AR092764A1 - Compuestos heterociclicos como plaguicidas - Google Patents
Compuestos heterociclicos como plaguicidasInfo
- Publication number
- AR092764A1 AR092764A1 ARP130103555A ARP130103555A AR092764A1 AR 092764 A1 AR092764 A1 AR 092764A1 AR P130103555 A ARP130103555 A AR P130103555A AR P130103555 A ARP130103555 A AR P130103555A AR 092764 A1 AR092764 A1 AR 092764A1
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- Prior art keywords
- alkyl
- alkoxy
- carbonylamino
- cycloalkyl
- alkenyl
- Prior art date
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- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/38—Nitrogen atoms
- C07D231/40—Acylated on said nitrogen atom
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
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- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
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- A61P33/02—Antiprotozoals, e.g. for leishmaniasis, trichomoniasis, toxoplasmosis
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- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
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- A61P33/14—Ectoparasiticides, e.g. scabicides
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- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/06—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
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- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/18—One oxygen or sulfur atom
- C07D231/20—One oxygen atom attached in position 3 or 5
- C07D231/22—One oxygen atom attached in position 3 or 5 with aryl radicals attached to ring nitrogen atoms
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- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/04—1,2,3-Triazoles; Hydrogenated 1,2,3-triazoles
- C07D249/06—1,2,3-Triazoles; Hydrogenated 1,2,3-triazoles with aryl radicals directly attached to ring atoms
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- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
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- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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- C07D403/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
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- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
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- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
- C07D417/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C07D231/56—Benzopyrazoles; Hydrogenated benzopyrazoles
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- Organic Chemistry (AREA)
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- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
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- Thiazole And Isothizaole Compounds (AREA)
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Abstract
Reivindicación 1: Uso de los compuestos de la fórmula (1) en donde A representa un radical seleccionada del grupo de fórmulas (2) en donde la línea de puntos significa el enlace con Q y en donde A lleva además m sustituyentes R²; Q representa un radical seleccionado del grupo de fórmulas (3) en donde el nitrógeno está unido al anillo A y la flecha significa en cada caso el enlace con D, y D representa un radical de la fórmula (4) en donde el nitrógeno está unido a Q y la flecha significa el enlace con B; B representa un radical seleccionado del grupo de fórmulas (5) en donde la línea de puntos significa el enlace con D y en donde B lleva además n sustituyentes R⁷; Y representa CR⁸ o nitrógeno; Z representa oxígeno o azufre; R¹ representa un radical de la serie de halógeno, ciano, nitro, amino, hidroxi, representa alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, cicloalquilo C₃₋₆, alcoxi C₁₋₆, alquenil C₃₋₆-oxi, alquinil C₃₋₆-oxi, cicloalquil C₃₋₆-oxi, alquil C₁₋₆-carboniloxi, alquenil C₂₋₆-carboniloxi, alquinil C₂₋₆-carboniloxi, cicloalquil C₃₋₆-carboniloxi, alcoxi C₁₋₆-carboniloxi, alquil C₁₋₆-sulfoniloxi, alquil C₁₋₆-amino, alquenil C₃₋₆-amino, alquinil C₃₋₆-amino, cicloalquil C₃₋₆-amino, alquil C₁₋₆-carbonilamino, alquenil C₂₋₆-carbonilamino, alquinil C₂₋₆-carbonilamino, cicloalquil C₃₋₆-carbonilamino, alcoxi C₁₋₆-carbonilamino, alquil C₁₋₆-sulfonilamino, alquil C₁₋₆-tio, alquenil C₃₋₆-tio, alquinil C₃₋₆-tio, cicloalquil C₃₋₆-tio, alquil C₁₋₆-sulfinilo, alquil C₁₋₆-sulfonilo, alquil C₁₋₆-carbonilo, alcoxi C₁₋₆-imino-alquilo C₁₋₆, alcoxi C₁₋₆-carbonilo, aminocarbonilo, alquil C₁₋₆-aminocarbonilo, di-(alquil C₁₋₆)-aminocarbonilo, aminotiocarbonilo, alquil C₁₋₆-aminosulfonilo, alquil C₁₋₆-sulfonilamino, alquil C₁₋₆-carbonilamino, alquil C₁₋₆-tiocarbonilamino, bicicloalquilo C₄₋₁₂, arilo, ariloxi, arilamino, ariltio, heteroarilo, heteroariloxi, heteroarilamino y heteroariltio dado el caso mono- o polisustituidos, igual o diferente, en donde los sustituyentes están seleccionados, de modo independiente entre sí de halógeno, ciano, nitro, hidroxi, amino, alquilo C₁₋₆, alcoxi C₁₋₆, cicloalquilo C₃₋₆, haloalcoxi C₁₋₆, alquil C₁₋₆-tio, arilo, ariloxi, ariltio, heteroarilo, heteroariloxi y heteroariltio; R² representa un radical de la serie de halógeno, ciano, nitro, amino, hidroxi, representa alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, cicloalquilo C₃₋₆, alcoxi C₁₋₆, alquen C₃₋₆-oxi, alquin C₃₋₆-oxi, cicloalcoxi C₃₋₈, alquil C₁₋₆-carboniloxi, alquenil C₂₋₆-carboniloxi, alquinil C₂₋₆-carboniloxi, cicloalquil C₃₋₆-carboniloxi, alcoxi C₁₋₆-carboniloxi, alquil C₁₋₆-sulfoniloxi, alquil C₁₋₆-amino, di-(alquil C₁₋₆)-amino, alquenil C₃₋₆-amino, alquinil C₃₋₆-amino, cicloalquil C₃₋₆-amino, alquil C₁₋₆-carbonilamino, alquenil C₂₋₆-carbonilamino, alquinil C₂₋₆-carbonilamino, cicloalquil C₃₋₆-carbonilamino, alcoxi C₁₋₆-carbonilamino, alquil C₁₋₆-sulfonilamino, alquil C₁₋₆-tio, alquenil C₃₋₆-tio, alquinil C₃₋₆-tio, cicloalquil C₃₋₆-tio, alquil C₁₋₆-sulfinilo, alquil C₁₋₆-sulfonilo, alquil C₁₋₆-carbonilo, alcoxi C₁₋₆-imino-alquilo C₁₋₆, alcoxi C₁₋₆-carbonilo, aminocarbonilo, alquil C₁₋₆-aminocarbonilo, di-(alquil C₁₋₆)-aminocarbonilo, aminotiocarbonilo, alquil C₁₋₆-aminosulfonilo, alquil C₁₋₆-sulfonilamino, alquil C₁₋₆-carbonilamino, alquil C₁₋₆-tiocarbonilamino, bicicloalquilo C₄₋₁₂, arilo, ariloxi, arilamino, ariltio, heteroarilo, heteroariloxi, heteroarilamino y heteroariltio dado el caso mono- o polisustituidos, igual o diferente, en donde los sustituyentes están seleccionados, de modo independiente entre sí, de halógeno, ciano, nitro, hidroxi, amino, alquilo C₁₋₆, alcoxi C₁₋₆, cicloalquilo C₃₋₆, haloalcoxi C₁₋₆ y alquil C₁₋₆-tio, arilo, ariloxi, ariltio, heteroarilo, heteroariloxi y heteroariltio; R³ representa un radical de la serie de hidrógeno, halógeno, ciano, nitro, amino, hidroxi, alquilo C₁₋₆, alcoxi C₁₋₆, haloalquilo C₁₋₆ y haloalcoxi C₁₋₆; R⁴ representa un radical de la serie de hidrógeno, halógeno, amino, hidroxi, alquilo C₁₋₆, alcoxi C₁₋₆, haloalquilo C₁₋₆ y haloalcoxi C₁₋₆; R⁵ representa un radical de la serie de hidrógeno, alquilo C₁₋₆, cicloalquilo C₃₋₆, haloalquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₃₋₆, cicloalquil C₃₋₆-alquilo C₁₋₆, ciano-alquilo C₁₋₆, alquil C₁₋₆-carbonilo, alquenil C₂₋₆-carbonilo, haloalquil C₁₋₆-carbonilo, haloalquenil C₂₋₆-carbonilo, alcoxi C₁₋₆-alquilo C₁₋₆, alcoxi C₁₋₆-carbonilo, alquil C₁₋₆-sulfonilo y haloalquil C₁₋₆-sulfonilo o representa C(=O)-B; R⁶ representa un radical de la serie de hidrógeno (sólo en los radicales B-26, B-33, B-36 y B-42), halógeno, ciano, nitro, amino, hidroxi, carboxilo, representa alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, cicloalquilo C₃₋₆, alcoxi C₁₋₆, alquen C₃₋₆-oxi, alquin C₃₋₆-oxi, cicloalcoxi C₃₋₆, alquil C₁₋₆-carboniloxi, alquenil C₂₋₆-carboniloxi, alquinil C₂₋₆-carboniloxi, cicloalquil C₃₋₆- carboniloxi, alcoxi C₁₋₆-carboniloxi, alquil C₁₋₆-sulfoniloxi, alquil C₁₋₆-carbonilamino, alquenil C₂₋₆-carbonilamino, alquinil C₂₋₆-carbonilamino, cicloalquil C₃₋₆-carbonilamino, alcoxi C₁₋₆-carbonilamino, alquil C₁₋₆-sulfonilamino, alquil C₁₋₆-tio, alquil C₁₋₆-sulfinilo, alquil C₁₋₆-sulfonilo, alquil C₁₋₆-carbonilo, alcoxi C₁₋₆-imino-alquilo C₁₋₆, alcoxi C₁₋₆-carbonilo, aminocarbonilo, alquil C₁₋₆-aminocarbonilo, di-(alquil C₁₋₆)-aminocarbonilo, aminotiocarbonilo, alquil C₁₋₆-aminosulfonilo, alquil C₁₋₆-sulfonilamino, alquil C₁₋₆-carbonilamino, haloalquil C₁₋₆-carbonilamino, alquil C₁₋₆-tiocarbonilamino, bicicloalquilo C₄₋₁₂, arilo, ariloxi, heteroarilo, heteroariloxi dado el caso mono- o polisustituidos, igual o diferente, en donde los sustituyentes están seleccionados, de modo independiente entre sí, de halógeno, ciano, nitro, hidroxi, amino, alquilo C₁₋₆, alcoxi C₁₋₆, cicloalquilo C₃₋₆, haloalcoxi C₁₋₆ y alquil C₁₋₆-tio; R⁷ representa un radical de la serie de halógeno, nitro, ciano, amino, hidroxi, representa alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, cicloalquilo C₃₋₆, alcoxi C₁₋₆, alquen C₃₋₆-oxi, alquin C₃₋₆-oxi, cicloalcoxi C₃₋₆, alquil C₁₋₆-carboniloxi, alquenil C₂₋₆-carboniloxi, alquinil C₂₋₆-carboniloxi, cicloalquil C₃₋₆-carboniloxi, alcoxi C₁₋₆-carboniloxi, alquil C₁₋₆-sulfoniloxi, alquil C₁₋₆-carbonilamino, alquenil C₂₋₆-carbonilamino, alquinil C₂₋₆-carbonilamino, cicloalquil
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