TWI324105B - - Google Patents
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- TWI324105B TWI324105B TW095135593A TW95135593A TWI324105B TW I324105 B TWI324105 B TW I324105B TW 095135593 A TW095135593 A TW 095135593A TW 95135593 A TW95135593 A TW 95135593A TW I324105 B TWI324105 B TW I324105B
- Authority
- TW
- Taiwan
- Prior art keywords
- film
- adhesive layer
- polymer
- liquid crystal
- retardation film
- Prior art date
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- 239000012790 adhesive layer Substances 0.000 claims description 235
- 239000004973 liquid crystal related substance Substances 0.000 claims description 165
- 239000011241 protective layer Substances 0.000 claims description 94
- 229920005989 resin Polymers 0.000 claims description 90
- 239000011347 resin Substances 0.000 claims description 90
- -1 polyethylene terephthalate Polymers 0.000 claims description 73
- 230000001070 adhesive effect Effects 0.000 claims description 72
- 229920001577 copolymer Polymers 0.000 claims description 63
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 61
- 239000000853 adhesive Substances 0.000 claims description 60
- 210000002858 crystal cell Anatomy 0.000 claims description 59
- 239000000178 monomer Substances 0.000 claims description 56
- 239000003431 cross linking reagent Substances 0.000 claims description 45
- 239000011521 glass Substances 0.000 claims description 41
- 229920006254 polymer film Polymers 0.000 claims description 41
- 239000000203 mixture Substances 0.000 claims description 37
- 150000001875 compounds Chemical class 0.000 claims description 33
- 238000004132 cross linking Methods 0.000 claims description 33
- 235000021419 vinegar Nutrition 0.000 claims description 32
- 239000000052 vinegar Substances 0.000 claims description 31
- 150000002978 peroxides Chemical class 0.000 claims description 29
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 27
- 125000000217 alkyl group Chemical group 0.000 claims description 26
- 239000007822 coupling agent Substances 0.000 claims description 26
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 20
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 20
- 230000032683 aging Effects 0.000 claims description 19
- 229920003122 (meth)acrylate-based copolymer Polymers 0.000 claims description 18
- 229910052799 carbon Inorganic materials 0.000 claims description 16
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 14
- 230000009477 glass transition Effects 0.000 claims description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 239000012461 cellulose resin Substances 0.000 claims description 10
- 239000005001 laminate film Substances 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims description 6
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 4
- 229910052702 rhenium Inorganic materials 0.000 claims description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 230000008020 evaporation Effects 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
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- 238000000034 method Methods 0.000 description 99
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- 239000000758 substrate Substances 0.000 description 50
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- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 36
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- 238000002834 transmittance Methods 0.000 description 25
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 24
- 239000000047 product Substances 0.000 description 23
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- 239000004372 Polyvinyl alcohol Substances 0.000 description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 15
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- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 12
- 239000007787 solid Substances 0.000 description 12
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- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 11
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- 238000001035 drying Methods 0.000 description 11
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- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 9
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- 239000002585 base Substances 0.000 description 8
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- IBPADELTPKRSCQ-UHFFFAOYSA-N 9h-fluoren-1-yl prop-2-enoate Chemical compound C1C2=CC=CC=C2C2=C1C(OC(=O)C=C)=CC=C2 IBPADELTPKRSCQ-UHFFFAOYSA-N 0.000 description 7
- 238000005227 gel permeation chromatography Methods 0.000 description 7
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
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- 239000004743 Polypropylene Substances 0.000 description 6
- 239000003522 acrylic cement Substances 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000000470 constituent Substances 0.000 description 6
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- 229920001155 polypropylene Polymers 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 5
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- 238000009792 diffusion process Methods 0.000 description 5
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 5
- 238000010030 laminating Methods 0.000 description 5
- 239000012528 membrane Substances 0.000 description 5
- 229920005604 random copolymer Polymers 0.000 description 5
- 229910052707 ruthenium Inorganic materials 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 238000005266 casting Methods 0.000 description 4
- 238000003851 corona treatment Methods 0.000 description 4
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 150000002431 hydrogen Chemical group 0.000 description 4
- 238000005286 illumination Methods 0.000 description 4
- 239000012948 isocyanate Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- RTTZISZSHSCFRH-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)benzene Chemical class O=C=NCC1=CC=CC(CN=C=O)=C1 RTTZISZSHSCFRH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 229920008347 Cellulose acetate propionate Polymers 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 3
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229920002978 Vinylon Polymers 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- IYNWNKYVHCVUCJ-UHFFFAOYSA-N bismuth Chemical compound [Bi].[Bi] IYNWNKYVHCVUCJ-UHFFFAOYSA-N 0.000 description 3
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 3
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- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
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- UMRZSTCPUPJPOJ-KNVOCYPGSA-N norbornane Chemical group C1C[C@H]2CC[C@@H]1C2 UMRZSTCPUPJPOJ-KNVOCYPGSA-N 0.000 description 3
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- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
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- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- 125000003396 thiol group Chemical group [H]S* 0.000 description 2
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
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-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
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- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/13363—Birefringent elements, e.g. for optical compensation
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- G—PHYSICS
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- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
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| JP3676474B2 (ja) * | 1996-01-09 | 2005-07-27 | 日東電工株式会社 | 光学フィルム及び液晶表示装置 |
| JP2982869B2 (ja) | 1998-04-16 | 1999-11-29 | インターナショナル・ビジネス・マシーンズ・コーポレイション | 液晶表示装置 |
| JP2001272542A (ja) * | 2000-03-27 | 2001-10-05 | Nitto Denko Corp | 光学補償フィルム付き偏光板及び液晶表示装置 |
| JP4421120B2 (ja) * | 2001-01-23 | 2010-02-24 | 日東電工株式会社 | 液晶表示用広視野角偏光フィルムの製造方法 |
| JP4434554B2 (ja) | 2002-01-18 | 2010-03-17 | 旭化成ケミカルズ株式会社 | 表面保護用粘着フィルム |
| JP4017156B2 (ja) * | 2003-01-27 | 2007-12-05 | 日東電工株式会社 | 粘着型光学補償層付偏光板および画像表示装置 |
| JP2005242171A (ja) * | 2004-02-27 | 2005-09-08 | Sekisui Chem Co Ltd | 偏光子保護フィルム及び偏光板 |
| TW200540146A (en) * | 2004-04-15 | 2005-12-16 | Nitto Denko Corp | Adhesive composition, adhesive layer and method for producing the same |
| JP5187930B2 (ja) | 2004-04-15 | 2013-04-24 | 日東電工株式会社 | 粘着剤組成物、粘着剤層、およびその製造方法 |
| JP4587459B2 (ja) | 2004-12-17 | 2010-11-24 | 日東電工株式会社 | 光学部材用粘着剤組成物および光学部材用粘着剤層の製造方法 |
| JP4121030B2 (ja) * | 2004-08-19 | 2008-07-16 | 日東電工株式会社 | 保護フィルム付位相差板、その製造方法、保護フィルム付粘着型位相差板および保護フィルム付粘着型光学素材 |
| JP4807774B2 (ja) * | 2005-10-20 | 2011-11-02 | 日東電工株式会社 | 液晶パネルおよび液晶表示装置 |
| JP4697871B2 (ja) * | 2005-10-20 | 2011-06-08 | 日東電工株式会社 | 積層フィルム |
-
2005
- 2005-10-20 JP JP2005305198A patent/JP4697871B2/ja not_active Expired - Lifetime
-
2006
- 2006-09-14 CN CN2006800326071A patent/CN101258028B/zh active Active
- 2006-09-14 US US12/090,307 patent/US7929086B2/en not_active Expired - Fee Related
- 2006-09-14 WO PCT/JP2006/318255 patent/WO2007046202A1/ja not_active Ceased
- 2006-09-14 KR KR1020087002550A patent/KR101031208B1/ko active Active
- 2006-09-26 TW TW095135593A patent/TW200736050A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US7929086B2 (en) | 2011-04-19 |
| US20090279030A1 (en) | 2009-11-12 |
| TW200736050A (en) | 2007-10-01 |
| WO2007046202A1 (ja) | 2007-04-26 |
| JP4697871B2 (ja) | 2011-06-08 |
| KR101031208B1 (ko) | 2011-04-26 |
| KR20080027907A (ko) | 2008-03-28 |
| JP2007111970A (ja) | 2007-05-10 |
| CN101258028A (zh) | 2008-09-03 |
| CN101258028B (zh) | 2013-04-03 |
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