AR017422A1 - Compuesto organometalico adecuado para usar como catalizador para la preparacion de un ester y proceso para preparar dicho ester. - Google Patents
Compuesto organometalico adecuado para usar como catalizador para la preparacion de un ester y proceso para preparar dicho ester.Info
- Publication number
- AR017422A1 AR017422A1 ARP980106093A ARP980106093A AR017422A1 AR 017422 A1 AR017422 A1 AR 017422A1 AR P980106093 A ARP980106093 A AR P980106093A AR P980106093 A ARP980106093 A AR P980106093A AR 017422 A1 AR017422 A1 AR 017422A1
- Authority
- AR
- Argentina
- Prior art keywords
- ester
- catalyst
- preparation
- prepare
- composite
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0212—Alkoxylates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0255—Phosphorus containing compounds
- B01J31/0257—Phosphorus acids or phosphorus acid esters
- B01J31/0258—Phosphoric acid mono-, di- or triesters ((RO)(R'O)2P=O), i.e. R= C, R'= C, H
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- B01J31/068—Polyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/84—Boron, aluminium, gallium, indium, thallium, rare-earth metals, or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/49—Esterification or transesterification
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/31—Aluminium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polyesters Or Polycarbonates (AREA)
- Catalysts (AREA)
Abstract
Un compuesto organometálico para usar como un catalizador para la preparacion de un éster que comprende al producto de la reaccion de un ortoéstercondensado de titanio, circonio o aluminio, un alcohol que contiene al menos dos grupos hidroxilo, unco mpuesto de organofosforo que contiene al menos un grupoP-OH y una base. Un proceso para la preparacion de un éster que comprende llevar a cabo una reaccion de esterificacion ante la presencia del catalizador. Enotra realizacion, el compuestoorganome tálico adecuado para usar como catalizador en un proceso de esterificacion comprende al producto de la reaccion de,además, ácido 2-hidroxi carboxílico.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9725419.7A GB9725419D0 (en) | 1997-12-02 | 1997-12-02 | Esterification catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
AR017422A1 true AR017422A1 (es) | 2001-09-05 |
Family
ID=10822947
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP980106093A AR017422A1 (es) | 1997-12-02 | 1998-12-01 | Compuesto organometalico adecuado para usar como catalizador para la preparacion de un ester y proceso para preparar dicho ester. |
Country Status (25)
Country | Link |
---|---|
US (1) | US6372929B1 (es) |
EP (1) | EP1035916B1 (es) |
JP (1) | JP4377053B2 (es) |
KR (1) | KR100552882B1 (es) |
CN (1) | CN1167508C (es) |
AR (1) | AR017422A1 (es) |
AT (1) | ATE205114T1 (es) |
AU (1) | AU746951B2 (es) |
BR (1) | BR9814709A (es) |
CA (1) | CA2309697A1 (es) |
CO (1) | CO4810385A1 (es) |
DE (1) | DE69801596T2 (es) |
ES (1) | ES2162478T3 (es) |
GB (1) | GB9725419D0 (es) |
HU (1) | HUP0004493A3 (es) |
ID (1) | ID24715A (es) |
MY (1) | MY128075A (es) |
NO (1) | NO20002782L (es) |
NZ (1) | NZ504219A (es) |
PL (1) | PL192913B1 (es) |
RU (1) | RU2181307C2 (es) |
SK (1) | SK8312000A3 (es) |
TR (1) | TR200001539T2 (es) |
TW (1) | TW448073B (es) |
WO (1) | WO1999028033A1 (es) |
Families Citing this family (64)
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US6255441B1 (en) | 1998-04-17 | 2001-07-03 | E. I. Du Pont De Nemours And Company | Titanium-containing catalyst composition and processes therefor and therewith |
GB9912210D0 (en) * | 1999-05-25 | 1999-07-28 | Acma Ltd | Esterification catalysts |
IT1315212B1 (it) * | 1999-07-26 | 2003-02-03 | Consiglio Nazionale Ricerche | Impiego di ortoesteri per la sintesi di acidi chirali in processi diesterificazione irreversibili biocatalizzati. |
ATE283882T1 (de) | 1999-08-24 | 2004-12-15 | Toyo Boseki | Polymerisationskatalysatoren für polyester, damit hergestellte polyester und verfahren zur herstellung von polyester |
US6075115A (en) * | 1999-10-19 | 2000-06-13 | E. I. Du Pont De Nemours And Company | Process for the production of 5-sulfo isophthalate bis-glycolate ester metal salts and oxysulfonated polyesters made therefrom |
US6166170A (en) * | 1999-12-02 | 2000-12-26 | E. I. Du Pont De Nemours And Company | Esterification catalysts and processes therefor and therewith |
US6372879B1 (en) | 2000-01-07 | 2002-04-16 | Atofina Chemicals, Inc. | Polyester polycondensation with catalyst and a catalyst enhancer |
TW546330B (en) * | 2000-01-07 | 2003-08-11 | Teijin Ltd | Biaxially oriented polyester film for metal sheet laminating molding |
JP5152608B2 (ja) * | 2000-01-26 | 2013-02-27 | 東洋紡株式会社 | ポリエステル重合触媒およびこれを用いて製造されたポリエステル並びにポリエステルの製造方法 |
US6355817B1 (en) * | 2000-07-15 | 2002-03-12 | Exxonmobil Chemical Patents Inc. | Optimized catalyst addition to enhance esterification catalyst performance |
US6303738B1 (en) * | 2000-08-04 | 2001-10-16 | E. I. Du Pont De Nemours And Company | Esterification process |
MXPA03002116A (es) | 2000-09-12 | 2003-06-19 | Toyo Boseki | Poliester, metodo para producirlo y catalizador para la polimerizacion del mismo. |
US7767612B2 (en) * | 2000-11-21 | 2010-08-03 | Johnson Matthey Plc | Esterification catalyst, polyester process and polyester article |
DE10059612A1 (de) * | 2000-12-01 | 2002-06-20 | Bayer Ag | Titan-/Zirkonium-Katalysatoren sowie deren Verwendung zur Herstellung von Estern oder Polyestern |
KR100905831B1 (ko) * | 2001-01-18 | 2009-07-02 | 토요 보세키 가부시기가이샤 | 폴리에스테르 중합촉매, 폴리에스테르 및 폴리에스테르의제조방법 |
US6914107B2 (en) * | 2001-01-24 | 2005-07-05 | E. I. Du Pont De Nemours And Company | Catalyst composition and process therewith |
JP5028712B2 (ja) * | 2001-02-23 | 2012-09-19 | 東洋紡績株式会社 | 白色配向ポリエステルフィルム |
CN1328300C (zh) * | 2001-02-23 | 2007-07-25 | 东洋纺织株式会社 | 聚酯聚合催化剂、利用其制得的聚酯和聚酯的制造方法 |
US6489433B2 (en) | 2001-02-23 | 2002-12-03 | E. I. Du Pont De Nemours And Company | Metal-containing composition and process therewith |
US6506853B2 (en) | 2001-02-28 | 2003-01-14 | E. I. Du Pont De Nemours And Company | Copolymer comprising isophthalic acid |
DE10127146A1 (de) * | 2001-06-02 | 2002-12-05 | Zimmer Ag | Verfahren zur Herstellung von Polybutylenterephthalat |
CA2451994C (en) | 2001-07-16 | 2011-03-22 | Teijin Limited | Catalyst for polyester production and process for producing polyester with the same |
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JP3962235B2 (ja) * | 2001-08-29 | 2007-08-22 | 帝人ファイバー株式会社 | ポリエステル繊維及びその製造方法 |
WO2003027166A1 (en) | 2001-09-20 | 2003-04-03 | Teijin Limited | Process for producing poly(ethylene-aromatic dicarboxylate ester) resin and resin product |
GB0128205D0 (en) * | 2001-11-26 | 2002-01-16 | Ici Plc | Catalyst and process |
KR100589970B1 (ko) | 2002-02-14 | 2006-06-19 | 미쓰이 가가쿠 가부시키가이샤 | 폴리에스테르 수지 및 폴리에스테르 제조용 촉매, 이촉매를 이용하는 폴리에스테르 수지의 제조 방법, 이촉매에 의해 얻어지는 폴리에스테르 수지 및 이폴리에스테르 수지로 이루어지는 중공 성형 용기 |
KR100469901B1 (ko) * | 2002-04-08 | 2005-02-02 | 도레이새한 주식회사 | 폴리에스테르 제조용 촉매조성물 |
KR20030084183A (ko) * | 2002-04-25 | 2003-11-01 | 켐엔텍 주식회사 | 폴리에스테르의 제조방법 |
US20030203811A1 (en) | 2002-04-25 | 2003-10-30 | Putzig Donald Edward | Stable aqueous solutions comprising titanium and zinc and process therewith |
GB0215961D0 (en) * | 2002-07-10 | 2002-08-21 | Ici Plc | Supported catalyst |
US6841505B2 (en) | 2002-07-26 | 2005-01-11 | E..I. Du Pont De Nemours And Company | Titanium-zirconium catalyst compositions and use thereof |
US6953768B2 (en) | 2002-11-26 | 2005-10-11 | Teck Cominco Metals Ltd. | Multi-component catalyst system for the polycondensation manufacture of polyesters |
GB0228267D0 (en) * | 2002-12-04 | 2003-01-08 | Johnson Matthey Plc | Catalyst and process |
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TWI402293B (zh) | 2006-04-06 | 2013-07-21 | Teijin Fibers Ltd | Production method of polyethylene terephthalate |
ATE552823T1 (de) * | 2006-05-19 | 2012-04-15 | Mary Kay Inc | Zubereitungen enthaltend glycerylsalicylatverbindungen |
US7745368B2 (en) * | 2006-07-28 | 2010-06-29 | Eastman Chemical Company | Non-precipitating alkali/alkaline earth metal and aluminum compositions made with organic hydroxyacids |
US7709593B2 (en) * | 2006-07-28 | 2010-05-04 | Eastman Chemical Company | Multiple feeds of catalyst metals to a polyester production process |
US7709595B2 (en) * | 2006-07-28 | 2010-05-04 | Eastman Chemical Company | Non-precipitating alkali/alkaline earth metal and aluminum solutions made with polyhydroxyl ether solvents |
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WO2015087412A1 (ja) * | 2013-12-11 | 2015-06-18 | 賢次郎 牧野 | 線状のアルコキシチタン酸・リン酸重合体の製造方法 |
CN104117378B (zh) * | 2014-06-29 | 2016-03-02 | 陈昆 | 酯化反应催化剂的制备方法 |
JP5861129B2 (ja) * | 2014-07-24 | 2016-02-16 | 健一 牧野 | 線状のアルコキシチタン酸・リン酸重合体の製造方法 |
Family Cites Families (7)
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---|---|---|---|---|
GB1421972A (en) * | 1973-07-16 | 1976-01-21 | Ici Ltd | Polyester catalysts |
US4087402A (en) * | 1975-09-30 | 1978-05-02 | Kenrich Petrochemicals, Inc. | Organo-titanate chelates and their uses |
US4072631A (en) * | 1976-12-01 | 1978-02-07 | Basf Wyandotte Corporation | Vanadyl alcoholate, organic titanate, polyhydric alcohol compositions as esterification/transesterification catalysts |
US5453479A (en) * | 1993-07-12 | 1995-09-26 | General Electric Company | Polyesterification catalyst |
DE19518943C2 (de) * | 1995-05-23 | 1999-12-09 | Inventa Fischer Gmbh | Verfahren zur Herstellung von Polyestern unter Verwendung von titanhaltigen Katalysator-Inhibitor-Kombinationen |
GB2314081B (en) * | 1996-06-11 | 2000-02-23 | Tioxide Specialties Ltd | Esterification process using an organotitanium or organozirconium catalyst |
EP0816354A1 (de) * | 1996-06-25 | 1998-01-07 | Bayer Ag | Verfahren zur Herstellung und Stabilisierung von aliphatischen Sechsringcarbonaten |
-
1997
- 1997-12-02 GB GBGB9725419.7A patent/GB9725419D0/en not_active Ceased
-
1998
- 1998-11-16 SK SK831-2000A patent/SK8312000A3/sk unknown
- 1998-11-16 BR BR9814709-9A patent/BR9814709A/pt not_active Application Discontinuation
- 1998-11-16 DE DE69801596T patent/DE69801596T2/de not_active Expired - Lifetime
- 1998-11-16 CN CNB988117010A patent/CN1167508C/zh not_active Expired - Lifetime
- 1998-11-16 CA CA002309697A patent/CA2309697A1/en not_active Abandoned
- 1998-11-16 AU AU11664/99A patent/AU746951B2/en not_active Ceased
- 1998-11-16 RU RU2000117273/04A patent/RU2181307C2/ru not_active IP Right Cessation
- 1998-11-16 EP EP98954609A patent/EP1035916B1/en not_active Expired - Lifetime
- 1998-11-16 AT AT98954609T patent/ATE205114T1/de not_active IP Right Cessation
- 1998-11-16 TR TR2000/01539T patent/TR200001539T2/xx unknown
- 1998-11-16 HU HU0004493A patent/HUP0004493A3/hu unknown
- 1998-11-16 KR KR1020007005951A patent/KR100552882B1/ko not_active IP Right Cessation
- 1998-11-16 NZ NZ504219A patent/NZ504219A/en unknown
- 1998-11-16 ID IDW20001038A patent/ID24715A/id unknown
- 1998-11-16 PL PL340912A patent/PL192913B1/pl unknown
- 1998-11-16 WO PCT/GB1998/003448 patent/WO1999028033A1/en active IP Right Grant
- 1998-11-16 JP JP2000523004A patent/JP4377053B2/ja not_active Expired - Lifetime
- 1998-11-16 ES ES98954609T patent/ES2162478T3/es not_active Expired - Lifetime
- 1998-11-27 TW TW087119733A patent/TW448073B/zh not_active IP Right Cessation
- 1998-11-30 MY MYPI98005421A patent/MY128075A/en unknown
- 1998-11-30 CO CO98070685A patent/CO4810385A1/es unknown
- 1998-12-01 AR ARP980106093A patent/AR017422A1/es active IP Right Grant
-
2000
- 2000-05-09 US US09/568,206 patent/US6372929B1/en not_active Expired - Lifetime
- 2000-05-31 NO NO20002782A patent/NO20002782L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
WO1999028033A1 (en) | 1999-06-10 |
GB9725419D0 (en) | 1998-01-28 |
CN1167508C (zh) | 2004-09-22 |
NO20002782L (no) | 2000-06-26 |
CA2309697A1 (en) | 1999-06-10 |
BR9814709A (pt) | 2000-10-03 |
JP4377053B2 (ja) | 2009-12-02 |
EP1035916A1 (en) | 2000-09-20 |
ID24715A (id) | 2000-08-03 |
SK8312000A3 (en) | 2000-10-09 |
US6372929B1 (en) | 2002-04-16 |
TR200001539T2 (tr) | 2000-12-21 |
ATE205114T1 (de) | 2001-09-15 |
HUP0004493A2 (hu) | 2001-04-28 |
CN1280522A (zh) | 2001-01-17 |
HUP0004493A3 (en) | 2006-04-28 |
DE69801596D1 (de) | 2001-10-11 |
RU2181307C2 (ru) | 2002-04-20 |
NZ504219A (en) | 2001-11-30 |
TW448073B (en) | 2001-08-01 |
KR100552882B1 (ko) | 2006-02-20 |
PL340912A1 (en) | 2001-03-12 |
PL192913B1 (pl) | 2006-12-29 |
EP1035916B1 (en) | 2001-09-05 |
ES2162478T3 (es) | 2001-12-16 |
MY128075A (en) | 2007-01-31 |
DE69801596T2 (de) | 2002-04-18 |
JP2001524536A (ja) | 2001-12-04 |
CO4810385A1 (es) | 1999-06-30 |
AU1166499A (en) | 1999-06-16 |
NO20002782D0 (no) | 2000-05-31 |
KR20010032669A (ko) | 2001-04-25 |
AU746951B2 (en) | 2002-05-09 |
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