WO2009036249A1 - Method for curing a dielectric film - Google Patents

Method for curing a dielectric film Download PDF

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Publication number
WO2009036249A1
WO2009036249A1 PCT/US2008/076134 US2008076134W WO2009036249A1 WO 2009036249 A1 WO2009036249 A1 WO 2009036249A1 US 2008076134 W US2008076134 W US 2008076134W WO 2009036249 A1 WO2009036249 A1 WO 2009036249A1
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WO
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Prior art keywords
dielectric film
approximately
radiation
low
exposing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2008/076134
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English (en)
French (fr)
Inventor
Junjun Liu
Dorel I. Toma
Eric M. Lee
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Tokyo Electron Ltd
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Tokyo Electron Ltd
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Priority to JP2010525019A priority Critical patent/JP2011502343A/ja
Priority to CN2008801070343A priority patent/CN101816059B/zh
Publication of WO2009036249A1 publication Critical patent/WO2009036249A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67011Apparatus for manufacture or treatment
    • H01L21/67098Apparatus for thermal treatment
    • H01L21/67115Apparatus for thermal treatment mainly by radiation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment
    • H01L21/31058After-treatment of organic layers

Definitions

  • the invention relates to a method for treating a dielectric film and, more particularly, to a method of curing a low dielectric constant (low-k) dielectric film and thermally treating the low-k dielectric film.
  • low-k low dielectric constant
  • interconnect delay is a major limiting factor in the drive to improve the speed and performance of integrated circuits (IC).
  • One way to minimize interconnect delay is to reduce interconnect capacitance by using low dielectric constant (low-k) materials as the insulating dielectric for metal wires in the IC devices.
  • low-k materials have been developed to replace relatively high dielectric constant insulating materials, such as silicon dioxide.
  • low-k films are being utilized for inter-level and intra-level dielectric layers between metal wires in semiconductor devices.
  • material films are formed with pores, i.e., porous low-k dielectric films.
  • Such low-k films can be deposited by a spin-on dielectric (SOD) method similar to the application of photo-resist, or by chemical vapor deposition (CVD).
  • SOD spin-on dielectric
  • CVD chemical vapor deposition
  • Low-k materials are less robust than more traditional silicon dioxide, and the mechanical strength deteriorates further with the introduction of porosity.
  • the porous low-k films can easily be damaged during plasma processing, thereby making desirable a mechanical strengthening process. It has been understood that enhancement of the material strength of porous low-k dielectrics is essential for their successful integration. Aimed at mechanical strengthening, alternative curing techniques are being explored to make porous low-k films more robust and suitable for integration.
  • the curing of a polymer includes a process whereby a thin film deposited for example using spin-on or vapor deposition (such as chemical vapor deposition CVD) techniques, is treated in order to cause cross-linking within the film.
  • free radical polymerization is understood to be the primary route for cross-linking.
  • mechanical properties such as for example the Young's modulus, the film hardness, the fracture toughness and the interfacial adhesion, are improved, thereby improving the fabrication robustness of the low-k film.
  • the objectives of post-deposition treatments may vary from film to film, including for example the removal of moisture, the removal of solvents, the burn-out of porogens used to form the pores in the porous dielectric film, the improvement of the mechanical properties for such films, and so on.
  • Low dielectric constant (low k) materials are conventionally thermally cured at a temperature in the range of 300 0 C to 400 0 C for CVD films. For instance, furnace curing has been sufficient in producing strong, dense low-k films with a dielectric constant greater than approximately 2.5. However, when processing porous dielectric films (such as ultra low-k films) with a high level of porosity, the degree of cross-linking achievable with thermal treatment (or thermal curing) is no longer sufficient to produce films of adequate strength for a robust interconnect structure.
  • the invention relates to a method for treating a dielectric film and, more particularly, to a method of curing a low dielectric constant (low-k) dielectric film.
  • a method of, and computer readable medium for, curing a low dielectric constant (low-k) dielectric film on a substrate wherein the dielectric constant of the low-k dielectric film is less than a value of approximately 4.
  • the method comprises exposing the low-k dielectric film to ultraviolet (UV) radiation. Following the UV exposure, the dielectric film is exposed to IR radiation.
  • UV ultraviolet
  • FIG. 1 is a flow chart of a method of treating a dielectric film according to an embodiment
  • FIG. 2 provides exemplary data for treating a dielectric film
  • FIGs. 3A through 3C are schematic representations of a transfer system for a drying system and a curing system according to an embodiment
  • FIG. 4 is a schematic cross-sectional view of a drying system according to another embodiment.
  • FIG. 5 is a schematic cross-sectional view of a curing system according to another embodiment.
  • alternative curing methods are more efficient in energy transfer, as compared to thermal curing processes, and the higher energy levels found in the form of energetic particles, such as accelerated electrons, ions, or neutrals, or in the form of energetic photons, can easily excite electrons in a low-k film, thus efficiently breaking chemical bonds and dissociating side groups.
  • These alternative curing methods facilitate the generation of cross-linking initiators (free radicals) and can improve the energy transfer required in actual cross-linking. As a result, the degree of cross-linking can be increased at a reduced thermal budget.
  • EB electron beam
  • UV ultraviolet
  • IR infrared
  • MW microwave
  • a method of curing a low dielectric constant (low-k) dielectric film on a substrate is described, wherein the dielectric constant of the low-k dielectric film is less than a value of approximately 4.
  • the method comprises exposing the low-k dielectric film to ultraviolet (UV) radiation. Following the UV exposure, the dielectric film is exposed to infrared (IR) radiation.
  • UV ultraviolet
  • IR infrared
  • the low-k dielectric film may be heated by elevating the temperature of the substrate to a cure temperature ranging from approximately 200 degrees C to approximately 600 degrees C. Alternatively, the cure temperature ranges from approximately 300 degrees C to approximately 500 degrees C. Further, during the UV exposure, the low-k dielectric film may be exposed to IR radiation.
  • the low-k dielectric film may be heated by elevating the temperature of the substrate to a thermal treatment temperature ranging from approximately 200 degrees C to approximately 600 degrees C.
  • the thermal treatment temperature ranges from approximately 300 degrees C to approximately 500 degrees C and, desirably, the thermal treatment temperature ranges from approximately 350 degrees C to approximately 450 degrees C.
  • the substrate, to be treated may be a semiconductor, a metallic conductor, or any other substrate to which the dielectric film is to be formed upon.
  • the dielectric film can have a dielectric constant value (before drying and/or curing, or after drying and/or curing, or both) less than the dielectric constant of SiO 2 , which is approximately 4 (e.g., the dielectric constant for thermal silicon dioxide can range from 3.8 to 3.9).
  • the dielectric film may have a dielectric constant (before drying and/or curing, or after drying PCT Docket No.: TDC-002 WO
  • the dielectric film may be described as a low dielectric constant (low-k) film or an ultra-low-k film.
  • the dielectric film may, for instance, include a dual phase porous low-k film which may have a higher dielectric constant prior to porogen burn-out than following porogen burn-out. Additionally, the dielectric film may have moisture and/or other contaminants which cause the dielectric constant to be higher prior to drying and/or curing than following drying and/or curing.
  • the dielectric film can be formed using chemical vapor deposition (CVD) techniques, or spin-on dielectric (SOD) techniques such as those offered in the Clean Track ACT 8 SOD and ACT 12 SOD coating systems commercially available from Tokyo Electron Limited (TEL).
  • the Clean Track ACT 8 (200 mm) and ACT 12 (300 mm) coating systems provide coat, bake, and cure tools for SOD materials.
  • the track system can be configured for processing substrate sizes of 100 mm, 200 mm, 300 mm, and greater.
  • Other systems and methods for forming a dielectric film on a substrate as known to those skilled in the art of both spin-on dielectric technology and CVD dielectric technology are suitable for the invention.
  • the dielectric film can, for example, be characterized as a low dielectric constant (or low-k) dielectric film.
  • the dielectric film may include at least one of an organic, inorganic, and inorganic-organic hybrid material. Additionally, the dielectric film may be porous or non-porous.
  • the dielectric film may include an inorganic, silicate-based material, such as oxidized organosilane (or organo siloxane), deposited using CVD techniques. Examples of such films include Black DiamondTM CVD organosilicate glass (OSG) films commercially available from Applied Materials, Inc., or CoralTM CVD films commercially available from Novellus Systems.
  • OSG Black DiamondTM CVD organosilicate glass
  • porous dielectric films can include single-phase materials, such as a silicon oxide-based matrix having terminal organic side groups that inhibit cross-linking during a curing process to create small voids (or pores).
  • porous dielectric films can include dual-phase materials, such as a silicon oxide-based matrix having inclusions of organic material (e.g., a porogen) that is decomposed and evaporated during a curing PCT Docket No.: TDC-002 WO
  • the dielectric film may include an inorganic, silicate- based material, such as hydrogen silsesquioxane (HSQ) or methyl silsesquioxane (MSQ), deposited using SOD techniques.
  • HSQ hydrogen silsesquioxane
  • MSQ methyl silsesquioxane
  • examples of such films include FOx HSQ commercially available from Dow Corning, XLK porous HSQ commercially available from Dow Corning, and JSR LKD-5109 commercially available from JSR Microelectronics.
  • the dielectric film can include an organic material deposited using SOD techniques.
  • Such films include SiLK-I, SiLK-J, SiLK-H, SiLK-D, porous SiLK-T, porous SiLK-Y, and porous SiLK-Z semiconductor dielectric resins commercially available from Dow Chemical, and FLARETM, and Nano- glass commercially available from Honeywell.
  • the method includes a flow chart 500 beginning in 510 with optionally drying the dielectric film on the substrate in a first processing system.
  • the first processing system may include a drying system configured to remove, or partially remove, one or more contaminants in the dielectric film, including, for example, moisture, solvent, porogen, or any other contaminant that may interfere with a subsequent curing process.
  • the dielectric film is exposed to UV radiation.
  • the UV-assisted curing of the dielectric film may be performed in a second processing system.
  • the second processing system may include a curing system configured to perform a UV-assisted cure of the dielectric film by causing or partially causing cross-linking within the dielectric film in order to, for example, improve the mechanical properties of the dielectric film.
  • the substrate can be transferred from the first processing system to the second processing system under vacuum in order to minimize contamination.
  • the exposure of the dielectric film to UV radiation may include exposing the dielectric film to UV radiation from one or more UV lamps, one or more UV LEDs (light-emitting diodes), or one or more UV lasers, or a combination of two or more thereof.
  • the UV radiation may range in wavelength from approximately 100 nanometers to approximately 600 nanometers. Desirably, the UV radiation may range in wavelength from approximately 200 nanometers to approximately 400 nanometers and, more desirably, the UV radiation may range in wavelength from approximately 200 nanometers to approximately 300 nanometers.
  • the dielectric film may be heated by elevating the temperature of the substrate to a cure temperature ranging from approximately 200 degrees C to approximately 600 degrees C.
  • the cure temperature can range from approximately 300 degrees C to approximately 500 degrees C.
  • the dielectric film may be exposed to IR radiation.
  • the exposure of the dielectric film to IR radiation may include exposing the dielectric film to IR radiation from one or more IR lamps, one or more IR LEDs (light emitting diodes), or one or more IR lasers, or a combination of two or more thereof.
  • the IR radiation may range in wavelength from approximately 1 micron to approximately 25 microns. Desirably, the IR radiation may range in wavelength from approximately 8 microns to approximately 14 microns.
  • the dielectric film is exposed to IR radiation.
  • the exposure of the dielectric film to IR radiation may include exposing the dielectric film to IR radiation from one or more IR lamps, one or more IR LEDs (light emitting diodes), or one or more IR lasers, or both.
  • the IR radiation may range in wavelength from approximately 1 micron to approximately 25 microns. Desirably, the IR radiation may range in wavelength from approximately 8 microns to approximately 14 microns.
  • the dielectric film may be heated by elevating the temperature of the substrate to a thermal treatment temperature ranging from approximately 200 degrees C to approximately 600 degrees C. Alternatively, the thermal treatment temperature can range from approximately 300 degrees C to approximately 500 degrees C. Alternatively yet, the thermal treatment temperature can range from approximately 350 degrees C to approximately 550 degrees C.
  • the dielectric film may be heated through absorption of IR energy.
  • the heating may further include conductively heating the substrate by placing the substrate on a substrate holder, and heating the substrate holder using a heating device.
  • the heating device may include a resistive heating element.
  • the inventors have recognized that the energy level (hv) delivered and the rate that energy is delivered to the dielectric film (q') varies during different stages of the curing process.
  • the curing process can include mechanisms for generation of cross-link initiators, burn-out of porogens, decomposition of porogens, film cross-linking, and optionally cross-link initiator diffusion. Each mechanism may require a different energy level and rate at which energy is delivered to the dielectric film.
  • cross-link initiators may be generated using photon and phonon induced bond dissociation within the matrix material.
  • Bond dissociation can require energy levels having a wavelength less than or equal to approximately 300 to 400 nm.
  • porogen burn-out may be facilitated with photon absorption by the photosensitizer.
  • Porogen burn-out may require UV wavelengths, such as wavelengths less than or equal to approximately 300 to 400 nm.
  • cross-linking can be facilitated by thermal energy sufficient for bond formation and reorganization.
  • Bond formation and reorganization may require energy levels having a wavelength of approximately 9 microns which, for example, corresponds to the main absorbance peak in siloxane-based organosilicate low-k materials.
  • the IR exposure of the dielectric film, following the UV exposure may be performed in the same processing system as the UV exposure, i.e., the second processing system.
  • the IR exposure of the dielectric film, following the UV exposure may be performed in a different processing system than the UV exposure.
  • the IR exposure of the dielectric film may be performed in a third processing system, wherein the substrate can be transferred from the second processing system to the third processing system under vacuum in order to minimize contamination.
  • the dielectric film may optionally be post-treated in a post-treatment system configured to modify the cured dielectric film.
  • post-treatment can include spin coating or vapor depositing another film on the dielectric film in order to promote adhesion for PCT Docket No.: TDC-002 WO
  • adhesion promotion may be achieved in a post-treatment system by lightly bombarding the dielectric film with ions.
  • the post-treatment may comprise performing one or more of depositing another film on the dielectric film, cleaning the dielectric film, or exposing the dielectric film to plasma.
  • exemplary data is provided for treating a dielectric film.
  • the dielectric film comprises a porous dielectric film including dual-phase materials that is formed using a chemical vapor deposition (CVD) process. As illustrated in FIG.
  • CVD chemical vapor deposition
  • the refractive index is presented for several substrates, wherein each substrate has a dielectric film formed thereon which is to be cured by exposing the dielectric film to UV radiation at 266 nm.
  • the refractive index is provided for a pristine dielectric film, i.e., prior to curing (open bar), and it is provided for the corresponding cured dielectric film (cross-hatched bar).
  • the curing process causes a reduction of the refractive index, thus, indicating the removal of the second- phase constituent and the formation of pores.
  • the refractive index (for pristine and cured films) is provided for four (4) substrates where no additional heating of the dielectric film is performed, either before or after the curing process (i.e., "No additional thermal treatment”). Additionally, the refractive index (for pristine and cured films) is provided for five (5) substrates where the dielectric film is heated prior to the curing process (i.e., "Pre-cure thermal treatment”). Furthermore, the refractive index (for pristine and cured films) is provided for four (4) substrates where the dielectric film is heated following the curing process (i.e., "Post-cure thermal treatment").
  • FIG. 3A shows a processing system 1 for treating a dielectric film on a substrate, according to one embodiment.
  • the processing system 1 includes a drying system 10, and a curing system 20 coupled to the drying system 10.
  • the drying system 10 can be configured to remove, or reduce to sufficient levels, one or more contaminants in the dielectric film, including, for example, moisture, solvent, porogen, or any other contaminant that may interfere with a curing process performed in the curing system 20.
  • a sufficient reduction of a specific contaminant present within the dielectric film from prior to the drying process to following the drying process, can include a reduction of approximately 10% to approximately 100% of the specific contaminant.
  • the level of contaminant reduction may be measured using Fourier transform infrared (FTIR) spectroscopy, or mass spectroscopy.
  • FTIR Fourier transform infrared
  • mass spectroscopy or mass spectroscopy.
  • a sufficient reduction of a specific contaminant present within the dielectric film can range from approximately 50% to approximately 100%.
  • a sufficient reduction of a specific contaminant present within the dielectric film can range from approximately 80% to approximately 100%.
  • the curing system 20 may be configured to cure the dielectric film by causing or partially causing cross-linking within the dielectric film in order to, for example, improve the mechanical properties of the dielectric film. Furthermore, the curing system 20 may be configured to cure the dielectric film by causing or partially causing cross-link initiation, porogen burn-out, porogen decomposition, etc.
  • the curing system 20 can include one or more radiation sources configured to expose the substrate having the dielectric film to electro-magnetic (EM) radiation at multiple EM wavelengths.
  • the one or more radiation sources can include an infrared (IR) radiation source and an optional ultraviolet (UV) radiation source. The exposure of the substrate to UV radiation and optional IR radiation can be performed simultaneously, sequentially, or over-lapping one another.
  • the exposure of the substrate to UV radiation can, for instance, precede the exposure of the substrate to IR radiation or vice versa.
  • the IR radiation can include an IR wave-band source ranging from approximately 1 micron to approximately 25 microns and, desirably, ranging from approximately 8 microns to approximately 14 microns.
  • the UV radiation can include a UV wave-band source producing radiation ranging from approximately 100 nanometers (nm) to approximately 600 nm and, desirably, ranging from approximately 200 nm to approximately 400 nm.
  • a transfer system 30 can be coupled to the drying system 10 in order to transfer substrates into and out of the drying system 10 and the curing system 20, and exchange substrates with a multielement manufacturing system 40.
  • Transfer system 30 may transfer substrates to and from drying system 10 and curing system 20 while maintaining a vacuum environment.
  • the drying and curing systems 10, 20, and the transfer system 30 can, for example, include a processing element within the multi-element manufacturing system 40.
  • the multielement manufacturing system 40 can permit the transfer of substrates to and from processing elements including such devices as etch systems, deposition systems, coating systems, patterning systems, metrology systems, etc.
  • an isolation assembly 50 can be utilized to couple each system.
  • the isolation assembly 50 can include at least one of a thermal insulation assembly to provide thermal isolation, and a gate valve assembly to provide vacuum isolation.
  • the drying and curing systems 10 and 20, and transfer system 30 can be placed in any sequence. [0049] As described above, the IR exposure of the substrate can be performed in the drying system 10, or the curing system 20, or a separate treatment system (not shown).
  • FIG. 3B shows a processing system 100 for treating a dielectric film on a substrate.
  • the processing system 100 includes a "cluster-tool" arrangement for a drying system 1 10, and a curing system 120.
  • the drying system 1 10 can be configured to remove, or reduce to sufficient levels, one or more PCT Docket No.: TDC-002 WO
  • the curing system 120 can be configured to cure the dielectric film by causing or partially causing cross-linking within the dielectric film in order to, for example, improve the mechanical properties of the dielectric film.
  • the processing system 100 can optionally include a post-treatment system 140 configured to modify the cured dielectric film.
  • post-treatment can include spin coating or vapor depositing another film on the dielectric film in order to promote adhesion for subsequent films or improve hydrophobicity.
  • adhesion promotion may be achieved in a post- treatment system by lightly bombarding the dielectric film with ions by, for example, exposing the substrate to plasma.
  • a transfer system 130 can be coupled to the drying system 1 10 in order to transfer substrates into and out of the drying system 1 10, and can be coupled to the curing system 120 in order to transfer substrates into and out of the curing system 120, and can be coupled to the optional post-treatment system 140 in order to transfer substrates into and out of the post-treatment system 140.
  • Transfer system 130 may transfer substrates to and from drying system 1 10, curing system 120 and optional post-treatment system 140 while maintaining a vacuum environment.
  • transfer system 130 can exchange substrates with one or more substrate cassettes (not shown). Although only two or three process systems are illustrated in FIG.
  • transfer system 130 can access transfer system 130 including for example such devices as etch systems, deposition systems, coating systems, patterning systems, metrology systems, etc.
  • an isolation assembly 150 can be utilized to couple each system.
  • the isolation assembly 150 can include at least one of a thermal insulation assembly to provide thermal isolation, and a gate valve assembly to provide vacuum isolation.
  • the transfer system 130 can serve as part of the isolation assembly 150.
  • the IR exposure of the substrate can be performed in the drying system 1 10, or the curing system 120, or a separate treatment system (not shown).
  • FIG. 3C shows a processing system 200 for treating a dielectric film on a substrate.
  • the processing system 200 includes a drying system 210, and a curing system 220.
  • the drying system 210 can be configured to remove, or reduce to sufficient levels, one or more contaminants in the dielectric film, including, for example, moisture, solvent, porogen, or any other contaminant that may interfere with a curing process performed in the curing system 220.
  • the curing system 220 can be configured to cure the dielectric film by causing or partially causing cross-linking within the dielectric film in order to, for example, improve the mechanical properties of the dielectric film.
  • the processing system 200 can optionally include a post-treatment system 240 configured to modify the cured dielectric film.
  • post-treatment can include spin coating or vapor depositing another film on the dielectric film in order to promote adhesion for subsequent films or improve hydrophobicity.
  • adhesion promotion may be achieved in a post-treatment system by lightly bombarding the dielectric film with ions by, for example, exposing the substrate to plasma.
  • Drying system 210, curing system 220, and post-treatment system 240 can be arranged horizontally or may be arranged vertically (i.e., stacked). Also, as illustrated in FIG.
  • a transfer system 230 can be coupled to the drying system 210 in order to transfer substrates into and out of the drying system 210, can be coupled to the curing system 220 in order to transfer substrates into and out of the curing system 220, and can be coupled to the optional post-treatment system 240 in order to transfer substrates into and out of the post-treatment system 240.
  • Transfer system 230 may transfer substrates to and from drying system 210, curing system 220 and optional post-treatment system 240 while maintaining a vacuum environment.
  • transfer system 230 can exchange substrates with one or more substrate cassettes (not shown). Although only three process systems are illustrated in FIG. 3C, other process systems can access transfer system 230 including for example such devices as etch systems, deposition PCT Docket No.: TDC-002 WO
  • an isolation assembly 250 can be utilized to couple each system.
  • the isolation assembly 250 can include at least one of a thermal insulation assembly to provide thermal isolation, and a gate valve assembly to provide vacuum isolation.
  • the transfer system 230 can serve as part of the isolation assembly 250.
  • At least one of the drying system 10 and the curing system 20 of the processing system 1 as depicted in FIG. 3A includes at least two transfer openings to permit the passage of the substrate therethrough.
  • the drying system 10 includes two transfer openings, the first transfer opening permits the passage of the substrate between the drying system 10 and the transfer system 30 and the second transfer opening permits the passage of the substrate between the drying system and the curing system.
  • each treatment system 1 10, 120, 140 and 210, 220, 240, respectively includes at least one transfer opening to permit the passage of the substrate therethrough.
  • Drying system 300 includes a drying chamber 310 configured to produce a clean, contaminant-free environment for drying a substrate 325 resting on substrate holder 320.
  • the drying system 300 can include a thermal treatment device 330 coupled to drying chamber 310, or to substrate holder 320, and configured to evaporate contaminants, such as for example moisture, residual solvent, etc., by elevating the temperature of substrate 325.
  • the drying system 300 can include a microwave treatment device 340 coupled to the drying chamber 310, and configured to locally heat contaminants in the presence of an oscillating electric field.
  • the drying process can utilize the thermal treatment device 330, or the microwave treatment device 340, or both to facilitate drying a dielectric film on substrate 325.
  • the thermal treatment device 330 can include one or more conductive heating elements embedded in substrate holder 320 coupled to a power source and a temperature controller.
  • each heating element can include a resistive heating element coupled to a power source configured to supply electrical power.
  • the thermal treatment device 330 can include one or more radiative heating elements coupled to a power source and a controller.
  • each radiative heating element can include a heat lamp coupled to a power source configured to supply electrical power.
  • the temperature of substrate 325 can, for example, range from approximately 20 0 C to approximately 500 0 C, and desirably, the temperature may range from approximately 200 0 C to approximately 400 0 C.
  • the microwave treatment source 340 can include a variable frequency microwave source configured to sweep the microwave frequency through a bandwidth of frequencies. Frequency variation avoids charge build-up and, hence, permits damage-free application of microwave drying techniques to sensitive electronic devices.
  • the drying system 300 can include a drying system incorporating both a variable frequency microwave device and a thermal treatment device, such as for example the microwave furnace commercially available from Lambda Technologies, Inc. (860 Aviation Parkway, Suite 900, Morrisville, NC 27560).
  • the substrate holder 320 may or may not be configured to clamp substrate 325.
  • substrate holder 320 may be configured to mechanically or electrically clamp substrate 325.
  • drying system 300 can further include a gas injection system 350 coupled to the drying chamber and configured to introduce a purge gas to drying chamber 310.
  • the purge gas can, for example, include an inert gas, such as a noble gas or nitrogen.
  • drying system 300 can include a vacuum pumping system 355 coupled to drying chamber 310 and configured to evacuate the drying chamber 310.
  • substrate 325 can be subject to an inert gas environment with or without vacuum conditions.
  • drying system 300 can include a controller 360 coupled to drying chamber 310, substrate holder 320, thermal treatment device 330, PCT Docket No.: TDC-002 WO
  • Controller 360 includes a microprocessor, a memory, and a digital I/O port capable of generating control voltages sufficient to communicate and activate inputs to the drying system 300 as well as monitor outputs from the drying system 300.
  • a program stored in the memory is utilized to interact with the drying system 300 according to a stored process recipe.
  • the controller 360 can be used to configure any number of processing elements (310, 320, 330, 340, 350, or 355), and the controller 360 can collect, provide, process, store, and display data from processing elements.
  • the controller 360 can include a number of applications for controlling one or more of the processing elements.
  • controller 360 can include a graphic user interface (GUI) component (not shown) that can provide interfaces that enable a user to monitor and/or control one or more processing elements.
  • GUI graphic user interface
  • Curing system 400 includes a curing chamber 410 configured to produce a clean, contaminant-free environment for curing a substrate 425 resting on substrate holder 420.
  • Curing system 400 further includes one or more radiation sources configured to expose substrate 425 having the dielectric film to electro-magnetic (EM) radiation at single, multiple, narrow-band, or broadband EM wavelengths.
  • the one or more radiation sources can include an optional infrared (IR) radiation source 440 and an ultraviolet (UV) radiation source 445. The exposure of the substrate to UV radiation and optionally IR radiation can be performed simultaneously, sequentially, or over-lapping one another.
  • the IR radiation source 440 may include a broad-band IR source, or may include a narrow-band IR source.
  • the IR radiation source may include one or more IR lamps, one or more IR LEDs, or one or more IR lasers (continuous wave (CW), tunable, or pulsed), or any combination thereof.
  • the IR power may range from approximately 0.1 mW to approximately 2000 W.
  • the IR radiation wavelength may range from approximately 1 micron to approximately 25 microns and, desirably, can range from approximately 8 microns to approximately 14 microns.
  • the IR radiation source 440 may include an IR element, such as a ceramic element or silicon carbide PCT Docket No.: TDC-002 WO
  • the IR radiation source 440 can include a semiconductor laser (diode), or ion, Tksapphire, or dye laser with optical parametric amplification.
  • the UV radiation source 445 may include a broad-band UV source, or may include a narrow-band UV source.
  • the UV radiation source may include one or more UV lamps, one or more UV LEDs, or one or more UV lasers (continuous wave (CW), tunable, or pulsed), or any combination thereof.
  • UV radiation may be generated, for instance, from a microwave source, an arc discharge, a dielectric barrier discharge, or electron impact generation.
  • the UV power density may range from approximately 0.1 mW/cm 2 to approximately 2000 mW/cm 2 .
  • the UV wavelength may range from approximately 100 nanometers (nm) to approximately 600 nm and, desirably, may range from approximately 200 nm to approximately 400 nm.
  • the UV radiation source 445 may include a direct current (DC) or pulsed lamp, such as a Deuterium (D 2 ) lamp, having a spectral output ranging from approximately 180 nm to approximately 500 nm, or the UV radiation source 445 may include a semiconductor laser (diode), (nitrogen) gas laser, frequency-tripled Nd:YAG laser, or copper vapor laser.
  • the IR radiation source 440, or the UV radiation source 445, or both, may include any number of optical device to adjust one or more properties of the output radiation.
  • each source may further include optical filters, optical lenses, beam expanders, beam collimators, etc. Such optical manipulation devices as known to those skilled in the art of optics and EM wave propagation are suitable for the invention.
  • the substrate holder 420 can further include a temperature control system that can be configured to elevate and/or control the temperature of substrate 425.
  • the temperature control system can be a part of a thermal treatment device 430.
  • the substrate holder 420 can include one or more conductive heating elements embedded in substrate holder 420 coupled to a power source and a temperature controller.
  • each heating element can include a resistive heating element coupled to a power source configured to supply electrical power.
  • the substrate holder 420 could optionally include one or more radiative heating elements.
  • substrate 425 can, for example, range from approximately 20 0 C to approximately 500 0 C, and desirably, the temperature may range from approximately 200 0 C to approximately 400 0 C.
  • the substrate holder 420 may or may not be configured to clamp substrate 425.
  • substrate holder 420 may be configured to mechanically or electrically clamp substrate 425.
  • curing system 400 can further include a gas injection system 450 coupled to the curing chamber 410 and configured to introduce a purge gas to curing chamber 410.
  • the purge gas can, for example, include an inert gas, such as a noble gas or nitrogen.
  • the purge gas can include other gases, such as for example H 2 , NH3, C x H y , or any combination thereof.
  • curing system 400 can further include a vacuum pumping system 455 coupled to curing chamber 410 and configured to evacuate the curing chamber 410.
  • substrate 425 can be subject to a purge gas environment with or without vacuum conditions.
  • curing system 400 can include a controller 460 coupled to drying chamber 410, substrate holder 420, thermal treatment device 430, IR radiation source 440, UV radiation source 445, gas injection system 450, and vacuum pumping system 455.
  • Controller 460 includes a microprocessor, a memory, and a digital I/O port capable of generating control voltages sufficient to communicate and activate inputs to the curing system 400 as well as monitor outputs from the curing system 400.
  • a program stored in the memory is utilized to interact with the curing system 400 according to a stored process recipe.
  • the controller 460 can be used to configure any number of processing elements (410, 420, 430, 440, 445, 450, or 455), and the controller 460 can collect, provide, process, store, and display data from processing elements.
  • the controller 460 can include a number of applications for controlling one or more of the processing elements.
  • controller 460 can include a graphic user interface (GUI) component (not shown) that can provide easy to use interfaces that enable a user to monitor and/or control one or more processing elements.
  • GUI graphic user interface
  • the controllers 360 and 460 may be implemented as a DELL PRECISION WORKSTATION 610TM.
  • the controllers 360 and 460 may also PCT Docket No.: TDC-002 WO
  • the computer readable medium or memory for holding instructions programmed according to the teachings of the invention and for containing data structures, tables, records, or other data described herein.
  • Examples of computer readable media are compact discs, hard disks, floppy disks, tape, magneto-optical disks, PROMs (EPROM, EEPROM, flash EPROM), DRAM, SRAM, SDRAM, or any other magnetic medium, compact discs (e.g., CD-ROM), or any other optical medium, punch cards, paper tape, or other physical medium with patterns of holes, a carrier wave (described below), or any other medium from which a computer can read.
  • the controllers 360 and 460 may be locally located relative to the drying system 300 and curing system 400, or may be remotely located relative to the drying system 300 and curing system 400 via an internet or intranet. Thus, the controllers 360 and 460 can exchange data with the drying system 300 and curing system 400 using at least one of a direct connection, an intranet, and the internet.
  • the controllers 360 and 460 may be coupled to an intranet at a customer site (i.e., a device maker, etc.), or coupled to an intranet at a vendor site (i.e., an equipment manufacturer).
  • another computer i.e., controller, server, etc.
  • controllers 360 and 460 can access controllers 360 and 460 to exchange data via at least one of a direct connection, an intranet, and the internet.
  • embodiments of this invention may be used as or to support a software program executed upon some form of processing core (such as a processor of a computer, e.g., controller 360 or 460) or otherwise implemented or realized upon or within a machine-readable medium.
  • a machine-readable medium includes any mechanism for storing information in a form readable by a machine (e.g., a computer).
  • a machine- readable medium can include such as a read only memory (ROM); a random access memory (RAM); a magnetic disk storage media; an optical storage media; and a flash memory device, etc.

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Formation Of Insulating Films (AREA)
  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
PCT/US2008/076134 2007-09-13 2008-09-12 Method for curing a dielectric film Ceased WO2009036249A1 (en)

Priority Applications (2)

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JP2010525019A JP2011502343A (ja) 2007-09-13 2008-09-12 誘電膜の硬化方法
CN2008801070343A CN101816059B (zh) 2007-09-13 2008-09-12 使介电膜固化的方法

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US11/854,937 US20090075491A1 (en) 2007-09-13 2007-09-13 Method for curing a dielectric film
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JP (1) JP2011502343A (enExample)
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