US20060134051A1 - Glossy non-transfer composition comprising a sequenced polymer - Google Patents
Glossy non-transfer composition comprising a sequenced polymer Download PDFInfo
- Publication number
- US20060134051A1 US20060134051A1 US10/529,266 US52926605A US2006134051A1 US 20060134051 A1 US20060134051 A1 US 20060134051A1 US 52926605 A US52926605 A US 52926605A US 2006134051 A1 US2006134051 A1 US 2006134051A1
- Authority
- US
- United States
- Prior art keywords
- equal
- composition according
- block
- monomers
- glass transition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 0 [7*]N([8*])C(=O)C(=C)C Chemical compound [7*]N([8*])C(=O)C(=C)C 0.000 description 4
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/90—Block copolymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/927—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of insects, e.g. shellac
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/594—Mixtures of polymers
Definitions
- the present invention relates to a cosmetic composition for making up or caring for the skin, including the scalp, of both the human face and body, and human lips or integuments, for instance the hair, the eyelashes or the eyebrows, comprising a cosmetically acceptable organic liquid medium and a particular block polymer.
- Transport-resistant lip and skin makeup compositions are compositions that have the advantage of forming a deposit that does not transfer or that does not leave traces or marks, at least partially, on the supports with which they come into contact (glass, clothing, cigarette or fabrics).
- Known transfer-resistant compositions are based on silicone resins and volatile silicone oils and, although having improved staying power properties, have the drawback of leaving on the skin and the lips, after the volatile silicone oils have evaporated off, a film that becomes uncomfortable over time (sensation of drying out and of tautness) and is barely glossy.
- the aim of the present invention is to propose a novel route for formulating a cosmetic product, in particular a makeup product, which allows good “transfer-resistance” and gloss properties.
- This product especially has the advantage of comprising only one composition, in contrast with the product of patent application WO-A-97/17057.
- the product obtained according to the invention especially when it is a product for the lips, has good properties of migration resistance, staying power and absence of a sensation of drying out.
- One subject of the invention is a glossy, transfer-resistant composition for caring for or making up the skin and/or the lips and/or integuments, containing a film-forming linear block ethylenic polymer.
- the inventors have found, surprisingly, that the use of such a block polymer makes it possible to obtain a glossy, transfer-resistant composition.
- the composition according to the invention also has the advantage of having good staying power.
- composition of the invention may in particular constitute a haircare product or a makeup product for human body, lips or integuments having care and/or treating properties. It especially constitutes a lipstick or a lipgloss, an eyeshadow, attack to product, a mascara, an eyeliner, a product for artificially tanning the skin, an optionally tinted care or protecting cream, a hair-colouring product or a haircare product.
- a subject of the invention is, more specifically, a cosmetic composition containing a cosmetically acceptable organic liquid medium and a film-forming linear ethylenic block polymer, the said polymer being such that, when it is in sufficient amount in the composition:
- the composition according to the invention is a leave-in composition.
- the invention also relates to a cosmetic composition
- a cosmetic composition comprising an organic liquid medium and at least one block polymer as described below.
- gloss means the gloss as may be conventionally measured using a glossmeter by the following method.
- a coat of between 50 ⁇ m and 150 ⁇ m in thickness of the composition is spread using an automatic spreader onto a Leneta brand contrast card of reference Form 1A Penopac.
- the coat covers at least the white background of the card.
- the deposit is left to dry for 24 hours at a temperature of 30° C., and the gloss at 20° is then measured on the white background using a Byk Gardner brand glossmeter of reference microTri-Gloss.
- This measurement (between 0 and 100) is repeated at least three times, and the mean gloss is the mean of the at least three measurements taken.
- the mean gloss of the composition measured at 20° is advantageously greater than or equal to 30, better still greater than or equal to 35, better still greater than or equal to 40, better still greater than or equal to 45, better still greater than or equal to 50 out of 100, better still greater than or equal to 55, and better still greater than or equal to 60.
- the mean gloss of the composition, once spread onto a support, measured at 60° is greater than or equal to 50, better still greater than or equal to 60, better still greater than or equal to 65, better still greater than or equal to 70, better still greater than or equal to 75, better still greater than or equal to 80, better still greater than or equal to 85 or better still greater than or equal to 90 out of 100.
- the mean gloss at 60° is measured as follows.
- the gloss may be measured using a glossmeter, in a conventional manner, by the following method.
- a coat of between 50 ⁇ m and 150 ⁇ m in thickness of the composition is spread using an automatic spreader onto a Leneta brand contrast card of reference Form 1A Penopac.
- the coat covers at least the white background of the card.
- the deposit is left to dry for 24 hours at a temperature of 30° C., and the gloss at 60° is then measured on the white background using a Byk Gardner brand glossmeter of reference microTri-Gloss.
- This measurement (between 0 and 100) is repeated at least three times, and the mean gloss is the mean of the at least three measurements taken.
- the mean gloss of the composition measured at 20° is preferably greater than or equal to 35, preferably 40, 45 or 50 out of 100, and/or the mean gloss of the composition measured at 60° is preferably greater than or equal to 65, 70 or 75 out of 100.
- the composition advantageously constitutes a liquid lipstick.
- the transfer index of the composition according to the invention is preferably less than or equal to 40 out of 100. More preferably, the transfer index is less than or equal to 30, preferably less than or equal to 20, more preferably less than or equal to 15, preferably less than or equal to 10, preferably less than or equal to 5 out of 100, and preferably less than or equal to 2 out of 100.
- the transfer index may be measured according to the following method.
- a support (rectangle of 40 mm ⁇ 70 mm and 3 mm thick) of polyethylene foam that is adhesive on one of the faces, having a density of 33 kg/m 3 (sold under the name RE40X70EP3 from the company Joint Technique Lyonnais Ind) is preheated on a hotplate maintained at a temperature of 40° C. in order for the surface of the support to be maintained at a temperature of 33° C. ⁇ 1° C.
- the composition is applied over the entire non-adhesive surface of the support, by spreading it using a fine brush to obtain a deposit of about 15 ⁇ m of the composition, while leaving the support on the hotplate, and the support is then left to dry for 30 minutes.
- the support After drying, the support is bonded via its adhesive face onto an anvil 20 mm in diameter and equipped with a screw pitch.
- the support/deposit assembly is then cut up using a punch 18 mm in diameter.
- the anvil is then screwed onto a press (Statif Manuel Imada SV-2 from the company Someco) equipped with a tensile testing machine (Imada DPS-20 from the company Someco).
- White photocopier paper of 80 g/m 2 is placed on the bed of the press and the support/deposit assembly is then pressed on the paper at a pressure of 2.5 kg for 30 seconds. After removing the support/deposit assembly, some of the deposit is transferred onto the paper. The colour of the deposit transferred onto the paper is then measured using a Minolta CR300 calorimeter, the colour being characterized by the L*, a*, b* calorimetric parameters. The calorimetric parameters L* 0 , a* 0 and b* 0 of the colour of the plain paper used is determined.
- ⁇ E1 ⁇ square root over (( L* ⁇ L 0 *) 2 +( a* ⁇ a 0 *) 2 +( b* ⁇ b 0 *) 2 ) ⁇
- a total transfer reference is prepared by applying the composition directly onto a paper identical to the one used previously, at room temperature (25° C.), by spreading the composition using a fine brush and so as to obtain a deposit of about 15 ⁇ m of the composition, and the deposit is then left to dry for 30 minutes at room temperature (25° C.). After drying, the calorimetric parameters L*′, a*′ and b*′ of the colour of the deposit placed on the paper, corresponding to the reference colour of total transfer, is measured directly. The calorimetric parameters L*′ 0 , a*′ 0 and b*′ 0 of the colour of the plain paper used are determined.
- ⁇ E2 ⁇ square root over (( L*′ ⁇ L 0 *′) 2 +( a*′ ⁇ a 0 *) 2 +( b*′ ⁇ b 0 *′) 2 ) ⁇
- the transfer of the composition is equal to the ratio: 100 ⁇ E1/ ⁇ E2
- the measurement is performed on 4 supports in succession and the transfer value corresponds to the mean of the 4 measurements obtained with the 4 supports.
- the transfer index is equal to the mean of these four measurements.
- the invention also relates to a process for making up the skin and/or the lips and/or integuments, which consists in applying to the skin and/or the lips and/or integuments the composition as defined above.
- composition according to the invention may be applied to the skin of both the face and the scalp and of the body, mucous membranes, for instance the lips and the inside of the lower eyelids, and integuments, for instance the eyelashes, the hair, the eyebrows, or even body hairs.
- the invention also relates to the use of a block polymer in a sufficient amount in a cosmetic composition to impart gloss and transfer resistance to a deposit of the said composition.
- the invention also relates to the cosmetic use of the composition defined above to improve the gloss of the makeup on the skin and/or the lips and/or integuments.
- composition advantageously contains a small proportion of oils conventionally used to impart gloss, these oils generally being tacky.
- composition according to the invention advantageously contains less than 30%, less than 25%, less than 20% and better still less than 15% of at least one glossy oil.
- oil means a compound that is immiscible with water in all proportions, and which is liquid at room temperature (25° C.) and atmospheric pressure (760 mmHg).
- the glossy oil has, for example, a molar mass ranging from 650 to 10 000 g/mol and preferably from 750 to 7500 g/mol.
- the oil with a molar mass ranging from 650 to 10 000 g/mol may be chosen from:
- lipophilic polymers such as:
- esters such as:
- silicone oils such as phenylsilicones, for instance Belsil PDM 1000 from the company Wacker (MM 9000 g/mol),
- oils of plant origin such as sesame oil (820.6 g/mol)
- composition according to the present invention contains at least one block polymer.
- block polymer means a polymer comprising at least two different blocks and preferably at least three different blocks.
- the block polymer of the composition according to the invention is an ethylenic polymer.
- ethylenic polymer means a polymer obtained by polymerizing monomers comprising an ethylenic unsaturation.
- the block polymer of the composition according to the invention is a linear polymer.
- a polymer of non-linear structure is, for example, a polymer of branched, starburst or grafted structure, or the like.
- the block polymer of the composition according to the present invention is a film-forming polymer.
- film-forming polymer means a polymer capable of forming, by itself or in the presence of an auxiliary film-forming agent, a continuous film that adheres to a support and especially to keratin materials.
- the block polymer of the composition according to the invention is a non-elastomeric polymer.
- non-elastomeric polymer means a polymer which, when it is subjected to a constraint intended to stretch it (for example by 30% relative to its initial length), does not return to a length substantially identical to its initial length when the constraint ceases.
- non-elastomeric polymer denotes a polymer with an instantaneous recovery R i ⁇ 50% and a delayed recovery R 2h ⁇ 70% after having been subjected to a 30% elongation.
- R i is ⁇ 30% and R 2h ⁇ 50%.
- non-elastomeric nature of the polymer is determined according to the following protocol:
- a polymer film is prepared by pouring a solution of the polymer in a Teflon-coated mould, followed by drying for 7 days in an environment conditioned at 23 ⁇ 5° C. and 50 ⁇ 10% relative humidity.
- a film about 100 ⁇ m thick is thus obtained, from which are cut rectangular specimens (for example using a punch) 15 mm wide and 80 mm long.
- This sample is subjected to a tensile stress using a machine sold under the reference Zwick, under the same temperature and humidity conditions as for the drying.
- the specimens are pulled at a speed of 50 mm/min and the distance between the jaws is 50 mm, which corresponds to the initial length (l 0 ) of the specimen.
- the instantaneous recovery R i is determined in the following manner:
- R i ( ⁇ max ⁇ 1 )/ ⁇ max ) ⁇ 100
- the percentage residual elongation of the specimen ( ⁇ 2h ) is measured, 2 hours after returning to zero constraint.
- R 2h ( ⁇ max ⁇ 2h )/ ⁇ max ) ⁇ 100
- a block polymer according to one embodiment of the invention has an instantaneous recovery R i of 10% and a delayed recovery R 2h of 30%.
- the block polymer of the composition according to the invention does not comprise any styrene units.
- polymer free of styrene units means a polymer comprising less than 10%, preferably less than 5%, preferentially less than 2% and more preferentially less than 1% by weight i) of styrene units of formula —CH(C 6 H 5 )—CH 2 — or ii) of substituted styrene units, for instance methylstyrene, chlorostyrene or chloromethylstyrene.
- the block polymer of the composition according to the invention is derived from aliphatic ethylenic monomers.
- aliphatic monomer means a monomer comprising no aromatic groups.
- the block polymer is an ethylenic polymer derived from aliphatic ethylenic monomers comprising a carbon-carbon double bond and at least one ester group —COO— or amide group —CON—.
- the ester group may be linked to one of the two unsaturated carbons via the carbon atom or the oxygen atom.
- the amide group may be linked to one of the two unsaturated carbons via the carbon atom or the nitrogen atom.
- the block polymer comprises at least one first block and at least one second block.
- At least one block means one or more blocks.
- the block polymer comprises at least one first block and at least one second block that have different glass transition temperatures (Tg)
- first and second blocks may be linked together via an intermediate segment with a glass transition temperature between the glass transition temperatures of the first and second blocks.
- the block polymer comprises at least one first block and at least one second block linked together via an intermediate segment comprising at least one constituent monomer of the first block and at least one constituent monomer of the second block.
- the intermediate block is derived essentially from constituent monomers of the first block and of the second block.
- the term “essentially” means at least 85%, preferably at least 90%, better still 95% and even better still 100%.
- the intermediate segment comprising at least one constituent monomer of the first block and at least one constituent monomer of the second block of the polymer is a random polymer.
- the block polymer comprises at least one first block and at least one second block that are incompatible in the organic liquid medium of the composition of the invention.
- mutant blocks means that the mixture formed from the polymer corresponding to the first block and from the polymer corresponding to the second block is not miscible in the liquid that is in major amount by weight contained in the organic liquid medium of the composition, at room temperature (25° C.) and atmospheric pressure (10 5 Pa), for a content of the polymer mixture of greater than or equal to 5% by weight, relative to the total weight of the mixture (polymers and major organic liquid), it being understood that:
- the organic liquid medium comprises a mixture of organic liquids, in the case of two or more liquids present in identical mass proportions, the said polymer mixture is immiscible in at least one of them.
- the organic liquid medium comprises only one organic liquid
- this liquid obviously constitutes the liquid that is in major amount by weight.
- organic liquid medium means a medium containing at least one organic liquid, i.e. at least one organic compound that is liquid at room temperature (25° C.) and atmospheric pressure (10 5 Pa).
- the major liquid of the organic liquid medium is a volatile or non-volatile oil (fatty substance).
- the organic liquid is cosmetically acceptable (acceptable tolerance, toxicology and feel).
- the organic liquid medium is cosmetically acceptable, in the sense that it is compatible with keratin materials, for instance the oils or organic solvents commonly used in cosmetic compositions.
- the major liquid of the organic liquid medium is the polymerization solvent or one of the polymerization solvents of the block polymer, as are described below.
- polymerization solvent means a solvent or a mixture of solvents.
- the polymerization solvent may be chosen especially from ethyl acetate, butyl acetate, alcohols such as isopropanol and ethanol, aliphatic alkanes such as isododecane, and mixtures thereof.
- the polymerization solvent is a mixture of butyl acetate and isopropanol, or isododecane.
- the block polymer may be incorporated into the composition to a high solids content, typically greater than 10%, greater than 20%, more preferably greater than 30% and more preferentially greater than 45% by weight relative to the total weight of the composition, while at the same time being easy to formulate.
- the block polymer comprises no silicon atoms in its skeleton.
- skeleton means the main chain of the polymer, as opposed to the pendent side chains.
- the polymer according to the invention is not water-soluble, i.e. the polymer is not soluble in water or in a mixture of water and linear or branched lower monoalcohols containing from 2 to 5 carbon atoms, for instance ethanol, isopropanol or n-propanol, without pH modification, at an active material content of at least 1% by weight, at room temperature (25° C.).
- the block polymer has a polydispersity index I of greater than 2.
- the block polymer used in the compositions according to the invention has a polydispersity index I of greater than 2, for example ranging from 2 to 9, preferably greater than or equal to 2.5, for example ranging from 2.5 to 8 and better still greater than or equal to 2.8, and especially ranging from 2.8 to 6.
- the polydispersity index I of the polymer is equal to the ratio of the weight-average mass Mw to the number-average mass Mn.
- the weight-average molar mass (Mw) and number-average molar mass (Mn) are determined by gel permeation liquid chromatography (THF solvent, calibration curve established with linear polystyrene standards, refractometric detector).
- the weight-average mass (Mw) of the block polymer is preferably less than or equal to 300 000; it ranges, for example, from 35 000 to 200 000 and better still from 45 000 to 150 000.
- the number-average mass (Mn) of the block polymer is preferably less than or equal to 70 000; it ranges, for example, from 10 000 to 60 000 and better still from 12 000 to 50 000.
- Each block of the block polymer is derived from one type of monomer or from several different types of monomer.
- each block may consist of a homopolymer or a copolymer; this copolymer constituting the block may in turn be random or alternating.
- Tg values indicated for the first and second blocks in the present patent application are theoretical Tg values.
- the difference between the glass transition temperatures of the first and second blocks is generally greater than 10° C., preferably greater than 20° C. and better still greater than 30° C.
- the block polymer comprises at least one first block and at least one second block such that the first block may be chosen from:
- the expression: “between . . . and . . . ” is intended to denote a range of values for which the limits mentioned are excluded, and “from . . . to . . . ” and “ranging from . . . to . . . ” are intended to denote a range of values for which the limits are included.
- the block with a Tg of greater than or equal to 40° C. has, for example, a Tg ranging from 40 to 150° C., preferably greater than or equal to 50° C., for example ranging from 50° C. to 120° C. and better still greater than or equal to 60° C., for example ranging from 60° C. to 120° C.
- the block with a Tg of greater than or equal to 40° C. may be a homopolymer or a copolymer.
- the block with a Tg of greater than or equal to 40° C. may be totally or partially derived from one or more monomers, which are such that the homopolymer prepared from these monomers has a glass transition temperature of greater than or equal to 40° C.
- this block is a homopolymer, it is derived from monomers which are such that the homopolymers prepared from these monomers have glass transition temperatures of greater than or equal to 40° C.
- This first block may be a homopolymer consisting of only one type of monomer (for which the Tg of the corresponding homopolymer is greater than or equal to 40° C.).
- the first block is a copolymer
- it may be totally or partially derived from one or more monomers, the nature and concentration of which are chosen such that the Tg of the resulting copolymer is greater than or equal to 40° C.
- the copolymer may comprise, for example:
- Tg values of greater than or equal to 40° C., for example a Tg ranging from 40 to 150° C., preferably greater than or equal to 50° C., for example ranging from 50° C. to 120° C. and better still greater than or equal to 60° C., for example ranging from 60° C. to 120° C., and
- monomers which are such that the homopolymers prepared from these monomers have Tg values of less than 40° C., chosen from monomers with a Tg of between 20 and 40° C. and/or monomers with a Tg of less than or equal to 20° C., for example a Tg ranging from ⁇ 100 to 20° C., preferably less than 15° C., especially ranging from ⁇ 80° C. to 15° C. and better still less than 10° C., for example ranging from ⁇ 50° C. to 0° C., as described later.
- the monomers whose homopolymers have a glass transition temperature of greater than or equal to 40° C. are chosen, preferably, from the following monomers, also known as the main monomers:
- Main monomers that are particularly preferred are methyl methacrylate, isobutyl (meth)acrylate and isobornyl (meth)acrylate, and mixtures thereof.
- the block with a Tg of less than or equal to 20° C. has, for example, a Tg ranging from ⁇ 100 to 20° C., preferably less than or equal to 15° C., especially ranging from ⁇ 80° C. to 15° C. and better still less than or equal to 10° C., for example ranging from ⁇ 50° C. to 0° C.
- the block with a Tg of less than or equal to 20° C. may be a homopolymer or a copolymer.
- the block with a Tg of less than or equal to 20° C. may be totally or partially derived from one or more monomers, which are such that the homopolymer prepared from these monomers has a glass transition temperature of less than or equal to 20° C.
- this block is a homopolymer, it is derived from monomers which are such that the homopolymers prepared from these monomers have glass transition temperatures of less than or equal to 20° C.
- This second block may be a homopolymer consisting of only one type of monomer (for which the Tg of the corresponding homopolymer is less than or equal to 20° C.)
- the block with a Tg of less than or equal to 20° C. is a copolymer, it may be totally or partially derived from one or more monomers, the nature and concentration of which are chosen such that the Tg of the resulting copolymer is less than or equal to 20° C.
- It may comprise, for example
- one or more monomers whose corresponding homopolymer has a Tg of less than or equal to 20° C. for example a Tg ranging from ⁇ 100° C. to 20° C., preferably less than 15° C., especially ranging from ⁇ 80° C. to 15° C. and better still less than 10° C., for example ranging from ⁇ 50° C. to 0° C., and
- one or more monomers whose corresponding homopolymer has a Tg of greater than 20° C. such as monomers with a Tg of greater than or equal to 40° C., for example a Tg ranging from 40 to 150° C., preferably greater than or equal to 50° C., for example ranging from 50° C. to 120° C. and better still greater than or equal to 60° C., for example ranging from 60° C. to 120° C. and/or monomers with a Tg of between 20 and 40° C., as described above.
- the block with a Tg of less than or equal to 20° C. is a homopolymer.
- the monomers whose homopolymer has a Tg of less than or equal to 20° C. are preferably chosen from the following monomers, or main monomer:
- R 3 representing a linear or branched C 1 to C 12 unsubstituted alkyl group, with the exception of the tert-butyl group, in which one or more hetero atoms chosen from O, N and S is (are) optionally intercalated,
- the main monomers that are particularly preferred for the block with a Tg of less than or equal to 20° C. are alkyl acrylates whose alkyl chain contains from 1 to 10 carbon atoms, with the exception of the tert-butyl group, such as methyl acrylate, isobutyl acrylate and 2-ethylhexyl acrylate, and mixtures thereof.
- the block with a Tg of between 20 and 40° C. may be a homopolymer or a copolymer.
- the block with a Tg of between 20 and 40° C. may be totally or partially derived from one or more monomers, which are such that the homopolymer prepared from these monomers has a glass transition temperature of between 20 and 40° C.
- the block with a Tg of between 20 and 40° C. may be totally or partially derived from monomers, which are such that the corresponding homopolymer has a Tg of greater than or equal to 40° C. and from monomers which are such that the corresponding homopolymer has a Tg of less than or equal to 20° C.
- this block is a homopolymer, it is derived from monomers (or main monomer) which are such that the homopolymers prepared from these monomers have glass transition temperatures of between 20 and 40° C.
- This first block may be a homopolymer, consisting of only one type of monomer (for which the Tg of the corresponding homopolymer ranges from 20° C. to 40° C.).
- the monomers whose homopolymer has a glass transition temperature of between 20 and 40° C. are preferably chosen from n-butyl methacrylate, cyclodecyl acrylate, neopentyl acrylate and isodecylacrylamide, and mixtures thereof.
- the block with a Tg of between 20 and 40° C. is a copolymer, it is totally or partially derived from one or more monomers (or main monomer) whose nature and concentration are chosen such that the Tg of the resulting copolymer is between 20 and 40° C.
- the block with a Tg of between 20 and 40° C. is a copolymer totally or partially derived from:
- main monomers whose corresponding homopolymer has a Tg of greater than or equal to 40° C., for example a Tg ranging from 40° C. to 150° C., preferably greater than or equal to 50° C., for example ranging from 50 to 120° C. and better still greater than or equal to 60° C., for example ranging from 60° C. to 120° C., as described above, and/or
- main monomers whose corresponding homopolymer has a Tg of less than or equal to 20° C., for example a Tg ranging from ⁇ 100 to 20° C., preferably less than or equal to 15° C., especially ranging from ⁇ 80° C. to 15° C. and better still less than or equal to 10° C., for example ranging from ⁇ 50° C. to 0° C., as described above, the said monomers being chosen such that the Tg of the copolymer forming the first block is between 20 and 40° C.
- Such main monomers are chosen, for example, from methyl methacrylate, isobornyl acrylate and methacrylate, butyl acrylate and 2-ethylhexyl acrylate, and mixtures thereof.
- the proportion of the second block with a Tg of less than or equal to 20° C. ranges from 10% to 85% by weight, better still from 20% to 70% and even better still from 20% to 50% by weight of the polymer.
- each of the first and second blocks comprises at least one monomer chosen from acrylic acid, acrylic acid esters, (meth)acrylic acid and (meth)acrylic acid esters, and mixtures thereof.
- each of the first and second blocks is totally derived from at least one monomer chosen from acrylic acid, acrylic acid esters, (meth)acrylic acid and (meth)acrylic acid esters, and mixtures thereof.
- each of the blocks may contain in small proportion at least one constituent monomer of the other block.
- the first block may contain at least one constituent monomer of the second block, and vice versa.
- Each of the first and/or second blocks may comprise, in addition to the monomers indicated above, one or more other monomers known as additional monomers, which are different from the main monomers mentioned above.
- This additional monomer is chosen, for example, from:
- hydrophilic monomers such as:
- Additional monomers that are particularly preferred are acrylic acid, methacrylic acid and trifluoroethyl methacrylate, and mixtures thereof.
- each of the first and second blocks of the block polymer comprises at least one monomer chosen from (meth)acrylic acid esters and optionally at least one additional monomer such as (meth)acrylic acid, and mixtures thereof.
- each of the first and second blocks of the block polymer is totally derived from at least one monomer chosen from (meth)acrylic acid esters and optionally at least one additional monomer such as (meth)acrylic acid, and mixtures thereof.
- the block polymer is a non-silicone polymer, i.e. a polymer free of silicon atoms.
- This or these additional monomer(s) generally represent(s) an amount of less than or equal to 30% by weight, for example from 1% to 30% by weight, preferably from 5% to 20% by weight and more preferably from 7% to 15% by weight, relative to the total weight of the first and/or second blocks.
- the block polymer may be obtained by free-radical solution polymerization according to the following preparation process:
- the block polymer comprises a first block with a Tg of greater than or equal to 40° C., as described above in a) and a second block with a Tg of less than or equal to 20° C., as described above in b).
- the first block with a Tg of greater than or equal to 40° C. is a copolymer derived from monomers which are such that the homopolymer prepared from these monomers has a glass transition temperature of greater than or equal to 40° C., such as the monomers described above.
- the second block with a Tg of less than or equal to 20° C. is a homopolymer derived from monomers which are such that the homopolymer prepared from these monomers has a glass transition temperature of less than or equal to 20° C., such as the monomers described above.
- the proportion of the block with a Tg of greater than or equal to 40° C. ranges from 20% to 90%, better still from 30% to 80% and even better still from 50% to 70% by weight of the polymer.
- the proportion of the block with a Tg of less than or equal to 20° C. ranges from 5% to 75%, preferably from 15% to 50% and better still from 25% to 45% by weight of the polymer.
- the polymer according to the invention may comprise:
- a first block with a Tg of greater than or equal to 40° C. for example having a Tg ranging from 70 to 110° C., which is a methyl methacrylate/acrylic acid copolymer,
- an intermediate block which is a methyl methacrylate/acrylic acid/methyl acrylate copolymer.
- the polymer according to the invention may comprise:
- an intermediate block which is a methyl methacrylate/acrylic acid/methyl acrylate/trifluoroethyl methacrylate random copolymer.
- the polymer according to the invention may comprise:
- an intermediate block which is an isobornyl acrylate/isobutyl methacrylate/2-ethylhexyl acrylate random copolymer.
- the polymer according to the invention may comprise:
- an intermediate block which is an isobornyl acrylate/methyl methacrylate/2-ethylhexyl acrylate random copolymer.
- the polymer according to the invention may comprise:
- an intermediate block which is an isobornyl acrylate/isobornyl methacrylate/2-ethylhexyl acrylate random copolymer.
- the polymer according to the invention may comprise:
- an intermediate block which is an isobornyl methacrylate/isobutyl methacrylate/isobutyl acrylate random copolymer.
- the polymer according to the invention may comprise:
- an intermediate block which is an isobornyl acrylate/isobornyl methacrylate/isobutyl acrylate random copolymer.
- the polymer according to the invention may comprise:
- an intermediate block which is an isobornyl acrylate/isobutyl methacrylate/isobutyl acrylate random copolymer.
- the amounts are expressed in grams.
- isododecane 100 g are introduced into a 1 litre reactor and the temperature is then increased so as to pass from room temperature (25° C.) to 90° C. over 1 hour.
- the mixture is maintained at 90° C. for 1 hour 30 minutes.
- the mixture is maintained at 90° C. for 3 hours and is then cooled.
- This polymer has a weight-average mass of 77 000 and a number-average mass of 19 000, i.e. a polydispersity index I of 4.05.
- isododecane 100 g are introduced into a 1 litre reactor and the temperature is then increased so as to pass from room temperature (25° C.) to 90° C. over 1 hour.
- the mixture is maintained at 90° C. for 1 hour 30 minutes.
- the mixture is maintained at 90° C. for 3 hours and is then cooled.
- This polymer has a weight-average mass of 103 900 and a number-average mass of 21 300, i.e. a polydispersity index I of 4.89.
- isododecane 100 g are introduced into a 1 litre reactor and the temperature is then increased so as to pass from room temperature (25° C.) to 90° C. over 1 hour.
- the mixture is maintained at 90° C. for 1 hour 30 minutes.
- the mixture is maintained at 90° C. for 3 hours and is then cooled.
- This polymer has a weight-average mass of 144 200 and a number-average mass of 49 300, i.e. a polydispersity index I of 2.93.
- the block polymer comprises a first block having a glass transition temperature (Tg) of between 20 and 40° C., in accordance with the blocks described in c) and a second block having a glass transition temperature of less than or equal to 20° C., as described above in b) or a glass transition temperature of greater than or equal to 40° C., as described in a) above.
- Tg glass transition temperature
- the proportion of the first block with a Tg of between 20 and 40° C. ranges from 10% to 85%, better still from 30% to 80% and even better still from 50% to 70% by weight of the polymer.
- the second block is a block with a Tg of greater than or equal to 40° C., it is preferably present in a proportion ranging from 10% to 85% by weight, better still from 20% to 70% and even better still from 30% to 70% by weight of the polymer.
- the second block is a block with a Tg of less than or equal to 20° C., it is preferably present in a proportion ranging from 10% to 85% by weight, better still from 20% to 70% and even better still from 20% to 50% by weight of the polymer.
- the first block with a Tg of between 20 and 40° C. is a copolymer derived from monomers which are such that the corresponding homopolymer has a Tg of greater than or equal to 40° C., and from monomers which are such that the corresponding homopolymer has a Tg of less than or equal to 20° C.
- the second block with a Tg of less than or equal to 20° C. or with a Tg of greater than or equal to 40° C. is a homopolymer.
- the block polymer may comprise:
- an intermediate block comprising at least one methyl acrylate, methyl methacrylate monomer
- an intermediate block comprising methyl methacrylate, at least one acrylic acid monomer and at least one methyl acrylate monomer.
- the block polymer may comprise:
- an intermediate block which is an isobornyl acrylate/isobutyl methacrylate/2-ethylhexyl acrylate random copolymer.
- the block polymer may comprise:
- an intermediate block which is an isobornyl acrylate/methyl acrylate/acrylic acid random copolymer.
- composition according to the invention preferably contains from 0.1% to 60% by weight of active material (or solids), preferably from 0.5% to 50% by weight and more preferably from 1% to 40% by weight, of the polymer.
- composition according to the invention may comprise a hydrophilic medium comprising water or a mixture of water and of hydrophilic organic solvent(s), for instance alcohols and especially linear or branched lower monoalcohols containing from 2 to 5 carbon atoms, for instance ethanol, isopropanol or n-propanol, and polyols, for instance glycerol, diglycerol, propylene glycol, sorbitol, pentylene glycol and polyethylene glycols, or alternatively hydrophilic C 2 ethers and C 2 -C 4 aldehydes.
- hydrophilic medium comprising water or a mixture of water and of hydrophilic organic solvent(s), for instance alcohols and especially linear or branched lower monoalcohols containing from 2 to 5 carbon atoms, for instance ethanol, isopropanol or n-propanol, and polyols, for instance glycerol, diglycerol, propylene glycol, sorbitol, pent
- the water or the mixture of water and of hydrophilic organic solvents may be present in the composition according to the invention in a content ranging from 0.1% to 99% by weight and preferably from 10% to 80% by weight relative to the total weight of the composition.
- composition according to the invention comprises a cosmetically acceptable organic liquid medium (acceptable tolerance, toxicology and feel).
- the organic liquid medium of the composition contains at least one organic solvent, which is the or one of the polymerization solvent(s) for the block polymer as described above.
- the said organic solvent is the liquid that is in majority amount by weight in the organic liquid medium of the cosmetic composition.
- the organic liquid medium comprises fatty substances that are liquid at room temperature (in general 25° C.). These liquid fatty substances may be of animal, plant, mineral or synthetic origin.
- oils As fatty substances that are liquid at room temperature, often known as oils, which may be used in the invention, mention may be made of: hydrocarbon-based oils of animal origin such as perhydrosqualene; hydrocarbon-based plant oils such as liquid triglycerides of fatty acids containing from 4 to 10 carbon atoms, for instance heptanoic or octanoic acid triglycerides, or alternatively sunflower oil, corn oil, soybean oil, grapeseed oil, sesame seed oil, apricot oil, macadamia oil, castor oil, avocado oil, caprylic/capric acid triglycerides, jojoba oil or shea butter; linear or branched hydrocarbons, of mineral or synthetic origin, such as liquid paraffins and derivatives thereof, petroleum jelly, polydecenes, and hydrogenated polyisobutylene such as butter; synthetic esters and ethers, especially of fatty acids, for instance purcellin oil, isopropyl myristate, 2-ethylhe
- oils may be present in a content ranging from 0.01% to 90% and better still from 0.1% to 85% by weight relative to the total weight of the composition.
- the organic liquid medium of the composition according to the invention may also comprise one or more cosmetically acceptable organic solvents (acceptable tolerance, toxicology and feel).
- solvents may generally be present in a content ranging from 0.1% to 90%, preferably from 10% to 90% and better still from 30% to 90% by weight relative to the total weight of the composition.
- solvents that may be used in the composition of the invention, mention may be made, besides the hydrophilic organic solvents mentioned above, of ketones that are liquid at room temperature, such as methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, isophorone, cyclohexanone and acetone; propylene glycol ethers that are liquid at room temperature, such as propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate and dipropylene glycol mono-n-butyl ether; short-chain esters (containing from 3 to 8 carbon atoms in total), such as ethyl acetate, methyl acetate, propyl acetate, n-butyl acetate and isopentyl acetate; ethers that are liquid at room temperature, such as diethyl ether, dimethyl ether and dichlorodiethyl ether; alkanes that are liquid at room temperature, such
- composition may comprise, besides the block polymer described above an additional polymer such as a film-forming polymer.
- film-forming polymer means a polymer that is capable of forming, by itself or in the presence of an auxiliary film-forming agent, a continuous film that adheres to a support, especially to keratin materials.
- Film-forming polymers that may be mentioned in particular include acrylic polymers, polyurethanes, polyesters, polyamides, polyureas and cellulose-based polymers, for instance nitrocellulose.
- the polymer may be combined with one or more auxiliary film-forming agents.
- a film-forming agent may be chosen from any compound known to those skilled in the art as being capable of fulfilling the desired function, and may be chosen especially from plasticizers and coalescers.
- composition according to the invention may comprise at least one wax.
- wax means a lipophilic compound that is solid at room temperature (25° C.), which undergoes a reversible solid/liquid change of state, and which has a melting point of greater than or equal to 30° C., which may be up to 120° C.
- the melting point of the wax may be measured using a differential scanning calorimeter (DSC), for example the calorimeter sold under the name DSC 30 by the company Mettler.
- DSC differential scanning calorimeter
- the waxes may be hydrocarbon-based waxes, fluoro waxes and/or silicone waxes and may be of plant, mineral, animal and/or synthetic origin.
- the waxes have a melting point of greater than 25° C. and better still greater than 45° C.
- the nature and amount of the solid fatty substances depend on the desired mechanical properties and textures.
- the composition may contain from 0 to 50% by weight and better still from 1% to 30% by weight of waxes, relative to the total weight of the composition.
- composition according to the invention may also comprise one or more dyestuffs chosen from water-soluble dyes and pulverulent dyestuffs, for instance pigments, nacres and flakes that are well known to those skilled in the art.
- the dyestuffs may be present in the composition in a content ranging from 0.01% to 50% by weight and preferably from 0.01% to 30% by weight, relative to the weight of the composition.
- pigments should be understood as meaning white or coloured, mineral or organic particles of any shape, which are insoluble in the physiological medium and which are intended to colour the composition.
- nacres should be understood as meaning iridescent particles of any shape, produced especially by certain molluscs in their shell, or alternatively synthesized.
- the pigments may be white or coloured, and mineral and/or organic.
- mineral pigments that may be mentioned are titanium dioxide, optionally surface-treated, zirconium oxide or cerium oxide, and also zinc oxide, iron oxide (black, yellow or red) or chromium oxide, manganese violet, ultramarine blue, chromium hydrate and ferric blue, and metal powders, for instance aluminium powder or copper powder.
- organic pigments that may be mentioned are carbon black, pigments of D & C type, and lakes based on cochineal carmine or on barium, strontium, calcium or aluminium.
- pigments with an effect such as particles comprising a natural or synthetic, organic or mineral substrate, for example glass, acrylic resins, polyester, polyurethane, polyethylene terephthalate, ceramics or aluminas, the said substrate being uncoated or coated with metal substances, for instance aluminium, gold, silver, platinum, copper or bronze, or with metal oxides, for instance titanium dioxide, iron oxide or chromium oxide, and mixtures thereof.
- a natural or synthetic, organic or mineral substrate for example glass, acrylic resins, polyester, polyurethane, polyethylene terephthalate, ceramics or aluminas
- metal substances for instance aluminium, gold, silver, platinum, copper or bronze
- metal oxides for instance titanium dioxide, iron oxide or chromium oxide, and mixtures thereof.
- the nacreous pigments may be chosen from white nacreous pigments such as mica coated with titanium or with bismuth oxychloride, coloured nacreous pigments such as titanium mica coated with iron oxides, titanium mica coated especially with ferric blue or chromium oxide, titanium mica coated with an organic pigment of the abovementioned type and also nacreous pigments based on bismuth oxychloride. Interference pigments, especially liquid-crystal pigments or multilayer pigments, may also be used.
- the water-soluble dyes are, for example, beetroot juice or methylene blue.
- the composition according to the invention may also comprise one or more fillers, especially in a content ranging from 0.01% to 50% by weight and preferably ranging from 0.01% to 30% by weight, relative to the total weight of the composition.
- fillers should be understood as meaning colourless or white, mineral or synthetic particles of any shape, which are insoluble in the medium of the composition, irrespective of the temperature at which the composition is manufactured. These fillers serve especially to modify the rheology or the texture of the composition.
- the fillers may be mineral or organic in any form, platelet-shaped, spherical or oblong, irrespective of the crystallographic form (for example leaflet, cubic, hexagonal, orthorhombic, etc.). Mention may be made of talc, mica, silica, kaolin, polyamide (Nylon®) powders (Orgasol® from Atochem), poly- ⁇ -alanine powder and polyethylene powder, powders of tetrafluoroethylene polymers (Teflon®), lauroyllysine, starch, boron nitride, hollow polymer microspheres such as those of polyvinylidene chloride/acrylonitrile, for instance Expancel® (Nobel Industrie) or acrylic acid copolymers (Polytrap® from the company Dow Corning) and silicone resin microbeads (for example Tospearls® from Toshiba), elastomeric polyorganosiloxane particles, precipitated calcium carbonate, magnesium carbonate, magnesium hydrocarbonate
- the composition according to the invention may especially be in the form of a stick, a suspension, a dispersion, a solution, a gel, an emulsion, especially an oil-in-water (O/W) emulsion, a water-in-oil (W/O) emulsion or a multiple emulsion (W/O/W or polyol/O/W or O/W/O emulsion), in the form of a cream, a paste, a mousse, a dispersion of vesicles, especially of ionic or nonionic lipids, a two-phase or multi-phase lotion, a spray, a powder, a paste, especially a soft paste (especially a paste with a dynamic viscosity at 25° C. of about from 0.1 to 40 Pa ⁇ s under a shear rate of 200 s ⁇ 1 , after measurement for 10 minutes in cone/plate geometry).
- the composition may be anhydrous; for example, it may be an anhydrous paste.
- a person skilled in the art may select the appropriate galenical form, and also the method for preparing it, on the basis of his general knowledge, taking into account firstly the nature of the constituents used, especially their solubility in the support, and secondly the intended application for the composition.
- composition according to the invention may be a makeup composition, for instance products for the complexion (foundations), makeup rouges, eyeshadows, lipsticks, concealer products, blushers, mascaras, eyeliners, eyebrow makeup products, lip or eye pencils, nail products, such as nail varnishes, body makeup products or hair makeup products (hair mascara or hair lacquer).
- makeup rouges for the complexion
- eyeshadows lipsticks
- concealer products blushers
- mascaras eyeliners
- eyebrow makeup products lip or eye pencils
- nail products such as nail varnishes, body makeup products or hair makeup products (hair mascara or hair lacquer).
- composition according to the invention may also be a care product for body and facial skin, especially an antisun product or a skin-colouring product (such as a self-tanning product).
- the composition according to the invention may also be a haircare product, especially for holding or styling the hair or for shaping the hair.
- the haircare compositions are preferably shampoos, hairsetting gels or lotions, blow-drying lotions, or fixing and styling compositions such as lacquers or sprays.
- a subject of the present invention is also a cosmetic assembly comprising:
- the container may be in any adequate form. It may especially be in the form of a bottle, a tube, a jar, a case, a box, a sachet or a carton.
- the closing member may be in the form of a removable stopper, a lid, a cap, a tear-off strip or a capsule, especially of the type comprising a body attached to the container and a cover cap articulated on the body. It may also be in the form of a member for selectively closing the container, especially a pump, a valve or a flap valve.
- the container may be combined with an applicator, especially in the form of a brush comprising an arrangement of bristles maintained by a twisted wire.
- a twisted brush is described especially in patent U.S. Pat. No. 4,887,622.
- It may also be in the form of a comb comprising a plurality of application members, obtained especially by moulding. Such combs are described, for example, in patent FR 2 796 529.
- the applicator may be in the form of a fine brush, as described, for example, in patent FR 2 722 380.
- the applicator may be in the form of a block of foam or of elastomer, a felt or a spatula.
- the applicator may be free (tuft or sponge) or securely fastened to a rod borne by the closing member, as described, for example, in patent U.S. Pat. No. 5,492,426.
- the applicator may be securely fastened to the container, as described, for example, in patent FR 2 761 959.
- the product may be contained directly in the container, or indirectly.
- the product may be arranged on an impregnated support, especially in the form of a wipe or a pad, and arranged (individually or in plurality) in a box or in a sachet.
- an impregnated support especially in the form of a wipe or a pad, and arranged (individually or in plurality) in a box or in a sachet.
- Such a support incorporating the product is described, for example, in patent application WO 01/035-38.
- the closing member may be coupled to the container by screwing.
- the coupling between the closing member and the container is done other than by screwing, especially via a bayonet mechanism, by click-fastening, gripping, welding, bonding or by magnetic attraction.
- click-fastening in particular means any system involving the crossing of a bead or cord of material by elastic deformation of a portion, especially of the closing member, followed by return to the elastically unconstrained position of the said portion after the crossing of the bead or cord.
- the container may be at least partially made of thermoplastic material.
- thermoplastic materials that may be mentioned include polypropylene or polyethylene.
- the container is made of non-thermoplastic material, especially glass or metal (or alloy).
- the container may have rigid walls or deformable walls, especially in the form of a tube or a tubular bottle.
- the container may comprise means for distributing or facilitating the distribution of the composition.
- the container may have deformable walls so as to allow the composition to exit in response to a positive pressure inside the container, this positive pressure being caused by elastic (or non-elastic) squeezing of the walls of the container.
- the product may be driven out by a piston mechanism.
- the container may comprise a mechanism, especially a rack mechanism, a threaded-rod mechanism or a helical groove mechanism, and may be capable of moving a stick in the direction of the said aperture.
- a mechanism is described, for example, in patent FR 2 806 273 or in patent FR 2 775 566.
- Such a mechanism for a liquid product is described in patent FR 2 727 609.
- the container may consist of a carton with a base delimiting at least one housing containing the composition, and a lid, especially articulated on the base, and capable of at least partially covering the said base.
- a carton is described, for example, in patent application WO 03/018423 or in patent FR 2 791 042.
- the container may be equipped with a drainer arranged in the region of the aperture of the container.
- a drainer makes it possible to wipe the applicator and possibly the rod to which it may be securely fastened.
- Such a drainer is described, for example, in patent FR 2 792 618.
- the composition may be at atmospheric pressure inside the container (at room temperature) or pressurized, especially by means of a propellent gas (aerosol).
- a propellent gas especially by means of a propellent gas (aerosol).
- the container is equipped with a valve (of the type used for aerosols).
- the product Lipfinity is a lip makeup product comprising a pigmented liquid lipstick and a transparent colourless balm in the form of a stick.
- the gloss and transfer measurements were performed on the pigmented liquid lipstick composition of the product sold under the brand name Lipfinity.
- the transfer index is measured according to the method described above.
- Product whose transfer Transfer value index is evaluated (in %) Pigmented composition of 1.4 ⁇ 0.1 the product Lipfinity Example 4 1.3 ⁇ 0.9
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Insects & Arthropods (AREA)
- Zoology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Materials For Medical Uses (AREA)
- Fats And Perfumes (AREA)
- Paints Or Removers (AREA)
- Toys (AREA)
- Dental Preparations (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR02/11949 | 2002-09-26 | ||
FR0211949 | 2002-09-26 | ||
FR0216437 | 2002-12-20 | ||
FR02/16437 | 2002-12-20 | ||
FR0306121 | 2003-05-21 | ||
FR03/06121 | 2003-05-21 | ||
PCT/FR2003/002847 WO2004028485A2 (fr) | 2002-09-26 | 2003-09-26 | Composition brillante et non transfert comprenant un polymere sequence |
Publications (1)
Publication Number | Publication Date |
---|---|
US20060134051A1 true US20060134051A1 (en) | 2006-06-22 |
Family
ID=32045662
Family Applications (10)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/529,266 Abandoned US20060134051A1 (en) | 2002-09-26 | 2003-09-26 | Glossy non-transfer composition comprising a sequenced polymer |
US10/529,265 Active 2029-03-28 US9017704B2 (en) | 2002-09-26 | 2003-09-26 | Composition comprising a block polymer and a film-forming agent |
US10/528,835 Active 2028-09-08 US8992903B2 (en) | 2002-09-26 | 2003-09-26 | Composition comprising at least one block polymer and at least one gelling agent |
US10/529,218 Abandoned US20060115444A1 (en) | 2002-09-26 | 2003-09-26 | Glossy liquid composition comprising a sequenced polymer |
US10/528,699 Abandoned US20060134032A1 (en) | 2002-09-26 | 2003-09-26 | Nail varnish composition comprising a sequenced polymer |
US10/529,267 Abandoned US20060099164A1 (en) | 2002-09-26 | 2003-09-26 | Composition for coating keratin fibres, comprising a high dry extract that contains a sequenched polymer |
US10/529,318 Expired - Fee Related US7875265B2 (en) | 2002-09-26 | 2003-09-26 | Cosmetic composition comprising a sequenced polymer and a plasticizer |
US10/529,264 Abandoned US20060147403A1 (en) | 2002-09-26 | 2003-09-26 | Non-transfer cosmetic composition comprising a sequenced polymer |
US10/670,388 Abandoned US20040120906A1 (en) | 2002-09-26 | 2003-09-26 | Nail varnish composition comprising a block polymer |
US10/528,698 Abandoned US20060127334A1 (en) | 2002-09-26 | 2003-09-26 | Lipstick comprising a sequenced polymer |
Family Applications After (9)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/529,265 Active 2029-03-28 US9017704B2 (en) | 2002-09-26 | 2003-09-26 | Composition comprising a block polymer and a film-forming agent |
US10/528,835 Active 2028-09-08 US8992903B2 (en) | 2002-09-26 | 2003-09-26 | Composition comprising at least one block polymer and at least one gelling agent |
US10/529,218 Abandoned US20060115444A1 (en) | 2002-09-26 | 2003-09-26 | Glossy liquid composition comprising a sequenced polymer |
US10/528,699 Abandoned US20060134032A1 (en) | 2002-09-26 | 2003-09-26 | Nail varnish composition comprising a sequenced polymer |
US10/529,267 Abandoned US20060099164A1 (en) | 2002-09-26 | 2003-09-26 | Composition for coating keratin fibres, comprising a high dry extract that contains a sequenched polymer |
US10/529,318 Expired - Fee Related US7875265B2 (en) | 2002-09-26 | 2003-09-26 | Cosmetic composition comprising a sequenced polymer and a plasticizer |
US10/529,264 Abandoned US20060147403A1 (en) | 2002-09-26 | 2003-09-26 | Non-transfer cosmetic composition comprising a sequenced polymer |
US10/670,388 Abandoned US20040120906A1 (en) | 2002-09-26 | 2003-09-26 | Nail varnish composition comprising a block polymer |
US10/528,698 Abandoned US20060127334A1 (en) | 2002-09-26 | 2003-09-26 | Lipstick comprising a sequenced polymer |
Country Status (8)
Country | Link |
---|---|
US (10) | US20060134051A1 (ja) |
EP (10) | EP1421928A3 (ja) |
JP (8) | JP3981132B2 (ja) |
AT (7) | ATE488222T1 (ja) |
AU (10) | AU2003290143A1 (ja) |
BR (2) | BR0303890A (ja) |
DE (7) | DE60335007D1 (ja) |
WO (10) | WO2004028492A2 (ja) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040120906A1 (en) * | 2002-09-26 | 2004-06-24 | Beatrice Toumi | Nail varnish composition comprising a block polymer |
US20050095213A1 (en) * | 2003-09-26 | 2005-05-05 | Xavier Blin | Two-coat cosmetic product, cosmetic process of using thereof and makeup kit containing this product |
US20070148114A1 (en) * | 2005-11-09 | 2007-06-28 | Nathalie Jager Lezer | Composition in the form of a foam for coating the eyelashes |
US20070196306A1 (en) * | 2005-07-22 | 2007-08-23 | Nathalie Jager Lezer | Process for coating eyelashes |
US20070207096A1 (en) * | 2006-02-13 | 2007-09-06 | Virginie Puisset | Nail varnish having a gelled texture |
US20080014235A1 (en) * | 2002-09-26 | 2008-01-17 | L'oreal | Novel Block Polymers and Cosmetic Compositions and Processes Comprising Them |
US20080145325A1 (en) * | 2006-09-13 | 2008-06-19 | Lizabeth-Anne Coffey-Dawe | Nail varnish comprising at least one resin |
US20080175804A1 (en) * | 2006-11-16 | 2008-07-24 | Celine Farcet | Novel block polymers, compositions comprising them, and treatment methods |
US20080260665A1 (en) * | 2007-01-08 | 2008-10-23 | Laurence Guerchet | Nail varnish comprising at least one polycondensate and at least one polyoxyalkylene copolymer |
US20110020263A1 (en) * | 2009-06-01 | 2011-01-27 | L'oreal | Composition containing a block polymer and a nonvolatile ester oil |
US8119110B2 (en) | 2003-09-26 | 2012-02-21 | L'oreal S.A. | Cosmetic composition comprising a block polymer and a non-volatile silicone oil |
US8710152B2 (en) | 2006-07-27 | 2014-04-29 | L'oreal | Block polymers and their process of preparation |
US8728451B2 (en) | 2004-03-25 | 2014-05-20 | L'oreal | Styling composition comprising, in a predominantly aqueous medium, a pseudo-block polymer, processes employing same and uses thereof |
US9125468B2 (en) | 2010-03-29 | 2015-09-08 | L'oreal | Device for the application of fibers to human keratinous fibers |
US20180271766A1 (en) * | 2014-10-31 | 2018-09-27 | L'oreal | Acrylic polymer comprising alkoxysilane groups and cosmetic uses thereof |
US10532021B2 (en) | 2011-12-20 | 2020-01-14 | L'oreal | Composition comprising a specific acrylic polymer and a silicone copolymer, and method for treating keratin fibres using same |
US10744080B2 (en) | 2011-12-20 | 2020-08-18 | L'oreal | Method for the application of a pigment dyeing composition based on specific acrylic polymer and on silicone copolymer, and appropriate device |
US11376208B2 (en) | 2011-12-20 | 2022-07-05 | L'oreal | Pigment dyeing composition based on a particular acrylic polymer and silicone copolymer |
US11576852B2 (en) | 2012-06-29 | 2023-02-14 | L'oreal | Two coat process for dyeing keratin fibres |
US11771629B2 (en) | 2016-06-23 | 2023-10-03 | L'oreal | Process for the elongation and/or densification of fibers |
Families Citing this family (132)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7655231B2 (en) | 2003-02-19 | 2010-02-02 | Pfizer Inc. | Methods for treating pain by administering a nerve growth factor antagonist and an NSAID |
FR2851467B1 (fr) * | 2003-02-25 | 2006-07-07 | Oreal | Composition cosmetique comprenant une dispersion de particules de polymere et un ester d'acide et de polyol |
FR2851468B1 (fr) * | 2003-02-25 | 2008-07-11 | Oreal | Composition cosmetique comprenant une dispersion de particules de polymere et un compose plastifiant le polymere |
FR2860155A1 (fr) * | 2003-09-26 | 2005-04-01 | Oreal | Composition photoprotectrice a phase aqueuse continue contenant un polymere comprenant au moins deux sequences incompatibles l'une avec l'autre et ayant des temperatures de transition vitreuse differentes |
FR2860156B1 (fr) * | 2003-09-26 | 2007-11-02 | Oreal | Composition cosmetique comprenant un agent tenseur et un polymere ethylenique sequence particulier |
WO2005030155A1 (en) * | 2003-09-26 | 2005-04-07 | L'oréal | Continuous aqueous phase-based photoprotective composition containing a polymer comprising at least two blocks incompatible with each other and having different glass transition temperatures |
DE10358091A1 (de) * | 2003-12-10 | 2005-07-14 | Eckart Gmbh & Co. Kg | Kosmetische Zusammensetzung zur Erzeugung eines kosmetischen Überzugs mit einem metallisch und mehrfarbig schillernden Erscheinungsbild und künstlicher Fingernagel |
FR2864895A1 (fr) * | 2004-01-13 | 2005-07-15 | Oreal | Composition de revetement des fibres keratiniques comprenant un polymere sequence, un polymere cationique et un polymere anionique |
US20050220731A1 (en) * | 2004-03-23 | 2005-10-06 | Philippe Ilekti | Nail varnish composition comprising at least one polymer and at least one plasticizer |
FR2871372A1 (fr) * | 2004-06-11 | 2005-12-16 | Oreal | Composition cosmetique comprenant un polymere |
US20050281769A1 (en) * | 2004-06-11 | 2005-12-22 | Toumi Beatrice | Cosmetic composition comprising a polymer |
FR2871470B1 (fr) * | 2004-06-11 | 2007-01-12 | Oreal | Copolymere a gradient, composition et procede cosmetique de maquillage ou de soin |
FR2874311B1 (fr) | 2004-08-20 | 2006-11-17 | Oreal | Kit de maquillage ou de soin des ongles |
FR2876011B1 (fr) * | 2004-10-05 | 2006-12-29 | Oreal | Procede de maquillage d'un support et kit pour la mise en oeuvre de ce procede |
US9649261B2 (en) | 2004-10-05 | 2017-05-16 | L'oreal | Method of applying makeup to a surface and a kit for implementing such a method |
FR2879442B1 (fr) | 2004-12-21 | 2007-07-20 | Oreal | Composition cosmetique pour le maquillage resistante a l'eau et facilement demaquillable |
FR2880268B1 (fr) * | 2005-01-05 | 2008-10-24 | Oreal | Composition brillante et non transfert comprenant deux polymeres sequences |
FR2881648B1 (fr) * | 2005-02-04 | 2008-12-05 | Oreal | Composition cosmetique comprenant une dispersion de particules de polymeres, dispersion de particules de polymeres et procede cosmetique l'utilisant |
US20060193803A1 (en) * | 2005-02-04 | 2006-08-31 | Celine Farcet | Polymer particle dispersions, cosmetic compositions comprising at least one polymer particle dispersion, and cosmetic process using same |
EP1867664B1 (en) * | 2005-03-18 | 2011-11-30 | Kao Corporation | Cosmetic for eyelash |
FR2887770A1 (fr) * | 2005-07-04 | 2007-01-05 | Oreal | Produit de maquillage et/ou de soin "double-geste" |
FR2888115B1 (fr) * | 2005-07-08 | 2013-02-15 | Oreal | Fond de teint liquide, procede de maquillage et kit pour la mise en oeuvre d'un tel procede. |
FR2889921B1 (fr) | 2005-08-30 | 2007-12-28 | Oreal | Ensemble de conditionnement et d'application comportant un dispositif magnetique. |
US20070081954A1 (en) * | 2005-10-06 | 2007-04-12 | Nathalie Mougin | Dispersion of polymer particles, composition comprising it and cosmetic treatment method |
US20070134181A1 (en) * | 2005-12-08 | 2007-06-14 | L'oreal | Cosmetic composition comprising an ester of dimerdilinoleic acid and of polyol(s) and a silicone surfactant |
EP2045966B1 (en) * | 2005-12-22 | 2016-03-30 | Axis AB | Monitoring system and method for connecting a monitoring device to a service server |
WO2007078861A2 (en) * | 2005-12-30 | 2007-07-12 | Avon Products, Inc. | Method for imparting curl to eyelashes |
DE102006012354A1 (de) * | 2006-03-17 | 2007-09-20 | Bayer Materialscience Ag | Wässrige Dispersionen auf Basis von Nitrocellulose-Polyurethan-Teilchen |
JP2007308544A (ja) * | 2006-05-17 | 2007-11-29 | Hitachi Ltd | 低誘電率低屈折率ナノコンポジット材料 |
FR2902006B1 (fr) * | 2006-06-13 | 2009-06-05 | Oreal | Composition cosmetique pour les levres associant un tensioactif phosphate et un polymere silicone |
FR2905068B1 (fr) * | 2006-08-25 | 2008-10-31 | Oreal | Procede de maquillage des cils et ensemble de conditionnement. |
DE202007018702U1 (de) * | 2006-10-20 | 2009-02-19 | Faber-Castell Ag | Kosmetische Zubereitung zum Färben der Augenlider und der Augenbrauen |
GB0624729D0 (en) * | 2006-12-12 | 2007-01-17 | Univ Leeds | Reversible micelles and applications for their use |
FR2910280B1 (fr) | 2006-12-22 | 2009-01-23 | Oreal | Vernis a ongles comprenant un polycondensat et un copolymere polyoxyalkylene |
FR2911065B1 (fr) | 2007-01-04 | 2009-03-20 | Oreal | Kit de maquillage des fibres keratiniques. |
FR2915893B1 (fr) | 2007-05-10 | 2012-05-11 | Oreal | Composition cosmetique sous forme de mousse sans cire |
FR2915892B1 (fr) | 2007-05-10 | 2009-07-03 | Oreal | Composition sous forme de mousse comprenant un structurant polymerique |
US8562960B2 (en) | 2007-07-30 | 2013-10-22 | Elc Management, Llc | Cosmetic composition containing a polymer blend |
US20090035335A1 (en) * | 2007-07-30 | 2009-02-05 | Marotta Paul H | Cosmetic Composition Containing a Polymer Blend |
EP2025320A1 (fr) | 2007-08-10 | 2009-02-18 | L'Oréal | Ensemble de conditionnement et d'application d'un vernis à ongles de viscosité élevée |
US20090136439A1 (en) * | 2007-11-27 | 2009-05-28 | L'oreal | Cosmetic composition capable of imparting exceptional curl-retention properties |
US8916020B2 (en) * | 2007-12-05 | 2014-12-23 | 3M Innovative Properties Company | Assembly bonded to a structural adhesive and method and applicator for making it |
CN101951992B (zh) * | 2007-12-05 | 2015-06-10 | 欧莱雅公司 | 使用包含硅氧烷树脂和矿物填料的组合物的美容方法 |
FR2924939B1 (fr) | 2007-12-13 | 2010-02-26 | Oreal | Procede de coloration des cheveux a partir d'une composition comprenant un polymere filmogene hydrophobe, un pigment et un solvant volatil |
FR2925849B1 (fr) * | 2007-12-27 | 2010-06-04 | Oreal | Procede cosmetique procurant un effet allongeant des cils et kit correspondant a base d'un polymere filmogene |
ES2592878T3 (es) | 2008-01-30 | 2016-12-02 | L'oreal, S.A. | Artículo adhesivo que contiene colorante y/o agente activo |
FR2931670B1 (fr) | 2008-06-02 | 2015-05-22 | Oreal | Compositions a base de polyester dans une phase grasse et leurs utilisations. |
FR2936420A1 (fr) | 2008-09-30 | 2010-04-02 | Oreal | Composition et procede de maquillage des cils comprenant l'application de 2 compositions. |
FR2936419B1 (fr) | 2008-09-30 | 2010-10-01 | Oreal | Composition de maquillage des cils et ensemble de conditionnement. |
FR2937645B1 (fr) * | 2008-10-24 | 2010-12-17 | Oreal | Dispersion de particules souples de polymere, compostion cosmetique la comprenant et procede de traitement cosmetique |
FR2938764B1 (fr) | 2008-11-24 | 2012-06-08 | Oreal | Composition cosmetique solide pour application sur les fibres keratiniques |
FR2938763B1 (fr) * | 2008-11-24 | 2012-09-28 | Oreal | Composition cosmetique solide pour application sur les fibres keratiniques |
FR2939033B1 (fr) * | 2008-12-02 | 2012-08-31 | Oreal | Composition cosmetique de maquillage et/ou de soin des matieres keratiniques, et procede de maquillage |
EP2355785A4 (en) | 2008-12-09 | 2014-08-13 | Oréal Sa L | TRANSFER SOLID EMULSION WITH A TENSID |
FR2939657B1 (fr) | 2008-12-15 | 2011-02-11 | Oreal | Composition cosmetique comprenant une polyamine portant des groupes diazirines et utilisation pour le photo-greffage d'un polymere non saccharidique different des polymeres polyamines |
WO2010077940A2 (en) | 2008-12-16 | 2010-07-08 | Hy Si Bui | Water-insoluble reaction product of a polyamine and an oil-soluble high carbon polar modified polymer |
WO2010077887A2 (en) | 2008-12-16 | 2010-07-08 | L'oreal S.A | Transfer-resistant and long wear foundation in emulsion form containing oil absorbing powders |
FR2940115B1 (fr) | 2008-12-19 | 2012-06-15 | Oreal | Kit de revetement des matieres keratiniques comprenant un polysaccharide et un agent de reticulation chimique |
FR2940111B1 (fr) | 2008-12-19 | 2012-06-01 | Oreal | Kit de revetement des matieres keratiniques comprenant un polysaccharide et un agent de complexation ionique ou dative |
FR2943225B1 (fr) | 2009-03-17 | 2011-06-03 | Oreal | Dispositif de conditionnement et d'application d'au moins une composition cosmetique solide |
FR2943253B1 (fr) | 2009-03-20 | 2011-04-22 | Oreal | Composition contenant l'association de madecassoside, d'une arginine et de polysorbate |
FR2944958B1 (fr) | 2009-04-30 | 2011-07-08 | Oreal | Emulsion cire-dans-eau comprenant l'association d'un derive d'acide glutamique et d'un alkylpolyglycoside |
FR2945942B1 (fr) * | 2009-06-01 | 2012-12-28 | Oreal | Composition cosmetique comprenant un polymere sequence et une huile ester non volatile |
FR2945941B1 (fr) * | 2009-06-02 | 2011-06-24 | Oreal | Composition cosmetique comprenant un polymere sequence et une huile ester non volatile |
WO2010146147A2 (en) | 2009-06-18 | 2010-12-23 | L'oreal | Composition for treating keratin fibres comprising a block copolymer, a siloxane resin and a volatile solvent |
US8647611B2 (en) | 2009-06-29 | 2014-02-11 | L'oréal | Composition containing a polyol and a reaction product |
US8663667B2 (en) | 2009-06-29 | 2014-03-04 | L'oreal | Refreshing cream foundation in gel form |
BRPI1002598A2 (pt) * | 2009-06-29 | 2012-03-13 | L'oreal S.A. | Composição e método para a maquilagem dos cílios |
BRPI1003794A2 (pt) | 2009-06-29 | 2012-03-20 | L'oreal S.A. | composição e produto de reação |
EP2322247A2 (en) * | 2009-06-29 | 2011-05-18 | L'oreal S.A. | Composition comprising a polyol, a sugar silicone surfactant and an oil-soluble polar modified polymer |
EP2322245A3 (en) | 2009-06-29 | 2014-03-12 | L'oreal S.A. | Hydrating cream foundation in emulsion form |
US8652451B2 (en) * | 2009-06-29 | 2014-02-18 | L'oreal | Composition comprising a sugar silicone surfactant and a oil-soluble polar modified polymer |
JP5756604B2 (ja) * | 2009-07-21 | 2015-07-29 | リー ヘイル ダニー | ネイル用の除去可能なゲル適用向けの組成物、及びそれらの使用方法 |
FR2949675B1 (fr) * | 2009-09-08 | 2011-10-21 | Oreal | Composition cosmetique comprenant un polymere filmogene acide et une charge minerale basique |
FR2949958B1 (fr) | 2009-09-11 | 2012-10-05 | Oreal | Ensemble cosmetique de maquillage et/ou de soin des matieres keratiniques |
WO2011045740A2 (en) | 2009-10-12 | 2011-04-21 | L'oreal | Methods of photoprotecting a material against solar uv radiation using photonic particles; compositions |
WO2011045741A2 (en) | 2009-10-12 | 2011-04-21 | L'oreal | Photonic particles; compositions containing them; methods of photoprotecting various materials |
WO2011045746A2 (en) | 2009-10-12 | 2011-04-21 | L ' Oreal | A composition comprising a dispersion of photonic particles; methods of treating various materials |
JP2013508351A (ja) | 2009-10-22 | 2013-03-07 | ロレアル | 光防御組成物およびフィルム、ならびに製造方法 |
EP2335677A1 (fr) | 2009-12-17 | 2011-06-22 | L'Oréal | Composition cosmetique chargeante comprenant de l'alcool behenique a titre d'agent epaississant |
EP2356981B1 (en) * | 2009-12-18 | 2019-03-20 | L'Oréal SA | Mascara containing aqueous dispersion of polyurethane and a hard wax |
EP2353582A1 (fr) | 2009-12-18 | 2011-08-10 | L'Oréal | Composition de maquillage des cils et des sourcils |
KR20130103619A (ko) | 2010-03-29 | 2013-09-23 | 로레알 | 속눈썹 또는 눈썹의 메이크업용 조성물, 조합 및 방법 |
US9192561B2 (en) | 2010-05-14 | 2015-11-24 | L'oreal | Compositions containing hyperbranched polyol and acrylic film former |
FR2959932A1 (fr) | 2010-05-17 | 2011-11-18 | Oreal | Composition de maquillage et/ou de soin des fibres keratiniques presentant des proprietes de tenue ameliorees |
FR2961396B1 (fr) | 2010-06-16 | 2013-03-15 | Oreal | Procede de maquillage ou de soin des fibres keratiniques mettant en oeuvre des fibres retractables et utilisation |
WO2012061267A2 (en) * | 2010-11-02 | 2012-05-10 | L'oreal Sa | Two-step nail polish product |
FR2967058B1 (fr) | 2010-11-05 | 2013-10-04 | Oreal | Composition cosmetique et procede de recourbement des fibres keratiniques |
FR2967059B1 (fr) | 2010-11-05 | 2015-07-17 | Oreal | Composition cosmetique et procede de recourbement des fibres keratiniques |
FR2967057B1 (fr) * | 2010-11-05 | 2013-08-02 | Oreal | Composition cosmetique et procede de recourbement des fibres keratiniques |
FR2967912B1 (fr) | 2010-11-26 | 2013-05-10 | Oreal | Composition de maquillage des fibres keratiniques |
FR2968520B1 (fr) | 2010-12-14 | 2013-08-30 | Oreal | Element pour l'application de fibres sur des fibres keratiniques humaines |
US8747868B2 (en) | 2010-12-30 | 2014-06-10 | L'oreal | Reaction product of a polar modified polymer and an alkoxysilane and a composition containing the reaction product |
CN102199261B (zh) * | 2011-04-13 | 2012-09-19 | 山东交通学院 | 聚乙二醇-b-聚苯乙烯-b-聚全氟己基乙基丙烯酸酯及其制备方法 |
FR2982771B1 (fr) * | 2011-11-23 | 2013-12-20 | Oreal | Composition comprenant un copolymere bloc polysiloxane/polyuree, un copolymere ethylenique sequence et un solvant volatil |
FR2983718B1 (fr) * | 2011-12-12 | 2016-09-30 | Oreal | Emulsion huile-dans-eau solaire comprenant un polymere ethylenique lipophile, un copolymere d'olefine, un melange de tensio-actifs non-ioniques |
FR2984089B1 (fr) | 2011-12-20 | 2014-01-10 | Oreal | Dispositif d'application comprenant une composition a base de polymere filmogene hydrophobe et un solvant volatil, procede de traitement des fibres keratiniques le mettant en oeuvre |
WO2013102060A1 (en) | 2011-12-30 | 2013-07-04 | L'oreal | Compositions containing a silicon resin and a tackifying agent |
BR112014016245A8 (pt) | 2011-12-30 | 2017-07-04 | Oreal | composição e método de maquiar lábios e a pele |
US9226888B2 (en) | 2011-12-30 | 2016-01-05 | L'oreal | Compositions containing an acrylic film former, a tackifier and an ester |
FR2985422B1 (fr) | 2012-01-10 | 2014-08-08 | Oreal | Composition cosmetique solide a effets magnetiques |
FR2992558B1 (fr) | 2012-06-29 | 2014-06-20 | Oreal | Procede pour former un motif colore sur les fibres keratiniques avec une composition comprenant un polymere filmogene hydrophobe, au moins un solvant volatil et au moins un pigment. |
FR3015260B1 (fr) * | 2013-12-19 | 2018-08-31 | L'oreal | Composition anhydre anti-transpirante sous forme d'aerosol comprenant un actif anti-transpirant et un polymere ethylenique filmogene non hydrosoluble et sequence |
FR3025098B1 (fr) * | 2014-08-28 | 2018-03-09 | Oreal | Composition cosmetique de type gel facilement demaquillable |
FR3025099B1 (fr) * | 2014-08-28 | 2016-12-16 | Oreal | Composition cosmetique de type gel a tenue amelioree et non collante |
KR101773679B1 (ko) * | 2014-12-15 | 2017-08-31 | 주식회사 엘지생활건강 | 피부 외용제 조성물 |
KR101773681B1 (ko) * | 2014-12-15 | 2017-08-31 | 주식회사 엘지생활건강 | 피부 외용제 조성물 |
KR101773680B1 (ko) * | 2014-12-15 | 2017-08-31 | 주식회사 엘지생활건강 | 피부 외용제 조성물 |
KR101773682B1 (ko) * | 2014-12-15 | 2017-08-31 | 주식회사 엘지생활건강 | 피부 외용제 조성물 |
KR101773683B1 (ko) * | 2014-12-15 | 2017-08-31 | 주식회사 엘지생활건강 | 피부 외용제 조성물 |
KR101773684B1 (ko) * | 2014-12-15 | 2017-08-31 | 주식회사 엘지생활건강 | 피부 외용제 조성물 |
FR3030257B1 (fr) * | 2014-12-18 | 2016-12-23 | Oreal | Composition comprenant des particules de polymere et un epaississant mineral, procede la mettant en oeuvre |
FR3030261B1 (fr) * | 2014-12-18 | 2017-01-13 | Oreal | Composition comprenant des particules de polymere stabilise et un polymere filmogene hydrophobe |
FR3030260B1 (fr) * | 2014-12-18 | 2017-01-13 | Oreal | Composition comprenant des particules de polymere stabilise et un tensioactif non ionique |
CN107249564B (zh) * | 2014-12-18 | 2021-03-12 | 莱雅公司 | 包含聚合物颗粒、烃基油和烃基嵌段共聚物的组合物、和使用该组合物的方法 |
JP2017538745A (ja) * | 2014-12-18 | 2017-12-28 | ロレアル | サンケア組成物及び方法 |
FR3045378B1 (fr) * | 2015-12-22 | 2018-01-12 | L'oreal | Polymere sequence a groupements alcoxysilane et son utilisation en cosmetique |
US20190125652A1 (en) * | 2016-06-15 | 2019-05-02 | Mycone Dental Supply Co., Inc | One Part Acrylic Nail Formulation |
WO2018119038A1 (en) * | 2016-12-21 | 2018-06-28 | Ppg Industries Ohio, Inc. | Adhesion promoter |
US11708470B2 (en) | 2016-12-21 | 2023-07-25 | Ppg Industries Ohio, Inc. | Plastic substrate adhesion promoter with random copolymer |
US11628135B2 (en) | 2017-02-27 | 2023-04-18 | Coty, Inc. | Water-based nail-treatment composition |
WO2019014195A1 (en) | 2017-07-10 | 2019-01-17 | Coty Inc. | NAIL CURING COMPOSITION AND METHOD OF USE |
FR3075627B1 (fr) * | 2017-12-22 | 2021-11-05 | Oreal | Procede de traitement des cheveux mettant en oeuvre une dispersion de particules de polymere stabilisees dans un milieu non aqueux et un polymere filmogene hydrophobe |
FR3075628B1 (fr) * | 2017-12-22 | 2021-11-05 | Oreal | Composition aqueuse comprenant une dispersion de particules de polymere stabilisees dans un milieu non aqueux et un polymere filmogene hydrophobe |
US10543161B1 (en) * | 2018-08-24 | 2020-01-28 | L'oreal | Methods for protecting and improving the appearance of skin |
JP7179326B2 (ja) * | 2018-11-19 | 2022-11-29 | 株式会社サクラクレパス | 水性美爪料組成物 |
US20220117876A1 (en) * | 2018-11-26 | 2022-04-21 | Dsm Ip Assets B.V. | Cosmetic composition comprising specific hyperbranched copolymers and liquid dispersions of an acrylic polymer |
KR102331961B1 (ko) * | 2019-03-20 | 2021-11-25 | 주식회사 엘지생활건강 | 비수계 분산액, 그 제조 방법 및 그를 포함하는 화장료 조성물 |
FR3123805A1 (fr) * | 2021-06-11 | 2022-12-16 | Laboratoires De Biologie Vegetale Yves Rocher | Association de matieres premieres et composition cosmetique comprenant ladite association |
FR3130132B1 (fr) * | 2021-12-09 | 2023-11-17 | Oreal | Dispersion comprenant une particule polymerique, un agent stabilisant a groupe cycloalkyle, une huile, et de l’eau, procede de traitement des matieres keratiniques mettant en œuvre la dispersion |
WO2024049867A1 (en) | 2022-08-31 | 2024-03-07 | L'oreal | Cosmetic compositions with improved wear and transfer resistance |
FR3142901A1 (fr) | 2022-12-09 | 2024-06-14 | L'oreal | Compositions cosmétiques avec meilleure résistance à l’usure et au transfert |
Citations (87)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2781354A (en) * | 1956-03-26 | 1957-02-12 | John J Mccabe Jr | Imidazoline derivatives and process |
US3673160A (en) * | 1970-02-12 | 1972-06-27 | Rhodiaceta | Process for producing brilliant sulfonated polyamide-imide fibers and such fibers so produced |
US3802841A (en) * | 1971-06-14 | 1974-04-09 | Rhone Poulenc Textile | Nitro aromatic hydrocarbon,amino nitro aromatic & nitro aromatic phosphine oxides on aromatic polyamide-imide as light fading inhibitors for dyes thereon |
US3937811A (en) * | 1973-06-08 | 1976-02-10 | Societe Anonyme Dite: L'oreal | Fatty compositions for use in cosmetic makeup compositions and said cosmetic makeup compositions |
US4031307A (en) * | 1976-05-03 | 1977-06-21 | Celanese Corporation | Cationic polygalactomannan compositions |
US4030512A (en) * | 1974-12-30 | 1977-06-21 | Societe Anonyme Dite: L'oreal | Hair lacquer or setting lotion containing bi- or tri-sequenced copolymer |
US4032628A (en) * | 1970-04-07 | 1977-06-28 | Societe Anonyme Dite: L'oreal | Cosmetic emulsion compositions including black polymer emulsifiers |
US4152416A (en) * | 1976-09-17 | 1979-05-01 | Marra Dorothea C | Aerosol antiperspirant compositions delivering astringent salt with low mistiness and dustiness |
US4425326A (en) * | 1980-04-01 | 1984-01-10 | Societe Anonyme Dite : L'oreal | Anhydrous nail varnishes |
US4509949A (en) * | 1983-06-13 | 1985-04-09 | The B. F. Goodrich Company | Water thickening agents consisting of copolymers of crosslinked acrylic acids and esters |
US4728571A (en) * | 1985-07-19 | 1988-03-01 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafted copolymer release coating sheets and adhesive tapes |
US4981903A (en) * | 1989-08-07 | 1991-01-01 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafter copolymer topical binder composition with novel hydrophilic monomers and method of coating therewith |
US4981902A (en) * | 1989-08-07 | 1991-01-01 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafted copolymer non-pressure sensitive topical binder composition and method of coating therewith |
US5000937A (en) * | 1987-10-28 | 1991-03-19 | L'oreal | Transparent cosmetic composition that reflects infrared radiation and its use for protecting the human epidermis against infrared radiation |
US5110582A (en) * | 1981-03-25 | 1992-05-05 | Basf Aktiengesellschaft | Hair-setting preparation |
US5209924A (en) * | 1989-08-07 | 1993-05-11 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafted copolymer topical binder composition with novel fluorochemical comonomer and method of coating therewith |
US5219560A (en) * | 1989-03-20 | 1993-06-15 | Kobayashi Kose Co., Ltd. | Cosmetic composition |
US5391631A (en) * | 1992-06-25 | 1995-02-21 | Basf Aktiengesellschaft | Vinyl polymers produced by a two-stage procedure and their use as surface coating binders |
US5492426A (en) * | 1993-02-22 | 1996-02-20 | L'oreal | Deformable applicator with capillary feed |
US5519063A (en) * | 1991-07-25 | 1996-05-21 | L'oreal | Oily cosmetic composition containing, as a thickener, an association of two copolymers and optionally containing an amphiphilic rheology corrector |
US5711940A (en) * | 1993-10-01 | 1998-01-27 | Lvmh Recherche | Stable microdispersions and microgels based on acrylic polymers, method for obtaining them and compositions, particularly cosmetic compositions, containing them |
US5725882A (en) * | 1992-05-12 | 1998-03-10 | Minnesota Mining And Manufacturing Company | Vinyl-silicone copolymers in cosmetics and personal care products |
US5736125A (en) * | 1997-01-10 | 1998-04-07 | National Starch And Chemical Investment Holding Corporation | Compositions containing copolymers as a thickening agent |
US5747013A (en) * | 1994-01-17 | 1998-05-05 | L'oreal | Makeup cosmetic composition in the form of a mascara containing at least a wax and a pseudo-latex of cellulose derivatives |
US5756635A (en) * | 1991-12-24 | 1998-05-26 | Rhone-Poulenc Fibres | Process for spinning from solution of polyamide-imides (PAI) based on tolylene or met-phenylene diisocyanates and fibres thus obtained |
US5772347A (en) * | 1994-12-06 | 1998-06-30 | L'oreal | Dispenser for a product with a liquid-to-pasty consistency |
US5879095A (en) * | 1994-12-06 | 1999-03-09 | L'oreal | Dispenser for a product of liquid-to-pasty consistency, equipped with an application tip |
US5897870A (en) * | 1996-09-20 | 1999-04-27 | Basf Aktiengesellschaft | Aqeous or aqueous-alcoholic hair-cosmetic formulation |
US6033650A (en) * | 1995-06-26 | 2000-03-07 | Revlon Consumer Products Corporation | Glossy transfer resistant cosmetic compositions |
US6059473A (en) * | 1994-07-12 | 2000-05-09 | L'oreal | Applicator for applying a liquid cosmetic product and make-up assembly provided with such an applicator |
US6174968B1 (en) * | 1999-08-24 | 2001-01-16 | Shell Oil Company | Oil gel formulations containing polysiloxane block copolymers dissolved in hydrogenated silicone oils |
US6180123B1 (en) * | 1998-04-21 | 2001-01-30 | L'oreal | Composition for topical application comprising an olefin copolymer of controlled crystallization and use of such a copolymer in the manufacture of compositions for topical application |
US6197883B1 (en) * | 1999-06-03 | 2001-03-06 | Ppg Industries Ohio, Inc. | Thermosetting coating compositions containing flow modifiers prepared by controlled radical polymerization |
US6225390B1 (en) * | 1998-05-08 | 2001-05-01 | Shell Oil Company | Oil gel formulations containing polystyrene-polydimethylsiloxane or polyethylene-polydimethylsiloxane block copolymers dissolved in siloxane monomers |
US6228946B1 (en) * | 1998-07-03 | 2001-05-08 | Kuraray Co., Ltd. | Block copolymer and polymer composition comprising the same |
US6228967B1 (en) * | 1996-05-22 | 2001-05-08 | Mona Industries, Inc. | Organosilicone having a carboxyl functional group thereon |
US6238679B1 (en) * | 1998-03-09 | 2001-05-29 | L'oreal S.A. | Film-forming composition comprising a polyurethane in aqueous dispersion and a plasticizer |
EP1112735A1 (en) * | 1999-12-20 | 2001-07-04 | Avon Products, Inc. | Cosmetic composition applied to the eyelashes |
US6342237B1 (en) * | 1999-07-08 | 2002-01-29 | L'oréal | Make-up composition comprising fibers |
US20020015611A1 (en) * | 2000-03-16 | 2002-02-07 | Gilles Blondeel | Device for packaging and applying a cosmetic or care product |
US20020018759A1 (en) * | 2000-05-04 | 2002-02-14 | Pagano Frank Charles | Nail enamel compositions, related methods, and a two component kit for painting the nails |
US20020020424A1 (en) * | 1999-07-21 | 2002-02-21 | Gueret Jean-Louis H. | Applicator system and method |
US20020035237A1 (en) * | 1999-01-04 | 2002-03-21 | Lawson Nelson E. | Structured composition containing tertiary amide-terminated polyamide for personal care products |
US20020055562A1 (en) * | 1998-10-29 | 2002-05-09 | Butuc S. Gina | Gel compositions |
US20020054783A1 (en) * | 1997-04-15 | 2002-05-09 | L'oreal | Unit for packaging and applying a liquid product |
US20020061319A1 (en) * | 2000-09-29 | 2002-05-23 | Pascale Bernard | Film-forming cosmetic composition |
US20020064539A1 (en) * | 1998-02-11 | 2002-05-30 | L' Oreal | Cosmetic or dermatological composition contacting at least one natural or recombinant spider silk or an analog |
US20030003154A1 (en) * | 2001-05-04 | 2003-01-02 | L'oreal | Composition comprising at least one first semi-crystalline polymer and at least one second film-forming polymer |
US20030017182A1 (en) * | 2000-11-10 | 2003-01-23 | Florence Tournilhac | Cosmetic composition structured by a thermotropic liquid crystal polymer |
US20030017124A1 (en) * | 2001-04-10 | 2003-01-23 | L'oreal | Two-coat make-up product containing a goniochromatic pigment and monochrome pigment, and make-up kit containing this product |
US20030021815A9 (en) * | 2000-09-28 | 2003-01-30 | Jean Mondet | Cosmetic compositions comprising at least one continuous liquid fatty phase structured with polyurethanes, polyurethaneureas, and polyureas |
US20030024074A1 (en) * | 2001-08-01 | 2003-02-06 | Hartman Paul H. | Biconcave connector for tubular assemblies and tool handles |
US6518364B2 (en) * | 2000-09-28 | 2003-02-11 | Symyx Technologies, Inc. | Emulsion living-type free radical polymerization, methods and products of same |
US20030039621A1 (en) * | 2001-04-10 | 2003-02-27 | L'oreal | Two-coat make-up product, its use and a kit containing the make-up product |
US6531535B2 (en) * | 1999-01-29 | 2003-03-11 | Bayer Aktigensellschaft | Aqueous copolymers, a process for their preparation and their use in coating compositions |
US20030059392A1 (en) * | 2001-07-18 | 2003-03-27 | L'oreal | Composition for topical use containing a diblock polymer |
US6552146B1 (en) * | 1999-04-06 | 2003-04-22 | L'oreal S.A. | Composition comprising polymers having a star structure, the polymers, and their use |
US20040009136A1 (en) * | 2002-05-31 | 2004-01-15 | L'oreal | Aqueous hair treatment compositions, thickened with an amphiphilic linear block copolymer |
US20040014872A1 (en) * | 2000-06-16 | 2004-01-22 | Raether Roman Benedikt | Bonding agent composition containing solid matter, with radically polymerised block copolymers |
US20040013625A1 (en) * | 2002-07-22 | 2004-01-22 | Mohamed Kanji | Compositions comprising at least one heteropolymer and fibers, and methods of using the same |
US6685925B2 (en) * | 2000-10-03 | 2004-02-03 | Jean M. J. Frechet | Cosmetic and personal care compositions |
US6692733B1 (en) * | 1999-04-06 | 2004-02-17 | L'oreal | Composition comprising polymers having a star structure, the polymers, and their use |
US20040039101A1 (en) * | 2002-05-31 | 2004-02-26 | Claude Dubief | Washing compositions comprising at least one amphiphilic block copolymer and at least one cationic or amphoteric polymer |
US20040052752A1 (en) * | 2000-07-18 | 2004-03-18 | Henri Samain | Cosmetic composition containing a block copolymer consisting of blocks with different refractive indices |
US20040052745A1 (en) * | 2000-07-13 | 2004-03-18 | Pascale Bernard | Long-lasting make-up kit and method |
US20040077788A1 (en) * | 2002-07-19 | 2004-04-22 | Cid Centro De Investigacion Y Desarrollo Tecnologico, S.A. De. C.V. | Block copolymers containing functional groups |
US20040091444A1 (en) * | 2000-12-01 | 2004-05-13 | Loeffler Matthias | Decorative cosmetic and dermatological products |
US20040097657A1 (en) * | 2000-12-01 | 2004-05-20 | Roman Morschhaeuser | Acryoyldimethyltaurine acid-based grafted copolymers |
US20040093676A1 (en) * | 2001-04-03 | 2004-05-20 | Laurent Vidal | Novel dyeing composition for dyeing keratinous fibres comprising a particular dicationic monoazo dye |
US20040096409A1 (en) * | 2000-12-01 | 2004-05-20 | Matthias Loeffler | Deodorants and anti-perspirants |
US20050020779A1 (en) * | 2001-11-29 | 2005-01-27 | Nathalie Mougin | Block ethylenic copolymers cosmetic compositions containing them and cosmetic use of these copolymers |
US20050032998A1 (en) * | 2000-12-01 | 2005-02-10 | Roman Morschhaeuser | Cationically modified comb polymers based on acryloyldimethyl taurine acid |
US6881780B2 (en) * | 1995-06-19 | 2005-04-19 | The Lubrizol Corporation | Dispersant-viscosity improvers for lubricating oil compositions |
US20050089536A1 (en) * | 2000-12-01 | 2005-04-28 | Matthias Loffler | Use of comb copolymers based on acryloyldimethyltaurine acid in cosmetic, pharmaceutical and dermatological products |
US20050095213A1 (en) * | 2003-09-26 | 2005-05-05 | Xavier Blin | Two-coat cosmetic product, cosmetic process of using thereof and makeup kit containing this product |
US6891011B2 (en) * | 2000-12-01 | 2005-05-10 | Clariant Gmbh | Comb-shaped copolymers based on acryloyldimethyltaurine acid |
US20050106197A1 (en) * | 2003-09-26 | 2005-05-19 | Xavier Blin | Cosmetic composition comprising a block polymer and a non-volatile silicone oil |
US7022791B2 (en) * | 2000-12-01 | 2006-04-04 | Clarient Gmbh | Cosmetic, pharmaceutical and dermatological products containing an electrolyte |
US7025973B2 (en) * | 2000-12-01 | 2006-04-11 | Clariant Gmbh | Acid cosmetic, dermatological and pharmaceutical agents |
US20060093568A1 (en) * | 2002-09-26 | 2006-05-04 | Xavier Blin | Composition comprising a block polymer and a film-forming agent |
US20060099231A1 (en) * | 2002-09-06 | 2006-05-11 | De La Poterie Valerie | Make-up composition for keratin fibres such as eyelashes |
US7053146B2 (en) * | 2000-12-01 | 2006-05-30 | Clariant Gmbh | Compositions containing copolymers based on acryloyldimethyl aminoethylsulfonic acid and synergistic additives |
US20070003507A1 (en) * | 2001-11-29 | 2007-01-04 | L'oreal | Adhesive block ethylenic copolymers, cosmetic compositions containing them and cosmetic use of these copolymers |
US7176170B2 (en) * | 2002-05-31 | 2007-02-13 | L'oreal | Shampoo comprising at least one silicone and at least one anionic or nonionic, amphiphilic linear block copolymer |
US7186774B2 (en) * | 2000-12-01 | 2007-03-06 | Clariant Produkte (Deutschland) Gmbh | Silicone-modified comb polymers based on acryloyldimethyltaurine acid (2-acrylamido-2-methyl-1-propanesulfonic acid) |
US7332155B2 (en) * | 2000-12-01 | 2008-02-19 | Clariant Produkte (Deutschland) Gmbh | Surfactant-containing cosmetic, dermatological and pharmaceutical agents |
US20080069793A1 (en) * | 2000-12-01 | 2008-03-20 | Clariant Produkte (Deutschland) Gmbh | Surfactant-free cosmetic, dermatological and pharmaceutical agents |
Family Cites Families (197)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US811910A (en) * | 1903-03-12 | 1906-02-06 | Albert H Emery | Cartridge. |
USRE23514E (en) * | 1930-06-26 | 1952-06-24 | Artificial resins and process of | |
US2528378A (en) | 1947-09-20 | 1950-10-31 | John J Mccabe Jr | Metal salts of substituted quaternary hydroxy cycloimidinic acid metal alcoholates and process for preparation of same |
US2723248A (en) * | 1954-10-01 | 1955-11-08 | Gen Aniline & Film Corp | Film-forming compositions |
FR1222944A (fr) | 1958-04-15 | 1960-06-14 | Hoechst Ag | Polymères greffés et leur procédé de préparation |
FR1400366A (fr) | 1963-05-15 | 1965-05-28 | Oreal | Nouveaux composés pouvant être utilisés en particulier pour le traitement des cheveux |
FR1517743A (fr) | 1966-08-03 | 1968-03-22 | Oreal | Nouveaux copolymères et compositions cosmétiques contenant ces copolymères |
US4129711A (en) | 1965-03-03 | 1978-12-12 | L'oreal | Polymers comprising vinyl esters-crotonic acid |
LU54202A1 (fr) | 1967-07-28 | 1969-03-24 | Oreal | Procédé de préparation de nouveaux copolymères et compositions cosmétiques contenant ces copolymères |
US3925542A (en) | 1965-03-03 | 1975-12-09 | Oreal | Hair lacquer and wave setting compositions containing vinyl acetate-crotonic acid-containing polymers |
NL136457C (ja) | 1967-03-23 | |||
SE375780B (ja) | 1970-01-30 | 1975-04-28 | Gaf Corp | |
US3910862A (en) | 1970-01-30 | 1975-10-07 | Gaf Corp | Copolymers of vinyl pyrrolidone containing quarternary ammonium groups |
FR2079785A5 (en) | 1970-02-12 | 1971-11-12 | Rhodiaceta | Lustrous polyamide-imide based fibres by new process |
LU60676A1 (ja) | 1970-04-07 | 1972-02-10 | ||
US3836537A (en) * | 1970-10-07 | 1974-09-17 | Minnesota Mining & Mfg | Zwitterionic polymer hairsetting compositions and method of using same |
FR2140977A5 (en) | 1971-10-26 | 1973-01-19 | Oreal | Sequenced polymers - from lipophilic and hydrophilic monomers for cosmetic use |
CA981183A (en) | 1972-04-14 | 1976-01-06 | Albert L. Micchelli | Hair fixing compositions |
LU65552A1 (ja) | 1972-06-20 | 1973-12-27 | ||
USRE29871E (en) | 1973-06-08 | 1978-12-26 | L'oreal | Fatty compositions for use in cosmetic makeup compositions and said cosmetic makeup compositions |
LU69760A1 (ja) | 1974-04-01 | 1976-03-17 | ||
US4076912A (en) * | 1974-04-01 | 1978-02-28 | L'oreal | Tetrapolymers comprising (a) unsaturated acids (b) vinyl esters (c) branched allyl or methallyl esters and (d) vinyl ether or vinyl fatty ester or linear allyl or methallyl esters |
LU69759A1 (ja) | 1974-04-01 | 1976-03-17 | ||
US4070533A (en) * | 1974-04-01 | 1978-01-24 | L'oreal | Terpolymer of (a) crotonic acid (b) vinyl acetate and (c) allyl or methallyl esters |
US3915921A (en) * | 1974-07-02 | 1975-10-28 | Goodrich Co B F | Unsaturated carboxylic acid-long chain alkyl ester copolymers and tri-polymers water thickening agents and emulsifiers |
AT364706B (de) | 1976-04-06 | 1981-11-10 | Oreal | Kosmetisches mittel zur behandlung der haare |
LU75371A1 (ja) | 1976-07-12 | 1978-02-08 | ||
NL7703734A (nl) | 1976-04-06 | 1977-10-10 | Oreal | Nieuwe copolymeren van n-alkylacrylamiden of -me- thacrylamiden, de bereidingswijze ervan, als- mede hun gebruik in kosmetika. |
LU75370A1 (ja) | 1976-07-12 | 1978-02-08 | ||
GB1572837A (en) | 1976-05-06 | 1980-08-06 | Berger Jenson & Nicholson Ltd | Coating composition |
FR2357241A2 (fr) | 1976-07-08 | 1978-02-03 | Oreal | Nouvelle composition cosmetique a base de copolymeres anhydrides mono-esterifies ou mono-amidifies, copolymeres nouveaux et leur procede de preparation |
US4128631A (en) | 1977-02-16 | 1978-12-05 | General Mills Chemicals, Inc. | Method of imparting lubricity to keratinous substrates and mucous membranes |
CA1091160A (en) | 1977-06-10 | 1980-12-09 | Paritosh M. Chakrabarti | Hair preparation containing vinyl pyrrolidone copolymer |
US4165367A (en) | 1977-06-10 | 1979-08-21 | Gaf Corporation | Hair preparations containing vinyl pyrrolidone copolymer |
US4223009A (en) | 1977-06-10 | 1980-09-16 | Gaf Corporation | Hair preparation containing vinyl pyrrolidone copolymer |
US4131576A (en) | 1977-12-15 | 1978-12-26 | National Starch And Chemical Corporation | Process for the preparation of graft copolymers of a water soluble monomer and polysaccharide employing a two-phase reaction system |
FR2439798A1 (fr) | 1978-10-27 | 1980-05-23 | Oreal | Nouveaux copolymeres utilisables en cosmetique, notamment dans des laques et lotions de mises en plis |
US4296053A (en) * | 1979-05-24 | 1981-10-20 | Brown Group, Inc. | Method of making foamed plastisol insoles for shoes |
EP0080976B1 (de) | 1981-11-30 | 1986-09-24 | Ciba-Geigy Ag | Gemische aus quaternären, polymeren Ammoniumsalzen auf Acrylbasis, aus quaternären, mono- bis oligomeren Ammoniumsalzen und aus Tensiden, deren Herstellung und Verwendung in kosmetischen Mitteln |
US4459249A (en) * | 1982-01-22 | 1984-07-10 | Inoue Mtp Kabushiki Kaisha | Method of manufacturing a foamed protective and decorative molding for an automobile |
US4524037A (en) * | 1982-08-16 | 1985-06-18 | Michel Marc | Method and apparatus for forming a flexible thermoplastic resin foam article using an RF field |
US4525231A (en) * | 1983-06-08 | 1985-06-25 | Voplex Corporation | Method of making cushioned automotive strap handle |
US4514552A (en) | 1984-08-23 | 1985-04-30 | Desoto, Inc. | Alkali soluble latex thickeners |
US4592426A (en) * | 1984-12-10 | 1986-06-03 | Hughes Tool Company | Upper termination with sliding sleeve seals |
AU612965B2 (en) | 1985-08-12 | 1991-07-25 | Ciba Specialty Chemicals Water Treatments Limited | Polymeric thickeners and their production |
US4693935A (en) | 1986-05-19 | 1987-09-15 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafted copolymer pressure sensitive adhesive composition and sheet materials coated therewith |
JPH078505B2 (ja) * | 1986-07-30 | 1995-02-01 | 株式会社イノアックコ−ポレ−ション | プラスチツク発泡体の製造方法 |
FR2607373B1 (fr) | 1986-11-28 | 1989-02-24 | Oreal | Brosse pour l'application de mascara sur les cils |
JPS63313710A (ja) | 1987-06-16 | 1988-12-21 | Toray Silicone Co Ltd | 洗顔化粧料 |
EP0320218A3 (en) | 1987-12-11 | 1990-04-25 | The Procter & Gamble Company | Low glass transition temperature adhesive copolymers for use in hair styling products |
US5266321A (en) | 1988-03-31 | 1993-11-30 | Kobayashi Kose Co., Ltd. | Oily make-up cosmetic comprising oil base and silicone gel composition |
US5061481A (en) | 1989-03-20 | 1991-10-29 | Kobayashi Kose Co., Ltd. | Cosmetic composition having acryl-silicone graft copolymer |
US5156911A (en) | 1989-05-11 | 1992-10-20 | Landec Labs Inc. | Skin-activated temperature-sensitive adhesive assemblies |
DE69033073T2 (de) | 1989-08-07 | 1999-11-25 | Procter & Gamble | Haarpflege- und Fixierungsmittel |
US4972037A (en) | 1989-08-07 | 1990-11-20 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafted copolymer topical binder composition with novel fluorochemical comonomer and method of coating therewith |
EP0412707B1 (en) | 1989-08-07 | 1994-02-09 | The Procter & Gamble Company | Hair conditioning and styling compositions |
FR2685354B1 (fr) | 1991-12-24 | 1996-03-29 | Rhone Poulenc Fibres | Procede de filage de solutions de polyamides-imides (pai) a base de toluylene ou de metaphenylene diisocyanates et fibres ainsi obtenues. |
US6258916B1 (en) | 1991-12-24 | 2001-07-10 | Rhone-Poulenc Fibres | Process for spinning from solution of polyamide-imides (PAI) based on tolylene or meta-phenylene diisocyanates and fibers thus obtained |
JP3098604B2 (ja) | 1992-02-13 | 2000-10-16 | 株式会社コーセー | 口紅オーバーコート |
JPH07508027A (ja) | 1992-05-12 | 1995-09-07 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | 化粧品及びパーソナルケア製品におけるポリマー |
CZ277394A3 (en) | 1992-05-15 | 1995-08-16 | Procter & Gamble | Adhesives containing grafted polysiloxane polymer and cosmetic mixtures prepared therefrom |
EP0582152B1 (en) | 1992-07-28 | 2003-04-16 | Mitsubishi Chemical Corporation | A hair cosmetic composition |
DE4225045A1 (de) | 1992-07-29 | 1994-02-03 | Basf Ag | Verwendung von wasserlöslichen oder in Wasser dispergierbaren Polyurethanen als Hilfsmittel in kosmetischen und pharmazeutischen Zubereitungen und Polyurethane, die Polymilchsäurepolyole einpolymerisiert enthalten |
JP3393903B2 (ja) | 1992-11-30 | 2003-04-07 | 株式会社資生堂 | メーキャップ化粧料 |
US6663885B1 (en) | 1993-03-15 | 2003-12-16 | A. Natterman & Cie Gmbh | Aqueous liposome system and a method for the preparation of such a liposome system |
JP3214674B2 (ja) | 1993-03-26 | 2001-10-02 | 出光興産株式会社 | 新規スチリル化合物,その製造法およびそれからなる有機エレクトロルミネッセンス素子 |
JPH06279232A (ja) * | 1993-03-30 | 1994-10-04 | Nisshin Chem Ind Co Ltd | アイメークアップ化粧料 |
EP0619111B2 (en) | 1993-04-06 | 2005-09-14 | National Starch and Chemical Investment Holding Corporation | Use of polyurethanes with carboxylate functionality for hair fixative applications |
US5374388A (en) * | 1993-04-22 | 1994-12-20 | Lockheed Corporation | Method of forming contoured repair patches |
US5476901A (en) | 1993-06-24 | 1995-12-19 | The Procter & Gamble Company | Siloxane modified polyolefin copolymers |
US5472798A (en) | 1993-07-16 | 1995-12-05 | Nissan Motor Co., Ltd. | Coloring structure having reflecting and interfering functions |
US6106813A (en) | 1993-08-04 | 2000-08-22 | L'oreal | Polyester polyurethanes, process for preparing them, produced from the said polyester polyurethanes and their use in cosmetic compositions |
FR2708615B1 (fr) | 1993-08-04 | 1995-09-15 | Oreal | Nouveaux polyester-polyuréthannes, leur procédé de préparation, pseudo-latex réalisés à partir desdits polyester-polyuréthannes et leur utilisation dans des compositions cosmétiques. |
KR100295938B1 (ko) | 1993-08-23 | 2001-10-24 | 데이비드 엠 모이어 | 실리콘그라프트된열가소성탄성공중합체및이를함유한모발과피부보호조성물 |
FR2710552B1 (fr) | 1993-09-30 | 1995-12-22 | Lvmh Rech | Utilisation de copolymères-blocs acryliques comme agents mouillants et/ou dispersants des particules solides et dispersions en résultant. |
FR2711059B1 (fr) | 1993-10-15 | 1996-02-02 | Oreal | Composition cosmétique sous forme de vernis à ongles aqueux, coloré ou incolore, contenant en tant que substance filmogène des particules de polyester-polyuréthanne anionique à l'état dispersé. |
CN1079658C (zh) * | 1993-10-18 | 2002-02-27 | 普罗克特和甘保尔公司 | 不发汗唇膏 |
JP3410189B2 (ja) | 1993-12-28 | 2003-05-26 | 株式会社コーセー | アイメークアップ化粧料 |
FR2715306B1 (fr) | 1994-01-25 | 1996-03-15 | Oreal | Composition cosmétique ou dermopharmaceutique sous forme de pâte souple et procédé de préparation de ladite composition. |
US6160054A (en) | 1995-05-08 | 2000-12-12 | Fmc Corporation | Hetero-telechelic polymers and processes for making same |
JPH07309721A (ja) | 1994-05-17 | 1995-11-28 | Kao Corp | 2液型水系美爪料 |
JP3166482B2 (ja) | 1994-06-07 | 2001-05-14 | 日産自動車株式会社 | 反射干渉作用を有する発色構造体 |
FR2724843A1 (fr) | 1994-09-28 | 1996-03-29 | Lvmh Rech | Vernis a ongles contenant des microgels |
JPH08119836A (ja) | 1994-10-21 | 1996-05-14 | Nippon Oil & Fats Co Ltd | ネイル化粧用組成物 |
FR2727609B1 (fr) | 1994-12-06 | 1997-01-10 | Oreal | Ensemble de distribution pour l'application d'un produit de consistance liquide a pateuse |
US5686067A (en) | 1995-01-05 | 1997-11-11 | Isp Investments Inc. | Low voc hair spray compositions |
FR2733683B1 (fr) | 1995-05-05 | 1997-06-06 | Oreal | Composition de vernis a ongles comprenant un polyester reticule |
US5747017A (en) | 1995-05-15 | 1998-05-05 | Lip-Ink International | Lip cosmetic |
CN1070520C (zh) | 1995-06-15 | 2001-09-05 | 雷伊化学有限公司 | 由三嵌段共聚物制备的凝胶 |
FR2736057B1 (fr) | 1995-06-27 | 1997-08-01 | Oreal | Polycondensats sequences polyurethanes et/ou polyurees a greffons silicones, compositions cosmetiques les contenant et utilisations |
TW413692B (en) | 1995-06-30 | 2000-12-01 | Chiba Seifun Kk | Novel silicone derivatives, their production and use |
CZ140498A3 (cs) | 1995-11-07 | 1998-10-14 | The Procter & Gamble Company | Nestíratelné kosmetické prostředky |
US6071503A (en) * | 1995-11-07 | 2000-06-06 | The Procter & Gamble Company | Transfer resistant cosmetic compositions |
US5690918A (en) | 1995-12-19 | 1997-11-25 | Maybelline, Inc. | Solvent-based non-drying lipstick |
FR2743297B1 (fr) | 1996-01-05 | 1998-03-13 | Oreal | Composition cosmetiques a base de polycondensats ionisables multisequences polysiloxane/polyurethane et/ou polyuree en solution et utilisation |
FR2745174B1 (fr) | 1996-02-22 | 1998-04-30 | Oreal | Composition cosmetique de fixation et de brillance |
JP3605938B2 (ja) | 1996-03-29 | 2004-12-22 | 株式会社コーセー | 睫用化粧料 |
US5849318A (en) | 1996-06-26 | 1998-12-15 | Kao Corporation | Oil-based solid cosmetic composition |
US5783657A (en) | 1996-10-18 | 1998-07-21 | Union Camp Corporation | Ester-terminated polyamides of polymerized fatty acids useful in formulating transparent gels in low polarity liquids |
JP3814032B2 (ja) * | 1996-11-01 | 2006-08-23 | 本田技研工業株式会社 | 成形品 |
BR9705926A (pt) | 1996-11-26 | 1999-04-27 | Oreal | Composição tópica utilização e processo para limitar diminuir e/ou impedir a transfêrencia de uma composição |
FR2756176B1 (fr) | 1996-11-26 | 1998-12-18 | Oreal | Composition cosmetique comprenant un compose fluore et presentant un confort ameliore |
FR2758083B1 (fr) | 1997-01-03 | 1999-02-05 | Oreal | Composition cosmetique et/ou dermatologique contenant une dispersion d'un systeme polymerique et utilisation de ce systeme comme tenseur |
CN1224343A (zh) * | 1997-01-20 | 1999-07-28 | 莱雅公司 | 作为角质纤维涂饰剂,含有由可成膜聚合物微粒和非成膜微粒组成的一种成膜混合物的化妆用组合物 |
US6140431A (en) | 1997-02-27 | 2000-10-31 | Rohm And Haas Company | Process for preparing continuously variable-composition copolymers |
US6433068B1 (en) | 1997-03-07 | 2002-08-13 | David S. Morrison | Hydrocarbon gels as suspending and dispersing agents and products |
JP4149522B2 (ja) | 1997-03-26 | 2008-09-10 | エイヴォン プロダクツ,インク. | 耐摩耗性化粧品 |
US6267951B1 (en) * | 1997-03-26 | 2001-07-31 | Avon Products, Inc. | Cosmetic composition for the nails and hair |
US6303105B1 (en) * | 1997-03-26 | 2001-10-16 | Avon Products, Inc. | Cosmetic composition for imparting wear resistance and shine |
US5879670A (en) | 1997-03-31 | 1999-03-09 | Calgon Corporation | Ampholyte polymers for use in personal care products |
US6165457A (en) * | 1997-05-12 | 2000-12-26 | The Procter & Gamble Company | Personal care compositions containing toughened grafted polymers |
DE69839333T2 (de) | 1997-05-30 | 2009-07-09 | Shiseido Co. Ltd. | Zusammensetzung ein copolymer enthaltend das reaktive silyl-gruppen aufweist sowie verfahren zur verwendung |
JPH11124312A (ja) | 1997-10-20 | 1999-05-11 | Shiseido Co Ltd | パック化粧料及びその処理方法 |
US6153206A (en) * | 1997-08-27 | 2000-11-28 | Revlon Consumer Products Corporation | Cosmetic compositions |
JPH11100307A (ja) * | 1997-09-29 | 1999-04-13 | Kao Corp | 被膜形成剤及び化粧料 |
FR2774587B1 (fr) | 1998-02-09 | 2000-03-10 | Oreal | Utilisation d'une microdispersion de cire dans une composition cosmetique ou dermatologique |
FR2775566B1 (fr) | 1998-03-03 | 2000-05-12 | Oreal | Cupule porte raisin et ensemble de conditionnement pour un produit de maquillage la comportant |
FR2776509B1 (fr) | 1998-03-31 | 2001-08-10 | Oreal | Composition topique contenant un ester d'acide ou d'alcool gras ramifie en c24 a c28 |
FR2782003B1 (fr) * | 1998-08-10 | 2000-10-13 | Oreal | Composition de maquillage ou de soin sans transfert a base d'isoparaffines et de cires synthetiques fonctionnalisees |
US6068421A (en) | 1998-08-25 | 2000-05-30 | Rexam Cosmetic Packaging, Inc. | Protective shell for a cosmetic container |
WO2000026285A1 (en) * | 1998-10-29 | 2000-05-11 | Penreco | Gel compositions |
AU1316199A (en) * | 1998-11-12 | 2000-06-05 | Procter & Gamble Company, The | Cosmetic compositions |
US6423306B2 (en) * | 1999-02-26 | 2002-07-23 | L'oreal Sa | Cosmetic compositions containing di-block, tri-block, multi-block and radial block copolymers |
FR2791042B1 (fr) | 1999-03-16 | 2001-05-04 | Oreal | Ensemble articule monopiece |
JP2002539299A (ja) | 1999-03-18 | 2002-11-19 | カリフォルニア インスティチュート オブ テクノロジー | Aba型トリブロック及びジブロックコポリマー、並びにその生成方法 |
FR2792190B1 (fr) | 1999-04-16 | 2001-09-28 | Sophim | Procede de fabrication d'un emollient non gras a base de cires-esters |
FR2792618B1 (fr) | 1999-04-23 | 2001-06-08 | Oreal | Dispositif de conditionnement et d'application d'un produit ayant un organe d'essorage comprenant une fente |
US6254878B1 (en) * | 1999-07-01 | 2001-07-03 | E. I. Du Pont De Nemours And Company | Nail polish compositions containing acrylic polymers |
EP1199956A1 (fr) | 1999-07-09 | 2002-05-02 | Bourjois | Article pour l'application d'une composition topique et son procede de preparation |
FR2796272B1 (fr) | 1999-07-15 | 2003-09-19 | Oreal | Composition sans cire structuree sous forme rigide par un polymere |
FR2796529B1 (fr) * | 1999-07-21 | 2001-09-21 | Oreal | Dispositif de conditionnement et d'application d'un produit sur les cils ou les sourcils |
FR2796528B1 (fr) | 1999-07-21 | 2001-09-21 | Oreal | Dispositif de conditionnement et d'application d'un produit sur les cils ou les sourcils |
DE19939326A1 (de) | 1999-08-19 | 2001-02-22 | Basf Ag | Wässrige kosmetische Zusammensetzung |
FR2798061A1 (fr) | 1999-09-07 | 2001-03-09 | Oreal | Composition cosmetique comprenant des dispersions de particules de polymeres dans une phase grasse liquide |
US7101928B1 (en) | 1999-09-17 | 2006-09-05 | Landec Corporation | Polymeric thickeners for oil-containing compositions |
US6124490A (en) | 1999-10-26 | 2000-09-26 | Mona Industries, Inc. | Zwitterionic siloxane polymers and ionically cross-linked polymers formed therefrom |
US6309629B1 (en) * | 1999-12-14 | 2001-10-30 | Avon Products, Inc. | Wear resistant cosmetic compositions |
FR2803743B1 (fr) | 2000-01-14 | 2005-04-15 | Atofina | Compositions cosmetiques contenant des dispersions aqueuses de polymeres, filmogenes en l'absence de solvant organique |
DE10022247A1 (de) | 2000-05-08 | 2001-11-15 | Basf Ag | Polyurethan und dessen Verwendung zur Modifizierung rheologischer Eigenschaften |
FR2809306B1 (fr) * | 2000-05-23 | 2004-02-06 | Oreal | Utilisation en cosmetique de copolymeres ethyleniques sequences a caractere elastique et compositions les contenant |
JP4768103B2 (ja) * | 2000-06-06 | 2011-09-07 | 日東電工株式会社 | 粘着剤組成物とその粘着シ―ト類およびこれらの製造方法 |
FR2810237B1 (fr) | 2000-06-15 | 2002-07-26 | Oreal | Composition cosmetique filmogene |
US6423304B1 (en) | 2000-06-15 | 2002-07-23 | Cognis Corporation | Dimerized fatty acid based polyamides useful for clear candle and gel applications |
US6410005B1 (en) * | 2000-06-15 | 2002-06-25 | Pmd Holdings Corp. | Branched/block copolymers for treatment of keratinous substrates |
FR2811993B1 (fr) | 2000-07-21 | 2006-08-04 | Oreal | Nouveaux polymeres associatifs cationiques et leur utilisation comme epaississants |
AU9303801A (en) | 2000-10-25 | 2002-05-06 | 3M Innovative Properties Co | Acrylic-based copolymer compositions for cosmetic and personal care |
US20020076390A1 (en) | 2000-10-25 | 2002-06-20 | 3M Innovative Properties Company | Acrylic-based copolymer compositions for cosmetic and personal care |
FR2815847B1 (fr) | 2000-10-27 | 2002-12-13 | Oreal | Composition cosmetique comprenant des fibres et une cire |
DE10059826A1 (de) | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Kosmetische, pharmazeutische und dermatologische Mittel |
DE10059827A1 (de) | 2000-12-01 | 2002-06-20 | Clariant Gmbh | Kosmetische und dermatologische Haarbehandlungsmittel |
DE10059829A1 (de) | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Gepfropfte Kammpolymere auf Basis von Acryloyldimethyltaurinsäure |
DE10059833A1 (de) | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Fluormodifizierte Kammpolymere auf Basis von Acryloyldimethylaurinsäure |
JP2002201244A (ja) | 2000-12-28 | 2002-07-19 | Nippon Shokubai Co Ltd | アクリル系ブロック共重合体、制振材用組成物及びアクリル系ブロック共重合体の製造方法 |
US20020159960A1 (en) | 2001-02-27 | 2002-10-31 | Scancarella Neil D. | Method for improving the properties of transfer resistant lip compositions and related compositions and articles |
FR2823101B1 (fr) | 2001-04-10 | 2004-02-06 | Oreal | Produit de maquillage bi-couche, ses utilisations et kit de maquillage contenant ce produit |
JP4666442B2 (ja) | 2001-07-27 | 2011-04-06 | 株式会社吉野工業所 | 衝撃吸収容器 |
JP3971381B2 (ja) | 2001-08-21 | 2007-09-05 | ロレアル ユーエスエイ, インク. | 仮想ヒンジ |
CN1607934A (zh) * | 2001-09-13 | 2005-04-20 | 三菱化学株式会社 | 化妆品用树脂组合物及其化妆品 |
JP2003286142A (ja) | 2002-03-29 | 2003-10-07 | Mitsubishi Chemicals Corp | 毛髪化粧料用重合体組成物およびそれを用いた毛髪化粧料 |
JP4039829B2 (ja) * | 2001-09-13 | 2008-01-30 | 三菱化学株式会社 | 化粧料用樹脂組成物およびそれを用いた化粧料 |
FR2831430B1 (fr) | 2001-10-26 | 2004-02-06 | Oreal | Composition cosmetique et/ou de soin contenant un polyester-siloxane filmogene, non reticule |
EP1448646A2 (fr) | 2001-11-29 | 2004-08-25 | L'oreal | COPOLYMERES ETHYLENIQUES SEQUENCES ADHESIFS, COMPOSITIONS COSMETIQUES LES CONTENANT, ET UTILISATION DE CES COPOLYMERES EN COSMETIQUE |
FR2834458A1 (fr) | 2002-01-08 | 2003-07-11 | Oreal | Composition cosmetique filmogene, en particulier de vernis a ongles |
US20030185774A1 (en) | 2002-04-02 | 2003-10-02 | Dobbs Suzanne Winegar | Cosmetic coating composition comprising carboxyalkyl cellulose ester |
FR2840205B1 (fr) | 2002-05-31 | 2005-08-05 | Oreal | Shampooings contenant au moins un copolymere sequence amphiphile et au moins un polymere cationique ou amphotere |
FR2840209B1 (fr) * | 2002-05-31 | 2005-09-16 | Oreal | Composition capillaire aqueuse, epaissie par un copolymere lineaire sequence amphiphile |
FR2840206B1 (fr) | 2002-05-31 | 2005-08-05 | Oreal | Shampooing contenant au moins une silicone et au moins un copolymere lineaire sequence amphiphile, anionique ou non- ionique |
FR2842417B1 (fr) | 2002-07-19 | 2005-01-21 | Oreal | Composition cosmetique |
DE60314963T2 (de) | 2002-09-06 | 2008-04-10 | L'oreal | Verfahren zur dekorativen Behandlung der Wimpern mit einem Überzugsmittel, das ein klebriges Wachs enthält |
EP1534218B1 (fr) | 2002-09-06 | 2009-12-16 | L'oreal | Composition de maquillage des fibres keratiniques notamment des fibres keratiniques comme les cils |
US7923002B2 (en) | 2002-09-06 | 2011-04-12 | L'oreal S.A. | Composition for coating keratin fibres comprising a tacky wax |
GB2392910A (en) | 2002-09-10 | 2004-03-17 | Bayer Ag | 2-Oxopyrimidine derivatives and their use as human leukocyte elastase inhibitors |
EP1546113B1 (en) | 2002-09-10 | 2013-05-01 | Bayer Intellectual Property GmbH | Pyrimidinone derivatives as therapeutic agents against acute and chronic inflammatory, ischaemic and remodelling processes |
US20060128578A9 (en) | 2002-09-20 | 2006-06-15 | Nathalie Jager Lezer | Cosmetic composition comprising rigid fibres and at least one compound chosen from film-forming polymers and waxes |
FR2844709A1 (fr) | 2002-09-20 | 2004-03-26 | Oreal | Composition cosmetique comprenant des fibres rigides et une cire |
MXPA03008714A (es) * | 2002-09-26 | 2004-09-10 | Oreal | Polimeros secuenciados y composiciones cosmeticas que comprenden tales polimeros. |
US6905696B2 (en) | 2003-01-06 | 2005-06-14 | Color Access, Inc. | Alignment of enhancers in cosmetic compositions |
FR2860156B1 (fr) | 2003-09-26 | 2007-11-02 | Oreal | Composition cosmetique comprenant un agent tenseur et un polymere ethylenique sequence particulier |
FR2864894A1 (fr) * | 2004-01-13 | 2005-07-15 | Oreal | Composition de revetement des fibres keratiniques ayant un extrait sec eleve comprenant un polymere sequence et des fibres |
FR2864896B1 (fr) | 2004-01-13 | 2006-03-31 | Oreal | Composition de revetement des fibres keratiniques comprenant un polymere sequence et un polymere semi-cristallin |
US20050220731A1 (en) * | 2004-03-23 | 2005-10-06 | Philippe Ilekti | Nail varnish composition comprising at least one polymer and at least one plasticizer |
DE102004014806B4 (de) * | 2004-03-24 | 2006-09-14 | Daimlerchrysler Ag | Rapid-Technologie-Bauteil |
US8728451B2 (en) | 2004-03-25 | 2014-05-20 | L'oreal | Styling composition comprising, in a predominantly aqueous medium, a pseudo-block polymer, processes employing same and uses thereof |
FR2871057B1 (fr) | 2004-06-08 | 2006-07-28 | Oreal | Composition cosmetique contenant un ester et un agent filmogene |
US20050287103A1 (en) | 2004-06-08 | 2005-12-29 | Vanina Filippi | Cosmetic composition comprising at least one ester and at least one film-forming polymer |
FR2876011B1 (fr) | 2004-10-05 | 2006-12-29 | Oreal | Procede de maquillage d'un support et kit pour la mise en oeuvre de ce procede |
JP2006151867A (ja) | 2004-11-29 | 2006-06-15 | Rohto Pharmaceut Co Ltd | 固形リップグロス |
FR2880268B1 (fr) | 2005-01-05 | 2008-10-24 | Oreal | Composition brillante et non transfert comprenant deux polymeres sequences |
US20070134181A1 (en) | 2005-12-08 | 2007-06-14 | L'oreal | Cosmetic composition comprising an ester of dimerdilinoleic acid and of polyol(s) and a silicone surfactant |
FR2904320B1 (fr) * | 2006-07-27 | 2008-09-05 | Oreal | Polymeres sequences, et leur procede de preparation |
FR2904218B1 (fr) | 2006-07-27 | 2012-10-05 | Oreal | Composition cosmetique associant un copolymere, une huile non volatile et une huile brillante. |
CN101951992B (zh) | 2007-12-05 | 2015-06-10 | 欧莱雅公司 | 使用包含硅氧烷树脂和矿物填料的组合物的美容方法 |
ES2645387T3 (es) | 2009-06-01 | 2017-12-05 | L'oréal | Composición cosmética que comprende un polímero secuenciado y un aceite éster no volátil |
GB0922457D0 (en) | 2009-12-23 | 2010-02-03 | Parry Mark | GPS enabled software that appraises surfing performance on a mobile device |
US9192561B2 (en) | 2010-05-14 | 2015-11-24 | L'oreal | Compositions containing hyperbranched polyol and acrylic film former |
US8586013B2 (en) | 2010-12-30 | 2013-11-19 | L'oreal | Comfortable, long-wearing, transfer-resistant colored cosmetic compositions having a non-tacky feel |
US10076487B2 (en) | 2010-12-30 | 2018-09-18 | L'oreal | Comfortable, long-wearing, transfer-resistant colored cosmetic compositions |
-
2003
- 2003-09-26 BR BR0303890A patent/BR0303890A/pt not_active IP Right Cessation
- 2003-09-26 AT AT03776945T patent/ATE488222T1/de not_active IP Right Cessation
- 2003-09-26 EP EP20030292383 patent/EP1421928A3/fr not_active Ceased
- 2003-09-26 AU AU2003290143A patent/AU2003290143A1/en not_active Abandoned
- 2003-09-26 US US10/529,266 patent/US20060134051A1/en not_active Abandoned
- 2003-09-26 EP EP03778378A patent/EP1545443A2/fr not_active Withdrawn
- 2003-09-26 DE DE60335007T patent/DE60335007D1/de not_active Expired - Lifetime
- 2003-09-26 WO PCT/FR2003/002840 patent/WO2004028492A2/fr not_active Application Discontinuation
- 2003-09-26 WO PCT/FR2003/002842 patent/WO2004028488A2/fr active Application Filing
- 2003-09-26 AU AU2003283477A patent/AU2003283477A1/en not_active Abandoned
- 2003-09-26 AU AU2003299071A patent/AU2003299071A1/en not_active Abandoned
- 2003-09-26 AU AU2003299069A patent/AU2003299069A1/en not_active Abandoned
- 2003-09-26 EP EP20030780204 patent/EP1545439B1/fr not_active Expired - Lifetime
- 2003-09-26 AT AT03798230T patent/ATE488221T1/de not_active IP Right Cessation
- 2003-09-26 BR BR0314489A patent/BR0314489A/pt not_active IP Right Cessation
- 2003-09-26 AU AU2003283478A patent/AU2003283478A1/en not_active Abandoned
- 2003-09-26 EP EP20030798230 patent/EP1545436B1/fr not_active Expired - Lifetime
- 2003-09-26 AU AU2003299072A patent/AU2003299072A1/en not_active Abandoned
- 2003-09-26 DE DE60335996T patent/DE60335996D1/de not_active Expired - Lifetime
- 2003-09-26 US US10/529,265 patent/US9017704B2/en active Active
- 2003-09-26 US US10/528,835 patent/US8992903B2/en active Active
- 2003-09-26 US US10/529,218 patent/US20060115444A1/en not_active Abandoned
- 2003-09-26 EP EP03775450A patent/EP1545450A2/fr not_active Withdrawn
- 2003-09-26 WO PCT/FR2003/002841 patent/WO2004028493A2/fr active Application Filing
- 2003-09-26 JP JP2005501935A patent/JP3981132B2/ja not_active Expired - Lifetime
- 2003-09-26 US US10/528,699 patent/US20060134032A1/en not_active Abandoned
- 2003-09-26 WO PCT/FR2003/002843 patent/WO2004028489A2/fr active Application Filing
- 2003-09-26 EP EP20030798228 patent/EP1565148B1/fr not_active Expired - Lifetime
- 2003-09-26 WO PCT/FR2003/002845 patent/WO2004028491A2/fr active Application Filing
- 2003-09-26 US US10/529,267 patent/US20060099164A1/en not_active Abandoned
- 2003-09-26 AU AU2003286204A patent/AU2003286204A1/en not_active Abandoned
- 2003-09-26 DE DE60334709T patent/DE60334709D1/de not_active Expired - Lifetime
- 2003-09-26 AU AU2003285389A patent/AU2003285389A1/en not_active Abandoned
- 2003-09-26 JP JP2003336450A patent/JP2004269497A/ja active Pending
- 2003-09-26 WO PCT/FR2003/002848 patent/WO2004028486A2/fr active Application Filing
- 2003-09-26 DE DE60334921T patent/DE60334921D1/de not_active Expired - Lifetime
- 2003-09-26 JP JP2005501929A patent/JP3981128B2/ja not_active Expired - Fee Related
- 2003-09-26 WO PCT/FR2003/002849 patent/WO2004028487A2/fr active Application Filing
- 2003-09-26 EP EP20030776945 patent/EP1545438B1/fr not_active Expired - Lifetime
- 2003-09-26 EP EP20030782505 patent/EP1545440B1/fr not_active Expired - Lifetime
- 2003-09-26 JP JP2005501930A patent/JP3981129B2/ja not_active Expired - Fee Related
- 2003-09-26 EP EP20030798229 patent/EP1545441B1/fr not_active Expired - Lifetime
- 2003-09-26 AT AT03780204T patent/ATE485809T1/de not_active IP Right Cessation
- 2003-09-26 JP JP2005501928A patent/JP3984268B2/ja not_active Expired - Fee Related
- 2003-09-26 AT AT03798229T patent/ATE497756T1/de not_active IP Right Cessation
- 2003-09-26 JP JP2005501936A patent/JP3981133B2/ja not_active Expired - Lifetime
- 2003-09-26 DE DE60335009T patent/DE60335009D1/de not_active Expired - Lifetime
- 2003-09-26 AT AT03798231T patent/ATE487468T1/de not_active IP Right Cessation
- 2003-09-26 DE DE60335008T patent/DE60335008D1/de not_active Expired - Lifetime
- 2003-09-26 EP EP20030798231 patent/EP1545442B1/fr not_active Expired - Lifetime
- 2003-09-26 US US10/529,318 patent/US7875265B2/en not_active Expired - Fee Related
- 2003-09-26 JP JP2005501934A patent/JP3981131B2/ja not_active Expired - Fee Related
- 2003-09-26 AU AU2003288305A patent/AU2003288305A1/en not_active Abandoned
- 2003-09-26 US US10/529,264 patent/US20060147403A1/en not_active Abandoned
- 2003-09-26 US US10/670,388 patent/US20040120906A1/en not_active Abandoned
- 2003-09-26 DE DE60336577T patent/DE60336577D1/de not_active Expired - Lifetime
- 2003-09-26 US US10/528,698 patent/US20060127334A1/en not_active Abandoned
- 2003-09-26 AT AT03782505T patent/ATE488276T1/de not_active IP Right Cessation
- 2003-09-26 AU AU2003299070A patent/AU2003299070A1/en not_active Abandoned
- 2003-09-26 JP JP2005501932A patent/JP3981130B2/ja not_active Expired - Fee Related
- 2003-09-26 WO PCT/FR2003/002846 patent/WO2004028494A2/fr not_active Application Discontinuation
- 2003-09-26 WO PCT/FR2003/002847 patent/WO2004028485A2/fr active Application Filing
- 2003-09-26 WO PCT/FR2003/002844 patent/WO2004028490A2/fr not_active Application Discontinuation
- 2003-09-26 AT AT03798228T patent/ATE503457T1/de not_active IP Right Cessation
Patent Citations (100)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2781354A (en) * | 1956-03-26 | 1957-02-12 | John J Mccabe Jr | Imidazoline derivatives and process |
US3673160A (en) * | 1970-02-12 | 1972-06-27 | Rhodiaceta | Process for producing brilliant sulfonated polyamide-imide fibers and such fibers so produced |
US4032628A (en) * | 1970-04-07 | 1977-06-28 | Societe Anonyme Dite: L'oreal | Cosmetic emulsion compositions including black polymer emulsifiers |
US3802841A (en) * | 1971-06-14 | 1974-04-09 | Rhone Poulenc Textile | Nitro aromatic hydrocarbon,amino nitro aromatic & nitro aromatic phosphine oxides on aromatic polyamide-imide as light fading inhibitors for dyes thereon |
US3937811A (en) * | 1973-06-08 | 1976-02-10 | Societe Anonyme Dite: L'oreal | Fatty compositions for use in cosmetic makeup compositions and said cosmetic makeup compositions |
US4030512A (en) * | 1974-12-30 | 1977-06-21 | Societe Anonyme Dite: L'oreal | Hair lacquer or setting lotion containing bi- or tri-sequenced copolymer |
US4031307A (en) * | 1976-05-03 | 1977-06-21 | Celanese Corporation | Cationic polygalactomannan compositions |
US4152416A (en) * | 1976-09-17 | 1979-05-01 | Marra Dorothea C | Aerosol antiperspirant compositions delivering astringent salt with low mistiness and dustiness |
US4425326A (en) * | 1980-04-01 | 1984-01-10 | Societe Anonyme Dite : L'oreal | Anhydrous nail varnishes |
US5110582A (en) * | 1981-03-25 | 1992-05-05 | Basf Aktiengesellschaft | Hair-setting preparation |
US4509949A (en) * | 1983-06-13 | 1985-04-09 | The B. F. Goodrich Company | Water thickening agents consisting of copolymers of crosslinked acrylic acids and esters |
US4728571A (en) * | 1985-07-19 | 1988-03-01 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafted copolymer release coating sheets and adhesive tapes |
US5000937A (en) * | 1987-10-28 | 1991-03-19 | L'oreal | Transparent cosmetic composition that reflects infrared radiation and its use for protecting the human epidermis against infrared radiation |
US5219560A (en) * | 1989-03-20 | 1993-06-15 | Kobayashi Kose Co., Ltd. | Cosmetic composition |
US5209924A (en) * | 1989-08-07 | 1993-05-11 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafted copolymer topical binder composition with novel fluorochemical comonomer and method of coating therewith |
US4981903A (en) * | 1989-08-07 | 1991-01-01 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafter copolymer topical binder composition with novel hydrophilic monomers and method of coating therewith |
US4981902A (en) * | 1989-08-07 | 1991-01-01 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafted copolymer non-pressure sensitive topical binder composition and method of coating therewith |
US5519063A (en) * | 1991-07-25 | 1996-05-21 | L'oreal | Oily cosmetic composition containing, as a thickener, an association of two copolymers and optionally containing an amphiphilic rheology corrector |
US5756635A (en) * | 1991-12-24 | 1998-05-26 | Rhone-Poulenc Fibres | Process for spinning from solution of polyamide-imides (PAI) based on tolylene or met-phenylene diisocyanates and fibres thus obtained |
US5725882A (en) * | 1992-05-12 | 1998-03-10 | Minnesota Mining And Manufacturing Company | Vinyl-silicone copolymers in cosmetics and personal care products |
US5391631A (en) * | 1992-06-25 | 1995-02-21 | Basf Aktiengesellschaft | Vinyl polymers produced by a two-stage procedure and their use as surface coating binders |
US5492426A (en) * | 1993-02-22 | 1996-02-20 | L'oreal | Deformable applicator with capillary feed |
US5711940A (en) * | 1993-10-01 | 1998-01-27 | Lvmh Recherche | Stable microdispersions and microgels based on acrylic polymers, method for obtaining them and compositions, particularly cosmetic compositions, containing them |
US5747013A (en) * | 1994-01-17 | 1998-05-05 | L'oreal | Makeup cosmetic composition in the form of a mascara containing at least a wax and a pseudo-latex of cellulose derivatives |
US6059473A (en) * | 1994-07-12 | 2000-05-09 | L'oreal | Applicator for applying a liquid cosmetic product and make-up assembly provided with such an applicator |
US5772347A (en) * | 1994-12-06 | 1998-06-30 | L'oreal | Dispenser for a product with a liquid-to-pasty consistency |
US5879095A (en) * | 1994-12-06 | 1999-03-09 | L'oreal | Dispenser for a product of liquid-to-pasty consistency, equipped with an application tip |
US6881780B2 (en) * | 1995-06-19 | 2005-04-19 | The Lubrizol Corporation | Dispersant-viscosity improvers for lubricating oil compositions |
US6033650A (en) * | 1995-06-26 | 2000-03-07 | Revlon Consumer Products Corporation | Glossy transfer resistant cosmetic compositions |
US6228967B1 (en) * | 1996-05-22 | 2001-05-08 | Mona Industries, Inc. | Organosilicone having a carboxyl functional group thereon |
US5897870A (en) * | 1996-09-20 | 1999-04-27 | Basf Aktiengesellschaft | Aqeous or aqueous-alcoholic hair-cosmetic formulation |
US5736125A (en) * | 1997-01-10 | 1998-04-07 | National Starch And Chemical Investment Holding Corporation | Compositions containing copolymers as a thickening agent |
US6692173B2 (en) * | 1997-04-15 | 2004-02-17 | L'oreal | Unit for packaging and applying a liquid product |
US6386781B1 (en) * | 1997-04-15 | 2002-05-14 | L'oreal | Unit for packaging and applying a liquid product |
US20020054783A1 (en) * | 1997-04-15 | 2002-05-09 | L'oreal | Unit for packaging and applying a liquid product |
US20020064539A1 (en) * | 1998-02-11 | 2002-05-30 | L' Oreal | Cosmetic or dermatological composition contacting at least one natural or recombinant spider silk or an analog |
US6238679B1 (en) * | 1998-03-09 | 2001-05-29 | L'oreal S.A. | Film-forming composition comprising a polyurethane in aqueous dispersion and a plasticizer |
US6180123B1 (en) * | 1998-04-21 | 2001-01-30 | L'oreal | Composition for topical application comprising an olefin copolymer of controlled crystallization and use of such a copolymer in the manufacture of compositions for topical application |
US6225390B1 (en) * | 1998-05-08 | 2001-05-01 | Shell Oil Company | Oil gel formulations containing polystyrene-polydimethylsiloxane or polyethylene-polydimethylsiloxane block copolymers dissolved in siloxane monomers |
US6228946B1 (en) * | 1998-07-03 | 2001-05-08 | Kuraray Co., Ltd. | Block copolymer and polymer composition comprising the same |
US20020055562A1 (en) * | 1998-10-29 | 2002-05-09 | Butuc S. Gina | Gel compositions |
US20020035237A1 (en) * | 1999-01-04 | 2002-03-21 | Lawson Nelson E. | Structured composition containing tertiary amide-terminated polyamide for personal care products |
US6531535B2 (en) * | 1999-01-29 | 2003-03-11 | Bayer Aktigensellschaft | Aqueous copolymers, a process for their preparation and their use in coating compositions |
US6692733B1 (en) * | 1999-04-06 | 2004-02-17 | L'oreal | Composition comprising polymers having a star structure, the polymers, and their use |
US6552146B1 (en) * | 1999-04-06 | 2003-04-22 | L'oreal S.A. | Composition comprising polymers having a star structure, the polymers, and their use |
US6197883B1 (en) * | 1999-06-03 | 2001-03-06 | Ppg Industries Ohio, Inc. | Thermosetting coating compositions containing flow modifiers prepared by controlled radical polymerization |
US6342237B1 (en) * | 1999-07-08 | 2002-01-29 | L'oréal | Make-up composition comprising fibers |
US20020020424A1 (en) * | 1999-07-21 | 2002-02-21 | Gueret Jean-Louis H. | Applicator system and method |
US6866046B2 (en) * | 1999-07-21 | 2005-03-15 | L'oréal | Applicator system and method |
US6174968B1 (en) * | 1999-08-24 | 2001-01-16 | Shell Oil Company | Oil gel formulations containing polysiloxane block copolymers dissolved in hydrogenated silicone oils |
EP1112735A1 (en) * | 1999-12-20 | 2001-07-04 | Avon Products, Inc. | Cosmetic composition applied to the eyelashes |
US6843611B2 (en) * | 2000-03-16 | 2005-01-18 | L'oreal | Device for packaging and applying a cosmetic or care product |
US20020015611A1 (en) * | 2000-03-16 | 2002-02-07 | Gilles Blondeel | Device for packaging and applying a cosmetic or care product |
US20050002724A1 (en) * | 2000-03-16 | 2005-01-06 | L'oreal | Device for packaging and applying a cosmetic or care product |
US20020018759A1 (en) * | 2000-05-04 | 2002-02-14 | Pagano Frank Charles | Nail enamel compositions, related methods, and a two component kit for painting the nails |
US20040014872A1 (en) * | 2000-06-16 | 2004-01-22 | Raether Roman Benedikt | Bonding agent composition containing solid matter, with radically polymerised block copolymers |
US20040052745A1 (en) * | 2000-07-13 | 2004-03-18 | Pascale Bernard | Long-lasting make-up kit and method |
US20040052752A1 (en) * | 2000-07-18 | 2004-03-18 | Henri Samain | Cosmetic composition containing a block copolymer consisting of blocks with different refractive indices |
US20030021815A9 (en) * | 2000-09-28 | 2003-01-30 | Jean Mondet | Cosmetic compositions comprising at least one continuous liquid fatty phase structured with polyurethanes, polyurethaneureas, and polyureas |
US6518364B2 (en) * | 2000-09-28 | 2003-02-11 | Symyx Technologies, Inc. | Emulsion living-type free radical polymerization, methods and products of same |
US20020061319A1 (en) * | 2000-09-29 | 2002-05-23 | Pascale Bernard | Film-forming cosmetic composition |
US20040096411A1 (en) * | 2000-10-03 | 2004-05-20 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Cosmetic and personal care compositions |
US6685925B2 (en) * | 2000-10-03 | 2004-02-03 | Jean M. J. Frechet | Cosmetic and personal care compositions |
US6890522B2 (en) * | 2000-10-03 | 2005-05-10 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Cosmetic and personal care compositions |
US20030017182A1 (en) * | 2000-11-10 | 2003-01-23 | Florence Tournilhac | Cosmetic composition structured by a thermotropic liquid crystal polymer |
US7053146B2 (en) * | 2000-12-01 | 2006-05-30 | Clariant Gmbh | Compositions containing copolymers based on acryloyldimethyl aminoethylsulfonic acid and synergistic additives |
US20040096409A1 (en) * | 2000-12-01 | 2004-05-20 | Matthias Loeffler | Deodorants and anti-perspirants |
US20080107617A1 (en) * | 2000-12-01 | 2008-05-08 | Clariant Produkte (Deutschland) Gmbh | Surfactant-containing cosmetic, dermatological and pharmaceutical agents |
US6891011B2 (en) * | 2000-12-01 | 2005-05-10 | Clariant Gmbh | Comb-shaped copolymers based on acryloyldimethyltaurine acid |
US20040097657A1 (en) * | 2000-12-01 | 2004-05-20 | Roman Morschhaeuser | Acryoyldimethyltaurine acid-based grafted copolymers |
US20080069793A1 (en) * | 2000-12-01 | 2008-03-20 | Clariant Produkte (Deutschland) Gmbh | Surfactant-free cosmetic, dermatological and pharmaceutical agents |
US7332155B2 (en) * | 2000-12-01 | 2008-02-19 | Clariant Produkte (Deutschland) Gmbh | Surfactant-containing cosmetic, dermatological and pharmaceutical agents |
US20040091444A1 (en) * | 2000-12-01 | 2004-05-13 | Loeffler Matthias | Decorative cosmetic and dermatological products |
US7186405B2 (en) * | 2000-12-01 | 2007-03-06 | Clariant Produkte (Deutschland) Gmbh | Deodorants and anti-perspirants |
US7186774B2 (en) * | 2000-12-01 | 2007-03-06 | Clariant Produkte (Deutschland) Gmbh | Silicone-modified comb polymers based on acryloyldimethyltaurine acid (2-acrylamido-2-methyl-1-propanesulfonic acid) |
US7025973B2 (en) * | 2000-12-01 | 2006-04-11 | Clariant Gmbh | Acid cosmetic, dermatological and pharmaceutical agents |
US20050032998A1 (en) * | 2000-12-01 | 2005-02-10 | Roman Morschhaeuser | Cationically modified comb polymers based on acryloyldimethyl taurine acid |
US7022791B2 (en) * | 2000-12-01 | 2006-04-04 | Clarient Gmbh | Cosmetic, pharmaceutical and dermatological products containing an electrolyte |
US20050089536A1 (en) * | 2000-12-01 | 2005-04-28 | Matthias Loffler | Use of comb copolymers based on acryloyldimethyltaurine acid in cosmetic, pharmaceutical and dermatological products |
US20040093676A1 (en) * | 2001-04-03 | 2004-05-20 | Laurent Vidal | Novel dyeing composition for dyeing keratinous fibres comprising a particular dicationic monoazo dye |
US20030039621A1 (en) * | 2001-04-10 | 2003-02-27 | L'oreal | Two-coat make-up product, its use and a kit containing the make-up product |
US20030017124A1 (en) * | 2001-04-10 | 2003-01-23 | L'oreal | Two-coat make-up product containing a goniochromatic pigment and monochrome pigment, and make-up kit containing this product |
US20080014232A1 (en) * | 2001-04-10 | 2008-01-17 | L'oreal | Two-coat make-up product, its use and a kit containing the make-up product |
US20030003154A1 (en) * | 2001-05-04 | 2003-01-02 | L'oreal | Composition comprising at least one first semi-crystalline polymer and at least one second film-forming polymer |
US7358303B2 (en) * | 2001-05-04 | 2008-04-15 | L'Oréal, S.A. | Composition comprising at least one first semi-crystalline polymer and at least one second film-forming polymer |
US20030059392A1 (en) * | 2001-07-18 | 2003-03-27 | L'oreal | Composition for topical use containing a diblock polymer |
US20030024074A1 (en) * | 2001-08-01 | 2003-02-06 | Hartman Paul H. | Biconcave connector for tubular assemblies and tool handles |
US20070003507A1 (en) * | 2001-11-29 | 2007-01-04 | L'oreal | Adhesive block ethylenic copolymers, cosmetic compositions containing them and cosmetic use of these copolymers |
US20050020779A1 (en) * | 2001-11-29 | 2005-01-27 | Nathalie Mougin | Block ethylenic copolymers cosmetic compositions containing them and cosmetic use of these copolymers |
US20070003506A1 (en) * | 2001-11-29 | 2007-01-04 | L'oreal | Adhesive block ethylenic copolymers, cosmetic compositions containing them and cosmetic use of these copolymers |
US20040039101A1 (en) * | 2002-05-31 | 2004-02-26 | Claude Dubief | Washing compositions comprising at least one amphiphilic block copolymer and at least one cationic or amphoteric polymer |
US7176170B2 (en) * | 2002-05-31 | 2007-02-13 | L'oreal | Shampoo comprising at least one silicone and at least one anionic or nonionic, amphiphilic linear block copolymer |
US20040009136A1 (en) * | 2002-05-31 | 2004-01-15 | L'oreal | Aqueous hair treatment compositions, thickened with an amphiphilic linear block copolymer |
US20040077788A1 (en) * | 2002-07-19 | 2004-04-22 | Cid Centro De Investigacion Y Desarrollo Tecnologico, S.A. De. C.V. | Block copolymers containing functional groups |
US20040013625A1 (en) * | 2002-07-22 | 2004-01-22 | Mohamed Kanji | Compositions comprising at least one heteropolymer and fibers, and methods of using the same |
US20060099231A1 (en) * | 2002-09-06 | 2006-05-11 | De La Poterie Valerie | Make-up composition for keratin fibres such as eyelashes |
US20060099164A1 (en) * | 2002-09-26 | 2006-05-11 | De La Poterie Valerie | Composition for coating keratin fibres, comprising a high dry extract that contains a sequenched polymer |
US20060093568A1 (en) * | 2002-09-26 | 2006-05-04 | Xavier Blin | Composition comprising a block polymer and a film-forming agent |
US20050106197A1 (en) * | 2003-09-26 | 2005-05-19 | Xavier Blin | Cosmetic composition comprising a block polymer and a non-volatile silicone oil |
US20050095213A1 (en) * | 2003-09-26 | 2005-05-05 | Xavier Blin | Two-coat cosmetic product, cosmetic process of using thereof and makeup kit containing this product |
Cited By (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8992903B2 (en) | 2002-09-26 | 2015-03-31 | L'oreal | Composition comprising at least one block polymer and at least one gelling agent |
US20080014235A1 (en) * | 2002-09-26 | 2008-01-17 | L'oreal | Novel Block Polymers and Cosmetic Compositions and Processes Comprising Them |
US20060134032A1 (en) * | 2002-09-26 | 2006-06-22 | Philippe Ilekti | Nail varnish composition comprising a sequenced polymer |
US20060147402A1 (en) * | 2002-09-26 | 2006-07-06 | Xavier Blin | Composition comprising a sequenced polymer and a gelling agent |
US9017704B2 (en) | 2002-09-26 | 2015-04-28 | L'oreal | Composition comprising a block polymer and a film-forming agent |
US20040120906A1 (en) * | 2002-09-26 | 2004-06-24 | Beatrice Toumi | Nail varnish composition comprising a block polymer |
US20080014234A1 (en) * | 2002-09-26 | 2008-01-17 | L'oreal | Novel Block Polymers and Cosmetic Compositions and Processes Comprising Them |
US7915347B2 (en) | 2002-09-26 | 2011-03-29 | L'oreal S.A. | Block polymers and cosmetic compositions and processes comprising them |
US20080014158A1 (en) * | 2002-09-26 | 2008-01-17 | L'oreal | Novel Block Polymers and Cosmetic Compositions and Processes Comprising Them |
US7932324B2 (en) | 2002-09-26 | 2011-04-26 | L'oreal | Block polymers and cosmetic compositions and processes comprising them |
US7875265B2 (en) * | 2002-09-26 | 2011-01-25 | L'oreal | Cosmetic composition comprising a sequenced polymer and a plasticizer |
US7803877B2 (en) | 2002-09-26 | 2010-09-28 | L'oreal S.A. | Block polymers and cosmetic compositions and processes comprising them |
US20050095213A1 (en) * | 2003-09-26 | 2005-05-05 | Xavier Blin | Two-coat cosmetic product, cosmetic process of using thereof and makeup kit containing this product |
US8119110B2 (en) | 2003-09-26 | 2012-02-21 | L'oreal S.A. | Cosmetic composition comprising a block polymer and a non-volatile silicone oil |
US8728451B2 (en) | 2004-03-25 | 2014-05-20 | L'oreal | Styling composition comprising, in a predominantly aqueous medium, a pseudo-block polymer, processes employing same and uses thereof |
US20070196306A1 (en) * | 2005-07-22 | 2007-08-23 | Nathalie Jager Lezer | Process for coating eyelashes |
US8460645B2 (en) | 2005-07-22 | 2013-06-11 | L'oreal S.A. | Process for coating eyelashes |
US20070148114A1 (en) * | 2005-11-09 | 2007-06-28 | Nathalie Jager Lezer | Composition in the form of a foam for coating the eyelashes |
US8753617B2 (en) | 2005-11-09 | 2014-06-17 | L'oréal | Composition in the form of a foam for coating the eyelashes |
US20070207096A1 (en) * | 2006-02-13 | 2007-09-06 | Virginie Puisset | Nail varnish having a gelled texture |
US8710152B2 (en) | 2006-07-27 | 2014-04-29 | L'oreal | Block polymers and their process of preparation |
US20080145325A1 (en) * | 2006-09-13 | 2008-06-19 | Lizabeth-Anne Coffey-Dawe | Nail varnish comprising at least one resin |
US20100166685A1 (en) * | 2006-11-16 | 2010-07-01 | L'oreal S.A. | Novel block polymers, compositions comprising them, and treatment methods |
US20080175804A1 (en) * | 2006-11-16 | 2008-07-24 | Celine Farcet | Novel block polymers, compositions comprising them, and treatment methods |
US20080260665A1 (en) * | 2007-01-08 | 2008-10-23 | Laurence Guerchet | Nail varnish comprising at least one polycondensate and at least one polyoxyalkylene copolymer |
US9895561B2 (en) | 2009-06-01 | 2018-02-20 | L'oreal | Composition containing a block polymer and a nonvolatile ester oil |
US20110020263A1 (en) * | 2009-06-01 | 2011-01-27 | L'oreal | Composition containing a block polymer and a nonvolatile ester oil |
US9125468B2 (en) | 2010-03-29 | 2015-09-08 | L'oreal | Device for the application of fibers to human keratinous fibers |
US10532021B2 (en) | 2011-12-20 | 2020-01-14 | L'oreal | Composition comprising a specific acrylic polymer and a silicone copolymer, and method for treating keratin fibres using same |
US10744080B2 (en) | 2011-12-20 | 2020-08-18 | L'oreal | Method for the application of a pigment dyeing composition based on specific acrylic polymer and on silicone copolymer, and appropriate device |
US11376208B2 (en) | 2011-12-20 | 2022-07-05 | L'oreal | Pigment dyeing composition based on a particular acrylic polymer and silicone copolymer |
US11576852B2 (en) | 2012-06-29 | 2023-02-14 | L'oreal | Two coat process for dyeing keratin fibres |
US20180271766A1 (en) * | 2014-10-31 | 2018-09-27 | L'oreal | Acrylic polymer comprising alkoxysilane groups and cosmetic uses thereof |
US11771629B2 (en) | 2016-06-23 | 2023-10-03 | L'oreal | Process for the elongation and/or densification of fibers |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20060134051A1 (en) | Glossy non-transfer composition comprising a sequenced polymer | |
US8119110B2 (en) | Cosmetic composition comprising a block polymer and a non-volatile silicone oil | |
US7803877B2 (en) | Block polymers and cosmetic compositions and processes comprising them | |
US10117824B2 (en) | Gradient copolymer, composition including same and cosmetic make-up or care method | |
US7541414B2 (en) | Hyperbranched copolymer comprising monomers of choice, a composition, and a cosmetic method | |
US20080025934A1 (en) | Cosmetic composition combining a copolymer, a non-volatile oil and a glossy oil | |
US20050276779A1 (en) | Two coat cosmetic product, its method of use and make-up kit comprising this product | |
JP2006509809A (ja) | ポリマーを含む化粧用組成物 | |
US20060127339A1 (en) | Two-coat makeup product with improved staying power, uses thereof and makeup kit comprising this product | |
US20100178257A1 (en) | Block polymer, cosmetic composition comprising it and cosmetic treatment process | |
US20100166685A1 (en) | Novel block polymers, compositions comprising them, and treatment methods | |
US20060008431A1 (en) | Copolymer functionalized with an iodine atom, compositions comprising the copolymer and treatment processes | |
US20080181859A1 (en) | Novel block (Co)polymers, compositions containing them, method of treatment and method of preparation | |
JP2006002154A (ja) | ヨウ素原子で官能化されたコポリマー、それを含む組成物およびトリートメント法 | |
US20100021408A1 (en) | Block polymer, cosmetic composition comprising it and cosmetic treatment process | |
US20050288410A1 (en) | Copolymer functionalized with an iodine atom, composition comprising it and treatment process |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: L'OREAL S.A., FRANCE Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:BLIN, XAVIER;FERRARI, VERONIQUE;REEL/FRAME:017715/0007 Effective date: 20050512 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |