US3836537A - Zwitterionic polymer hairsetting compositions and method of using same - Google Patents

Zwitterionic polymer hairsetting compositions and method of using same Download PDF

Info

Publication number
US3836537A
US3836537A US30083272A US3836537A US 3836537 A US3836537 A US 3836537A US 30083272 A US30083272 A US 30083272A US 3836537 A US3836537 A US 3836537A
Authority
US
Grant status
Grant
Patent type
Prior art keywords
hair
zwitterionic
polymer
hairsetting
monomers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
Inventor
F Boerwinkle
D Waxberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
3M Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Grant date

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52Amides or imides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILET PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/06Preparations for styling the hair, e.g. by temporary shaping or colouring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • C08F20/34Esters containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52Amides or imides
    • C08F20/54Amides
    • C08F20/60Amides containing nitrogen in addition to the carbonamido nitrogen
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54Polymers characterized by specific structures/properties
    • A61K2800/542Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5428Polymers characterized by specific structures/properties characterized by the charge amphoteric or zwitterionic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S424/00Drug, bio-affecting and body treating compositions
    • Y10S424/02Resin hair settings

Abstract

HAIRSETTING IS ACHIEVED WITH A SOLUTION CONTAINING A ZWITTERIONIC POLYMER HAVING CARBOXYLATE AND AMMONIUM FUNCTIONALITY.

Description

United States Patent "Office 3,836,537 Patented Sept. 17, 1974 3,836,537 ZWITTERIONIC POLYMER HAIRSE'I'IING COM- POSITIONS AND METHOD OF USING SAME Fred P. Boerwinkle, Village of Lakeland, and Donald L. Waxberg, Village of Roseville, Minn. (both 3M Center, St. Paul, Minn. 55101) No Drawing. Continuation-impart of abandoned application Ser. No. 78,968, Oct. 7, 1970. This application Oct. 25, 1972, Ser. No. 300,832

Int. Cl. C08f 29/46, 37/00, 37/18 U.S. 'Cl. 26029.6 HN 22 Claims ABSTRACT OF THE DISCLOSURE Hairsetting is achieved with a solution containing a zwitterionic polymer having carboxylate and ammonium functionality.

CROSS-REFERENCE TO RELATED APPLICATION This is a continuation-in-part of application Ser. No. 78,968, filed Oct. 7, 1970 and now abandoned.

BACKGROUND OF THE INVENTION Almost since the beginning of time women have employed compositions of some sort to make straight hair curly and to hold it in position after doing so. Perhaps the earliest material employed was plain water which was used to soften hair, but hair which has been moistened, curled, and dried in curled condition retains its shape for only a short time. More recently, hair has been styled or arranged with solutions containing lacquers such as natural gums, resins, or synthetic plastics (e.g., polyvinyl pyrrolidone) which are deposited on the fibers of the hair to hold them in place.

Such prior art lacquers are known for their characteristics of making hair dulll, stiff, unnatural, sticky, and hard to clean. Many of them tend to flake unattractively. Some cause the hair to accumulate static electricity, making it difficult to comb or brush. Others, e.g., polyvinyl pyrrolidone, absorb moisture from the air and become sticky on damp days and hard and brittle in extremely dry weather. Still others are adversely affected by water vapor, permitting treated hair to lose its curl in moist weather.

SUMMARY The present invention provides a hairsetting composition which overcomes the objections inherent in the products of the prior art. In the practice of the invention, hair is imparted with a temporary setting which has excellent anti-static behavior and curl retention, gOOd comb-out and sheen, and which is easily removed by shampooing. Additionally, the excellent curl-retention is maintained at high relative humidity. The treated hair is flexible, readily arranged, pleasant smelling, clean, attractive, and glossy, retaining these characteristics for several days, regardless of the relative humidity of the air.

It has been found that zwitterionic polymers, when applied to hair fibers, provide the above-described desirable properties, maintaining very high curl-retention at high relative humidities.

In the context of the invention, the expressions zwitterionic polymer and zwitterionic monomer refer only to internally neutralized polymers and monomers con taining an acidic carboxylate group and a basic ammonium group.

DETAILED DESCRIPTION OF THE INVENTION In accordance with the invention, hair is treated with an aqueous solution containing from about 0.25 to about 10% by weight of zwitterionic polymer. Any one of a variety of such polymers will be useful in the practice of the invention but two particular types which have been found to be especially useful will be described below.

The aqueous solution of a zwitterionic polymer, to be useful for treating hair, should be sufficiently viscous to remain on hair fibers when applied thereto, and sufficiently thin to effectively wet the hair fibers. It has been found that useful zwitterionic polymers have a viscosity of about to 100,000 cps., preferably about 1,000 to about 25,000 cps., when tested at 24% solids in water with a Brookfield viscometer, using the appropriate spindle and speed therefor.

Aqueous solutions of the zwitterionic polymer that have been found to be most effective for setting hair have from about 0.25 to about 10% by weight, preferably about 1 to about 5%, of the zwitterionic polymer. Polymers having viscosities higher than those mentioned above when measured as 24% solids aqueous solutions or hairsetting solutions having excess of 10% by Weight of zwitterionic polymer provide a stiffer curl which is more difficult to comb-out and cause the hair fibers to feel undesirably slippery during application.

The hairsetting solutions of the invention may contain an alcohol as a co-solvent with water, particularly when the zwitterionic polymer is a copolymer containing a water-insoluble monomer, as will be hereinafter described. The solutions may also contain other additives that are normally found in conventional hairsetting solutions such as perfumes, coloring dyes and the like.

It has been also discovered that the addition of a small amount of zwitterionic polymer to prior art hairsetting solutions provides improved curl-retention and anti-static behavior. The addition of as little as 0.25% by weight of zwitterionic polymer to such prior art hairsetting compositions has been found to be effective for such purposes.

PRESENTLY PREFERRED ZW'ITTERIONIC POLYMERS (A) Homopolymers and copolymers may be prepared by polymerizing zwitterionic monomers having the general formula wherein R represents a polymerizable unsaturated group, which permits homopolymerization of the monomer or copolymerization with other polymerizable monomers. Such polymerizable unsaturated groups are preferably selected from the group consisting of acrylate, methacrylate, acrylamide, and methacrylamide. Subscripts x and y represent an integer from 1 to 3 inclusive to provide methylene, ethylene, or propylene groups in the polymer backbone, groups larger than 3 carbon atoms reducing the water solubility of the resultant polymer such that it may not be useful as a hair-setting composition. R and R represent hydrogen, methyl, ethyl or propyl radicals, larger alkyl radicals reducing the water solubility of the polymer. R and R represent a hydrogen atom or an alkyl radical, with the total sum of the carbon atoms in R and R not exceeding six, larger alkyl radicals also reducing the water solubility of the polymer.

Typical zwitterionic monomers having the general formula shown above and useful in preparing homopolymers or copolymers useful in the hairsetting compositions of the invention, include, beta-methacryloxyethyl beta-dimethyl amino propionate betaine. Zwitterionic monomers of this type may be prepared by methods known to the art, e.g., U.S. Pats. 2,744,130, and 2,777,872.

The aforementioned zwitterionic monomers may either be homopolymerized or copolymerized with other polymerizable monomers to provide the zwitterionic polymers useful for setting hair, the resultant polymer retaining the above-described desirable properties even when relatively large proportions of non-zwitterionic comonomer are used. Generally, the zwitterionic moiety of the desired copolymer should comprise at least, on a molar basis, about 10%, preferably at least about 20%, of the copolymer to retain the above-described properties. Typical water-soluble non-zwitterionic monomers suitable for copolymerization include vinyl pyrrolidone, dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate, diethylaminoethyl acrylate, and diethylaminoethyl methacrylate.

Other non-zwitterionic monomers which are not watersoluble, such as alkyl acrylates or methacrylates, e.g., methyl acrylate, and acrylamides, methacrylamides, or vinyl acetate, may also be copolymerized with the previously mentioned zwitterionic monomers to provide copolymers useful for setting hair. However, substantially less of this type of non-zwitterionic monomer is utilized so as to maintain the requisite solubility.

(B) Zwitterionic polymers containing carboxylate and ammonium functionality are also prepared by copolymerizing a monomer having basic ammonium functionality with monomer having acid carboxylate functionality. The acidic monomers are preferably substituted vinyl compounds of the general formula CR H=CR OO H, wherein R is a hydrogen atom or a CO H group and R is a hydrogen or chlorine atom or a methyl group; exemplary compounds of this type include acrylic acid, methacrylic acid, maleic acid and a-chloroacrylic acid. The basic monomers are preferably substituted vinyl compounds of the formula CH =CR COQ wherein R is a hydrogen atom or a methyl group and Q is an organic radical containing a basic nitrogen-containing group, such compounds including dialkyl aminoalkyl methacrylates (e.g., dimethylaminoethyl methacrylate), dialkyl aminoalkyl acrylates, N(1,1-dirnethyl-3-dimethyl-amino propyl) acrylamide methacrylamino pyridine, and the The zwitterionic copolymer produced from acidic and basic monomers preferably will be formed of monomers of acrylic acid or methacrylic acid polymerized with monomers of dimethylaminoethyl methacrylate or diethylaminoethyl acrylate.

For most purposes the mole ratio of basic monomer to the acidic monomer of the aforementioned zwitterionic copolymer ranges from 0.821 to 2.5 :1, preferably 1:1 to 15:1. In the case of difunctional monomers, suitable adjustment should be made in mole ratios to maintain a similar acid-base balance. For monomers with difunc tional acidity, the ratio of basic monomer to acidic monomer will be 1.7 :1 to :1, preferably 2:1 to 3:1. The resultant copolymer is preferably substantially completely neutralized, although partially neutralized copolymers are also useful for setting hair.

The neutralizing agents are acidic and basic compounds which will not, once having served their function, produce substances which will deleteriously affect hair or the copolymers ability to set hair. Acidic neutralizing agents include hydrochloric acid, acetic acid and the like. Basic neutralizing agents include ammonia, amines and the like.

Zwitterionic copolymers, besides being formed of acidic and basic monomers, may include additional monomers which do not contain acidic or basic groups, which may be added to reduce cost. Such monomers typically include lower alkyl acrylates or methacrylates, e.g., methyl acrylate, and acrylamides or methacrylamides. These neutral monomers, which can be water-soluble or water-insoluble, will be contained in the copolymer in proportions which do not adversely affect the solubility of the resultant copolymer. Typically, water-insoluble monomers will be a minor proportion of the resultant copolymer.

The effectiveness of zwitterionic polymers for use in hairsetting compositions is readily determined by means 4 of a curl retention test which also provides information with respect to anti-static behavior, comb-out, and sheen. In conducting the test, a predetermined weight of human hair (approximately 6 inch length) is shampooed, rinsed with water, saturated with the respective hairsetting composition being tested, and combed four times. Each hair swatch is then wound on a hair roller, secured with bobby pins and dried at 140 F. for approximately two and onehalf hours. Immediately following drying, the hair swatches are unwound from the rollers, brushed five times, and are then ready for determination of curl retention.

Ten hair swatches are prepared for each hairsetting composition to be tested. The initial hair length is recorded and the test swatches placed in a high relative humidity test environment (about relative humidity at about 75 F. for one hour). The change in curl length is observed immediately after the period of time in the humidity chamber, the percent of curl retention being calculated by the formula t L X where L is the length of the hair fully extended, L is the length of the hair when curled before exposure to the humidity environment, and L is the length of the hair after exposure to the high humidity environment. Because factors such as humidity in the drying oven, etc. cause results to be somewhat different for tests conducted on different days, all compositions are compared relative to a control sample evaluated at the same time. The percent curl retention for each hairsetting composition is then divided by the percent curl retention of the control and multiplied by 100 to obtain the relative curl retention. The composition of Example 1 was used as a control in each instance.

The following examples, in which all parts are by weight unless otherwise indicated, illustrate preparation of the hairsetting compositions of the invention, without limiting the scope thereof.

Example 1 As a control, polydimethylaminoethyl methacrylate fully quaternized with methyl bromide was prepared and evaluated as a hairsetting lotion at 3% solids by weight in water, as disclosed in British Pat. 1,161,642. When tested by the previously described method, a relative curl retention of 100 was obtained.

Example 2 This example illustrates preparation of a hairsetting composition utilizing a zwitterionic polymer comprising an 80:20 mole ratio copolymer of dimethylaminoethyl methacryloxyethyl, beta-dimethyl aminopropionate betaine.

A polymerization flask fitted with a stirrer, nitrogen inlet, thermocouple, and addition funnel, was charged with 2842 gms. of water, 315.2 gms. of a 37% hydrochloric acid water solution, 618 gms. of dimethylaminoethyl methacrylate, and 225.2 gms. of beta-dimethyl, beta-methacryloxyethylamino propionate. betaine. The solution, with stirring, was evacuated to boiling for about 30 minutes, the flask purged with nitrogen, and the solution heated to 600 C. for 16 hours, during which time ml. of water containing 40 gms. of K S O was added in four equal portions about 30 minutes apart. The resultant polymer solution had a Brookfield viscosity of 16,600 cps. at 25 C. (#4 spindle at 30 r.p.rn.).

The polymer, at 3% solids in water, was evaluated as a hairsetting resin by the previously described test method, a relative curl retention of 148, moderate comb-out, good sheen, and low static retention being obtained.

Examples 3-12 The following polymers were prepared in a manner y are integers from 1 to 3 inclusive, and R and R represent a hydrogen atom or an alkyl radical with the total sum of the carbon atoms in R and R not exceeding six, and

EXAMPLES 3l2 Composition Brookfield viscosity (cps.) and conditions Relative Temp NaZSZOa, curl re- Example Monomers Mole ratio percent 24% Spindle R.p.m. 3% Spindle Rpm. tention o u 4 DMAEMA-betaine 1 Homopolymer 60 0.5 9 21,500 4 154 DEAEA IMAA 3 50:50 60 1.0 .000 4 125 X fi Dimethyl fi-methacryloxyethylaminopropionate betaine. 2 Diethylaminoethyl acrylate.

3 Methacrylic acid.

4 Dimethylaminoethyl methacrylate.

5 Diethylaminoethyl methacrylate.

' N(l,1 dimethyl-3-dimethylaminopropyl) acrylamlde.

B 4% solids.

9 20% solids.

Example 14 Into a 5 liter flask was placed 2137 gms. anhydrous ethanol, 160.5 g. acrylic acid mole percent), 350 gms. dimethylaminoethyl methacrylate (35 mole percent), 164.3 gms. methyl acrylate (30 mole percent) and 1.687 gms. azobisisobutyronitrile. The solution was heated to 70 C. for 17 hrs, producing thereafter a white solution which was diluted with water to 3% solids to provide a hairsetting composition which gave a relative curl retention of 136.

Example 15 A polymer was prepared in a manner similar to that described in Example 14 except vinyl acetate was used in place of methyl acrylate. A relative curl retention of 119 was obtained with a 3 solution.

Example 16 A hairsetting composition was prepared containing 2.75 percent by weight polyvinyl pyrrolidone and 0.25% by weight of the polymer of Example 3 in water. Upon testing by the previously described method, the composition was found to have a relative curly retention of 106. As a comparison, a hairsetting lotion containing only 3% by weight polyvinyl pyrrolidone, was tested in the previously described manner and was found to have a relative curl retention of 86.

What is claimed is:

1. A method of setting hair comprising the sequential steps of (1) moistening the hair, (2) applying at ambient temperature an aqueous hairsetting composition comprising from about 0.25 to about 1 0% by weight of a zwitterionic polymer in water, said polymer containing at least 10% on a molar basis of zwitterionic moiety, a 24% solids aqueous solution of said polymer having a Brookfield viscosity of from about 100 to 100,000 cps. (3) and drying the hair, thereby imparting to said hair excellent anti-static behavior, comb-out, sheen, and high curl retention maintainable even at high relative humidity, said polymer being selected from a group consisting of (A) polymers of carboxy betaines having the repeating wherein R represents a polymerizable unsaturated group selected from the group consisting of acrylate, methacrylate, acrylamide and methacrylamide, R and R are hydrogen atoms or lower groups, x and 10% solids.

11 Excess amine neutralized with HCl.

12 Excess amine neutralized with acetic acid. 13 Acrylamide.

14 Run at 12% solids.

1E 12% solids.

N-(y-methacryloxy, fl hydr0xypropyl)N-trimethyl ammonium chloride.

(B) copolymers of monomers (1) and (2), shown below:

(1) substituted acidic vinyl compounds having the general formula =CR H=CR CO H wherein R represents a hydrogen atom or a carboxylic acid group and R represents a hydrogen atom, a chlorine atom or a methyl group, and

(2) substituted basic vinyl compounds having the general formula CH =CR COQ wherein R represents a hydrogen atom or a methyl group and Q is an organic radical containing a basic nitrogen-containing group, wherein said acidic and basic functionalities are retained in the copolymer structure and wherein the mole ratio of basic monomer to acidic monomer in said copolymer is from 0.8:1 to 2.5:1, except where R; is CO H, the mole ratio is 1.721 to 5:1.

2. The method of claim 1 wherein the (B)(l) monomers are selected from the group consisting of acrylic acid, maleic acid, u-chloroacrylic acid and methacrylic acid and the (B)(2) monomers are selected from the group consisting of dialkyl amino alkyl methacrylates, dialkylamino alkyl acrylates and methacrylamino pyridine, wherein molar amounts of basic monomer to acidic monomer in the copolymer are in a range of 0.8:1 to 2.5 :1 with excess acid or excess base being substantially neutralized, except where R is CO H, the mole ratio is 1.7:1 to 5:1.

3. The method of claim 2 wherein said range of basic monomer to acidic monomer in said copolymer is from 1:1 to 1.5 :1, except that where R is CO H, the mole ratio is 2:1 to 3:1.

4. The method of claim 1 wherein said zwitterionic polymer also contains non-zwitterionic monomer.

5. The method of claim 4. wherein said non-zwitterionic monomer is selected from a group consisting of vinyl pyrrolidone, dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, quaternary ammonium acrylates, quaternary ammonium methacrylates, alkyl acrylates, alkyl methacrylates, acrylamides, methacrylamides, and vinyl acetate.

6. The method of claim 1 wherein said (B)(2) monomer is selected from the group consisting of N(1,1-dimethyl 3-dimethylaminopropyl) acrylamide, dimethylaminoethyl methacrylate, diethylaminoethyl methacrylate, and diethylaminoethyl acrylate and wherein said (B) (1) monomer is selected from the group acrylic acid and methacrylic acid.

7. The method of claim 1 wherein said (A) monomer is beta-methacryloxyethyl beta-dimethyl aminopropionate betaine.

8. The method of claim 1 wherein R is selected from the group consisting of acrylate, methacrylate, acrylamide, and methacrylamide.

9. The method of claim 1 wherein x and y are 2.

10. The method of claim 1 wherein said aqueous hairsetting composition also contains an amount effective for setting hair of a water-soluble hairsetting resin previously known for setting hair.

11. The method of claim 10 wherein said previously known resin is polyvinyl pyrrolidone.

12. Method of claim 1 wherein said polymer is a copolymer of dimethylaminoethyl methacrylate and betamethacryloxyethyl beta-dimethyl aminopropionate betaine containing less than 30 mole percent of dimethylaminoethyl methacrylate.

13. Method of claim 1 wherein said polymer is a copolymer of vinyl acetate and beta-methacryloxyethyl betadimethyl aminopropionate betaine containing less than 80 mole percent of vinyl acetate.

14. Method of claim 1 wherein the polymer is a copolymer of beta-dimethyl beta-methacryloxyethyl aminopropionate betaine and less than 30 mole percent of a comonomer selected from the group consisting of quaternary ammonium acrylates and quaternary ammonium methacrylates.

15. The method of claim 1 wherein said hairsetting composition contains from 1-5% by weight zwitterionic polymer.

16. A liquid composition for imparting to hair treated therewith static-free behavior, good comb-out andl sheen, and high curl retention maintainable even at high relative humidity, consisting essentially of an aqueous solution containing from about 0.25 to about 10% by weight of a zwitterionic polymer containing at least 10% on a molar basis of zwitterionic moiety, a 24% solids aqueous solution of said polymer having a Brookfield viscosity of from about 100 to 100,000 cps, said polymer being a copolymer of monomers (1) and (2),

(1) substituted acidic vinyl compounds having the general formula CR H=CR OO H wherein R represents a hydrogen atom or a carboxylic acid group and R represents a hydrogen atom, a chlorine atom or a methyl group, and

(2) substituted basic vinyl compounds having the general formula CH =CR COQ wherein R represents a hydrogen atom or a methyl group and Q is an organic radical containing a basic nitrogen-containing group wherein said acidic and basic functionalities are retained in the copolymer structure, said acidic monomers being selected from the group consisting of acrylic acid, maleic acid, a-chloro-acrylic acid and methacrylic acid and said basic monomers being selected from the group consisting of diallrylamino alkyl methacrylates, dialkylamino alkyl acrylates and methacrylamino pyridine, wherein the mole ratio of said basic monomer to said acidic monomer in said copolymer is from 0.8:1 to 2.5:1, except where R; is CO H when said mole ratio is 1.7:1 to :1.

17. The composition of claim 16 wherein said zwitterionic polymer also contains non-zwitterionic monomer.

18. The composition of claim 17 wherein said nonzwitterionic monomer is selected from a group consisting of vinyl pyrrolidone, dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, quaternary ammonium acrylates, quaternary ammonium methacrylates, alkyl acrylates, alkyl methacrylates, and vinyl acetate.

' 19. The composition of claim 16 wherein said basic monomer is selected from the group consisting of N(l,ldimethyl-3-dimethylaminopropyl) acrylamide, dimethylaminoethyl methacrylate, and diethylaminoethyl acrylate and wherein said acidic monomer is selected from the group acrylic acid and methacrylic acid.

20. The composition of claim 16 wherein said hairsetting composition contains from 1-5% by weight zwitterionic polymer.

21. A liquid composition for imparting to hair treated therewith static-free behavior, good comb-out and sheen, and high curl retention maintainable even at high relative humidity, consisting essentially of an aqueous solution cotaining from about 0.25 to about 10% by weight of a zwitterionic polymer containing at least 10% on a molar basis of zwitterionic moiety, a 24% solids aqueous solution of said polymer having a Brookfield viscosity of from about to 100,000 cps, said polymer being selected from a group consisting of (A) polymers of carboxy betaines having the repeating formula wherein R represents a polymerizable unsaturated group selected from the group consisting of acrylate, methacrylate, acrylamide and methacrylamide, R and R are hydrogen atoms or lower alkyl groups, x and y are integers from 1 to 3 inclusive, and R and R represent a hydrogen atom or an alkyl radical with the total sum of the carbon atoms in R and R not exceeding six, and

(B) copolymers of monomers (1) and (2), shown below:

(1) substituted acidic vinyl compounds having the general formula CR H=CR CO H wherein R represents a hydrogen atom or a carboxylic acid group and R represents a hydrogen atom, a chlorine atom or a methyl group, and

(2) substituted basic vinyl compounds having the general formula OH =CR COQ wherein R represents a hydrogen atom or a methyl group and Q is an organic radical containing a basic nitrogen-containing group, wherein said acidic and basic functionalities are retained in the copolymer structure and wherein the mole ratio of the basic monomer to acidic monomer in said copolymer is from 0.8:1 to 2.5:1, except where R; is CO H, the mole ratio is 1.7:1 to 5:1, wherein said aqueous hairsetting composition also contains an amount efiective for setting hair of a water-soluble hairsetting resin previously known for setting hair.

22. The composition of claim 21 wherein said previously known resin is polyvinyl pyrrolidone.

References Cited UNITED STATES PATENTS 2,744,130 5/1956 Winberg 260-482 2,777,872 1/1957 lShaoklett 260-482 2,833,650 5/1958 Shacklett 96-114 2,834,758 5/1958 Shacklett 260-78 2,846,417 8/1958 Shacklett 260-78 3,598,641 8/1971 Miller et al 117-138.8 E 3,671,305 6/1972 Brown et al. 117-1388 F 3,689,470 9/1972 Shachat et al. 260-861 N OTHER REFERENCES Mitra et al. J. Electroanal. Chem. 15, 399-404 (1967).

Ryabov et al., Tr. Khim. Khim. T eckhnoL, 1967(2), 49-51.

Ryabov et al., Tr. Kkim. Khim. TecknoL, 1968(1), 51-55.

MELVIN GOLDSTEIN, Primary Examiner US. Cl. X.R.

132-7; 260-2936 WB; 424-71, Dig. 2

US3836537A 1970-10-07 1972-10-25 Zwitterionic polymer hairsetting compositions and method of using same Expired - Lifetime US3836537A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US7896870 true 1970-10-07 1970-10-07
US3836537A US3836537A (en) 1970-10-07 1972-10-25 Zwitterionic polymer hairsetting compositions and method of using same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US3836537A US3836537A (en) 1970-10-07 1972-10-25 Zwitterionic polymer hairsetting compositions and method of using same

Publications (1)

Publication Number Publication Date
US3836537A true US3836537A (en) 1974-09-17

Family

ID=26761171

Family Applications (1)

Application Number Title Priority Date Filing Date
US3836537A Expired - Lifetime US3836537A (en) 1970-10-07 1972-10-25 Zwitterionic polymer hairsetting compositions and method of using same

Country Status (1)

Country Link
US (1) US3836537A (en)

Cited By (243)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4066589A (en) * 1975-05-23 1978-01-03 Minnesota Mining And Manufacturing Company Solvent repellent complexes
US4075131A (en) * 1976-09-17 1978-02-21 Minnesota Mining And Manufacturing Company Conditioning shampoo
US4130524A (en) * 1977-12-01 1978-12-19 Northern Instruments Corporation Corrosion inhibiting compositions
US4131583A (en) * 1977-12-01 1978-12-26 Northern Instruments Corporation Corrosion inhibiting compositions
US4191674A (en) * 1975-07-25 1980-03-04 Ppg Industries, Inc. Zwitterion-containing compositions
EP0112592A2 (en) * 1982-12-23 1984-07-04 THE PROCTER & GAMBLE COMPANY Zwitterionic polymers having clay soil removal/anti-redeposition properties useful in detergent compositions
US4622378A (en) * 1982-12-23 1986-11-11 The Procter & Gamble Company Zwitterionic polymers having clay soil removal/anti-redeposition properties useful in detergent compositions
US4725282A (en) * 1984-06-27 1988-02-16 Wella Aktiengesellschaft Oxidative hair dyeing composition based upon a carrier of low viscosity
US4814101A (en) * 1987-03-16 1989-03-21 Henkel Kommanditgesellschaft Auf Aktien Zwitterionic polymers and their use in hair treatment preparations
US4842849A (en) * 1981-05-08 1989-06-27 L'oreal Composition intended for the treatment of keratin fibres, based on a cationic polymer and an anionic polymer containing vinylsulphonic groups
US4898725A (en) * 1985-02-02 1990-02-06 Henkel Kommanditgesellschaft Auf Aktien Preparations for washing or rinsing hair containing di- or tri- carboxylic acids
US4994088A (en) * 1985-09-30 1991-02-19 Kao Corporation Hair cosmetic composition
US4996059A (en) * 1979-11-28 1991-02-26 L'oreal Composition for the treatment of keratin fibers, based on amphoteric polymer and cationic polymer
US4996045A (en) * 1988-11-16 1991-02-26 National Starch And Chemical Investment Holding Corporation Hair fixative compositions containing alpha-aminomethylene phosphonate betaines
US5153289A (en) * 1985-01-02 1992-10-06 Exxon Research And Engineering Company Betaine copolymers-viscosifiers for water and brine
US5415856A (en) * 1990-05-08 1995-05-16 Preemptive Advertising Inc. Hair treatment compositions containing disaccharides
US5652296A (en) * 1994-08-19 1997-07-29 Minnesota Mining And Manufacturing Company Water-based adhesives
US5858341A (en) * 1994-01-11 1999-01-12 L'oreal Detergent cosmetic compositions for hair use and use thereof
US5916549A (en) * 1994-01-11 1999-06-29 L'oreal, S.A. Detergent cosmetic compositions for hair use and the use thereof
FR2780729A1 (en) * 1998-07-06 2000-01-07 Inst Francais Du Petrole Zwitterionic derivatives and the application properties of aqueous suspensions
US6260556B1 (en) 1999-01-29 2001-07-17 L'oreal Anhydrous composition for bleaching keratin fibers
US6277386B1 (en) 1998-02-25 2001-08-21 Basf Aktiengesellschaft Cosmetic
US6340664B1 (en) 1999-08-26 2002-01-22 Henkel Kommanditgesellschaft Auf Aktien (Kgaa) Laundry detergent or cleaning product tablets with partial coating
US6346234B1 (en) 1997-03-04 2002-02-12 L'oreal, S.A. Hair styling composition capable of being remodelled with a Tg of less than +10 °C
US6365697B1 (en) 1995-11-06 2002-04-02 Basf Aktiengesellschaft Water-soluble or water-dispersible polyurethanes with terminal acid groups, the production and the use thereof
US6391292B1 (en) 1998-11-26 2002-05-21 L'ORéAL S.A. Hairstyling composition comprising a polymer with particular characteristics and an ionic film forming polymer
US6399050B1 (en) 1999-06-18 2002-06-04 L'oreal S.A. Hair cosmetic composition in the form of a water-in-silicone emulsion comprising at least one fixing polymer
US6410004B1 (en) 1999-03-12 2002-06-25 Basf Aktiengesellschaft Polyureas and water-soluble or water-dispersible polymeric salts
US20020086040A1 (en) * 2000-10-30 2002-07-04 Christine Dupuis Cosmetic composition which provides good hold properties and which comprises a copolymer with an acid unit
US20020085988A1 (en) * 1996-11-04 2002-07-04 Takanori Nambu Hair styling composition
US6436151B2 (en) 1999-12-30 2002-08-20 L'oreal S.A. Compositions for oxidation dyeing keratin fibers comprising at least one oxidation dye, at least one thickening polymer comprising at least one fatty chain, and at least one fatty alcohol comprising more than twenty carbon atoms and uses thereof
US6444197B2 (en) 1999-12-13 2002-09-03 L'oreal S.A. Bleaching composition for keratin fibers, comprising a combination of two polyurethane polyethers
US20020193265A1 (en) * 2001-03-30 2002-12-19 Beatrice Perron Detergent cosmetic compositions containing an anionic surfactant derived from amino acids and salts thereof and a soluble conditioning agent and uses thereof
US20020192165A1 (en) * 2001-03-13 2002-12-19 L'oreal Aerosol compositions comprising a polysaccharide grafted with a polysiloxane
US20020197226A1 (en) * 2001-03-13 2002-12-26 Franck Giroud Composition comprising a polysaccharide grafted with a polysiloxane, and non-cellulosic, non-fixing thickener
US6506372B1 (en) 1999-06-25 2003-01-14 L'oreal S.A. Cosmetic compositions containing an amphoteric polymer and a fixing/conditioner polymer, and their uses
US20030023782A1 (en) * 2001-07-26 2003-01-30 International Business Machines Corp. Microprocessor system bus protocol providing a fully pipelined input/output DMA write mechanism
US6541032B1 (en) 1999-10-13 2003-04-01 Basf Aktiengesellschaft Use of finely divided dye-containing polymers PD as color-imparting constituent in cosmetic compositions
US6548051B2 (en) 2000-08-16 2003-04-15 L′Oreal Hair styling composition comprising adhesive particles
US20030074747A1 (en) * 2001-07-27 2003-04-24 Patricia Vuarier Composition for the oxidation dyeing of keratin fibres, comprising at least one fatty alcohol chosen from mono- and polyglycerolated fatty alcohols and a particular polyol
US6555100B1 (en) 1997-12-31 2003-04-29 L'ORéAL S.A. Compositions for treating keratinous materials containing a combination of a zwitterion polymer and a water insoluble non-volatile silicon
US20030103929A1 (en) * 2001-09-11 2003-06-05 Mireille Maubru Cosmetic compositions containing a methacrylic acid copolymer, a silicone and a cationic polymer, and uses thereof
US20030103926A1 (en) * 2001-09-11 2003-06-05 Mireille Maubru Cosmetic compositions containing a methacrylic acid copolymer, a dimethicone, a nacreous agent and a cationic polymer, and uses thereof
US20030108503A1 (en) * 2001-09-11 2003-06-12 Mireille Maubru Cosmetic compositions containing a methacrylic acid copolymer, a silicone and a cationic polymer, and uses thereof
US20030118537A1 (en) * 2001-11-08 2003-06-26 Priscille Devin-Baudoin Process for permanently reshaping the hair using particular aminosilicones
US20030129155A1 (en) * 2001-11-08 2003-07-10 Priscille Devin-Baudoin Use of particular aminosilicones as a pre-or post-treatment of processes for bleaching keratin fibres
US20030126692A1 (en) * 2001-11-08 2003-07-10 Priscille Devin-Baudoin Use of particular aminosilicones as a pre-treatment of processes for coloring keratin fibers with direct dyes or with oxidation dyes
US20030131424A1 (en) * 2000-04-12 2003-07-17 Marie-Pascale Audousset Oxidation dyeing composition for ketatinous fibres comprising a 3,5-diamino-pyridine derivative and a cationic or amphoteric polymer
US6602303B2 (en) 2000-08-11 2003-08-05 L'oreal S.A. Composition for the oxidation dyeing of keratinous fibers comprising at least one oxidation dye and at least one cationic amphiphilic polymer, and dyeing methods
US20030147841A1 (en) * 2001-11-08 2003-08-07 Frederic Legrand Reducing composition for treating keratin fibres, comprising a particular aminosilicone
US20030147818A1 (en) * 2001-11-15 2003-08-07 Claude Dubief Preparation of polysaccharide betainate type compounds, compounds obtained, their use and compositions comprising them
US20030147842A1 (en) * 2001-11-08 2003-08-07 Serge Restle Cosmetic compositions containing a particular aminosilicone and a conditioner, and uses thereof
US20030147840A1 (en) * 2001-11-08 2003-08-07 Frederic Legrand Reducing composition for treating keratin fibres, comprising a particular aminosilicone
US20030147827A1 (en) * 2001-11-08 2003-08-07 Sandrine Decoster Cosmetic compositions containing a particular aminosilicone and a thickener, and uses thereof
US20030152543A1 (en) * 2001-11-08 2003-08-14 Frederic Legrand Oxidizing composition for treating keratin fibres, comprising a particular aminosilicone
US20030152542A1 (en) * 2001-11-08 2003-08-14 Sandrine Decoster Cosmetic compositions containing a particular aminosilicone and a thickener, and uses thereof
US20030152541A1 (en) * 2001-11-08 2003-08-14 Frederic Legrand Oxidizing composition for treating keratin fibres, comprising a particular aminosilicone
US20030157049A1 (en) * 2001-11-08 2003-08-21 Jonathan Gawtrey Cosmetic compositions containing a particular aminosilicone and a conditioner, and uses thereof
US6635262B2 (en) 2000-03-14 2003-10-21 L'oreal S.A. Roll-on applicator comprising a hair composition
US20040014631A1 (en) * 2000-12-23 2004-01-22 Henriette Weber Washing and cleaning agent coated moulding body
US20040019981A1 (en) * 2000-11-08 2004-02-05 Francois Cottard Direct dyeing composition for keratinous fibres comprising a cationic associative polyurethane
US20040025266A1 (en) * 2000-11-08 2004-02-12 Francois Cottard Oxidation dyeing composition for karatinous fibres comprising a cationic associative polyurethane
US6695887B2 (en) 1999-12-30 2004-02-24 L'oreal S.A. Compositions for oxidation dyeing keratin fibers comprising at least one fatty alcohol having more than twenty carbon atoms and at least one oxyalkylenated nonionic surfactant with an hlb greater than 5
US20040034947A1 (en) * 2000-11-08 2004-02-26 Frederic Legrand Bleachng composition for keratinous fibres comprising an associate polyurethane
US20040034946A1 (en) * 2000-11-08 2004-02-26 Frederic Legrand Composition for bleaching or permanent waving of keratinous fibers comprising a cationic associative polyurethane
US20040049861A1 (en) * 2000-12-04 2004-03-18 Francois Cottard Oxidation dyeing composition for keratinous fibres comprising an associative polymer and a pearling agent
US20040060125A1 (en) * 2000-04-12 2004-04-01 Marie-Pascale Audouset Oxidation dyeing composition for keratinous fibres comprising a 3,5-diamino-pyridine derivative and a particular thickening polymer
US20040060126A1 (en) * 2000-12-04 2004-04-01 Francois Cottard Dyeing composition for keratinous fibres comprising an associative polymer and a polymer with acrylamide units, dialkyldiallylammonium halide, and vinylic carboxylic acid
US20040071652A1 (en) * 2000-10-27 2004-04-15 Christine Dupuis Foam-like cosmetic hair composition comprising at least a aminoplast-ether skeleton thickening polymer
US20040093675A1 (en) * 2001-04-02 2004-05-20 Laurent Vidal Dyeing composition for dyeing kerationou fibres comprising a cationic azo-dye
WO2004043330A2 (en) 2002-11-07 2004-05-27 L'oreal Cosmetic composition comprising at least one specific cyclic carbonate which may be polymerised
US20040102528A1 (en) * 2001-12-07 2004-05-27 Brian Walchuk Anionic copolymers prepared in an inverse emulsion matrix and their use in preparing cellulosic fiber compositions
US20040122807A1 (en) * 2002-12-24 2004-06-24 Hamilton Darin E. Methods and systems for performing search interpretation
US20040136935A1 (en) * 2000-08-16 2004-07-15 L'oreal S.A. Hair styling composition comprising encapsulated adhesives
US20040133994A1 (en) * 2002-10-21 2004-07-15 Francois Cottard Oxidation dyeing composition for keratin fibers comprising a cationic poly(vinyllactam) and at least One C10-C14 fatty alcohol, methods and devices for oxidation dyeing
US20040133995A1 (en) * 2002-10-21 2004-07-15 Francois Cottard Oxidation dyeing composition for keratin fibers comprising a cationic poly(vinyllactam) and at least one C10-C14 fatty acid, methods and devices for oxidation dyeing
US20040143039A1 (en) * 2002-12-06 2004-07-22 Martha Hollomon Cationic or amphoteric copolymers prepared in an inverse emulsion matrix and their use in preparing cellulosic fiber compositions
US20040163186A1 (en) * 2002-12-06 2004-08-26 Frederic Simonet Oxidation dye composition for keratin fibers, comprising at least one oxidation dye, at least one associative polymer, at least one nonionic cellulose-based compound not comprising a C8-C30 fatty chain, and at least one cationic polymer with a charge density of greater than 1 meq/g and not comprising a C8-C30 fatty chain
US6800098B1 (en) 1999-12-08 2004-10-05 L'oreal, S.A. Oxidation dye composition for keratinic fibres containing a thickening polymer with an ether plastic skeleton
US6803047B1 (en) 1997-03-14 2004-10-12 L'oreal Vaporizable gelled composition
US20040205902A1 (en) * 2002-12-06 2004-10-21 Francois Cottard Composition for the oxidation dyeing of keratin fibers, comprising at least one non-oxyalkenylated fatty alcohol, at least one oxidation dye, at least one associative polymer, and at least one amide of an alkanolamine and a C14-C30 fatty acid
US20040208843A1 (en) * 2002-09-24 2004-10-21 Gabin Vic Cosmetic composition comprising an exogenous ligand-receptor system adsorbed or covalently attached to keratin materials, and hair treatment using this composition or constituent elements thereof
US20040221401A1 (en) * 2003-03-25 2004-11-11 L'oreal S.A. Composition for dyeing keratinous fibers, comprising a hydroxycarboxylic acid or a salt, ready-to-use composition comprising it, implementation process and device
US20040226110A1 (en) * 2003-01-16 2004-11-18 Frederic Legrand Ready-to-use bleaching compositions, preparation process and bleaching process
US20040235700A1 (en) * 2003-01-16 2004-11-25 Frederic Legrand Ready-to-use bleaching compositions, preparation process and bleaching process
US20040237213A1 (en) * 2001-06-12 2004-12-02 Gregory Plos Dyeing composition for human keratinous fibres with direct dyes and dicationic compounds
US20040237217A1 (en) * 2003-03-25 2004-12-02 L'oreal S.A. Composition for dyeing keratinous fibers, comprising at least one polycarboxylic acid or a salt, ready-to-use composition comprising it, implementation process and device
US20050011017A1 (en) * 2003-03-25 2005-01-20 L'oreal S.A. Oxidizing composition comprising hydroxycarboxylic acids and salts thereof as complexing agents for dyeing, bleaching or permanently reshaping keratin fibres
US20050039270A1 (en) * 2003-03-25 2005-02-24 L'oreal S.A. Use of polycarboxylic acids and salts thereof as complexing agents in oxidizing compositions for dyeing, bleaching or permanently reshaping keratin fibres
US20050063933A1 (en) * 2003-06-17 2005-03-24 Sabine Vrignaud Cosmetic hair composition comprising isoeicosane and at least one nonsilicone fixing polymer
US20050118126A1 (en) * 2003-10-24 2005-06-02 Isabelle Rollat Cosmetic hair composition comprising at least one fixing polymer and at least one compound capable of swelling by the action of heat
US20050125912A1 (en) * 2001-12-21 2005-06-16 Patricia Desenne Dyeing composition for keratinous fibers comprising an oxyethylene rapeseed fatty acid amide
US20050136027A1 (en) * 2003-06-17 2005-06-23 Sabine Vrignaud Cosmetic hair composition based on isoeicosane and on a silicone fixing polyurethane
US6916344B1 (en) 1999-12-08 2005-07-12 L'oreal S.A. Direct dyeing composition for keratinic fibers containing a thickening polymer with an ether plastic skeleton
US6919073B2 (en) 2001-05-16 2005-07-19 L'oreal S.A. Pulverulent composition for bleaching human keratin fibers
US20050158265A1 (en) * 2003-06-17 2005-07-21 Sabine Vrignaud Cosmetic hair composition comprising tridecyl trimellitate and at least one fixing polymer
US20050169869A1 (en) * 2003-11-18 2005-08-04 L'oreal Cosmetic composition comprising at least one gellan gum or derivative thereof, at least one monovalent salt, and at least one suspension compound, processes using this composition, and uses thereof
US20050169873A1 (en) * 2003-12-19 2005-08-04 Isabelle Rollat Styling composition comprising, in a predominantly aqueous medium, an elastic cationic polyurethane, processes using it and uses thereof
US20050175569A1 (en) * 2004-01-07 2005-08-11 Geraldine Fack Cosmetic compositions comprising a cation, a drawing polymer and a thickener, and cosmetic treatment processes
US6932964B1 (en) 1998-08-26 2005-08-23 Basf Aktiengesellschaft Cosmetic composition with water-soluble or water-dispersible polymers
US20050186165A1 (en) * 2003-11-18 2005-08-25 Estelle Mathonneau Cosmetic composition based on a cosmetically active compound and a gel comprising at least one crosslinked network of crosslinked polymer particles
US20050186151A1 (en) * 2003-08-11 2005-08-25 Franck Giroud Cosmetic composition comprising stabilized and optionally coated metal particles
US20050188475A1 (en) * 2004-01-07 2005-09-01 Alain Lagrange Dyeing composition comprising at least one fluorindine compound for the dyeing of keratinic fibers, dyeing process comprising the composition and compound
US20050208005A1 (en) * 2003-08-11 2005-09-22 Franck Giroud Cosmetic composition comprising particles having a core-shell structure
US20050220728A1 (en) * 2004-03-22 2005-10-06 Mohamed Kanji Cosmetic composition comprising a polyglycerolated silicone elastomer
US20050220723A1 (en) * 2004-03-25 2005-10-06 Katarina Benabdillah Aerosol device comprising a propellant and a styling composition comprising, in a predominantly aqueous medium, a pseudo-block polymer and an additional fixing polymer; processes therefor and uses thereof
US20050232884A1 (en) * 2004-04-02 2005-10-20 Thomas Fondin Method for treating hair fibers
US20050232883A1 (en) * 2004-04-02 2005-10-20 Thomas Fondin Method for treating hair fibers
US20050232885A1 (en) * 2004-01-07 2005-10-20 L'oreal Detergent cosmetic compositions comprising at least one surfactant, at least one drawing polymer and at least one nonsilicone conditioner, and use thereof
US20050238599A1 (en) * 2001-11-08 2005-10-27 L'oreal S.A. Process for permanently reshaping the hair using particular aminosilicones
US20050257335A1 (en) * 2004-04-08 2005-11-24 Christophe Dumousseaux Composition for application to the skin, to the lips, to the nails, and/or to hair
US20050287103A1 (en) * 2004-06-08 2005-12-29 Vanina Filippi Cosmetic composition comprising at least one ester and at least one film-forming polymer
US6984250B1 (en) 1999-12-08 2006-01-10 L'oreal Composition, method, and kit for the bleaching or permanent reshaping of keratin fibers, comprising at least one thickening polymer with an aminoplast-ether skeleton
US20060013791A1 (en) * 2004-07-16 2006-01-19 L'oreal Cosmetic composition comprising a defined silicone polymer and a film former
US20060024259A1 (en) * 2004-07-29 2006-02-02 Sabine Vrignaud Cosmetic composition comprising, in a non-fatty medium, at least one linear sulfonic polyester and at least one nonionic thickening polymer, processes using this composition and uses thereof
US20060024261A1 (en) * 2004-07-29 2006-02-02 Bebot Cecile Cosmetic compositions comprising a linear sulfonic polyester and a polyurethane, processes using these compositions and uses thereof
US20060024260A1 (en) * 2004-07-29 2006-02-02 Cecile Bebot Cosmetic composition comprising a water-dispersible linear sulphonic polyester and a modified guar gum, methods employing this composition and uses
US20060024255A1 (en) * 2004-07-30 2006-02-02 L'oréal Hair styling compositions comprising adhesive particles and non-adhesive particles
US20060041054A1 (en) * 2002-10-02 2006-02-23 Christophe Dumousseaux Compositions to be applied to the skin and the integuments
US20060039876A1 (en) * 2002-10-02 2006-02-23 Christophe Dumousseaux Compositions to be applied to the skin and the integuments
EP1634580A1 (en) 2004-09-09 2006-03-15 L'oreal Hairstyling composition comprising a combination of a hydrophilic highly porous polymeric material and a fixing polymer
EP1634620A1 (en) 2004-09-10 2006-03-15 L'oreal Kosmetische Zusammensetzung enthaltend Käfigstruktur besitzenden Verbindugen
US20060057094A1 (en) * 2004-09-09 2006-03-16 Estelle Mathonneau Hair styling composition comprising at least one hydrophilic polymeric high porosity material and at least one fixing polymer
US20060062748A1 (en) * 2004-09-10 2006-03-23 Estelle Mathonneau Cosmetic composition comprising at least one cage-like structure compound
US20060088493A1 (en) * 2004-10-13 2006-04-27 Gabin Vic Composition and process for the cosmetic treatment of keratin materials based on electrophilic monomers and non-silicone polymers
EP1656968A1 (en) 2004-11-16 2006-05-17 L'oreal Pressurized article for hair treatment
EP1671898A1 (en) 2004-11-16 2006-06-21 L'oreal Pressurized container for hairstyling
US20060147402A1 (en) * 2002-09-26 2006-07-06 Xavier Blin Composition comprising a sequenced polymer and a gelling agent
US20060156479A1 (en) * 2004-12-23 2006-07-20 Leila Hercouet Use of at least one compound chosen from porphyrin compounds and phthalocyanin compounds for dyeing human keratin materials, compositions comprising them, a dyeing process, and compounds therefor
EP1685825A1 (en) 2005-01-28 2006-08-02 L'oreal Hair treating process and its uses
US20060171910A1 (en) * 2004-12-30 2006-08-03 Audrey Ricard Cosmetic composition containing an alkoxylated alcohol ester and a hydrocarbon-based ester oil
US20060177399A1 (en) * 2004-11-16 2006-08-10 Herve Jourdan Pressurized device for hair fiber styling and use of the same for hair fiber styling and/or hair
US20060188461A1 (en) * 2004-07-29 2006-08-24 Cecile Bebot Linear sulfonic polyester as a water-resistant hair fixing agent
US20060210507A1 (en) * 2004-10-28 2006-09-21 Ludivine Laurent Cosmetic composition comprising at least one sulphonic polyester and at least one polyurethane
US20060230546A1 (en) * 2005-02-28 2006-10-19 Eric Bone Anhydrous composition in the form of a film comprising at least one film-forming polymer and at least one oxidation dye, preparation, and dyeing process
US20060236469A1 (en) * 2005-02-28 2006-10-26 Eric Bone Anhydrous composition in the form of a film comprising a film-forming polymer and oxidizing agent, preparation and process for coloring keratinous fibers employing the anhydrous composition
US20060242771A1 (en) * 2005-02-28 2006-11-02 Eric Bone Anhydrous composition in the form of a film comprising a film-forming polymer and a direct dye, preparation and dyeing process using the composition
US20060248662A1 (en) * 2005-03-31 2006-11-09 Frederic Legrand Dye composition with a reduced content of starting materials, and process for dyeing keratin fibers using the same
US20060257339A1 (en) * 2005-05-13 2006-11-16 L'oreal Use of conductive polymer nanofibers for treating keratinous surfaces
US20060263316A1 (en) * 2005-04-29 2006-11-23 Priscille Devin-Baudoin Semipermanent hair shaping method
US20060260069A1 (en) * 2005-03-31 2006-11-23 Frederic Legrand Dye composition comprising at least one fatty acid ester and process for dyeing keratin fibers using the same
US20060260632A1 (en) * 2005-04-29 2006-11-23 Catherine Campain Semipermanent hair shaping method
US20060260071A1 (en) * 2005-03-31 2006-11-23 Frederic Legrand Dye composition comprising at least one cellulose and process for dyeing keratin fibers using the dye composition
US20060260070A1 (en) * 2005-03-31 2006-11-23 Frederic Legrand Dye composition comprising at least one glycerol ester and a process for dyeing keratin fibers using the composition
US7141079B2 (en) 2000-04-12 2006-11-28 L′Oreal Oxidation dyeing composition for keratinous fibers and dyeing method using same
US20060265817A1 (en) * 2005-03-31 2006-11-30 Frederic Legrand Dye composition comprising at least one non-ionic associative polymer and process for dyeing keratin fibers using same
US20060280711A1 (en) * 2005-06-14 2006-12-14 L'oreal Process for treating marionette lines
US20070009454A1 (en) * 2005-07-08 2007-01-11 L'oreal Make-up method involving a magnetic interaction
US20070020215A1 (en) * 2005-01-28 2007-01-25 Estelle Mathonneau Hair treatment method
US20070105734A1 (en) * 2005-10-28 2007-05-10 Sandrine Decoster Composition for washing keratin materials and cosmetic treatment process using said composition
US20070141006A1 (en) * 2004-03-17 2007-06-21 Aude Livoreil Cosmetic compositions containing modified polyamines and the uses thereof
US20070184002A1 (en) * 2006-01-20 2007-08-09 Sabine Vrignaud Non-washing cosmetic composition comprising at least one ionic fixing polymer and at least one ester of polyethylene glycol and of fatty acid, and method for fixing a hairstyle
US20070184001A1 (en) * 2006-01-20 2007-08-09 Sabine Vrignaud Cosmetic composition comprising a nonionic fixing polymer and a specific ester of polyethylene glycol and of fatty acid, and a method for fixing the hairstyle
US20070190008A1 (en) * 2005-12-20 2007-08-16 Catherine Campain Process for permanently reshaping the hair, comprising applying to the hair at least one precipitated fixing polymer, and multi-compartment device
US7258852B2 (en) 2001-09-11 2007-08-21 L'oreal S.A. Cosmetic compositions containing a methacrylic acid copolymer and an oil, and uses thereof
US20080014158A1 (en) * 2002-09-26 2008-01-17 L'oreal Novel Block Polymers and Cosmetic Compositions and Processes Comprising Them
US20080019933A1 (en) * 2006-07-21 2008-01-24 L'oreal Method of making-up dark skin
US20080031829A1 (en) * 2006-08-04 2008-02-07 Regis Beitone Cosmetic composition comprising at least one polysaccharide of lambda-carrageenan type in aerosol form, method for the cosmetic treatment of keratinous fibers, and product comprising the composition
US20080044366A1 (en) * 2004-04-08 2008-02-21 L'oreal S.A. Compositions for application to the skin, to the lips, to the nails, and/or to hair
US7335348B2 (en) 2000-07-18 2008-02-26 L'oreal Hairstyling composition which makes possible remodelling of the hairstyle and process for remodelling the hairstyle using such a composition
US20080089853A1 (en) * 2004-10-22 2008-04-17 Basf Aktiengesellschaft Amphoteric Ethyl Methacrylate Copolymers and Use Thereof
US20080102046A1 (en) * 2006-07-21 2008-05-01 L'oreal Cosmetic composition
US20080105272A1 (en) * 2004-10-05 2008-05-08 L'oreal Method Of Applying Makeup By Means Of A Magnetic Composition Including At Least One Interferential Pigment
EP1920755A1 (en) 2006-11-10 2008-05-14 L'Oréal Method for permanently deforming keratinous fibres comprising a step of applying an intermediate rinsing component comprising a monovalent metal cation salt or an ammonia salt and an organic acid
US20080119554A1 (en) * 2004-11-26 2008-05-22 Rajiv Jalan Compositions Comprising Ornithine And Phenylacetate Or Phenylbutyrate For Treating Hepatic Encephalopathy
US20080120792A1 (en) * 2005-02-28 2008-05-29 Gregory Plos Dyeing of in Particular Human Keratin Materials by Dry Thermal Transfer of a Direct Azomethine Dye, Composition Comprising the Said Dye and its Method of Preparation
US20080127429A1 (en) * 2006-10-25 2008-06-05 Gaelle Brun Coloring composition of keratinous fibers comprising at least one polysiloxane/polyurea block copolymer
US20080148495A1 (en) * 2006-12-22 2008-06-26 L'oreal Cosmetic composition for keratinous substrates with triarylmethane compounds
US20080148496A1 (en) * 2005-02-28 2008-06-26 Gregory Plos Dyeing of in Particular Human Keratin Materials by Dry Thermal Transfer of a Direct Dye, Composition Comprising the Said Dye and Its Method of Preparation
US20080168608A1 (en) * 2005-02-28 2008-07-17 Gregory Plos Dyeing of in Particular Human Keratin Materials by Dry Thermal Transfer of a Direct Anthraquinone Dye, Composition Comprising the Said Dye and Its Method of Preparation
US20080193405A1 (en) * 2005-01-28 2008-08-14 Basf Aktiengesellschaft Use of a Water-In-Water Emulsion Polymers in the Form of a Thickener for Cosmetic Preparations
EP1961489A1 (en) 2007-02-23 2008-08-27 L'Oreal Device for spraying a gloss composition
EP1961490A1 (en) 2007-02-23 2008-08-27 L'Oreal Device for spraying a fixing composition
US20080260658A1 (en) * 2005-10-07 2008-10-23 Basf Se Hair Setting Compositions Based on T-Butyl Acrylate and Hydroxyalkyl Methacrylate
US20080286221A1 (en) * 2004-10-22 2008-11-20 Basf Aktiengesellschaft Anionic Ethyl Methacrylate Copolymers and Use Thereof
EP2039345A1 (en) 2007-09-14 2009-03-25 L'Oréal Cosmetic compositions containing a cationic copolymer and a particular triglyceride and uses thereof
US20090081148A1 (en) * 2000-08-25 2009-03-26 L'oreal S.A. Protection of keratinous fibers using ceramides and/or glycoceramides
EP2065023A2 (en) 2007-11-30 2009-06-03 L'Oreal Hairstyling composition comprising at least one (meth)acrylic copolymer and at least one pearlescent agent
EP2065024A2 (en) 2007-11-30 2009-06-03 L'Oreal Hairstyling composition comprising (meth)acrylic copolymers and at least one oil
US20090162295A1 (en) * 2005-08-11 2009-06-25 Basf Aktiengesellschaft Setting polymers based on polyester acrylates
EP2105127A1 (en) 2008-03-26 2009-09-30 Bayer MaterialScience AG Hair fixing composition
EP2106833A1 (en) 2008-04-02 2009-10-07 Bayer MaterialScience AG Particle derived from drying a liquid nano-uric dispersion
US7651533B2 (en) 2005-03-31 2010-01-26 Oreal Dye composition with a reduced content of starting materials, process for dyeing keratin fibers using the same and device therefor
US20100117621A1 (en) * 2006-10-13 2010-05-13 Lutron Electronics Co., Inc. Method of load shedding to reduce the total power consumption of a load control system
US20100172857A1 (en) * 1998-11-03 2010-07-08 L'oreal Aerosol device containing a condensation polymer comprising at least a polyurethane and/or polyurea unit
US7771492B2 (en) 1999-12-30 2010-08-10 L'oreal S.A. Compositions for oxidation dyeing keratin fibers comprising at least one thickening polymer comprising at least one fatty chain and at least one fatty alcohol chosen from monoglycerolated fatty alcohols and polyglycerolated fatty alcohols
EP2221043A1 (en) 2009-02-21 2010-08-25 Bayer MaterialScience AG Hair fixing compound
US20100297051A1 (en) * 2009-05-22 2010-11-25 Feuillette Laetitia Cosmetic composition comprising at least one elastomeric anionic polyurethane and at least one non-ionic thickener
WO2010133658A2 (en) 2009-05-22 2010-11-25 L'oréal A cosmetic composition comprising at least one elastomeric anionic polyurethane and at least one non-ionic thickener
WO2010133660A2 (en) 2009-05-22 2010-11-25 L'oreal Cosmetic composition comprising at least one elastomeric polyurethane
US20100297052A1 (en) * 2009-05-22 2010-11-25 Feuillette Laetitia Cosmetic composition comprising at least one elastomeric polyurethane
DE102009042727A1 (en) 2009-09-23 2011-04-07 Bayer Materialscience Ag Use of a composition comprising nitrocellulose-polyurethane-polyurea particles as a cosmetic for hair designing and setting
US20110150796A1 (en) * 2008-09-04 2011-06-23 Basf Se Precipitation polymerization in the presence of glycerin monostearate
US20110206623A1 (en) * 2007-08-23 2011-08-25 Evonik Goldschmidt Gmbh Novel dipolar ionic compounds comprising formulations and the use thereof
US20110218295A1 (en) * 2010-03-02 2011-09-08 Basf Se Anionic associative rheology modifiers
WO2011117403A2 (en) 2010-03-25 2011-09-29 L'oréal Composition comprising a silicone copolymer, a silicone surfactant and a non-volatile pdms, cosmetic treatment method and use.
WO2011157796A1 (en) 2010-06-17 2011-12-22 L'oreal Cosmetic composition comprising a branched sulphonic polyester and a particular thickener and uses in hair styling
US8119110B2 (en) 2003-09-26 2012-02-21 L'oreal S.A. Cosmetic composition comprising a block polymer and a non-volatile silicone oil
WO2012032057A2 (en) 2010-09-06 2012-03-15 L'oreal Cosmetic composition comprising a fixing polymer and a specific thickener and uses in styling
WO2012035053A1 (en) 2010-09-14 2012-03-22 L'oreal Cosmetic composition comprising a fixing polymer and an antidandruff agent
WO2012049145A1 (en) 2010-10-12 2012-04-19 L'oreal Cosmetic composition comprising a particular silicon derivative and one or more acrylic thickening polymers
WO2012065971A2 (en) 2010-11-19 2012-05-24 L'oreal Cosmetic composition comprising at least one elastomeric polyurethane and at least one cationic polymer
WO2012080255A2 (en) 2010-12-14 2012-06-21 L'oreal Fan-shaped aerosol device for styling the hair
WO2012080661A2 (en) 2010-12-14 2012-06-21 L'oreal Aerosol device having two compartments including an alcoholic or hydroalcoholic hairstyling composition, and hairstyling method
WO2012107887A2 (en) 2011-02-08 2012-08-16 L'oreal Process for applying a hair care composition to hair
US8246940B2 (en) 2003-11-18 2012-08-21 L'oreal S.A. Cosmetic composition comprising gellan gum or a derivative thereof, a fixing polymer, a monovalent salt and an alcohol, process of using the same
WO2012130683A1 (en) 2011-03-25 2012-10-04 Bayer Materialscience Ag Polyurethane urea mixture for hair cosmetics
WO2012164065A2 (en) 2011-06-01 2012-12-06 L'oreal Process for treating straightened keratin fibres
WO2013042274A1 (en) 2011-09-22 2013-03-28 L'oreal Cosmetic cleansing composition
WO2013045379A1 (en) 2011-09-30 2013-04-04 L'oreal Method for the temporary coloured shaping of keratinous fibres
WO2013092719A1 (en) 2011-12-19 2013-06-27 L'oreal Cosmetic composition comprising an anionic or nonionic associative polymer, fixing polymer and at least 2% of a surfactant
WO2013092708A1 (en) 2011-12-19 2013-06-27 L'oreal Cosmetic composition comprising an anionic or nonionic associative polymer, fixing polymer and a particular surfactant
WO2013110653A1 (en) 2012-01-23 2013-08-01 L'oreal Composition comprising at least one specific alkoxysilane polymer
WO2013131969A2 (en) 2012-03-09 2013-09-12 Bayer Materialscience Llc Effect of the polyurethane film former on the efficacy of acne treatment
US8544475B2 (en) 2005-08-30 2013-10-01 L'oreal Packaging and applicator assembly including a magnetic device, a magnetic device, a method of forming a pattern on a nail using a magnetic device and a method of manufacturing a magnetic device
WO2013160442A2 (en) 2012-04-26 2013-10-31 L'oreal Cosmetic composition comprising a fatty-chain silane and a particular fixing polymer
WO2013160440A2 (en) 2012-04-26 2013-10-31 L'oreal Process for treating hair with a pressurized cosmetic composition comprising a fatty-chain silane
WO2013167530A2 (en) 2012-05-07 2013-11-14 L'oreal Aerosol device based on a calcium salt and a fixing polymer
WO2013190078A2 (en) 2012-06-21 2013-12-27 L'oreal Cosmetic composition comprising hydrophobic silica aerogel particles and a fixing polymer
WO2014023675A1 (en) 2012-08-07 2014-02-13 L'oreal Cosmetic composition comprising at least one particular fixing polymer and at least one particular thickening polymer
WO2014023782A1 (en) 2012-08-07 2014-02-13 L'oreal Two-phase cosmetic composition and pump bottle containing it
DE202013011676U1 (en) 2012-11-09 2014-02-14 L'oreal Composition containing a dicarbonyl compound
EP2712609A1 (en) 2012-09-26 2014-04-02 Bayer MaterialScience AG Polyurethane-urea compound for skin and hair cosmetics
US8710152B2 (en) 2006-07-27 2014-04-29 L'oreal Block polymers and their process of preparation
US8728451B2 (en) 2004-03-25 2014-05-20 L'oreal Styling composition comprising, in a predominantly aqueous medium, a pseudo-block polymer, processes employing same and uses thereof
WO2014091012A1 (en) 2012-12-14 2014-06-19 L'oreal Cosmetic composition in powder form comprising a (meth)acrylic thickening polymer, a fixing polymer and water-insoluble particles
WO2014111579A2 (en) 2013-01-18 2014-07-24 L'oreal Hair shaping process in which is applied a particular styling composition, which is rinsed out
WO2014124977A1 (en) 2013-02-15 2014-08-21 L'oreal Cosmetic composition comprising a vinylformamide / vinylformamine copolymer, a cellulose-based thickening polymer and an amphoteric or zwitterionic surfactant
US8821841B2 (en) 2005-08-11 2014-09-02 Basf Se Copolymers for cosmetic applications
WO2014188007A1 (en) 2013-05-24 2014-11-27 L'oreal Cosmetic composition comprising an aqueous phase and a fatty phase that are visually distinct
WO2015063122A1 (en) 2013-10-30 2015-05-07 L'oreal Expanded dyeing composition comprising an inert gas, an oxidation dye and an oxyalkylenated nonionic surfactant
WO2015075280A1 (en) 2014-08-05 2015-05-28 Bayer Materialscience Ag Polyurethane urea solutions for hair-styling compositions
EP3020453A1 (en) 2014-11-17 2016-05-18 Covestro Deutschland AG Polyurethane ureas for aqueous nail varnish compositions
EP3020454A1 (en) 2014-11-17 2016-05-18 Covestro Deutschland AG Polyurethane urea substances for hair styling compositions
WO2016096654A1 (en) 2014-12-17 2016-06-23 L'oreal Dye composition comprising a para-phenylenediamine oxidation base and an amphoteric or cationic polymer in a medium rich in fatty substances
US9456978B2 (en) 2012-12-28 2016-10-04 L'oreal Cosmetic compositions containing a silicone-organic polymer hybrid compound
US9649261B2 (en) 2004-10-05 2017-05-16 L'oreal Method of applying makeup to a surface and a kit for implementing such a method
WO2017108565A1 (en) 2015-12-21 2017-06-29 L'oreal Composition comprising a vinylformamide/vinylamine copolymer, a fixing polymer and a particular combination of surfactants
WO2017117522A1 (en) 2015-12-31 2017-07-06 L'oreal Compositions containing polycarbodiimides and amino compounds for treating keratinous substrates
WO2017117552A1 (en) 2015-12-31 2017-07-06 L'oreal Compositions containing polycarbodiimides for treating keratinous substrates
WO2017117543A1 (en) 2015-12-31 2017-07-06 L'oreal Compositions containing polycarbodiimides and latex polymers for treating keratinous substrates
WO2018115002A1 (en) 2016-12-21 2018-06-28 L'oreal Hair composition comprising a guanidine salt, an alkanolamine and ammonium hydroxide and cationic and/or amphoteric polymers
EP3384897A1 (en) 2017-04-03 2018-10-10 Covestro Deutschland AG Cosmetic compositions for hair with special carbodiimides

Cited By (334)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4066589A (en) * 1975-05-23 1978-01-03 Minnesota Mining And Manufacturing Company Solvent repellent complexes
US4191674A (en) * 1975-07-25 1980-03-04 Ppg Industries, Inc. Zwitterion-containing compositions
US4075131A (en) * 1976-09-17 1978-02-21 Minnesota Mining And Manufacturing Company Conditioning shampoo
US4130524A (en) * 1977-12-01 1978-12-19 Northern Instruments Corporation Corrosion inhibiting compositions
US4131583A (en) * 1977-12-01 1978-12-26 Northern Instruments Corporation Corrosion inhibiting compositions
US4996059A (en) * 1979-11-28 1991-02-26 L'oreal Composition for the treatment of keratin fibers, based on amphoteric polymer and cationic polymer
US5958392A (en) * 1979-11-28 1999-09-28 L'oreal Composition for the treatment of keratin fibers, based on amphoteric polymers and cationic polymers
US4842849A (en) * 1981-05-08 1989-06-27 L'oreal Composition intended for the treatment of keratin fibres, based on a cationic polymer and an anionic polymer containing vinylsulphonic groups
US4622378A (en) * 1982-12-23 1986-11-11 The Procter & Gamble Company Zwitterionic polymers having clay soil removal/anti-redeposition properties useful in detergent compositions
EP0112592A2 (en) * 1982-12-23 1984-07-04 THE PROCTER & GAMBLE COMPANY Zwitterionic polymers having clay soil removal/anti-redeposition properties useful in detergent compositions
EP0112592A3 (en) * 1982-12-23 1987-09-02 The Procter & Gamble Company Zwitterionic polymers having clay soil removal/anti-redezwitterionic polymers having clay soil removal/anti-redeposition properties useful in detergent compositions position properties useful in detergent compositions
US4725282A (en) * 1984-06-27 1988-02-16 Wella Aktiengesellschaft Oxidative hair dyeing composition based upon a carrier of low viscosity
US5153289A (en) * 1985-01-02 1992-10-06 Exxon Research And Engineering Company Betaine copolymers-viscosifiers for water and brine
US4898725A (en) * 1985-02-02 1990-02-06 Henkel Kommanditgesellschaft Auf Aktien Preparations for washing or rinsing hair containing di- or tri- carboxylic acids
US4994088A (en) * 1985-09-30 1991-02-19 Kao Corporation Hair cosmetic composition
US4814101A (en) * 1987-03-16 1989-03-21 Henkel Kommanditgesellschaft Auf Aktien Zwitterionic polymers and their use in hair treatment preparations
US4996045A (en) * 1988-11-16 1991-02-26 National Starch And Chemical Investment Holding Corporation Hair fixative compositions containing alpha-aminomethylene phosphonate betaines
US5415856A (en) * 1990-05-08 1995-05-16 Preemptive Advertising Inc. Hair treatment compositions containing disaccharides
US5858341A (en) * 1994-01-11 1999-01-12 L'oreal Detergent cosmetic compositions for hair use and use thereof
US5916549A (en) * 1994-01-11 1999-06-29 L'oreal, S.A. Detergent cosmetic compositions for hair use and the use thereof
US6051213A (en) * 1994-01-11 2000-04-18 L'oreal Detergent cosmetic compositions for hair use and use thereof
US5652296A (en) * 1994-08-19 1997-07-29 Minnesota Mining And Manufacturing Company Water-based adhesives
US6365697B1 (en) 1995-11-06 2002-04-02 Basf Aktiengesellschaft Water-soluble or water-dispersible polyurethanes with terminal acid groups, the production and the use thereof
US20020085988A1 (en) * 1996-11-04 2002-07-04 Takanori Nambu Hair styling composition
US6346234B1 (en) 1997-03-04 2002-02-12 L'oreal, S.A. Hair styling composition capable of being remodelled with a Tg of less than +10 °C
US6803047B1 (en) 1997-03-14 2004-10-12 L'oreal Vaporizable gelled composition
US6555100B1 (en) 1997-12-31 2003-04-29 L'ORéAL S.A. Compositions for treating keratinous materials containing a combination of a zwitterion polymer and a water insoluble non-volatile silicon
US6277386B1 (en) 1998-02-25 2001-08-21 Basf Aktiengesellschaft Cosmetic
WO2000001746A1 (en) * 1998-07-06 2000-01-13 Institut Francais Du Petrole Zwitterion derivatives and application to aqueous suspension properties
US6410671B1 (en) * 1998-07-06 2002-06-25 Institute Francais Du Petrole Zwitterion derivative and application to aqueous suspension properties
FR2780729A1 (en) * 1998-07-06 2000-01-07 Inst Francais Du Petrole Zwitterionic derivatives and the application properties of aqueous suspensions
US6932964B1 (en) 1998-08-26 2005-08-23 Basf Aktiengesellschaft Cosmetic composition with water-soluble or water-dispersible polymers
US20100172857A1 (en) * 1998-11-03 2010-07-08 L'oreal Aerosol device containing a condensation polymer comprising at least a polyurethane and/or polyurea unit
US6391292B1 (en) 1998-11-26 2002-05-21 L'ORéAL S.A. Hairstyling composition comprising a polymer with particular characteristics and an ionic film forming polymer
US6260556B1 (en) 1999-01-29 2001-07-17 L'oreal Anhydrous composition for bleaching keratin fibers
US6800276B2 (en) 1999-03-12 2004-10-05 Basf Aktiengesellschaft Polyureas and water-soluble or water-dispersible polymeric salts
US6410004B1 (en) 1999-03-12 2002-06-25 Basf Aktiengesellschaft Polyureas and water-soluble or water-dispersible polymeric salts
US6399050B1 (en) 1999-06-18 2002-06-04 L'oreal S.A. Hair cosmetic composition in the form of a water-in-silicone emulsion comprising at least one fixing polymer
US6506372B1 (en) 1999-06-25 2003-01-14 L'oreal S.A. Cosmetic compositions containing an amphoteric polymer and a fixing/conditioner polymer, and their uses
US6340664B1 (en) 1999-08-26 2002-01-22 Henkel Kommanditgesellschaft Auf Aktien (Kgaa) Laundry detergent or cleaning product tablets with partial coating
US6541032B1 (en) 1999-10-13 2003-04-01 Basf Aktiengesellschaft Use of finely divided dye-containing polymers PD as color-imparting constituent in cosmetic compositions
US6916344B1 (en) 1999-12-08 2005-07-12 L'oreal S.A. Direct dyeing composition for keratinic fibers containing a thickening polymer with an ether plastic skeleton
US6984250B1 (en) 1999-12-08 2006-01-10 L'oreal Composition, method, and kit for the bleaching or permanent reshaping of keratin fibers, comprising at least one thickening polymer with an aminoplast-ether skeleton
US6800098B1 (en) 1999-12-08 2004-10-05 L'oreal, S.A. Oxidation dye composition for keratinic fibres containing a thickening polymer with an ether plastic skeleton
US6444197B2 (en) 1999-12-13 2002-09-03 L'oreal S.A. Bleaching composition for keratin fibers, comprising a combination of two polyurethane polyethers
US7771492B2 (en) 1999-12-30 2010-08-10 L'oreal S.A. Compositions for oxidation dyeing keratin fibers comprising at least one thickening polymer comprising at least one fatty chain and at least one fatty alcohol chosen from monoglycerolated fatty alcohols and polyglycerolated fatty alcohols
US6436151B2 (en) 1999-12-30 2002-08-20 L'oreal S.A. Compositions for oxidation dyeing keratin fibers comprising at least one oxidation dye, at least one thickening polymer comprising at least one fatty chain, and at least one fatty alcohol comprising more than twenty carbon atoms and uses thereof
US6695887B2 (en) 1999-12-30 2004-02-24 L'oreal S.A. Compositions for oxidation dyeing keratin fibers comprising at least one fatty alcohol having more than twenty carbon atoms and at least one oxyalkylenated nonionic surfactant with an hlb greater than 5
US6635262B2 (en) 2000-03-14 2003-10-21 L'oreal S.A. Roll-on applicator comprising a hair composition
US7141079B2 (en) 2000-04-12 2006-11-28 L′Oreal Oxidation dyeing composition for keratinous fibers and dyeing method using same
US20040060125A1 (en) * 2000-04-12 2004-04-01 Marie-Pascale Audouset Oxidation dyeing composition for keratinous fibres comprising a 3,5-diamino-pyridine derivative and a particular thickening polymer
US20030131424A1 (en) * 2000-04-12 2003-07-17 Marie-Pascale Audousset Oxidation dyeing composition for ketatinous fibres comprising a 3,5-diamino-pyridine derivative and a cationic or amphoteric polymer
US7335348B2 (en) 2000-07-18 2008-02-26 L'oreal Hairstyling composition which makes possible remodelling of the hairstyle and process for remodelling the hairstyle using such a composition
US6602303B2 (en) 2000-08-11 2003-08-05 L'oreal S.A. Composition for the oxidation dyeing of keratinous fibers comprising at least one oxidation dye and at least one cationic amphiphilic polymer, and dyeing methods
US20040136935A1 (en) * 2000-08-16 2004-07-15 L'oreal S.A. Hair styling composition comprising encapsulated adhesives
US6548051B2 (en) 2000-08-16 2003-04-15 L′Oreal Hair styling composition comprising adhesive particles
US8703109B2 (en) 2000-08-25 2014-04-22 L'oreal Protection of keratinous fibers using ceramides and/or glycoceramides
US20090081148A1 (en) * 2000-08-25 2009-03-26 L'oreal S.A. Protection of keratinous fibers using ceramides and/or glycoceramides
US20040071652A1 (en) * 2000-10-27 2004-04-15 Christine Dupuis Foam-like cosmetic hair composition comprising at least a aminoplast-ether skeleton thickening polymer
US20020086040A1 (en) * 2000-10-30 2002-07-04 Christine Dupuis Cosmetic composition which provides good hold properties and which comprises a copolymer with an acid unit
US20070272265A1 (en) * 2000-10-30 2007-11-29 L'oreal Cosmetic composition which provides good hold properties and which comprises a copolymer with an acid unit
US20040025266A1 (en) * 2000-11-08 2004-02-12 Francois Cottard Oxidation dyeing composition for karatinous fibres comprising a cationic associative polyurethane
US7066965B2 (en) 2000-11-08 2006-06-27 L'oreal S.A. Bleaching composition for keratinous fibers comprising an associate polyurethane
US20040034947A1 (en) * 2000-11-08 2004-02-26 Frederic Legrand Bleachng composition for keratinous fibres comprising an associate polyurethane
US7077869B2 (en) 2000-11-08 2006-07-18 L'oreal S.A. Composition for bleaching or permanent waving of keratinous fibers comprising a cationic associative polyurethane
US7101405B2 (en) 2000-11-08 2006-09-05 L'oreal S.A. Oxidation dyeing composition for karatinous fibers comprising a cationic associative polyurethane
US20040019981A1 (en) * 2000-11-08 2004-02-05 Francois Cottard Direct dyeing composition for keratinous fibres comprising a cationic associative polyurethane
US7108726B2 (en) 2000-11-08 2006-09-19 L'oreal S.A. Direct dyeing composition for keratinous fibres comprising a cationic associative polyurethane
US20040034946A1 (en) * 2000-11-08 2004-02-26 Frederic Legrand Composition for bleaching or permanent waving of keratinous fibers comprising a cationic associative polyurethane
US7364594B2 (en) 2000-12-04 2008-04-29 L'oreal S.A. Dyeing composition for keratinous fibres comprising an associative polymer and a polymer with acrylamide units, dialkyldiallylammonium halide, and vinylic carboxylic acid
US7431740B2 (en) 2000-12-04 2008-10-07 L'oreal, S.A. Oxidation dyeing composition for keratinous fibers comprising an associative polymer and a pearling agent
US20040049861A1 (en) * 2000-12-04 2004-03-18 Francois Cottard Oxidation dyeing composition for keratinous fibres comprising an associative polymer and a pearling agent
US20040060126A1 (en) * 2000-12-04 2004-04-01 Francois Cottard Dyeing composition for keratinous fibres comprising an associative polymer and a polymer with acrylamide units, dialkyldiallylammonium halide, and vinylic carboxylic acid
US20040014631A1 (en) * 2000-12-23 2004-01-22 Henriette Weber Washing and cleaning agent coated moulding body
US6812200B2 (en) 2000-12-23 2004-11-02 Henkel Kommanditgesellschaft Auf Aktien Process for coating detergent tablets
US20020192165A1 (en) * 2001-03-13 2002-12-19 L'oreal Aerosol compositions comprising a polysaccharide grafted with a polysiloxane
US20020197226A1 (en) * 2001-03-13 2002-12-26 Franck Giroud Composition comprising a polysaccharide grafted with a polysiloxane, and non-cellulosic, non-fixing thickener
US20020193265A1 (en) * 2001-03-30 2002-12-19 Beatrice Perron Detergent cosmetic compositions containing an anionic surfactant derived from amino acids and salts thereof and a soluble conditioning agent and uses thereof
US20040093675A1 (en) * 2001-04-02 2004-05-20 Laurent Vidal Dyeing composition for dyeing kerationou fibres comprising a cationic azo-dye
US20050201960A1 (en) * 2001-05-16 2005-09-15 L'oreal S.A. Pulverulent composition for bleaching human keratin fibers
US6919073B2 (en) 2001-05-16 2005-07-19 L'oreal S.A. Pulverulent composition for bleaching human keratin fibers
US7189266B2 (en) 2001-06-12 2007-03-13 L'oreal, S.A. Dyeing composition for human keratinous fibres with direct dyes and dicationic compounds
US20040237213A1 (en) * 2001-06-12 2004-12-02 Gregory Plos Dyeing composition for human keratinous fibres with direct dyes and dicationic compounds
US20030023782A1 (en) * 2001-07-26 2003-01-30 International Business Machines Corp. Microprocessor system bus protocol providing a fully pipelined input/output DMA write mechanism
US20060248664A1 (en) * 2001-07-27 2006-11-09 Patricia Vuarier Composition for the oxidation dyeing of keratin fibres, comprising at least one fatty alcohol chosen from mono- and polyglycerolated fatty alcohols and a particular polyol
US7402180B2 (en) 2001-07-27 2008-07-22 L'ORéAL S.A. Composition for the oxidation dyeing of keratin fibres, comprising at least one fatty alcohol chosen from mono- and polyglycerolated fatty alcohols and a particular polyol
US20030074747A1 (en) * 2001-07-27 2003-04-24 Patricia Vuarier Composition for the oxidation dyeing of keratin fibres, comprising at least one fatty alcohol chosen from mono- and polyglycerolated fatty alcohols and a particular polyol
US20040001796A9 (en) * 2001-09-11 2004-01-01 Mireille Maubru Cosmetic compositions containing a methacrylic acid copolymer, a dimethicone, a nacreous agent and a cationic polymer, and uses thereof
US20030103929A1 (en) * 2001-09-11 2003-06-05 Mireille Maubru Cosmetic compositions containing a methacrylic acid copolymer, a silicone and a cationic polymer, and uses thereof
US7258852B2 (en) 2001-09-11 2007-08-21 L'oreal S.A. Cosmetic compositions containing a methacrylic acid copolymer and an oil, and uses thereof
US20030103926A1 (en) * 2001-09-11 2003-06-05 Mireille Maubru Cosmetic compositions containing a methacrylic acid copolymer, a dimethicone, a nacreous agent and a cationic polymer, and uses thereof
US20030108503A1 (en) * 2001-09-11 2003-06-12 Mireille Maubru Cosmetic compositions containing a methacrylic acid copolymer, a silicone and a cationic polymer, and uses thereof
US7504094B2 (en) 2001-11-08 2009-03-17 L'oreal, S.A. Cosmetic compositions containing a particular aminosilicone and a thickener, and uses thereof
US7223385B2 (en) 2001-11-08 2007-05-29 L'oreal S.A. Cosmetic compositions containing a particular aminosilicone and a conditioner, and uses thereof
US7220408B2 (en) 2001-11-08 2007-05-22 L'oreal, S.A. Cosmetic compositions containing a particular aminosilicone and a thickener, and uses thereof
US7510705B2 (en) 2001-11-08 2009-03-31 L'oreal, S.A. Process for permanently reshaping the hair using particular aminosilicones
US20030157049A1 (en) * 2001-11-08 2003-08-21 Jonathan Gawtrey Cosmetic compositions containing a particular aminosilicone and a conditioner, and uses thereof
US7128902B2 (en) 2001-11-08 2006-10-31 L'oreal, Sa Reducing composition for treating keratin fibres, comprising a particular aminosilicone
US20030152541A1 (en) * 2001-11-08 2003-08-14 Frederic Legrand Oxidizing composition for treating keratin fibres, comprising a particular aminosilicone
US20030152542A1 (en) * 2001-11-08 2003-08-14 Sandrine Decoster Cosmetic compositions containing a particular aminosilicone and a thickener, and uses thereof
US20030152543A1 (en) * 2001-11-08 2003-08-14 Frederic Legrand Oxidizing composition for treating keratin fibres, comprising a particular aminosilicone
US20030129155A1 (en) * 2001-11-08 2003-07-10 Priscille Devin-Baudoin Use of particular aminosilicones as a pre-or post-treatment of processes for bleaching keratin fibres
US20030147827A1 (en) * 2001-11-08 2003-08-07 Sandrine Decoster Cosmetic compositions containing a particular aminosilicone and a thickener, and uses thereof
US7138109B2 (en) 2001-11-08 2006-11-21 L'oreal, Sa Use of particular aminosilicones as a pre-or post-treatment of processes for bleaching keratin fibres
US7135167B2 (en) 2001-11-08 2006-11-14 L'oreal, Sa Oxidizing composition for treating keratin fibers, comprising a particular aminosilicone
US20030147842A1 (en) * 2001-11-08 2003-08-07 Serge Restle Cosmetic compositions containing a particular aminosilicone and a conditioner, and uses thereof
US20030147841A1 (en) * 2001-11-08 2003-08-07 Frederic Legrand Reducing composition for treating keratin fibres, comprising a particular aminosilicone
US20050238599A1 (en) * 2001-11-08 2005-10-27 L'oreal S.A. Process for permanently reshaping the hair using particular aminosilicones
US20030126692A1 (en) * 2001-11-08 2003-07-10 Priscille Devin-Baudoin Use of particular aminosilicones as a pre-treatment of processes for coloring keratin fibers with direct dyes or with oxidation dyes
US20030118537A1 (en) * 2001-11-08 2003-06-26 Priscille Devin-Baudoin Process for permanently reshaping the hair using particular aminosilicones
US20070202065A1 (en) * 2001-11-08 2007-08-30 L'oreal S.A. Process for permanently reshaping the hair using particular aminosilicones
US20070154434A1 (en) * 2001-11-08 2007-07-05 L'oreal S.A. Cosmetic compositions containing a particular aminosilicone and a thickener, and uses thereof
US7485289B2 (en) 2001-11-08 2009-02-03 L'oreal, S.A. Cosmetic compositions containing a particular aminosilicone and a conditioner, and uses thereof
US20030147840A1 (en) * 2001-11-08 2003-08-07 Frederic Legrand Reducing composition for treating keratin fibres, comprising a particular aminosilicone
US20070154441A1 (en) * 2001-11-08 2007-07-05 L'oreal S.A. Cosmetic compositions containing a particular aminosilicone and a conditioner, and uses thereof
US20070160557A1 (en) * 2001-11-15 2007-07-12 L'oreal S.A. Preparation of polysaccharide betainate type compounds, compounds obtained, their use and compositions comprising them
US20030147818A1 (en) * 2001-11-15 2003-08-07 Claude Dubief Preparation of polysaccharide betainate type compounds, compounds obtained, their use and compositions comprising them
US7211268B2 (en) 2001-11-15 2007-05-01 L'oreal S.A. Preparation of polysaccharide betainate type compounds, compounds obtained, their use and compositions comprising them
US20040102528A1 (en) * 2001-12-07 2004-05-27 Brian Walchuk Anionic copolymers prepared in an inverse emulsion matrix and their use in preparing cellulosic fiber compositions
US7250448B2 (en) * 2001-12-07 2007-07-31 Hercules Incorporated Anionic copolymers prepared in an inverse emulsion matrix and their use in preparing cellulosic fiber compositions
US20050125912A1 (en) * 2001-12-21 2005-06-16 Patricia Desenne Dyeing composition for keratinous fibers comprising an oxyethylene rapeseed fatty acid amide
US7153331B2 (en) 2001-12-21 2006-12-26 L'oreal S.A. Dyeing composition for keratinous fibers comprising an oxyethylene rapeseed fatty acid amide
US20040208843A1 (en) * 2002-09-24 2004-10-21 Gabin Vic Cosmetic composition comprising an exogenous ligand-receptor system adsorbed or covalently attached to keratin materials, and hair treatment using this composition or constituent elements thereof
US20060147402A1 (en) * 2002-09-26 2006-07-06 Xavier Blin Composition comprising a sequenced polymer and a gelling agent
US7803877B2 (en) 2002-09-26 2010-09-28 L'oreal S.A. Block polymers and cosmetic compositions and processes comprising them
US7875265B2 (en) 2002-09-26 2011-01-25 L'oreal Cosmetic composition comprising a sequenced polymer and a plasticizer
US7915347B2 (en) 2002-09-26 2011-03-29 L'oreal S.A. Block polymers and cosmetic compositions and processes comprising them
US7932324B2 (en) 2002-09-26 2011-04-26 L'oreal Block polymers and cosmetic compositions and processes comprising them
US20080014158A1 (en) * 2002-09-26 2008-01-17 L'oreal Novel Block Polymers and Cosmetic Compositions and Processes Comprising Them
US8992903B2 (en) 2002-09-26 2015-03-31 L'oreal Composition comprising at least one block polymer and at least one gelling agent
US9017704B2 (en) 2002-09-26 2015-04-28 L'oreal Composition comprising a block polymer and a film-forming agent
US20080014234A1 (en) * 2002-09-26 2008-01-17 L'oreal Novel Block Polymers and Cosmetic Compositions and Processes Comprising Them
US8007772B2 (en) 2002-10-02 2011-08-30 L'oreal S.A. Compositions to be applied to the skin and the integuments
US20060039876A1 (en) * 2002-10-02 2006-02-23 Christophe Dumousseaux Compositions to be applied to the skin and the integuments
US20060041054A1 (en) * 2002-10-02 2006-02-23 Christophe Dumousseaux Compositions to be applied to the skin and the integuments
US20040133995A1 (en) * 2002-10-21 2004-07-15 Francois Cottard Oxidation dyeing composition for keratin fibers comprising a cationic poly(vinyllactam) and at least one C10-C14 fatty acid, methods and devices for oxidation dyeing
US7323015B2 (en) 2002-10-21 2008-01-29 L'oreal S.A. Oxidation dyeing composition for keratin fibers comprising a cationic poly(vinyllactam) and at least One C10-C14 fatty alcohol, methods and devices for oxidation dyeing
US7147672B2 (en) 2002-10-21 2006-12-12 L'oreal S.A. Oxidation dyeing composition for keratin fibers comprising a cationic poly(vinyllactam) and at least one C10-C14 fatty acid, methods and devices for oxidation dyeing
US20040133994A1 (en) * 2002-10-21 2004-07-15 Francois Cottard Oxidation dyeing composition for keratin fibers comprising a cationic poly(vinyllactam) and at least One C10-C14 fatty alcohol, methods and devices for oxidation dyeing
WO2004043330A2 (en) 2002-11-07 2004-05-27 L'oreal Cosmetic composition comprising at least one specific cyclic carbonate which may be polymerised
US20080104775A1 (en) * 2002-12-06 2008-05-08 L,Oreal S.A. Oxidation dye composition for keratin fibers, comprising at least one oxidation dye, at least one associative polymer, at least one nonionic cellulose-based compound not comprising a C8-C30 fatty chain, and at least one cationic polymer with a charge density of greater than 1 MEQ/G and not comprising a C8-C30 fatty chain
US7329287B2 (en) 2002-12-06 2008-02-12 L'oreal S.A. Oxidation dye composition for keratin fibers, comprising at least one oxidation dye, at least one associative polymer, at least one nonionic cellulose-based compound not comprising a C8-C30 fatty chain, and at least one cationic polymer with a charge density of greater than 1 meq/g and not comprising a C8-C30 fatty chain
US7396874B2 (en) 2002-12-06 2008-07-08 Hercules Incorporated Cationic or amphoteric copolymers prepared in an inverse emulsion matrix and their use in preparing cellulosic fiber compositions
US20040143039A1 (en) * 2002-12-06 2004-07-22 Martha Hollomon Cationic or amphoteric copolymers prepared in an inverse emulsion matrix and their use in preparing cellulosic fiber compositions
US20040163186A1 (en) * 2002-12-06 2004-08-26 Frederic Simonet Oxidation dye composition for keratin fibers, comprising at least one oxidation dye, at least one associative polymer, at least one nonionic cellulose-based compound not comprising a C8-C30 fatty chain, and at least one cationic polymer with a charge density of greater than 1 meq/g and not comprising a C8-C30 fatty chain
US20040205902A1 (en) * 2002-12-06 2004-10-21 Francois Cottard Composition for the oxidation dyeing of keratin fibers, comprising at least one non-oxyalkenylated fatty alcohol, at least one oxidation dye, at least one associative polymer, and at least one amide of an alkanolamine and a C14-C30 fatty acid
US7326256B2 (en) 2002-12-06 2008-02-05 L'ORéAL S.A. Composition for the oxidation dyeing of keratin fibers, comprising at least one non-oxyalkenylated fatty alcohol, at least one oxidation dye, at least one associative polymer, and at least one amide of an alkanolamine and a C14-C30 fatty acid
US7771491B2 (en) 2002-12-06 2010-08-10 L'oreal S.A. Oxidation dye composition for keratin fibers, comprising at least one oxidation dye, at least one associative polymer, at least one nonionic cellulose-based compound not comprising a C8-C30 fatty chain, and at least one cationic polymer with a charge density of greater than 1 meq/g and not comprising a C8-C30 fatty chain
US20040122807A1 (en) * 2002-12-24 2004-06-24 Hamilton Darin E. Methods and systems for performing search interpretation
US7217298B2 (en) 2003-01-16 2007-05-15 L'oreal S.A. Ready-to-use bleaching compositions, preparation process and bleaching process
US20040235700A1 (en) * 2003-01-16 2004-11-25 Frederic Legrand Ready-to-use bleaching compositions, preparation process and bleaching process
US7226486B2 (en) 2003-01-16 2007-06-05 L'oreal S.A Ready-to-use bleaching compositions, preparation process and bleaching process
US20040226110A1 (en) * 2003-01-16 2004-11-18 Frederic Legrand Ready-to-use bleaching compositions, preparation process and bleaching process
US20050011017A1 (en) * 2003-03-25 2005-01-20 L'oreal S.A. Oxidizing composition comprising hydroxycarboxylic acids and salts thereof as complexing agents for dyeing, bleaching or permanently reshaping keratin fibres
US7303588B2 (en) 2003-03-25 2007-12-04 L'oreal S.A. Composition for dyeing keratinous fibers, comprising at least one polycarboxylic acid or a salt, ready-to-use composition comprising it, implementation process and device
US20050039270A1 (en) * 2003-03-25 2005-02-24 L'oreal S.A. Use of polycarboxylic acids and salts thereof as complexing agents in oxidizing compositions for dyeing, bleaching or permanently reshaping keratin fibres
US20040221401A1 (en) * 2003-03-25 2004-11-11 L'oreal S.A. Composition for dyeing keratinous fibers, comprising a hydroxycarboxylic acid or a salt, ready-to-use composition comprising it, implementation process and device
US7267696B2 (en) 2003-03-25 2007-09-11 L'oreal S.A. Composition for dyeing keratinous fibers, comprising a hydroxycarboxylic acid or a salt, ready-to-use composition comprising it, implementation process and device
US20040237217A1 (en) * 2003-03-25 2004-12-02 L'oreal S.A. Composition for dyeing keratinous fibers, comprising at least one polycarboxylic acid or a salt, ready-to-use composition comprising it, implementation process and device
US20050158265A1 (en) * 2003-06-17 2005-07-21 Sabine Vrignaud Cosmetic hair composition comprising tridecyl trimellitate and at least one fixing polymer
US20050136027A1 (en) * 2003-06-17 2005-06-23 Sabine Vrignaud Cosmetic hair composition based on isoeicosane and on a silicone fixing polyurethane
US20050063933A1 (en) * 2003-06-17 2005-03-24 Sabine Vrignaud Cosmetic hair composition comprising isoeicosane and at least one nonsilicone fixing polymer
US20050208005A1 (en) * 2003-08-11 2005-09-22 Franck Giroud Cosmetic composition comprising particles having a core-shell structure
US20050186151A1 (en) * 2003-08-11 2005-08-25 Franck Giroud Cosmetic composition comprising stabilized and optionally coated metal particles
US8119110B2 (en) 2003-09-26 2012-02-21 L'oreal S.A. Cosmetic composition comprising a block polymer and a non-volatile silicone oil
US20050118126A1 (en) * 2003-10-24 2005-06-02 Isabelle Rollat Cosmetic hair composition comprising at least one fixing polymer and at least one compound capable of swelling by the action of heat
US8399001B2 (en) 2003-11-18 2013-03-19 L'oreal Cosmetic composition comprising at least one gellan gum or derivative thereof, at least one monovalent salt, and at least one suspension compound, processes using this composition, and uses thereof
US8246940B2 (en) 2003-11-18 2012-08-21 L'oreal S.A. Cosmetic composition comprising gellan gum or a derivative thereof, a fixing polymer, a monovalent salt and an alcohol, process of using the same
US20050169869A1 (en) * 2003-11-18 2005-08-04 L'oreal Cosmetic composition comprising at least one gellan gum or derivative thereof, at least one monovalent salt, and at least one suspension compound, processes using this composition, and uses thereof
US20050186165A1 (en) * 2003-11-18 2005-08-25 Estelle Mathonneau Cosmetic composition based on a cosmetically active compound and a gel comprising at least one crosslinked network of crosslinked polymer particles
US20050169873A1 (en) * 2003-12-19 2005-08-04 Isabelle Rollat Styling composition comprising, in a predominantly aqueous medium, an elastic cationic polyurethane, processes using it and uses thereof
US20050175569A1 (en) * 2004-01-07 2005-08-11 Geraldine Fack Cosmetic compositions comprising a cation, a drawing polymer and a thickener, and cosmetic treatment processes
US20050188475A1 (en) * 2004-01-07 2005-09-01 Alain Lagrange Dyeing composition comprising at least one fluorindine compound for the dyeing of keratinic fibers, dyeing process comprising the composition and compound
US7294152B2 (en) 2004-01-07 2007-11-13 L'oreal S.A. Dyeing composition comprising at least one fluorindine compound for the dyeing of keratinic fibers, dyeing process comprising the composition and compound
US20050232885A1 (en) * 2004-01-07 2005-10-20 L'oreal Detergent cosmetic compositions comprising at least one surfactant, at least one drawing polymer and at least one nonsilicone conditioner, and use thereof
US20070141006A1 (en) * 2004-03-17 2007-06-21 Aude Livoreil Cosmetic compositions containing modified polyamines and the uses thereof
US20050220728A1 (en) * 2004-03-22 2005-10-06 Mohamed Kanji Cosmetic composition comprising a polyglycerolated silicone elastomer
US7378103B2 (en) 2004-03-22 2008-05-27 L'oreal Cosmetic composition comprising a polyglycerolated silicone elastomer
US8728451B2 (en) 2004-03-25 2014-05-20 L'oreal Styling composition comprising, in a predominantly aqueous medium, a pseudo-block polymer, processes employing same and uses thereof
US20050220723A1 (en) * 2004-03-25 2005-10-06 Katarina Benabdillah Aerosol device comprising a propellant and a styling composition comprising, in a predominantly aqueous medium, a pseudo-block polymer and an additional fixing polymer; processes therefor and uses thereof
US7976831B2 (en) 2004-04-02 2011-07-12 L'oreal S.A. Method for treating hair fibers
US20050232884A1 (en) * 2004-04-02 2005-10-20 Thomas Fondin Method for treating hair fibers
US9675822B2 (en) 2004-04-02 2017-06-13 L'oreal Method for treating hair fibers
US20050232883A1 (en) * 2004-04-02 2005-10-20 Thomas Fondin Method for treating hair fibers
US7981404B2 (en) 2004-04-08 2011-07-19 L'oreal S.A. Composition for application to the skin, to the lips, to the nails, and/or to hair
US20080044366A1 (en) * 2004-04-08 2008-02-21 L'oreal S.A. Compositions for application to the skin, to the lips, to the nails, and/or to hair
US20050257335A1 (en) * 2004-04-08 2005-11-24 Christophe Dumousseaux Composition for application to the skin, to the lips, to the nails, and/or to hair
US20050287103A1 (en) * 2004-06-08 2005-12-29 Vanina Filippi Cosmetic composition comprising at least one ester and at least one film-forming polymer
US20060013791A1 (en) * 2004-07-16 2006-01-19 L'oreal Cosmetic composition comprising a defined silicone polymer and a film former
US20060188461A1 (en) * 2004-07-29 2006-08-24 Cecile Bebot Linear sulfonic polyester as a water-resistant hair fixing agent
US20060024261A1 (en) * 2004-07-29 2006-02-02 Bebot Cecile Cosmetic compositions comprising a linear sulfonic polyester and a polyurethane, processes using these compositions and uses thereof
US20060024260A1 (en) * 2004-07-29 2006-02-02 Cecile Bebot Cosmetic composition comprising a water-dispersible linear sulphonic polyester and a modified guar gum, methods employing this composition and uses
US20060024259A1 (en) * 2004-07-29 2006-02-02 Sabine Vrignaud Cosmetic composition comprising, in a non-fatty medium, at least one linear sulfonic polyester and at least one nonionic thickening polymer, processes using this composition and uses thereof
US20060024255A1 (en) * 2004-07-30 2006-02-02 L'oréal Hair styling compositions comprising adhesive particles and non-adhesive particles
EP1627664A1 (en) 2004-07-30 2006-02-22 L'oreal Hair styling composition comprising adhesive particles and non-adhesive particles
EP1634580A1 (en) 2004-09-09 2006-03-15 L'oreal Hairstyling composition comprising a combination of a hydrophilic highly porous polymeric material and a fixing polymer
US20060057094A1 (en) * 2004-09-09 2006-03-16 Estelle Mathonneau Hair styling composition comprising at least one hydrophilic polymeric high porosity material and at least one fixing polymer
US20060062748A1 (en) * 2004-09-10 2006-03-23 Estelle Mathonneau Cosmetic composition comprising at least one cage-like structure compound
EP1634620A1 (en) 2004-09-10 2006-03-15 L'oreal Kosmetische Zusammensetzung enthaltend Käfigstruktur besitzenden Verbindugen
US9649261B2 (en) 2004-10-05 2017-05-16 L'oreal Method of applying makeup to a surface and a kit for implementing such a method
US9609934B2 (en) 2004-10-05 2017-04-04 L'oreal Method of applying makeup by means of a magnetic composition including at least one interferential pigment
US20080105272A1 (en) * 2004-10-05 2008-05-08 L'oreal Method Of Applying Makeup By Means Of A Magnetic Composition Including At Least One Interferential Pigment
US20090130037A1 (en) * 2004-10-05 2009-05-21 L'oreal Method of Applying Makeup to a Surface and a Kit for Implementing such a Method
US20080127990A1 (en) * 2004-10-05 2008-06-05 L'oreal Method of Applying Makeup to a Surface by Means of a Magnetic Composition Including Reflective Particles Having Metallic Luster
US20060088493A1 (en) * 2004-10-13 2006-04-27 Gabin Vic Composition and process for the cosmetic treatment of keratin materials based on electrophilic monomers and non-silicone polymers
US20080286221A1 (en) * 2004-10-22 2008-11-20 Basf Aktiengesellschaft Anionic Ethyl Methacrylate Copolymers and Use Thereof
US8039568B2 (en) 2004-10-22 2011-10-18 Basf Se Anionic ethyl methacrylate copolymers and use thereof
US8034888B2 (en) 2004-10-22 2011-10-11 Basf Se Amphoteric ethyl methacrylate copolymers and use thereof
US20080089853A1 (en) * 2004-10-22 2008-04-17 Basf Aktiengesellschaft Amphoteric Ethyl Methacrylate Copolymers and Use Thereof
US20060210507A1 (en) * 2004-10-28 2006-09-21 Ludivine Laurent Cosmetic composition comprising at least one sulphonic polyester and at least one polyurethane
EP1671898A1 (en) 2004-11-16 2006-06-21 L'oreal Pressurized container for hairstyling
EP1656968A1 (en) 2004-11-16 2006-05-17 L'oreal Pressurized article for hair treatment
US20060177399A1 (en) * 2004-11-16 2006-08-10 Herve Jourdan Pressurized device for hair fiber styling and use of the same for hair fiber styling and/or hair
US20080119554A1 (en) * 2004-11-26 2008-05-22 Rajiv Jalan Compositions Comprising Ornithine And Phenylacetate Or Phenylbutyrate For Treating Hepatic Encephalopathy
US20060156479A1 (en) * 2004-12-23 2006-07-20 Leila Hercouet Use of at least one compound chosen from porphyrin compounds and phthalocyanin compounds for dyeing human keratin materials, compositions comprising them, a dyeing process, and compounds therefor
US7429275B2 (en) 2004-12-23 2008-09-30 L'oreal S.A. Use of at least one compound chosen from porphyrin compounds and phthalocyanin compounds for dyeing human keratin materials, compositions comprising them, a dyeing process, and compounds therefor
US20060171910A1 (en) * 2004-12-30 2006-08-03 Audrey Ricard Cosmetic composition containing an alkoxylated alcohol ester and a hydrocarbon-based ester oil
US20080193405A1 (en) * 2005-01-28 2008-08-14 Basf Aktiengesellschaft Use of a Water-In-Water Emulsion Polymers in the Form of a Thickener for Cosmetic Preparations
EP1685825A1 (en) 2005-01-28 2006-08-02 L'oreal Hair treating process and its uses
US7815901B2 (en) 2005-01-28 2010-10-19 L'ORéAL S.A. Hair treatment method
US20070020215A1 (en) * 2005-01-28 2007-01-25 Estelle Mathonneau Hair treatment method
US20060230546A1 (en) * 2005-02-28 2006-10-19 Eric Bone Anhydrous composition in the form of a film comprising at least one film-forming polymer and at least one oxidation dye, preparation, and dyeing process
US20080168608A1 (en) * 2005-02-28 2008-07-17 Gregory Plos Dyeing of in Particular Human Keratin Materials by Dry Thermal Transfer of a Direct Anthraquinone Dye, Composition Comprising the Said Dye and Its Method of Preparation
US7722680B2 (en) 2005-02-28 2010-05-25 L'oreal S.A. Dyeing of human keratin materials by dry thermal transfer of a direct dye, composition comprising the said dye and its method of preparation
US20080148496A1 (en) * 2005-02-28 2008-06-26 Gregory Plos Dyeing of in Particular Human Keratin Materials by Dry Thermal Transfer of a Direct Dye, Composition Comprising the Said Dye and Its Method of Preparation
US20080120792A1 (en) * 2005-02-28 2008-05-29 Gregory Plos Dyeing of in Particular Human Keratin Materials by Dry Thermal Transfer of a Direct Azomethine Dye, Composition Comprising the Said Dye and its Method of Preparation
US20060242771A1 (en) * 2005-02-28 2006-11-02 Eric Bone Anhydrous composition in the form of a film comprising a film-forming polymer and a direct dye, preparation and dyeing process using the composition
US20060236469A1 (en) * 2005-02-28 2006-10-26 Eric Bone Anhydrous composition in the form of a film comprising a film-forming polymer and oxidizing agent, preparation and process for coloring keratinous fibers employing the anhydrous composition
US7645304B2 (en) 2005-02-28 2010-01-12 L'oreal S.A. Dyeing of in particular human keratin materials by dry thermal transfer of a direct azomethine dye, composition comprising the said dye and its method of preparation
US7651535B2 (en) 2005-02-28 2010-01-26 L'oreal S.A. Dyeing of in particular human keratin materials by dry thermal transfer of a direct anthraquinone dye, composition comprising the said dye and its method of preparation
US20060260069A1 (en) * 2005-03-31 2006-11-23 Frederic Legrand Dye composition comprising at least one fatty acid ester and process for dyeing keratin fibers using the same
US20060248662A1 (en) * 2005-03-31 2006-11-09 Frederic Legrand Dye composition with a reduced content of starting materials, and process for dyeing keratin fibers using the same
US20060260071A1 (en) * 2005-03-31 2006-11-23 Frederic Legrand Dye composition comprising at least one cellulose and process for dyeing keratin fibers using the dye composition
US20060260070A1 (en) * 2005-03-31 2006-11-23 Frederic Legrand Dye composition comprising at least one glycerol ester and a process for dyeing keratin fibers using the composition
US20060265817A1 (en) * 2005-03-31 2006-11-30 Frederic Legrand Dye composition comprising at least one non-ionic associative polymer and process for dyeing keratin fibers using same
US7569078B2 (en) 2005-03-31 2009-08-04 L'oreal S.A. Dye composition comprising at least one cellulose and process for dyeing keratin fibers using the dye composition
US7442214B2 (en) 2005-03-31 2008-10-28 L'oreal S.A. Dye composition comprising at least one non-ionic associative polymer and process for dyeing keratin fibers using same
US7578854B2 (en) 2005-03-31 2009-08-25 L'oreal S.A. Dye composition comprising at least one fatty acid ester and process for dyeing keratin fibers using the same
US7651533B2 (en) 2005-03-31 2010-01-26 Oreal Dye composition with a reduced content of starting materials, process for dyeing keratin fibers using the same and device therefor
US7550015B2 (en) 2005-03-31 2009-06-23 L'oreal S.A. Dye composition with a reduced content of starting materials, and process for dyeing keratin fibers using the same
US7575605B2 (en) 2005-03-31 2009-08-18 L'oreal S.A. Dye composition comprising at least one glycerol ester and a process for dyeing keratin fibers using the composition
US7824664B2 (en) 2005-04-29 2010-11-02 L'oreal S.A. Semipermanent hair shaping method
US20060260632A1 (en) * 2005-04-29 2006-11-23 Catherine Campain Semipermanent hair shaping method
US20060263316A1 (en) * 2005-04-29 2006-11-23 Priscille Devin-Baudoin Semipermanent hair shaping method
US7744859B2 (en) 2005-04-29 2010-06-29 L'oreal S.A. Semipermanent hair shaping method
US20060257339A1 (en) * 2005-05-13 2006-11-16 L'oreal Use of conductive polymer nanofibers for treating keratinous surfaces
US20060280711A1 (en) * 2005-06-14 2006-12-14 L'oreal Process for treating marionette lines
US20070009454A1 (en) * 2005-07-08 2007-01-11 L'oreal Make-up method involving a magnetic interaction
US20090162295A1 (en) * 2005-08-11 2009-06-25 Basf Aktiengesellschaft Setting polymers based on polyester acrylates
US8821841B2 (en) 2005-08-11 2014-09-02 Basf Se Copolymers for cosmetic applications
US8544475B2 (en) 2005-08-30 2013-10-01 L'oreal Packaging and applicator assembly including a magnetic device, a magnetic device, a method of forming a pattern on a nail using a magnetic device and a method of manufacturing a magnetic device
US20080260658A1 (en) * 2005-10-07 2008-10-23 Basf Se Hair Setting Compositions Based on T-Butyl Acrylate and Hydroxyalkyl Methacrylate
US7867969B2 (en) 2005-10-28 2011-01-11 L'oreal S.A. Composition for washing keratin materials comprising a magnesium salt anionic surfactant
US20070105734A1 (en) * 2005-10-28 2007-05-10 Sandrine Decoster Composition for washing keratin materials and cosmetic treatment process using said composition
US20070190008A1 (en) * 2005-12-20 2007-08-16 Catherine Campain Process for permanently reshaping the hair, comprising applying to the hair at least one precipitated fixing polymer, and multi-compartment device
US20070184002A1 (en) * 2006-01-20 2007-08-09 Sabine Vrignaud Non-washing cosmetic composition comprising at least one ionic fixing polymer and at least one ester of polyethylene glycol and of fatty acid, and method for fixing a hairstyle
US20070184001A1 (en) * 2006-01-20 2007-08-09 Sabine Vrignaud Cosmetic composition comprising a nonionic fixing polymer and a specific ester of polyethylene glycol and of fatty acid, and a method for fixing the hairstyle
US20080102046A1 (en) * 2006-07-21 2008-05-01 L'oreal Cosmetic composition
US20080019933A1 (en) * 2006-07-21 2008-01-24 L'oreal Method of making-up dark skin
US8710152B2 (en) 2006-07-27 2014-04-29 L'oreal Block polymers and their process of preparation
US8545817B2 (en) 2006-08-04 2013-10-01 L'oreal Cosmetic composition comprising at least one polysaccharide of λ-carrageenan type in aerosol form, method for the cosmetic treatment of keratinous fibers, and product comprising the composition
US20080031829A1 (en) * 2006-08-04 2008-02-07 Regis Beitone Cosmetic composition comprising at least one polysaccharide of lambda-carrageenan type in aerosol form, method for the cosmetic treatment of keratinous fibers, and product comprising the composition
US20100117621A1 (en) * 2006-10-13 2010-05-13 Lutron Electronics Co., Inc. Method of load shedding to reduce the total power consumption of a load control system
US20080127429A1 (en) * 2006-10-25 2008-06-05 Gaelle Brun Coloring composition of keratinous fibers comprising at least one polysiloxane/polyurea block copolymer
US7799093B2 (en) 2006-10-25 2010-09-21 L'ORéAL S.A. Coloring composition of keratinous fibers comprising at least one polysiloxane/polyurea block copolymer
EP1920755A1 (en) 2006-11-10 2008-05-14 L'Oréal Method for permanently deforming keratinous fibres comprising a step of applying an intermediate rinsing component comprising a monovalent metal cation salt or an ammonia salt and an organic acid
US20080148495A1 (en) * 2006-12-22 2008-06-26 L'oreal Cosmetic composition for keratinous substrates with triarylmethane compounds
EP1938791A2 (en) 2006-12-22 2008-07-02 L'Oréal Cosmetic composition for keratinous substrates containing triarylmethane compounds
US7416567B2 (en) 2006-12-22 2008-08-26 L'oreal Cosmetic composition for keratinous substrates with triarylmethane compounds
EP1961489A1 (en) 2007-02-23 2008-08-27 L'Oreal Device for spraying a gloss composition
EP1961490A1 (en) 2007-02-23 2008-08-27 L'Oreal Device for spraying a fixing composition
US20110206623A1 (en) * 2007-08-23 2011-08-25 Evonik Goldschmidt Gmbh Novel dipolar ionic compounds comprising formulations and the use thereof
EP2039345A1 (en) 2007-09-14 2009-03-25 L'Oréal Cosmetic compositions containing a cationic copolymer and a particular triglyceride and uses thereof
EP2065024A2 (en) 2007-11-30 2009-06-03 L'Oreal Hairstyling composition comprising (meth)acrylic copolymers and at least one oil
EP2065023A2 (en) 2007-11-30 2009-06-03 L'Oreal Hairstyling composition comprising at least one (meth)acrylic copolymer and at least one pearlescent agent
EP2105127A1 (en) 2008-03-26 2009-09-30 Bayer MaterialScience AG Hair fixing composition
EP2106833A1 (en) 2008-04-02 2009-10-07 Bayer MaterialScience AG Particle derived from drying a liquid nano-uric dispersion
US20110150796A1 (en) * 2008-09-04 2011-06-23 Basf Se Precipitation polymerization in the presence of glycerin monostearate
EP2221043A1 (en) 2009-02-21 2010-08-25 Bayer MaterialScience AG Hair fixing compound
WO2010094419A2 (en) 2009-02-21 2010-08-26 Bayer Materialscience Ag Hair styling composition
US20100215608A1 (en) * 2009-02-21 2010-08-26 Bayer Materialscience Ag Hair setting composition
US20100297052A1 (en) * 2009-05-22 2010-11-25 Feuillette Laetitia Cosmetic composition comprising at least one elastomeric polyurethane
US20100297051A1 (en) * 2009-05-22 2010-11-25 Feuillette Laetitia Cosmetic composition comprising at least one elastomeric anionic polyurethane and at least one non-ionic thickener
WO2010133658A2 (en) 2009-05-22 2010-11-25 L'oréal A cosmetic composition comprising at least one elastomeric anionic polyurethane and at least one non-ionic thickener
WO2010133660A2 (en) 2009-05-22 2010-11-25 L'oreal Cosmetic composition comprising at least one elastomeric polyurethane
DE102009042727A1 (en) 2009-09-23 2011-04-07 Bayer Materialscience Ag Use of a composition comprising nitrocellulose-polyurethane-polyurea particles as a cosmetic for hair designing and setting
US20110218295A1 (en) * 2010-03-02 2011-09-08 Basf Se Anionic associative rheology modifiers
WO2011117403A2 (en) 2010-03-25 2011-09-29 L'oréal Composition comprising a silicone copolymer, a silicone surfactant and a non-volatile pdms, cosmetic treatment method and use.
WO2011157796A1 (en) 2010-06-17 2011-12-22 L'oreal Cosmetic composition comprising a branched sulphonic polyester and a particular thickener and uses in hair styling
WO2012032057A2 (en) 2010-09-06 2012-03-15 L'oreal Cosmetic composition comprising a fixing polymer and a specific thickener and uses in styling
US9833400B2 (en) 2010-09-06 2017-12-05 L'oreal Cosmetic composition comprising a fixing polymer and a specific thickener and uses in styling
WO2012035053A1 (en) 2010-09-14 2012-03-22 L'oreal Cosmetic composition comprising a fixing polymer and an antidandruff agent
WO2012049145A1 (en) 2010-10-12 2012-04-19 L'oreal Cosmetic composition comprising a particular silicon derivative and one or more acrylic thickening polymers
WO2012065971A2 (en) 2010-11-19 2012-05-24 L'oreal Cosmetic composition comprising at least one elastomeric polyurethane and at least one cationic polymer
WO2012080255A2 (en) 2010-12-14 2012-06-21 L'oreal Fan-shaped aerosol device for styling the hair
WO2012080661A2 (en) 2010-12-14 2012-06-21 L'oreal Aerosol device having two compartments including an alcoholic or hydroalcoholic hairstyling composition, and hairstyling method
WO2012107887A2 (en) 2011-02-08 2012-08-16 L'oreal Process for applying a hair care composition to hair
WO2012130683A1 (en) 2011-03-25 2012-10-04 Bayer Materialscience Ag Polyurethane urea mixture for hair cosmetics
US9180086B2 (en) 2011-06-01 2015-11-10 L'oreal Process for treating straightened keratin fibres
US9610241B2 (en) 2011-06-01 2017-04-04 L'oreal Process for treating straightened keratin fibres
WO2012164065A2 (en) 2011-06-01 2012-12-06 L'oreal Process for treating straightened keratin fibres
WO2013042274A1 (en) 2011-09-22 2013-03-28 L'oreal Cosmetic cleansing composition
WO2013045379A1 (en) 2011-09-30 2013-04-04 L'oreal Method for the temporary coloured shaping of keratinous fibres
WO2013092719A1 (en) 2011-12-19 2013-06-27 L'oreal Cosmetic composition comprising an anionic or nonionic associative polymer, fixing polymer and at least 2% of a surfactant
WO2013092708A1 (en) 2011-12-19 2013-06-27 L'oreal Cosmetic composition comprising an anionic or nonionic associative polymer, fixing polymer and a particular surfactant
WO2013110653A1 (en) 2012-01-23 2013-08-01 L'oreal Composition comprising at least one specific alkoxysilane polymer
US9198851B2 (en) 2012-01-23 2015-12-01 L'oreal Composition comprising at least one specific alkoxysilane polymer
WO2013131969A2 (en) 2012-03-09 2013-09-12 Bayer Materialscience Llc Effect of the polyurethane film former on the efficacy of acne treatment
WO2013160440A2 (en) 2012-04-26 2013-10-31 L'oreal Process for treating hair with a pressurized cosmetic composition comprising a fatty-chain silane
WO2013160442A2 (en) 2012-04-26 2013-10-31 L'oreal Cosmetic composition comprising a fatty-chain silane and a particular fixing polymer
WO2013167530A2 (en) 2012-05-07 2013-11-14 L'oreal Aerosol device based on a calcium salt and a fixing polymer
WO2013190078A2 (en) 2012-06-21 2013-12-27 L'oreal Cosmetic composition comprising hydrophobic silica aerogel particles and a fixing polymer
WO2014023675A1 (en) 2012-08-07 2014-02-13 L'oreal Cosmetic composition comprising at least one particular fixing polymer and at least one particular thickening polymer
WO2014023782A1 (en) 2012-08-07 2014-02-13 L'oreal Two-phase cosmetic composition and pump bottle containing it
WO2014048655A2 (en) 2012-09-26 2014-04-03 Bayer Materialscience Ag Method for treating keratinous fibers to achieve a shape memory effect
EP2712609A1 (en) 2012-09-26 2014-04-02 Bayer MaterialScience AG Polyurethane-urea compound for skin and hair cosmetics
DE202013011676U1 (en) 2012-11-09 2014-02-14 L'oreal Composition containing a dicarbonyl compound
WO2014091012A1 (en) 2012-12-14 2014-06-19 L'oreal Cosmetic composition in powder form comprising a (meth)acrylic thickening polymer, a fixing polymer and water-insoluble particles
US9456978B2 (en) 2012-12-28 2016-10-04 L'oreal Cosmetic compositions containing a silicone-organic polymer hybrid compound
WO2014111579A2 (en) 2013-01-18 2014-07-24 L'oreal Hair shaping process in which is applied a particular styling composition, which is rinsed out
WO2014124977A1 (en) 2013-02-15 2014-08-21 L'oreal Cosmetic composition comprising a vinylformamide / vinylformamine copolymer, a cellulose-based thickening polymer and an amphoteric or zwitterionic surfactant
WO2014188007A1 (en) 2013-05-24 2014-11-27 L'oreal Cosmetic composition comprising an aqueous phase and a fatty phase that are visually distinct
WO2015063122A1 (en) 2013-10-30 2015-05-07 L'oreal Expanded dyeing composition comprising an inert gas, an oxidation dye and an oxyalkylenated nonionic surfactant
WO2015075280A1 (en) 2014-08-05 2015-05-28 Bayer Materialscience Ag Polyurethane urea solutions for hair-styling compositions
EP3020454A1 (en) 2014-11-17 2016-05-18 Covestro Deutschland AG Polyurethane urea substances for hair styling compositions
EP3020453A1 (en) 2014-11-17 2016-05-18 Covestro Deutschland AG Polyurethane ureas for aqueous nail varnish compositions
WO2016096654A1 (en) 2014-12-17 2016-06-23 L'oreal Dye composition comprising a para-phenylenediamine oxidation base and an amphoteric or cationic polymer in a medium rich in fatty substances
WO2017108565A1 (en) 2015-12-21 2017-06-29 L'oreal Composition comprising a vinylformamide/vinylamine copolymer, a fixing polymer and a particular combination of surfactants
WO2017117552A1 (en) 2015-12-31 2017-07-06 L'oreal Compositions containing polycarbodiimides for treating keratinous substrates
WO2017117543A1 (en) 2015-12-31 2017-07-06 L'oreal Compositions containing polycarbodiimides and latex polymers for treating keratinous substrates
WO2017117522A1 (en) 2015-12-31 2017-07-06 L'oreal Compositions containing polycarbodiimides and amino compounds for treating keratinous substrates
WO2018115002A1 (en) 2016-12-21 2018-06-28 L'oreal Hair composition comprising a guanidine salt, an alkanolamine and ammonium hydroxide and cationic and/or amphoteric polymers
WO2018184993A1 (en) 2017-04-03 2018-10-11 Covestro Deutschland Ag Cosmetic compositions comprising special carbodiimides, for hair
EP3384897A1 (en) 2017-04-03 2018-10-10 Covestro Deutschland AG Cosmetic compositions for hair with special carbodiimides

Similar Documents

Publication Publication Date Title
US3716633A (en) Vinyl acetate-crotonic acid-unsaturated ester or ether polymers in hair lacquers and setting lotions
US3472243A (en) Treating damaged living human hair with water soluble polymerizable vinyl monomers
US5498407A (en) Poly(2-hydroxyethyl methacrylate) and all copolymers of poly-HEMA fibers and cosmetic compositions containing same
US4710374A (en) Cosmetic composition containing cationic polymers and anionic latexes
US4425326A (en) Anhydrous nail varnishes
US4880618A (en) Use of partially acetylated polyvinyl alcohol as a foaming agent in compositions in the form of aerosols
US4192861A (en) Hydrocarbon propelled aerosol hair spray compositions
US20040052748A1 (en) Compositions of anionic polymeric rheology modifiers and cationic materials
US4994088A (en) Hair cosmetic composition
US5194260A (en) Cosmetic composition for the hair contains a film forming polymer and a silicone incorporated in a wax microdispersion and a cosmetic treatment using the same
US4803071A (en) Hair care compositions
US20010022967A1 (en) Hair styling compositions
US5009880A (en) Composition and process for the treatment of keratin materials with polymers
US4923694A (en) Hydrolysis resistant vinyl lactam amino acrylamide polymers
US4075131A (en) Conditioning shampoo
US5747016A (en) Organopolysiloxanes and a method of setting hair using the same
US5603926A (en) Cosmetic composition comprising cationic polymer thickener
US20050244353A1 (en) Method for achieving shape memory effects on hair by combining shape memory polymers with cationic active ingredients
US4157388A (en) Hair and fabric conditioning compositions containing polymeric ionenes
US5089252A (en) Cosmetic composition for treating keratin fibres, and process for treating the latter
US5085859A (en) Hair fixatives
US4289752A (en) Cosmetic compositions containing N-alkylacrylamide or N-alkylmethacrylamide based copolymers
US5338541A (en) Dual cationic terpolymers providing superior conditioning properties in hair, skin and nail care products
US4839166A (en) Cosmestic compositions containing a cationic polymer and an anionic polymer as thickening agent
US4172887A (en) Hair conditioning compositions containing crosslinked polyaminopolyamides