TR200001539T2 - Esterleşme katalizörleri - Google Patents

Esterleşme katalizörleri

Info

Publication number
TR200001539T2
TR200001539T2 TR2000/01539T TR200001539T TR200001539T2 TR 200001539 T2 TR200001539 T2 TR 200001539T2 TR 2000/01539 T TR2000/01539 T TR 2000/01539T TR 200001539 T TR200001539 T TR 200001539T TR 200001539 T2 TR200001539 T2 TR 200001539T2
Authority
TR
Turkey
Prior art keywords
catalyst
ester
reaction product
esterification
organometallic compound
Prior art date
Application number
TR2000/01539T
Other languages
English (en)
Inventor
Ridland John
Wesley Hepplewhite Iain
Original Assignee
Acma Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Acma Limited filed Critical Acma Limited
Publication of TR200001539T2 publication Critical patent/TR200001539T2/tr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0257—Phosphorus acids or phosphorus acid esters
    • B01J31/0258—Phosphoric acid mono-, di- or triesters ((RO)(R'O)2P=O), i.e. R= C, R'= C, H
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/068—Polyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/84—Boron, aluminium, gallium, indium, thallium, rare-earth metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/49—Esterification or transesterification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Catalysts (AREA)

Abstract

Bir ester hazirlanmasinda katalizör olarak kullanim için uygun olan bir organometalik bilesik, titanyum, zirkonyum veya alüminyumun bir orto esteri veya kondanse orto esteri ile en az iki hidroksil grubu ihtiva eden bir alkol, en az bir P-OH grubu ihtiva eden bir organofosfor bilesigi ve bir bazin reaksiyon ürününden olusur. Bir ester hazirlamaya mahsus yöntem, bir esterlestirme reaksiyonunun bu katalizör varliginda yapilmasini içerir. Baska bir sikta, bir esterlesme yönteminde katalizör olarak kullanim için uygun olan organometalik bilesik, yukaridakilere ilaveten 2-hidroksi karboksilik asit içeren bilesenlerin reaksiyon ürününden olusur.
TR2000/01539T 1997-12-02 1998-11-16 Esterleşme katalizörleri TR200001539T2 (tr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB9725419.7A GB9725419D0 (en) 1997-12-02 1997-12-02 Esterification catalysts

Publications (1)

Publication Number Publication Date
TR200001539T2 true TR200001539T2 (tr) 2000-12-21

Family

ID=10822947

Family Applications (1)

Application Number Title Priority Date Filing Date
TR2000/01539T TR200001539T2 (tr) 1997-12-02 1998-11-16 Esterleşme katalizörleri

Country Status (25)

Country Link
US (1) US6372929B1 (tr)
EP (1) EP1035916B1 (tr)
JP (1) JP4377053B2 (tr)
KR (1) KR100552882B1 (tr)
CN (1) CN1167508C (tr)
AR (1) AR017422A1 (tr)
AT (1) ATE205114T1 (tr)
AU (1) AU746951B2 (tr)
BR (1) BR9814709A (tr)
CA (1) CA2309697A1 (tr)
CO (1) CO4810385A1 (tr)
DE (1) DE69801596T2 (tr)
ES (1) ES2162478T3 (tr)
GB (1) GB9725419D0 (tr)
HU (1) HUP0004493A3 (tr)
ID (1) ID24715A (tr)
MY (1) MY128075A (tr)
NO (1) NO20002782L (tr)
NZ (1) NZ504219A (tr)
PL (1) PL192913B1 (tr)
RU (1) RU2181307C2 (tr)
SK (1) SK8312000A3 (tr)
TR (1) TR200001539T2 (tr)
TW (1) TW448073B (tr)
WO (1) WO1999028033A1 (tr)

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Also Published As

Publication number Publication date
PL192913B1 (pl) 2006-12-29
SK8312000A3 (en) 2000-10-09
NO20002782L (no) 2000-06-26
JP4377053B2 (ja) 2009-12-02
EP1035916A1 (en) 2000-09-20
CO4810385A1 (es) 1999-06-30
CN1167508C (zh) 2004-09-22
NZ504219A (en) 2001-11-30
BR9814709A (pt) 2000-10-03
RU2181307C2 (ru) 2002-04-20
ID24715A (id) 2000-08-03
GB9725419D0 (en) 1998-01-28
WO1999028033A1 (en) 1999-06-10
HUP0004493A2 (hu) 2001-04-28
DE69801596T2 (de) 2002-04-18
AR017422A1 (es) 2001-09-05
JP2001524536A (ja) 2001-12-04
CN1280522A (zh) 2001-01-17
PL340912A1 (en) 2001-03-12
EP1035916B1 (en) 2001-09-05
HUP0004493A3 (en) 2006-04-28
TW448073B (en) 2001-08-01
AU1166499A (en) 1999-06-16
NO20002782D0 (no) 2000-05-31
ES2162478T3 (es) 2001-12-16
MY128075A (en) 2007-01-31
KR20010032669A (ko) 2001-04-25
US6372929B1 (en) 2002-04-16
DE69801596D1 (de) 2001-10-11
KR100552882B1 (ko) 2006-02-20
CA2309697A1 (en) 1999-06-10
AU746951B2 (en) 2002-05-09
ATE205114T1 (de) 2001-09-15

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