JPS5674123A - Preparation of polyester - Google Patents
Preparation of polyesterInfo
- Publication number
- JPS5674123A JPS5674123A JP15148079A JP15148079A JPS5674123A JP S5674123 A JPS5674123 A JP S5674123A JP 15148079 A JP15148079 A JP 15148079A JP 15148079 A JP15148079 A JP 15148079A JP S5674123 A JPS5674123 A JP S5674123A
- Authority
- JP
- Japan
- Prior art keywords
- polyester
- mol
- glycol
- compound
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Polyesters Or Polycarbonates (AREA)
Abstract
PURPOSE: To obtain a polyester of high polymerization degree having good thermal stability without discoloration in a short time, by adding a specific phosphorus compound to the reaction system in the presence of a glycol-soluble tungsten compound as a catalyst.
CONSTITUTION: In preparing a polyester from terephthalic acid or a dicarboxylic acid (ester-forming derivative) consisting of the terephthalic acid essentially and ethylene glycol or a glycol consisting of the ethylene glycol (ester-forming derivative) essentially, a glycol-soluble tungsten compound as a catalyst in an amount of 0.2× 10-4W5×10-4mol/mol an acid component consituting the polyester is used, and a phsphorus compound expressed by the formula (R1 is H or lower alkyl; R2 is H, lower alkyl or OH) in an amount of 0.2×10-4W10×10-4mol/mol the acid component constituting the polyester is added to the system.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15148079A JPS5674123A (en) | 1979-11-22 | 1979-11-22 | Preparation of polyester |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15148079A JPS5674123A (en) | 1979-11-22 | 1979-11-22 | Preparation of polyester |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5674123A true JPS5674123A (en) | 1981-06-19 |
Family
ID=15519417
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP15148079A Pending JPS5674123A (en) | 1979-11-22 | 1979-11-22 | Preparation of polyester |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5674123A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10136885A1 (en) * | 2001-07-24 | 2003-02-13 | Inst Angewandte Chemie Berlin | Highly active peroxotungsten catalyst used in oxidation reactions in both solvent- and halogen-free systems, contains an oxyfunctionalized phosphonic acid (or its alkali or ammonium salt) as stabilizer |
JP2006016427A (en) * | 2004-06-30 | 2006-01-19 | Mitsubishi Chemicals Corp | Method for producing polyester |
JP2006124599A (en) * | 2004-11-01 | 2006-05-18 | Mitsubishi Chemicals Corp | Catalyst for polyester polycondensation reaction and method for producing polyester |
-
1979
- 1979-11-22 JP JP15148079A patent/JPS5674123A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10136885A1 (en) * | 2001-07-24 | 2003-02-13 | Inst Angewandte Chemie Berlin | Highly active peroxotungsten catalyst used in oxidation reactions in both solvent- and halogen-free systems, contains an oxyfunctionalized phosphonic acid (or its alkali or ammonium salt) as stabilizer |
DE10136885C2 (en) * | 2001-07-24 | 2003-09-25 | Inst Angewandte Chemie Berlin | Peroxotungsten catalysts with oxyfunctionalized phosphonic acids and their use |
JP2006016427A (en) * | 2004-06-30 | 2006-01-19 | Mitsubishi Chemicals Corp | Method for producing polyester |
JP2006124599A (en) * | 2004-11-01 | 2006-05-18 | Mitsubishi Chemicals Corp | Catalyst for polyester polycondensation reaction and method for producing polyester |
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