E242176T1
- Authority
- AT
- Austria
- Prior art keywords
- aluminum oxide
- producing
- same
- concentration
- alumina
- Prior art date
Links
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical group [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title abstract 6
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title 1
- 229910052782 aluminium Inorganic materials 0.000 title 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 title 1
- 229910001593 boehmite Inorganic materials 0.000 abstract 2
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 abstract 2
- 239000000969 carrier Substances 0.000 abstract 1
- 239000013078 crystal Substances 0.000 abstract 1
- 238000004134 energy conservation Methods 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
- C04B35/111—Fine ceramics
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/624—Sol-gel processing
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/10—One-dimensional structures
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/14—Pore volume
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/16—Pore diameter
- C01P2006/17—Pore diameter distribution
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/21—Attrition-index or crushing strength of granulates
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
- C01P2006/82—Compositional purity water content
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Catalysts (AREA)
- Colloid Chemistry (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7822796 | 1996-03-05 | ||
PCT/JP1997/000663 WO1997032817A1 (fr) | 1996-03-05 | 1997-03-04 | Sol d'alumine, son procede de preparation, procede de preparation d'un moulage d'alumine l'utilisant, et catalyseur a base d'alumine ainsi prepare |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE242176T1 true ATE242176T1 (de) | 2003-06-15 |
Family
ID=13656172
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT97903661T ATE242176T1 (de) | 1996-03-05 | 1997-03-04 | Aluminiumoxidsol, verfahren zu dessen herstellung,verfahren zur herstellung eines aluminiumoxidteils unter verwendung derselben und daraus hergestellte katalysator auf basis von aluminiumoxid |
Country Status (8)
Country | Link |
---|---|
US (1) | US6171573B1 (de) |
EP (1) | EP0885844B1 (de) |
JP (1) | JP3304360B2 (de) |
KR (1) | KR100402831B1 (de) |
CN (1) | CN1120129C (de) |
AT (1) | ATE242176T1 (de) |
DE (1) | DE69722596D1 (de) |
WO (1) | WO1997032817A1 (de) |
Families Citing this family (72)
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JPH1017321A (ja) * | 1996-06-27 | 1998-01-20 | Catalysts & Chem Ind Co Ltd | アルミナ小球体およびその製造方法 |
US6048470A (en) * | 1996-12-20 | 2000-04-11 | Asahi Glass Company Ltd. | Alumina sol, alumina hydrate powder and processes for their production |
EP1081285B1 (de) * | 1998-02-23 | 2008-06-04 | Kao Corporation | Verfahren zum fertigen von gegenständen aus papiermasse |
ID28988A (id) * | 1998-12-28 | 2001-07-19 | Corning Inc | Keramik alumina dengan luas permukaan yang tinggi dan kekuatan yang tinggi |
JP4204132B2 (ja) * | 1999-02-19 | 2009-01-07 | 大塚化学ホールディングス株式会社 | 摩擦材 |
BR0001560B1 (pt) | 1999-04-09 | 2010-04-06 | processo para produzir um corpo cerámico-catalisador, e, corpo cerámico-catalisador. | |
JP2001187773A (ja) | 2000-01-06 | 2001-07-10 | Mitsubishi Chemicals Corp | アクリロニトリル組成物 |
JP4540785B2 (ja) * | 2000-01-11 | 2010-09-08 | 日揮触媒化成株式会社 | 排ガス浄化用触媒成型体 |
WO2001056926A1 (fr) * | 2000-02-04 | 2001-08-09 | Goro Sato | Composition d'alumine et son procede de preparation |
JP2002177794A (ja) * | 2000-09-29 | 2002-06-25 | Denso Corp | セラミック触媒体およびセラミック担体 |
JP2002172323A (ja) * | 2000-09-29 | 2002-06-18 | Denso Corp | セラミック触媒体、セラミック担体とその製造方法 |
US7067452B2 (en) * | 2000-09-29 | 2006-06-27 | Denso Corporation | Ceramic catalyst body |
US20020077248A1 (en) * | 2000-09-29 | 2002-06-20 | Tomohiko Nakanishi | Ceramic carrier and ceramic catalyst body |
JP4030320B2 (ja) * | 2001-03-22 | 2008-01-09 | 株式会社デンソー | セラミック体およびセラミック触媒体 |
JP3997825B2 (ja) | 2001-06-28 | 2007-10-24 | 株式会社デンソー | セラミックフィルタおよび触媒付セラミックフィルタ |
JP2003200062A (ja) * | 2001-10-26 | 2003-07-15 | Denso Corp | 車両用触媒 |
US20030092567A1 (en) * | 2001-11-12 | 2003-05-15 | Masakazu Tanaka | Ceramic catalyst body |
JP2003164760A (ja) * | 2001-11-29 | 2003-06-10 | Denso Corp | セラミック触媒体 |
JP2003230838A (ja) * | 2001-12-06 | 2003-08-19 | Denso Corp | セラミック触媒体 |
JP4271400B2 (ja) | 2002-02-14 | 2009-06-03 | 株式会社デンソー | 触媒体 |
US20050124745A1 (en) | 2002-04-19 | 2005-06-09 | Saint-Gobain Ceramics & Plastics, Inc. | Flame retardant composites |
DK1499666T3 (da) * | 2002-04-19 | 2010-01-18 | Saint Gobain Ceramics | Bøhmitpartikler og polymermaterialer, der indeholder disse |
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DE102006051661A1 (de) * | 2006-11-02 | 2008-05-08 | Evonik Degussa Gmbh | Zubereitung zur Herstellung feuerfester Materialien |
KR100833790B1 (ko) * | 2007-02-28 | 2008-05-29 | 재단법인서울대학교산학협력재단 | 알루미나 제어로젤 담체에 담지된 금속촉매, 그 제조 방법및 상기 촉매를 이용한 액화천연가스의 수증기 개질 반응에의한 수소 제조방법 |
KR100885637B1 (ko) | 2007-06-25 | 2009-02-25 | 고려대학교 산학협력단 | 액화천연가스의 수증기 개질반응용 니켈-알루미나 제어로젤촉매 및 그 제조방법 |
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US8460768B2 (en) | 2008-12-17 | 2013-06-11 | Saint-Gobain Ceramics & Plastics, Inc. | Applications of shaped nano alumina hydrate in inkjet paper |
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FR3022235B1 (fr) * | 2014-06-13 | 2021-05-07 | Ifp Energies Now | Gel haute dispersibilite et son procede de preparation |
FR3022163B1 (fr) * | 2014-06-13 | 2021-05-07 | Ifp Energies Now | Catalyseur a base de nickel mesoporeux et macroporeux ayant un diametre median macroporeux superieur a 200 nm et son utilisation en hydrogenation |
FR3022161B1 (fr) | 2014-06-13 | 2021-05-07 | Ifp Energies Now | Catalyseur a phase active de nickel comalaxee mesoporeux et macroporeux ayant un diametre median macroporeux superieur a 300 nm et son utilisation en hydrogenation |
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EP3878816A1 (de) * | 2020-03-13 | 2021-09-15 | Almatis GmbH | Verfahren zur herstellung von hochreinem aluminiummonohydrat und alpha-aluminiumoxid |
CN111333410B (zh) * | 2020-03-16 | 2022-05-20 | 苏州柔陶新材料有限公司 | 可纺性铝溶胶、其制备方法及氧化铝连续纤维 |
CN111606340A (zh) * | 2020-06-08 | 2020-09-01 | 沈阳铝镁设计研究院有限公司 | 一种高低浓度铝酸钠溶液蒸发生产工艺 |
CN111792660A (zh) * | 2020-07-15 | 2020-10-20 | 东北大学 | 一种利用氯化铝生产勃姆石微钠米粉末的方法 |
CN113233483A (zh) * | 2021-05-22 | 2021-08-10 | 邹平恒嘉新材料科技有限公司 | 一种纳米级勃姆石材料制备方法 |
CN115445592B (zh) * | 2022-10-04 | 2023-10-27 | 南京通图化工新材料有限公司 | 一种用于连续重整催化剂的铝溶胶的制备方法 |
CN118439638B (zh) * | 2024-07-04 | 2024-09-03 | 湖南荣岚智能科技有限公司 | 一种具有定向纳米结构的氧化铝气凝胶及其制备方法 |
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US2915475A (en) * | 1958-12-29 | 1959-12-01 | Du Pont | Fibrous alumina monohydrate and its production |
JPS467164Y1 (de) | 1968-04-02 | 1971-03-13 | ||
JPS4716395Y1 (de) | 1968-09-24 | 1972-06-08 | ||
DE2104897A1 (de) * | 1971-02-03 | 1972-08-17 | Bayer | Verfahren zur Herstellung von kolloidalem faserförmigen Böhmit |
JPS5021319A (de) | 1973-06-27 | 1975-03-06 | ||
US3928236A (en) | 1974-11-25 | 1975-12-23 | Kaiser Aluminium Chem Corp | Alumina catalyst carriers and the process for producing them |
JPS599437B2 (ja) | 1976-09-01 | 1984-03-02 | 藤沢薬品工業株式会社 | びんの洗浄装置 |
FR2398540A1 (fr) * | 1977-07-29 | 1979-02-23 | Raffinage Cie Francaise | Procede de preparation d'alumines a porosite controlee et applications des alumines ainsi preparees |
FR2449650A1 (fr) * | 1979-02-26 | 1980-09-19 | Rhone Poulenc Ind | Procede de preparation d'alumine au moins partiellement sous forme de boehmite ultra-fine |
JPS5913446A (ja) | 1982-07-14 | 1984-01-24 | Hitachi Ltd | 分散処理システム |
JPS60166220A (ja) | 1984-02-09 | 1985-08-29 | Sumitomo Alum Smelt Co Ltd | 無定形繊維状アルミナゾルの製造方法 |
US4555394A (en) * | 1984-06-01 | 1985-11-26 | Chiyoda Chemical Engineering & Construction Co., Ltd. | Process for the preparation of alumina |
JPS6126512A (ja) | 1984-07-12 | 1986-02-05 | Chiyoda Chem Eng & Constr Co Ltd | シヤ−プな細孔分布を有する多孔質アルミナの製造方法 |
EP0176476A1 (de) | 1984-09-14 | 1986-04-02 | Schweizerische Aluminium Ag | Verfahren zur Herstellung von hochaktivem, dispersem Aluminiumleichtoxidhydrat und Formkörper aus Aluminiumleichtoxid sowie Verfahren zur Herstellung der Formkörper |
JPH0685875B2 (ja) | 1985-08-05 | 1994-11-02 | 触媒化成工業株式会社 | 炭化水素油の接触分解用触媒と接触分解法 |
EP0394501B1 (de) | 1989-04-17 | 1992-10-07 | H.C. Starck GmbH & Co. KG | Verfahren zur Herstellung von alpha-A1203-Sinterkörpern |
US5178849A (en) * | 1991-03-22 | 1993-01-12 | Norton Company | Process for manufacturing alpha alumina from dispersible boehmite |
JP3119271B2 (ja) | 1991-07-24 | 2000-12-18 | 日産化学工業株式会社 | アルミナゾル及びその製造方法 |
JPH06104568A (ja) | 1992-09-18 | 1994-04-15 | Toshiba Corp | 多層配線板の製造方法 |
JP3462891B2 (ja) | 1993-06-28 | 2003-11-05 | 川研ファインケミカル株式会社 | 透明性に優れ、かつ粘度安定性の良いアルミナゾルの製造方法 |
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1997
- 1997-03-04 DE DE69722596T patent/DE69722596D1/de not_active Expired - Lifetime
- 1997-03-04 WO PCT/JP1997/000663 patent/WO1997032817A1/ja active IP Right Grant
- 1997-03-04 KR KR10-1998-0706976A patent/KR100402831B1/ko not_active IP Right Cessation
- 1997-03-04 EP EP97903661A patent/EP0885844B1/de not_active Expired - Lifetime
- 1997-03-04 JP JP53166297A patent/JP3304360B2/ja not_active Expired - Lifetime
- 1997-03-04 AT AT97903661T patent/ATE242176T1/de not_active IP Right Cessation
- 1997-03-04 US US09/142,440 patent/US6171573B1/en not_active Expired - Fee Related
- 1997-03-04 CN CN97192792A patent/CN1120129C/zh not_active Expired - Fee Related
Also Published As
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CN1120129C (zh) | 2003-09-03 |
KR100402831B1 (ko) | 2004-05-06 |
KR19990087539A (ko) | 1999-12-27 |
US6171573B1 (en) | 2001-01-09 |
CN1237146A (zh) | 1999-12-01 |
EP0885844B1 (de) | 2003-06-04 |
EP0885844A4 (de) | 1999-01-13 |
JP3304360B2 (ja) | 2002-07-22 |
WO1997032817A1 (fr) | 1997-09-12 |
EP0885844A1 (de) | 1998-12-23 |
DE69722596D1 (de) | 2003-07-10 |
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