GB2058103A - An aqueous hair conditioning composition containing a silicone polymer and a cationic polymer and method for conditioning hair - Google Patents

An aqueous hair conditioning composition containing a silicone polymer and a cationic polymer and method for conditioning hair Download PDF

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GB2058103A
GB2058103A GB8027440A GB8027440A GB2058103A GB 2058103 A GB2058103 A GB 2058103A GB 8027440 A GB8027440 A GB 8027440A GB 8027440 A GB8027440 A GB 8027440A GB 2058103 A GB2058103 A GB 2058103A
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composition
polymer
composition according
molecular weight
hair
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Bristol Myers Co
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Bristol Myers Co
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/594—Mixtures of polymers

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A hair conditioning composition comprises a silicone polymer (e.g. a polydimethylsiloxane containing aminoethylaminopropyl groups) and a cationic polymer (e.g. cyclized dimethyldiallyl ammonium chloride polymers and copolymers thereof with acrylamide, poly(dimethyl butenyl ammonium) chloride compounds and quaternized polyvinyl pyridine) in an aqueous medium and a method of conditioning hair involving the application of said composition to the hair.

Description

SPECIFICATION An aqueous hair conditioning composition containing a silicone polymer and a cationic polymer and method for conditioning hair This invention relates to compositions that are useful in conditioning hair and to processes for conditioning hair that employ such compositions.
It is known in the prior art to treat hair with certain quaternary amine compounds for the purpose of conditioning hair, i.e. to improve its combability, manageability, to impart soft feel, lustrous appearance, etc.
Although such prior art compositions have proven effective in varying degrees, one of the chief drawbacks has been the transiency of the effect, i.e. it does not survive repeated shampooing. Some improvement in conditioning stability to shampooing can be attained with certain classes of silicone polymers. Examples of such polymers is amodimethicone, the structural formula of which is:
where x andy are cardinal numbers depending on molecular weight and the weight average molecular weight is approximately between 5,000 and 100,000. However, even the use of such silicone polymers leaves something to be desired.
It has been now found that both the conditioning efficacy and the durability of the conditioning effect of such silicone polymers can be greatly enhanced by incorporating into the conditioning formulation one or more cationic polymers. The polymers that are useful for the purposes of the pesent invention can vary over a wide range. Cationic polymers that have been found to be particularly useful herein are those sold under the trade name MERQUAT (e.g. MERQUAT 100 and MERQUAT 550), ONAMER (e.g. ONAMER M) and quaternized polyvinyl pyridines.
MERQUAT 100 is a polymer of dimethyldiallyl amonium chloride and are probably mixtures of compounds having the following formulas:
These vary in molecular weight and n is a cardinal number which depends on molecular weight. Ordinarily, however, the polymers of this class that will be employed have a molecular weight in the range of from about 4,000 to about 550,000 and preferably in the range of from about 20,000 to about 100,000. MERQUAT 550 is a copolymers of dimethyldiallyl ammonium chloride and acrylamide. This is believed to have the formula:
and a molecular weight in the range of from about 5,000 to about 550,000, and n and m are cardinal numbers which depend on molecular weight.
The ONAMER type polymers that are useful for the present purposes are poly(dimethylbutenyl ammonium chloride)-a, - bis(triethanol ammonium chloride) compounds that may be described by the general formula:
wherein n is a cardinal number which is molecular weight dependent. The molecular weights of these polymers that may be employed will be in the range from about 800 to about 5000 and preferably in the range of from about 1000 to about 3000.
A third variety of cationic materials that have been found particularly useful are polymers and copolymers of quaternized polyvinylpyridine. These are described by the general formula:
Wherein Ris an alkyl radical of C1-C20 and the and the X- is an anion such as a halide, sulfate or carboxylate, and n is a cardinal number which depends on molecular weight. These also will have a molecular weight in the range of from about 5000 to about 100,000.
As an example of the cationic polymer of this group, the following may be mentioned:
polyvinyl methyl pyridinium iodide having an average M.W. of 50,000.
The quantity of cationic polymer contained in the formulation will depend on the particular results that are desired. Ordinarily, this will constitute between about .01% to about 10% by weight based on the total weight of the aqueous compositions with the optimal range being between about .05% to about 3% on the same weight basis.
The amount of silicone polymer that will be incorporated in the present hair conditioning composition may also vary somewhat. Usually, however, this will comprise from about 0.2% to about 10% by weight based on the total weight of the composition and preferably from about 1% to about 4%.
Although the cationic polymers mentioned above and the silicone polymers are the essential active ingredients in the present compositions, the compositions contemplated by the present invention may also contain other ingredients which may serve to improve the organoleptic character of the product or its ease of application. Thus, it is within the purview of this invention to incorporate such materials as fragrance, thickening agents, opacifiers, etc. in the compositions of this invention.
The carrier for delivering the compositions of the present invention will generally be an aqueous vehicle.
This may take any of a variety of forms e.g. solutions, aqueous emulsions, aqueous gels, etc. As used herein, the term aqueous carrier is intended to include the cases wherein water is essentially the only material that constitutes the vehicle as well as those cases wherein the water is mixed with subtantial quantities of other ingredients e.g. solvents, thickening agents, emulsifying agents, gelling agents, etc.
The compositions of the present invention may be applied to hair in any suitable manner. One typical procedure involves applying the conditioning composition, such as described in Example I below to freshly shampooed hair, working it gently into the hair mass, leaving the said composition on hair for one to five minutes and rinsing the hair thoroughly with water prior to combing. The amount of the conditioning composition applied to hair may vary but, in general, should not be less than 1% of the hair weight and does not exceed 20% of the hair weight.
The following Examples are given to further illustrate the present invention. It is to be understood, however, that the invention is not limited thereto.
Example I Ingredient % by weight Silicone Polymer (Amodimethicone)* in form of emulsion 1.6 Merquat 100** 1.6 Hydroxyethyl cellulose 1.5 Citric acid 0.5 Water OS to 100.0 *CTFA name (RD Number 977069-10-5). The commercial product is Dow-Corning Cationic Emulsion 929 which is a mixture of the emulsified polymer and 1.9% tallowtrimethyl ammonium dichloride, and 1.7% Nonoxynol-lO, an alkyl phenoxy polyoxy ethylene ethanol with 10 mols ethylene oxide.
**CTFA name Quaternium M-40 (RD Number 977066-02-6) Example II Ingredient % by weight Amodmethicone 1.6 Polyvinyl allyl pyridinium sulfate 1.6 Hydroxyethyl cellulose 1.5 Citric acid 0.5 Water OS to 100.0 Example Ill Ingredient % by weight Amodimethicone 1.6 Merquat 550 0.8 Polyvinyl methyl pyridinium iodide 0.8 Hydroxyethyl cellulose 1.5 Citric acid 0.5 Water QS to 100.0 Example IV Ingredient % by weight Silicone Polymer (Amodimethicone) in form of emulsion (Dow Corning Cationic Emulsion 929) 2.0 Onamer M*** 1.5 Hydroxyethyl cellulose 1.2 Water OS to 100.0 ***poly(dimethyl butenyl ammonium chloride)-a,-bis(tri-ethanol ammonium chloride) Av. M.W. about 1000-2000.
Example V Ingredient % by weight Silicone Polymer (Amodimethicone) in form of emulsion (Dow Corning Cationic Emulsion 929) 1.75 Stearyl alcohol 1.6 Glyceryl monostearate 1.5 Mineral oil 0.8 Merquat 550**** 0.4 Propyl paraben 0.5 Water QS to 100.0 ****CTFA name Quaternium M41 (RD Number 977066-03-7) The conditioning efficacy and durability is illustrated in the following experiment, the normal, Caucasian hair being used as the test substrate.
Swatches of intact Caucasian hair were shampooed with Herbal Essence Shampoo in accordance with the instructions present on the label. The ratio of the amount of shampoo to weight of hair and quantity of water used for rinsing after shampooing were all maintained so as to simulate conditions on the head. After rinsing, the conditioning material of Example I above was applied to hair (0.1 g of each product per 1 g of hair). It was worked in for 30 seconds and left on the hairfor an additional minute after which time the hair was rinsed and combed. The combing measurements were performed by the procedure described in the paper by Garcia and Diaz (J. Soc. Cosmetic Cheem, 27,379, 1976). The test essentially involves passing of a hair tress through a comb attached to a strain gauge which in turn is connected to a recording device.Force is expended to accomplish the passage of the tress through the comb, and the maximum force read off the recorded in the objective measure of combing ease.
Having determined the combing properties of hair after shampooing and conditioning treatments, the swatches were shampooed five times and again tested for combing. The results of combability tests are summarized in Table I below. In the Table, the "Maximum Combing Force" is expressed in units of Gram Force (G). The higher the values, the harder it was to comb the hair.
TABLE I Effect of Conditioning on Combing Ease Maximum Procedure # Treatment Combing Force(G) 1 Shampooing 80 2 Proc. (1)followed by treatment with conven tional conditioner 42 3 Proc. (2) followed by 5 shampoos 97 4 Proc. (1)followed by treatment with composition for Example I without the Merquat 29 5 Proc. (4) followed by 5 shampoos 60 6 Proc. (1) followed by treatment with composition from Example 1 12 7 Proc. (6) followed by 5 shampoos 18 Even better durability of conditioning properties was obtained with compositions of Example IV. Again, freshly shampooed, brown Caucasian hair tresses were used in the experiment. The results are given in Table Il below.
TABLE II Effect of Conditioning on Combing Ease Maximum Procedure w Treatment Combing Force (G) 1 Shampooing 92 2 Proc. (1) followed by treatment with composition of Example II without the Onamer 19 3 Proc. (2) followed by 10 consecutive shampoo- 79 ings 4 Proc. (1) followed by treatment with composition Example II 11 5 Proc. (4) followed by 10 consecutive shampoo ings 16 Although the invention has been described with reference to specific forms thereof, it will be understood that many changes and modifications may be made without departing from the scope of this invention.

Claims (14)

1. An aqueous composition useful in conditioning hair comprising, on a weight basis and based on the total weight of the composition: (a) from about 0.2% to about 10% of a silicone polymer; (b) from about .01 to about 10% of at least one cationic polymer; and (c) an aqueous carrier.
2. A composition according to claim 1 in which said silicone polymer comprises from about 1% to about 4% by weight of said composition and said cationic polymer comprises from about .05% to about 3% by weight.
3. A composition according to claim 1 or 2 in which said silicone polymer is in the form of an aqueous emulsion of a polymer constituted of the following structural units:
wherein x andy are cardinal numbers depending on molecular weight and the weight average molecular weight of the polymer is approximately between 5,000 and 100,000.
4. A composition according to any of claims 1 - 3 in which said cationic polymer is at least in part a homopolymerofdimethyldiallyl ammonium chloride.
5. A composition according to claim 4wherein said cationic homopolymer comprises monomeric units of the formula:
or mixtures thereof.
6. A composition according to claim 4 or 5 in which said homopolymers have a molecular weight within the range of from about 4000 to about 550,000.
7. A composition according to any of claims 1 - 3 in which said cationic polymer is a copolymer of dimethyldiallyl ammonium chloride and acrylamide.
8. A composition according to claim 7 in which said cationic copolymer is made up of monomeric units of the formula:
in which n and mare molecularweight-dependentcardinal numbers and in which said copolymer has a molecular weight in the range of from about 5000 to about 550,000.
9. A composition according to any of claims 1 - 3 in which said cationic polymer is at least in part a poly(di-methylbutenyl ammonium chloride)-a,-bis(triethanol ammonium chloride).
10. A composition according to claim 9 in which said cationic polymer comprises monomeric units of the formula:
in which n is a molecular weight-dependent cardinal number and in which said cationic polymer has a molecular weight in the range of from about 800 to about 5000.
11. A composition according to any of claims 1 - 10, in which said cationic polymer is at least in part a quarternized polyvinyl pyridine.
12. The composition of claim 11, wherein said polyvinyl pyridine comprises monomeric units of the formula:
wherein R is an alkyl radical having between 1 and 20 carbon atoms, X is an anion and n is a molecular weight-dependant cardinal number, the polymer having a weight average molecular weight in the range of from about 5,000 to about 100,000.
13. The composition of claim 12, wherein said anion is a sulfate, halide or carboxylate.
14. A composition accordng to claim 1, whose composition is substantially as indicated in any of the foregoing Examples 1 to 5.
GB8027440A 1979-08-23 1980-08-22 An aqueous hair conditioning composition containing a silicone polymer and a cationic polymer and method for conditioning hair Withdrawn GB2058103A (en)

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US6898679A 1979-08-23 1979-08-23
US16546880A 1980-07-11 1980-07-11

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DE (1) DE3029306A1 (en)
DK (1) DK360680A (en)
FI (1) FI802631A (en)
FR (1) FR2463612A1 (en)
GB (1) GB2058103A (en)
GR (1) GR69885B (en)
IT (1) IT1145700B (en)
NL (1) NL8004710A (en)
NO (1) NO802492L (en)
SE (1) SE8005886L (en)

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4450152A (en) * 1981-10-29 1984-05-22 Toray Silicone Company, Ltd. Composition used to groom hair
EP0117360A1 (en) * 1982-12-27 1984-09-05 Dow Corning Corporation Aqueous compositions containing siloxane and a metallorganic additive
US4487883A (en) * 1982-12-27 1984-12-11 Dow Corning Corporation One-part moisture cured aminosiloxanes
FR2548019A1 (en) * 1983-07-01 1985-01-04 Oreal HAIR COMPOSITION AND METHOD FOR TREATING HAIR
FR2562794A1 (en) * 1984-04-13 1985-10-18 Oreal HAIR COMPOSITION AND METHOD FOR TREATING HAIR
US4563347A (en) * 1982-05-20 1986-01-07 Dow Corning Corporation Compositions used to condition hair
FR2570599A1 (en) * 1984-09-21 1986-03-28 Oreal COSMETIC COMPOSITIONS BASED ON CATIONIC SILICONE, HYDROSOLUBLE HETEROPOLYSACCHARIDE AND ELECTROLYTE
FR2571614A1 (en) * 1984-10-12 1986-04-18 Oreal DETERGENT COSMETIC COMPOSITIONS
US4601902A (en) * 1983-07-30 1986-07-22 Dow Corning Ltd. Compositions and process for treating hair
US4764363A (en) * 1986-04-04 1988-08-16 The Procter & Gamble Company Hair styling mousse
US4770873A (en) * 1983-06-15 1988-09-13 Clairol, Incorporated Neutralizing composition and method for hair waving and straightening
US4782095A (en) * 1984-02-22 1988-11-01 Union Carbide Corporation Water-in-volatile silicone emulsifier concentrates
US4801447A (en) * 1984-02-22 1989-01-31 Union Carbide Corporation Water-in-volatile silicone emulsifier concentrates, water-in-volatile silicone emulsions that are useful in personal-care formulations and methods of making same
US4820308A (en) * 1984-10-12 1989-04-11 L'oreal Detergent cosmetic compositions containing a soap and cationic compound and direct dye
GB2222949A (en) * 1988-09-15 1990-03-28 Euro Celtique Sa Lice control
EP0392320A2 (en) * 1989-04-14 1990-10-17 Kao Corporation Shampoo composition
US5049377A (en) * 1990-03-02 1991-09-17 Dow Corning Corporation Hair-care composition and methods of treating hair
FR2677995A1 (en) * 1991-06-21 1992-12-24 Oreal COMPOSITION FOR WASHING AND / OR CONDITIONING KERATINIC MATERIALS, CONTAINING A SILICONE AND AN AMPHOTERIC POLYMER DERIVED FROM DIALLYLDIALKYLAMMONIUM AND AN ANIONIC MONOMER.
FR2678633A1 (en) * 1991-07-04 1993-01-08 Oreal COMPOSITION FOR THE WASHING AND / OR CONDITIONING OF KERATINIC MATERIALS BASED ON HYDROXYACYLAMINO FUNCTIONAL SILICONE AND SUBSTANTIVE POLYMERS.
US5211883A (en) * 1989-04-14 1993-05-18 Kao Corporation Shampoo composition
USRE34584E (en) 1984-11-09 1994-04-12 The Procter & Gamble Company Shampoo compositions
US5326483A (en) * 1993-02-19 1994-07-05 Dow Corning Corporation Method of making clear shampoo products
EP0729742A2 (en) * 1995-03-01 1996-09-04 Kao Corporation Hair cosmetic composition containing an amino-modified silicon polymer
FR2831799A1 (en) * 2001-11-08 2003-05-09 Oreal Cosmetic composition useful for washing or care of keratinic materials comprises water-soluble conditioner and aminoethylaminopropyl silicone
WO2016074142A1 (en) * 2014-11-11 2016-05-19 The Procter & Gamble Company Detergent or cleaning compositions with improved sudsing profile
WO2016172158A1 (en) * 2015-04-21 2016-10-27 Kao Usa Wash-out hair treatment composition

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5213793A (en) * 1984-01-13 1993-05-25 The Gillette Company Hair conditioning
FR2761599B1 (en) * 1997-04-07 1999-12-03 Oreal COSMETIC COMPOSITIONS CONTAINING A LOW MOLECULAR MASS CATIONIC POLYMER AND THEIR USES
FR2926990B1 (en) * 2008-01-31 2014-05-09 Oreal COSMETIC COMPOSITION COMPRISING VINYLFORMAMIDE / VINYLFORMAMINE COPOLYMER AND SILICONE, AND USE THEREOF FOR CAPILLARY TREATMENT

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE783231A (en) * 1972-05-10 1972-09-01 Gillette Co Hair treatment before washing - with cationic polymer soln, to improve ease of combing and reduce static charges
DE2327066C3 (en) * 1973-05-26 1975-11-20 Hans Schwarzkopf Gmbh, 2000 Hamburg Means and methods for setting hair
LU68901A1 (en) * 1973-11-30 1975-08-20
US3964500A (en) * 1973-12-26 1976-06-22 Lever Brothers Company Lusterizing shampoo containing a polysiloxane and a hair-bodying agent
DE2631419A1 (en) * 1975-07-16 1977-02-03 Procter & Gamble Europ COMPOSITIONS FOR TEXTILE TREATMENT

Cited By (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4450152A (en) * 1981-10-29 1984-05-22 Toray Silicone Company, Ltd. Composition used to groom hair
US4563347A (en) * 1982-05-20 1986-01-07 Dow Corning Corporation Compositions used to condition hair
EP0117360A1 (en) * 1982-12-27 1984-09-05 Dow Corning Corporation Aqueous compositions containing siloxane and a metallorganic additive
US4487883A (en) * 1982-12-27 1984-12-11 Dow Corning Corporation One-part moisture cured aminosiloxanes
US4770873A (en) * 1983-06-15 1988-09-13 Clairol, Incorporated Neutralizing composition and method for hair waving and straightening
US4597962A (en) * 1983-07-01 1986-07-01 L'oreal Hair-care composition and hair treatment process
FR2548019A1 (en) * 1983-07-01 1985-01-04 Oreal HAIR COMPOSITION AND METHOD FOR TREATING HAIR
US4601902A (en) * 1983-07-30 1986-07-22 Dow Corning Ltd. Compositions and process for treating hair
US4782095A (en) * 1984-02-22 1988-11-01 Union Carbide Corporation Water-in-volatile silicone emulsifier concentrates
US4801447A (en) * 1984-02-22 1989-01-31 Union Carbide Corporation Water-in-volatile silicone emulsifier concentrates, water-in-volatile silicone emulsions that are useful in personal-care formulations and methods of making same
FR2562794A1 (en) * 1984-04-13 1985-10-18 Oreal HAIR COMPOSITION AND METHOD FOR TREATING HAIR
FR2570599A1 (en) * 1984-09-21 1986-03-28 Oreal COSMETIC COMPOSITIONS BASED ON CATIONIC SILICONE, HYDROSOLUBLE HETEROPOLYSACCHARIDE AND ELECTROLYTE
US4749565A (en) * 1984-09-21 1988-06-07 L'oreal Cosmetic compositions based on cationic silicone, water-soluble heteropolysaccharide and electrolyte
FR2571614A1 (en) * 1984-10-12 1986-04-18 Oreal DETERGENT COSMETIC COMPOSITIONS
US4820308A (en) * 1984-10-12 1989-04-11 L'oreal Detergent cosmetic compositions containing a soap and cationic compound and direct dye
US4710314A (en) * 1984-10-12 1987-12-01 L'oreal Detergent cosmetic composition containing a soap and cationic compound
USRE34584E (en) 1984-11-09 1994-04-12 The Procter & Gamble Company Shampoo compositions
US4764363A (en) * 1986-04-04 1988-08-16 The Procter & Gamble Company Hair styling mousse
GB2222949B (en) * 1988-09-15 1992-12-23 Euro Celtique Sa Manufacture of a medicament for controlling lice or their ova
GB2222949A (en) * 1988-09-15 1990-03-28 Euro Celtique Sa Lice control
US5211883A (en) * 1989-04-14 1993-05-18 Kao Corporation Shampoo composition
EP0392320A2 (en) * 1989-04-14 1990-10-17 Kao Corporation Shampoo composition
EP0392320A3 (en) * 1989-04-14 1992-03-04 Kao Corporation Shampoo composition
US5049377A (en) * 1990-03-02 1991-09-17 Dow Corning Corporation Hair-care composition and methods of treating hair
FR2677995A1 (en) * 1991-06-21 1992-12-24 Oreal COMPOSITION FOR WASHING AND / OR CONDITIONING KERATINIC MATERIALS, CONTAINING A SILICONE AND AN AMPHOTERIC POLYMER DERIVED FROM DIALLYLDIALKYLAMMONIUM AND AN ANIONIC MONOMER.
EP0521748A1 (en) * 1991-06-21 1993-01-07 L'oreal Washing and/or conditioning composition for keratinous material containing a silicone and an amphoteric polymer derivative of diallyldialkylammonium and an anionic monomer
US5650383A (en) * 1991-06-21 1997-07-22 L'oreal Composition for washing and/or conditioning keratinous matter, containing a silicone and an amphoteric polymer derived from diallydialkylammonium and from an anionic monomer
EP0526279A1 (en) * 1991-07-04 1993-02-03 L'oreal Composition for the care of the hair containing hydroxyacylamino modified silicone and substantive polymers
FR2678633A1 (en) * 1991-07-04 1993-01-08 Oreal COMPOSITION FOR THE WASHING AND / OR CONDITIONING OF KERATINIC MATERIALS BASED ON HYDROXYACYLAMINO FUNCTIONAL SILICONE AND SUBSTANTIVE POLYMERS.
US5627148A (en) * 1991-07-04 1997-05-06 Oreal Washing and/or conditioning composition for keratinous materials based on a silicone containing a hydroxyacylamino functional group and on substantive polymers
US5326483A (en) * 1993-02-19 1994-07-05 Dow Corning Corporation Method of making clear shampoo products
EP0729742A2 (en) * 1995-03-01 1996-09-04 Kao Corporation Hair cosmetic composition containing an amino-modified silicon polymer
EP0729742A3 (en) * 1995-03-01 1997-07-09 Kao Corp Hair cosmetic composition containing an amino-modified silicon polymer
FR2831799A1 (en) * 2001-11-08 2003-05-09 Oreal Cosmetic composition useful for washing or care of keratinic materials comprises water-soluble conditioner and aminoethylaminopropyl silicone
WO2016074142A1 (en) * 2014-11-11 2016-05-19 The Procter & Gamble Company Detergent or cleaning compositions with improved sudsing profile
WO2016074537A1 (en) * 2014-11-11 2016-05-19 The Procter & Gamble Company Detergent or cleaning compositions with improved sudsing profile
WO2016172158A1 (en) * 2015-04-21 2016-10-27 Kao Usa Wash-out hair treatment composition

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IT1145700B (en) 1986-11-05
NL8004710A (en) 1981-02-25
GR69885B (en) 1982-07-20
AU6081680A (en) 1981-02-26
SE8005886L (en) 1981-02-24
DK360680A (en) 1981-02-24
FR2463612A1 (en) 1981-02-27
NO802492L (en) 1981-02-24
IT8049463A0 (en) 1980-08-11
FI802631A (en) 1981-02-24
DE3029306A1 (en) 1981-03-12

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