TWI243707B - Composite membrane and method for making the same - Google Patents

Info

Publication number

TWI243707B

TWI243707B TW090109021A TW90109021A TWI243707B TW I243707 B TWI243707 B TW I243707B TW 090109021 A TW090109021 A TW 090109021A TW 90109021 A TW90109021 A TW 90109021A TW I243707 B TWI243707 B TW I243707B

Authority

TW

Taiwan

Prior art keywords

phosphate

phosphine

bis

tri

patent application

Prior art date

2000-04-17

Links

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• Global Dossier
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• 238000000034 method Methods 0.000 title claims abstract description 49
• 239000012528 membrane Substances 0.000 title claims abstract description 36
• 239000002131 composite material Substances 0.000 title claims abstract description 17
• 150000001412 amines Chemical class 0.000 claims abstract description 90
• 239000008139 complexing agent Substances 0.000 claims abstract description 77
• 230000004907 flux Effects 0.000 claims abstract description 41
• 239000004952 Polyamide Substances 0.000 claims abstract description 17
• 238000006243 chemical reaction Methods 0.000 claims abstract description 17
• 229920002647 polyamide Polymers 0.000 claims abstract description 17
• 238000001223 reverse osmosis Methods 0.000 claims abstract description 16
• 230000008569 process Effects 0.000 claims abstract description 3
• XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 332
• 229910019142 PO4 Inorganic materials 0.000 claims description 307
• 239000010452 phosphate Substances 0.000 claims description 305
• NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 293
• -1 fluorenyl compound Chemical class 0.000 claims description 203
• 229910000073 phosphorus hydride Inorganic materials 0.000 claims description 168
• 239000010408 film Substances 0.000 claims description 78
• 239000000243 solution Substances 0.000 claims description 61
• 150000003839 salts Chemical class 0.000 claims description 53
• 239000002253 acid Substances 0.000 claims description 30
• 235000011180 diphosphates Nutrition 0.000 claims description 30
• XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims description 29
• 229940122361 Bisphosphonate Drugs 0.000 claims description 28
• 150000004663 bisphosphonates Chemical class 0.000 claims description 28
• 229910052698 phosphorus Inorganic materials 0.000 claims description 28
• 150000001875 compounds Chemical class 0.000 claims description 27
• 239000011574 phosphorus Substances 0.000 claims description 26
• ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 25
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
• OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 24
• 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 21
• 239000000126 substance Substances 0.000 claims description 20
• 239000000463 material Substances 0.000 claims description 15
• 229920000768 polyamine Polymers 0.000 claims description 15
• 125000003118 aryl group Chemical group 0.000 claims description 10
• 230000008859 change Effects 0.000 claims description 10
• 150000004820 halides Chemical class 0.000 claims description 10
• 229910052717 sulfur Inorganic materials 0.000 claims description 10
• 239000010409 thin film Substances 0.000 claims description 10
• 230000000737 periodic effect Effects 0.000 claims description 8
• 229910052742 iron Inorganic materials 0.000 claims description 7
• 229920000642 polymer Polymers 0.000 claims description 7
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
• 125000001931 aliphatic group Chemical group 0.000 claims description 6
• 229910052799 carbon Inorganic materials 0.000 claims description 6
• 125000000623 heterocyclic group Chemical group 0.000 claims description 6
• 230000003993 interaction Effects 0.000 claims description 6
• 229910052760 oxygen Inorganic materials 0.000 claims description 6
• 239000001301 oxygen Substances 0.000 claims description 6
• UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 6
• 229910052787 antimony Inorganic materials 0.000 claims description 5
• 239000007864 aqueous solution Substances 0.000 claims description 5
• 229910052785 arsenic Inorganic materials 0.000 claims description 5
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
• 229910052804 chromium Inorganic materials 0.000 claims description 5
• 229910052802 copper Inorganic materials 0.000 claims description 5
• 229910052751 metal Inorganic materials 0.000 claims description 5
• 239000002184 metal Substances 0.000 claims description 5
• 239000012466 permeate Substances 0.000 claims description 5
• 229910052711 selenium Inorganic materials 0.000 claims description 5
• 229910052710 silicon Inorganic materials 0.000 claims description 5
• 229910052714 tellurium Inorganic materials 0.000 claims description 5
• 229910052725 zinc Inorganic materials 0.000 claims description 5
• 239000004642 Polyimide Substances 0.000 claims description 4
• QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
• 125000000217 alkyl group Chemical group 0.000 claims description 4
• 229920001721 polyimide Polymers 0.000 claims description 4
• 238000004090 dissolution Methods 0.000 claims description 3
• 229910052759 nickel Inorganic materials 0.000 claims description 3
• 150000003003 phosphines Chemical class 0.000 claims description 3
• VKFFEYLSKIYTSJ-UHFFFAOYSA-N tetraazanium;phosphonato phosphate Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].[O-]P([O-])(=O)OP([O-])([O-])=O VKFFEYLSKIYTSJ-UHFFFAOYSA-N 0.000 claims description 3
• 230000026030 halogenation Effects 0.000 claims description 2
• 238000005658 halogenation reaction Methods 0.000 claims description 2
• 229910052745 lead Inorganic materials 0.000 claims description 2
• 239000010703 silicon Substances 0.000 claims description 2
• 229910021653 sulphate ion Inorganic materials 0.000 claims description 2
• 125000004434 sulfur atom Chemical group 0.000 claims 4
• DAVPISDSWNRILV-UHFFFAOYSA-N P(=O)(O)(O)C1=NC=2NC(NC(C=2N1)=O)=O Chemical compound P(=O)(O)(O)C1=NC=2NC(NC(C=2N1)=O)=O DAVPISDSWNRILV-UHFFFAOYSA-N 0.000 claims 2
• BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims 2
• ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims 2
• 238000011084 recovery Methods 0.000 claims 2
• 239000004254 Ammonium phosphate Substances 0.000 claims 1
• 229910000148 ammonium phosphate Inorganic materials 0.000 claims 1
• 235000019289 ammonium phosphates Nutrition 0.000 claims 1
• 125000004429 atom Chemical group 0.000 claims 1
• MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims 1
• 230000002140 halogenating effect Effects 0.000 claims 1
• 150000002632 lipids Chemical group 0.000 claims 1
• 230000003647 oxidation Effects 0.000 claims 1
• 238000007254 oxidation reaction Methods 0.000 claims 1
• 150000008300 phosphoramidites Chemical class 0.000 claims 1
• WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 claims 1
• MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 claims 1
• 238000001728 nano-filtration Methods 0.000 abstract description 6
• 238000004519 manufacturing process Methods 0.000 abstract description 3
• 150000001266 acyl halides Chemical class 0.000 abstract 3
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 509
• 235000021317 phosphate Nutrition 0.000 description 306
• 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 55
• 238000011049 filling Methods 0.000 description 42
• CMPQUABWPXYYSH-UHFFFAOYSA-N phenyl phosphate Chemical compound OP(O)(=O)OC1=CC=CC=C1 CMPQUABWPXYYSH-UHFFFAOYSA-N 0.000 description 30
• 229940048084 pyrophosphate Drugs 0.000 description 30
• 230000002079 cooperative effect Effects 0.000 description 29
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 27
• RPGWZZNNEUHDAQ-UHFFFAOYSA-N phenylphosphine Chemical compound PC1=CC=CC=C1 RPGWZZNNEUHDAQ-UHFFFAOYSA-N 0.000 description 25
• ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 24
• GPAYUJZHTULNBE-UHFFFAOYSA-N diphenylphosphine Chemical compound C=1C=CC=CC=1PC1=CC=CC=C1 GPAYUJZHTULNBE-UHFFFAOYSA-N 0.000 description 22
• 239000002904 solvent Substances 0.000 description 16
• 239000003795 chemical substances by application Substances 0.000 description 14
• 238000001035 drying Methods 0.000 description 14
• 241000894007 species Species 0.000 description 13
• 239000002585 base Substances 0.000 description 12
• 239000004305 biphenyl Substances 0.000 description 12
• 235000010290 biphenyl Nutrition 0.000 description 12
• ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 12
• 238000002360 preparation method Methods 0.000 description 12
• 238000011282 treatment Methods 0.000 description 12
• RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 12
• 239000000203 mixture Substances 0.000 description 10
• 239000000178 monomer Substances 0.000 description 10
• 150000003013 phosphoric acid derivatives Chemical class 0.000 description 10
• ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 9
• XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
• 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 9
• FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
• 239000011248 coating agent Substances 0.000 description 8
• 238000000576 coating method Methods 0.000 description 8
• 150000002500 ions Chemical class 0.000 description 8
• 238000002156 mixing Methods 0.000 description 8
• 125000003277 amino group Chemical group 0.000 description 7
• 239000007789 gas Substances 0.000 description 7
• 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 7
• 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 7
• 230000000717 retained effect Effects 0.000 description 7
• 238000012360 testing method Methods 0.000 description 7
• ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 6
• QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
• 229910052776 Thorium Inorganic materials 0.000 description 6
• WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 6
• 150000002894 organic compounds Chemical class 0.000 description 6
• 239000012071 phase Substances 0.000 description 6
• STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical class CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 6
• UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 5
• VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
• GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical group C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 5
• 230000015572 biosynthetic process Effects 0.000 description 5
• 239000000460 chlorine Substances 0.000 description 5
• 229910052801 chlorine Inorganic materials 0.000 description 5
• 239000011651 chromium Substances 0.000 description 5
• NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 5
• 125000000524 functional group Chemical group 0.000 description 5
• 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
• 150000007857 hydrazones Chemical class 0.000 description 5
• 238000001471 micro-filtration Methods 0.000 description 5
• 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
• PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
• HLHZHCMELZFILJ-UHFFFAOYSA-N octan-4-yl dihydrogen phosphate Chemical compound CCCCC(CCC)OP(O)(O)=O HLHZHCMELZFILJ-UHFFFAOYSA-N 0.000 description 5
• 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
• 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
• OSRJBXRUXTUMBY-UHFFFAOYSA-N triheptylphosphane Chemical compound CCCCCCCP(CCCCCCC)CCCCCCC OSRJBXRUXTUMBY-UHFFFAOYSA-N 0.000 description 5
• ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 4
• 230000008901 benefit Effects 0.000 description 4
• HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 4
• LRNMTOCGEKHHAH-UHFFFAOYSA-N butan-2-yl dihydrogen phosphate Chemical compound CCC(C)OP(O)(O)=O LRNMTOCGEKHHAH-UHFFFAOYSA-N 0.000 description 4
• IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 4
• 239000013626 chemical specie Substances 0.000 description 4
• DVZIQPGIAQDYQH-UHFFFAOYSA-N diheptyl hydrogen phosphate Chemical compound CCCCCCCOP(O)(=O)OCCCCCCC DVZIQPGIAQDYQH-UHFFFAOYSA-N 0.000 description 4
• QDMDHWSMYFYOTN-UHFFFAOYSA-N heptan-4-yl dihydrogen phosphate Chemical compound CCCC(CCC)OP(O)(O)=O QDMDHWSMYFYOTN-UHFFFAOYSA-N 0.000 description 4
• IDWOBGCWYWUXCW-UHFFFAOYSA-N hexan-2-yl dihydrogen phosphate Chemical compound CCCCC(C)OP(O)(O)=O IDWOBGCWYWUXCW-UHFFFAOYSA-N 0.000 description 4
• VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
• VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
• STMLQIACVZOCHU-UHFFFAOYSA-N octan-2-yl dihydrogen phosphate Chemical compound CCCCCCC(C)OP(O)(O)=O STMLQIACVZOCHU-UHFFFAOYSA-N 0.000 description 4
• YJBMMHPCGWCCOH-UHFFFAOYSA-N octan-3-yl dihydrogen phosphate Chemical compound CCCCCC(CC)OP(O)(O)=O YJBMMHPCGWCCOH-UHFFFAOYSA-N 0.000 description 4
• WRKCIHRWQZQBOL-UHFFFAOYSA-N octyl dihydrogen phosphate Chemical compound CCCCCCCCOP(O)(O)=O WRKCIHRWQZQBOL-UHFFFAOYSA-N 0.000 description 4
• AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 4
• XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 4
• 239000011734 sodium Substances 0.000 description 4
• 229910052708 sodium Inorganic materials 0.000 description 4
• 239000011780 sodium chloride Substances 0.000 description 4
• RMZAYIKUYWXQPB-UHFFFAOYSA-N trioctylphosphane Chemical compound CCCCCCCCP(CCCCCCCC)CCCCCCCC RMZAYIKUYWXQPB-UHFFFAOYSA-N 0.000 description 4
• WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
• WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
• QLZHNIAADXEJJP-UHFFFAOYSA-N Phenylphosphonic acid Chemical class OP(O)(=O)C1=CC=CC=C1 QLZHNIAADXEJJP-UHFFFAOYSA-N 0.000 description 3
• 150000001298 alcohols Chemical class 0.000 description 3
• 229910052782 aluminium Inorganic materials 0.000 description 3
• 150000001409 amidines Chemical class 0.000 description 3
• 229910021529 ammonia Inorganic materials 0.000 description 3
• 238000004458 analytical method Methods 0.000 description 3
• BNMJSBUIDQYHIN-UHFFFAOYSA-N butyl dihydrogen phosphate Chemical compound CCCCOP(O)(O)=O BNMJSBUIDQYHIN-UHFFFAOYSA-N 0.000 description 3
• 150000007942 carboxylates Chemical class 0.000 description 3
• 239000010949 copper Substances 0.000 description 3
• LJJVZJSGXHJIPP-UHFFFAOYSA-N ethylpentyl Chemical group [CH2+]CCC[CH]C[CH2-] LJJVZJSGXHJIPP-UHFFFAOYSA-N 0.000 description 3
• KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 3
• 229910052732 germanium Inorganic materials 0.000 description 3
• GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 3
• 238000010438 heat treatment Methods 0.000 description 3
• CNPKMYBCUOVDCE-UHFFFAOYSA-N heptan-2-yl dihydrogen phosphate Chemical compound CCCCCC(C)OP(O)(O)=O CNPKMYBCUOVDCE-UHFFFAOYSA-N 0.000 description 3
• WUFOXJPREAWDFD-UHFFFAOYSA-N heptan-3-yl dihydrogen phosphate Chemical compound CCCCC(CC)OP(O)(O)=O WUFOXJPREAWDFD-UHFFFAOYSA-N 0.000 description 3
• AXSGBDGQLKZKQI-UHFFFAOYSA-N hexan-3-yl dihydrogen phosphate Chemical compound CCCC(CC)OP(O)(O)=O AXSGBDGQLKZKQI-UHFFFAOYSA-N 0.000 description 3
• PHNWGDTYCJFUGZ-UHFFFAOYSA-N hexyl dihydrogen phosphate Chemical compound CCCCCCOP(O)(O)=O PHNWGDTYCJFUGZ-UHFFFAOYSA-N 0.000 description 3
• 230000007062 hydrolysis Effects 0.000 description 3
• 238000006460 hydrolysis reaction Methods 0.000 description 3
• 238000009434 installation Methods 0.000 description 3
• 125000005647 linker group Chemical group 0.000 description 3
• 238000005259 measurement Methods 0.000 description 3
• 150000002739 metals Chemical class 0.000 description 3
• 238000012856 packing Methods 0.000 description 3
• 125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 description 3
• 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 3
• 229920002098 polyfluorene Polymers 0.000 description 3
• 239000011669 selenium Substances 0.000 description 3
• 238000005507 spraying Methods 0.000 description 3
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
• 239000011701 zinc Substances 0.000 description 3
• GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 2
• YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 2
• WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 2
• XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
• JGSYKOGZFMBYAQ-UHFFFAOYSA-N CC[P]CC Chemical compound CC[P]CC JGSYKOGZFMBYAQ-UHFFFAOYSA-N 0.000 description 2
• JYFHYPJRHGVZDY-UHFFFAOYSA-N Dibutyl phosphate Chemical compound CCCCOP(O)(=O)OCCCC JYFHYPJRHGVZDY-UHFFFAOYSA-N 0.000 description 2
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical group CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
• KKUKTXOBAWVSHC-UHFFFAOYSA-N Dimethylphosphate Chemical compound COP(O)(=O)OC KKUKTXOBAWVSHC-UHFFFAOYSA-N 0.000 description 2
• QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
• VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 2
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
• CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
• BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
• IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
• NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
• QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
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• 125000003368 amide group Chemical group 0.000 description 1
• 125000000747 amidyl group Chemical group [H][N-]* 0.000 description 1
• 239000000908 ammonium hydroxide Substances 0.000 description 1
• 150000008064 anhydrides Chemical class 0.000 description 1
• 125000000129 anionic group Chemical group 0.000 description 1
• 239000008346 aqueous phase Substances 0.000 description 1
• 239000003125 aqueous solvent Substances 0.000 description 1
• 229910052786 argon Inorganic materials 0.000 description 1
• 150000001491 aromatic compounds Chemical class 0.000 description 1
• 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
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• 230000009286 beneficial effect Effects 0.000 description 1
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• 125000006267 biphenyl group Chemical group 0.000 description 1
• ZLMKQJQJURXYLC-UHFFFAOYSA-N bis(2-ethylhexoxy)-oxophosphanium Chemical compound CCCCC(CC)CO[P+](=O)OCC(CC)CCCC ZLMKQJQJURXYLC-UHFFFAOYSA-N 0.000 description 1
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• VEYMELJZIZTCKO-UHFFFAOYSA-N butyl diheptan-3-yl phosphate Chemical compound CCCCC(CC)OP(=O)(OCCCC)OC(CC)CCCC VEYMELJZIZTCKO-UHFFFAOYSA-N 0.000 description 1
• JVMHFHNCWPAQEK-UHFFFAOYSA-N butyl diheptan-4-yl phosphate Chemical compound CCCCOP(=O)(OC(CCC)CCC)OC(CCC)CCC JVMHFHNCWPAQEK-UHFFFAOYSA-N 0.000 description 1
• LRIOWFFQMMTNAF-UHFFFAOYSA-N butyl diheptyl phosphate Chemical compound CCCCCCCOP(=O)(OCCCC)OCCCCCCC LRIOWFFQMMTNAF-UHFFFAOYSA-N 0.000 description 1
• CRSPMRUULWKRSV-UHFFFAOYSA-N butyl dihexan-2-yl phosphate Chemical compound CCCCC(C)OP(=O)(OCCCC)OC(C)CCCC CRSPMRUULWKRSV-UHFFFAOYSA-N 0.000 description 1
• VRWZWQBHJLHTRN-UHFFFAOYSA-N butyl dihexan-3-yl phosphate Chemical compound CCCCOP(=O)(OC(CC)CCC)OC(CC)CCC VRWZWQBHJLHTRN-UHFFFAOYSA-N 0.000 description 1
• KXRDCTOXSGAUJA-UHFFFAOYSA-N butyl dihexyl phosphate Chemical compound CCCCCCOP(=O)(OCCCC)OCCCCCC KXRDCTOXSGAUJA-UHFFFAOYSA-N 0.000 description 1
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• HGTQMWPQXZWQRE-UHFFFAOYSA-N butyl dioctan-3-yl phosphate Chemical compound CCCCCC(CC)OP(=O)(OCCCC)OC(CC)CCCCC HGTQMWPQXZWQRE-UHFFFAOYSA-N 0.000 description 1
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• COPHVUDURPSYBO-UHFFFAOYSA-N butyl dioctyl phosphate Chemical compound CCCCCCCCOP(=O)(OCCCC)OCCCCCCCC COPHVUDURPSYBO-UHFFFAOYSA-N 0.000 description 1
• RGVAKNWGKBROPQ-UHFFFAOYSA-N butyl dipentan-2-yl phosphate Chemical class CCCCOP(=O)(OC(C)CCC)OC(C)CCC RGVAKNWGKBROPQ-UHFFFAOYSA-N 0.000 description 1
• GURGLJZVSNHVCE-UHFFFAOYSA-N butyl dipentan-3-yl phosphate Chemical compound CCCCOP(=O)(OC(CC)CC)OC(CC)CC GURGLJZVSNHVCE-UHFFFAOYSA-N 0.000 description 1
• NBHKNKULFJUFEV-UHFFFAOYSA-N butyl dipentyl phosphate Chemical compound CCCCCOP(=O)(OCCCC)OCCCCC NBHKNKULFJUFEV-UHFFFAOYSA-N 0.000 description 1
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• FWNZSQVVCQVDOJ-UHFFFAOYSA-N butyl octyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OCCCC FWNZSQVVCQVDOJ-UHFFFAOYSA-N 0.000 description 1
• GDHYXEJZFJQZPB-UHFFFAOYSA-N butyl pentyl hydrogen phosphate Chemical compound CCCCCOP(O)(=O)OCCCC GDHYXEJZFJQZPB-UHFFFAOYSA-N 0.000 description 1
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• ROKKESZHFRSLMO-UHFFFAOYSA-N butyl(dioctyl)phosphane Chemical compound CCCCCCCCP(CCCC)CCCCCCCC ROKKESZHFRSLMO-UHFFFAOYSA-N 0.000 description 1
• NSUWIICJYJTDAX-UHFFFAOYSA-N butyl-decan-4-yl-trihydroxy-lambda5-phosphane Chemical compound CCCCCCC(CCC)P(O)(O)(O)CCCC NSUWIICJYJTDAX-UHFFFAOYSA-N 0.000 description 1
• MDUACDVHFVHCRK-UHFFFAOYSA-N butyl-di(heptan-2-yl)phosphane Chemical compound CCCCCC(C)P(CCCC)C(C)CCCCC MDUACDVHFVHCRK-UHFFFAOYSA-N 0.000 description 1
• NRRNMGXRQHERLW-UHFFFAOYSA-N butyl-di(heptan-3-yl)phosphane Chemical compound CCCCC(CC)P(CCCC)C(CC)CCCC NRRNMGXRQHERLW-UHFFFAOYSA-N 0.000 description 1
• WBZJCLRWVREOHH-UHFFFAOYSA-N butyl-di(heptan-4-yl)phosphane Chemical compound CCCCP(C(CCC)CCC)C(CCC)CCC WBZJCLRWVREOHH-UHFFFAOYSA-N 0.000 description 1
• LWQFACWEKHDRLT-UHFFFAOYSA-N butyl-di(hexan-2-yl)phosphane Chemical compound CCCCC(C)P(CCCC)C(C)CCCC LWQFACWEKHDRLT-UHFFFAOYSA-N 0.000 description 1
• QKUQSEQGUMBKHJ-UHFFFAOYSA-N butyl-di(hexan-3-yl)phosphane Chemical compound CCCCP(C(CC)CCC)C(CC)CCC QKUQSEQGUMBKHJ-UHFFFAOYSA-N 0.000 description 1
• IYNSIOSWDRZKSP-UHFFFAOYSA-N butyl-di(octan-2-yl)phosphane Chemical compound CCCCCCC(C)P(CCCC)C(C)CCCCCC IYNSIOSWDRZKSP-UHFFFAOYSA-N 0.000 description 1
• UGNJZLLOWOWYGQ-UHFFFAOYSA-N butyl-di(octan-3-yl)phosphane Chemical compound CCCCCC(CC)P(CCCC)C(CC)CCCCC UGNJZLLOWOWYGQ-UHFFFAOYSA-N 0.000 description 1
• AGBFJGITXLOAGL-UHFFFAOYSA-N butyl-di(octan-4-yl)phosphane Chemical compound CCCCC(CCC)P(CCCC)C(CCC)CCCC AGBFJGITXLOAGL-UHFFFAOYSA-N 0.000 description 1
• OBUOEEUFMIUOIL-UHFFFAOYSA-N butyl-ethyl-heptylphosphane Chemical compound CCCCCCCP(CC)CCCC OBUOEEUFMIUOIL-UHFFFAOYSA-N 0.000 description 1
• DVQCSQKAKACEGZ-UHFFFAOYSA-N butyl-ethyl-hexylphosphane Chemical compound CCCCCCP(CC)CCCC DVQCSQKAKACEGZ-UHFFFAOYSA-N 0.000 description 1
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• IYEONUWDCJJQLZ-UHFFFAOYSA-N butyl-trihydroxy-undecan-4-yl-lambda5-phosphane Chemical compound CCCCCCCC(CCC)P(O)(O)(O)CCCC IYEONUWDCJJQLZ-UHFFFAOYSA-N 0.000 description 1
• 229910052792 caesium Inorganic materials 0.000 description 1
• 239000011575 calcium Substances 0.000 description 1
• 229910052791 calcium Inorganic materials 0.000 description 1
• 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
• 125000002091 cationic group Chemical group 0.000 description 1
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• 229920000457 chlorinated polyvinyl chloride Polymers 0.000 description 1
• 239000012320 chlorinating reagent Substances 0.000 description 1
• 150000001805 chlorine compounds Chemical class 0.000 description 1
• 238000004587 chromatography analysis Methods 0.000 description 1
• 238000004140 cleaning Methods 0.000 description 1
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• 229910017052 cobalt Inorganic materials 0.000 description 1
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• GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
• JAWGVVJVYSANRY-UHFFFAOYSA-N cobalt(3+) Chemical compound [Co+3] JAWGVVJVYSANRY-UHFFFAOYSA-N 0.000 description 1
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• 238000004737 colorimetric analysis Methods 0.000 description 1
• 230000000052 comparative effect Effects 0.000 description 1
• 230000009918 complex formation Effects 0.000 description 1
• 230000000536 complexating effect Effects 0.000 description 1
• 238000007796 conventional method Methods 0.000 description 1
• 230000000875 corresponding effect Effects 0.000 description 1
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• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
• 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
• LQVWRJVXNVMLKR-UHFFFAOYSA-N decan-3-yl dihydrogen phosphate Chemical compound CCCCCCCC(CC)OP(O)(O)=O LQVWRJVXNVMLKR-UHFFFAOYSA-N 0.000 description 1
• VEUUGZQJNGFYBU-UHFFFAOYSA-N decan-4-yl dihydrogen phosphate Chemical compound CCCCCCC(CCC)OP(O)(O)=O VEUUGZQJNGFYBU-UHFFFAOYSA-N 0.000 description 1
• IOBJGLZSURKVQX-UHFFFAOYSA-N decyl(ethoxy)phosphinic acid Chemical compound CCCCCCCCCCP(O)(=O)OCC IOBJGLZSURKVQX-UHFFFAOYSA-N 0.000 description 1
• DZQISOJKASMITI-UHFFFAOYSA-N decyl-dioxido-oxo-$l^{5}-phosphane;hydron Chemical compound CCCCCCCCCCP(O)(O)=O DZQISOJKASMITI-UHFFFAOYSA-N 0.000 description 1
• GMQLHPPPELBHKD-UHFFFAOYSA-N decyl-ethyl-trihydroxy-lambda5-phosphane Chemical compound CCCCCCCCCCP(O)(O)(O)CC GMQLHPPPELBHKD-UHFFFAOYSA-N 0.000 description 1
• DWHUEFYNZKYMMY-UHFFFAOYSA-N decylphosphinic acid Chemical compound CCCCCCCCCCP(O)=O DWHUEFYNZKYMMY-UHFFFAOYSA-N 0.000 description 1
• 210000001787 dendrite Anatomy 0.000 description 1
• 230000001419 dependent effect Effects 0.000 description 1
• 238000010612 desalination reaction Methods 0.000 description 1
• DBUFZLCXJQFEBP-UHFFFAOYSA-N di(heptan-2-yl)-methylphosphane Chemical compound CCCCCC(C)P(C)C(C)CCCCC DBUFZLCXJQFEBP-UHFFFAOYSA-N 0.000 description 1
• AJNJYBVMIMKWTP-UHFFFAOYSA-N di(heptan-2-yl)-phenylphosphane Chemical compound CCCCCC(C)P(C(C)CCCCC)C1=CC=CC=C1 AJNJYBVMIMKWTP-UHFFFAOYSA-N 0.000 description 1
• HNVNMEZSSCNGRL-UHFFFAOYSA-N di(heptan-2-yl)-propan-2-ylphosphane Chemical compound CCCCCC(C)P(C(C)C)C(C)CCCCC HNVNMEZSSCNGRL-UHFFFAOYSA-N 0.000 description 1
• LMYBOJICJLLAHL-UHFFFAOYSA-N di(heptan-2-yl)-propylphosphane Chemical compound CCCCCC(C)P(CCC)C(C)CCCCC LMYBOJICJLLAHL-UHFFFAOYSA-N 0.000 description 1
• MQBZIDZJUNTDOE-UHFFFAOYSA-N di(heptan-3-yl)-methylphosphane Chemical compound CCCCC(CC)P(C)C(CC)CCCC MQBZIDZJUNTDOE-UHFFFAOYSA-N 0.000 description 1
• LDIXGOCWSPGHFI-UHFFFAOYSA-N di(heptan-3-yl)-propan-2-ylphosphane Chemical compound CCCCC(CC)P(C(C)C)C(CC)CCCC LDIXGOCWSPGHFI-UHFFFAOYSA-N 0.000 description 1
• JXMUUWQFUUUJHN-UHFFFAOYSA-N di(heptan-3-yl)-propylphosphane Chemical compound CCCCC(CC)P(CCC)C(CC)CCCC JXMUUWQFUUUJHN-UHFFFAOYSA-N 0.000 description 1
• PSPFXDXJHVASTB-UHFFFAOYSA-N di(heptan-4-yl)-methylphosphane Chemical compound CCCC(CCC)P(C)C(CCC)CCC PSPFXDXJHVASTB-UHFFFAOYSA-N 0.000 description 1
• INJKYCUGQPYYGC-UHFFFAOYSA-N di(heptan-4-yl)-propan-2-ylphosphane Chemical compound CCCC(CCC)P(C(C)C)C(CCC)CCC INJKYCUGQPYYGC-UHFFFAOYSA-N 0.000 description 1
• QTVPSKQYRRDASW-UHFFFAOYSA-N di(heptan-4-yl)-propylphosphane Chemical compound CCCC(CCC)P(CCC)C(CCC)CCC QTVPSKQYRRDASW-UHFFFAOYSA-N 0.000 description 1
• ICLSLMPMMCPQST-UHFFFAOYSA-N di(hexan-2-yl)-methylphosphane Chemical compound CCCCC(C)P(C)C(C)CCCC ICLSLMPMMCPQST-UHFFFAOYSA-N 0.000 description 1
• FFXJGANYEWKUQZ-UHFFFAOYSA-N di(hexan-2-yl)-propylphosphane Chemical compound CCCCC(C)P(CCC)C(C)CCCC FFXJGANYEWKUQZ-UHFFFAOYSA-N 0.000 description 1
• IFLAWFVGKYMWSZ-UHFFFAOYSA-N di(hexan-3-yl)-methylphosphane Chemical compound CCCC(CC)P(C)C(CC)CCC IFLAWFVGKYMWSZ-UHFFFAOYSA-N 0.000 description 1
• DTQXKAMYVZJNDY-UHFFFAOYSA-N di(hexan-3-yl)-propylphosphane Chemical compound CCCC(CC)P(CCC)C(CC)CCC DTQXKAMYVZJNDY-UHFFFAOYSA-N 0.000 description 1
• JILUVVJYOFGZAU-UHFFFAOYSA-N di(octan-2-yl)-phenylphosphane Chemical compound CCCCCCC(C)P(C(C)CCCCCC)C1=CC=CC=C1 JILUVVJYOFGZAU-UHFFFAOYSA-N 0.000 description 1
• JRPWZVGPIHSVSX-UHFFFAOYSA-N di(octan-2-yl)-propan-2-ylphosphane Chemical compound CCCCCCC(C)P(C(C)C)C(C)CCCCCC JRPWZVGPIHSVSX-UHFFFAOYSA-N 0.000 description 1
• RCNDVLRYKKZKBS-UHFFFAOYSA-N di(octan-2-yl)-propylphosphane Chemical compound CCCCCCC(C)P(CCC)C(C)CCCCCC RCNDVLRYKKZKBS-UHFFFAOYSA-N 0.000 description 1
• QCXSXQYOHOXWEB-UHFFFAOYSA-N di(octan-3-yl)-phenylphosphane Chemical compound CCCCCC(CC)P(C(CC)CCCCC)C1=CC=CC=C1 QCXSXQYOHOXWEB-UHFFFAOYSA-N 0.000 description 1
• SRQYNRZLITUHBC-UHFFFAOYSA-N di(octan-3-yl)-propan-2-ylphosphane Chemical compound CCCCCC(CC)P(C(C)C)C(CC)CCCCC SRQYNRZLITUHBC-UHFFFAOYSA-N 0.000 description 1
• PUIOYIARFPAHRG-UHFFFAOYSA-N di(octan-4-yl)-phenylphosphane Chemical compound CCCCC(CCC)P(C(CCC)CCCC)C1=CC=CC=C1 PUIOYIARFPAHRG-UHFFFAOYSA-N 0.000 description 1
• CFJYXIAWNRUKOC-UHFFFAOYSA-N di(octan-4-yl)-propan-2-ylphosphane Chemical compound CCCCC(CCC)P(C(C)C)C(CCC)CCCC CFJYXIAWNRUKOC-UHFFFAOYSA-N 0.000 description 1
• UAJUDLKNGNDXKW-UHFFFAOYSA-N di(octan-4-yl)-propylphosphane Chemical compound CCCCC(CCC)P(CCC)C(CCC)CCCC UAJUDLKNGNDXKW-UHFFFAOYSA-N 0.000 description 1
• HDFFVHSMHLDSLO-UHFFFAOYSA-M dibenzyl phosphate Chemical compound C=1C=CC=CC=1COP(=O)([O-])OCC1=CC=CC=C1 HDFFVHSMHLDSLO-UHFFFAOYSA-M 0.000 description 1
• QZVALCYYGHPQRD-UHFFFAOYSA-N dibutan-2-yl hydrogen phosphate Chemical compound CCC(C)OP(O)(=O)OC(C)CC QZVALCYYGHPQRD-UHFFFAOYSA-N 0.000 description 1
• KOZZHKFDXSNGNX-UHFFFAOYSA-N dibutan-2-yl phenyl phosphate Chemical compound CCC(C)OP(=O)(OC(C)CC)OC1=CC=CC=C1 KOZZHKFDXSNGNX-UHFFFAOYSA-N 0.000 description 1
• YICSVBJRVMLQNS-UHFFFAOYSA-N dibutyl phenyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OC1=CC=CC=C1 YICSVBJRVMLQNS-UHFFFAOYSA-N 0.000 description 1
• BVXOPEOQUQWRHQ-UHFFFAOYSA-N dibutyl phosphite Chemical compound CCCCOP([O-])OCCCC BVXOPEOQUQWRHQ-UHFFFAOYSA-N 0.000 description 1
• FEYYOXFAQQJEIG-UHFFFAOYSA-N dibutyl sulfite Chemical compound CCCCOS(=O)OCCCC FEYYOXFAQQJEIG-UHFFFAOYSA-N 0.000 description 1
• CBAXKGZPFRYMIV-UHFFFAOYSA-N didecyl(trihydroxy)-$l^{5}-phosphane Chemical compound CCCCCCCCCCP(O)(O)(O)CCCCCCCCCC CBAXKGZPFRYMIV-UHFFFAOYSA-N 0.000 description 1
• KLXFSKITMRWDPM-UHFFFAOYSA-N diethyl 2-sulfanylbutanedioate Chemical compound CCOC(=O)CC(S)C(=O)OCC KLXFSKITMRWDPM-UHFFFAOYSA-N 0.000 description 1
• UCQFCFPECQILOL-UHFFFAOYSA-N diethyl hydrogen phosphate Chemical compound CCOP(O)(=O)OCC UCQFCFPECQILOL-UHFFFAOYSA-N 0.000 description 1
• UAEWCWCMYQAIDR-UHFFFAOYSA-N diethyl methyl phosphate Chemical compound CCOP(=O)(OC)OCC UAEWCWCMYQAIDR-UHFFFAOYSA-N 0.000 description 1
• ITJPTURSPJESQC-UHFFFAOYSA-N diethyl pentyl phosphate Chemical compound CCCCCOP(=O)(OCC)OCC ITJPTURSPJESQC-UHFFFAOYSA-N 0.000 description 1
• KROAAJPGNMNTTP-UHFFFAOYSA-N diheptan-2-yl hydrogen phosphate Chemical compound CCCCCC(C)OP(O)(=O)OC(C)CCCCC KROAAJPGNMNTTP-UHFFFAOYSA-N 0.000 description 1
• QJERURIAEWFRBH-UHFFFAOYSA-N diheptan-3-yl hydrogen phosphate Chemical compound CCCCC(CC)OP(O)(=O)OC(CC)CCCC QJERURIAEWFRBH-UHFFFAOYSA-N 0.000 description 1
• GQZUIPGTJYLKSK-UHFFFAOYSA-N diheptan-4-yl methyl phosphate Chemical compound CCCC(CCC)OP(=O)(OC)OC(CCC)CCC GQZUIPGTJYLKSK-UHFFFAOYSA-N 0.000 description 1
• HDHASXPRDZUJCF-UHFFFAOYSA-N diheptan-4-yl phenyl phosphate Chemical compound CCCC(CCC)OP(=O)(OC(CCC)CCC)OC1=CC=CC=C1 HDHASXPRDZUJCF-UHFFFAOYSA-N 0.000 description 1
• KHCZGCMALIRTMF-UHFFFAOYSA-N diheptyl phenyl phosphate Chemical compound CCCCCCCOP(=O)(OCCCCCCC)OC1=CC=CC=C1 KHCZGCMALIRTMF-UHFFFAOYSA-N 0.000 description 1
• DNJWGDRCDNRDIL-UHFFFAOYSA-N diheptyl(propan-2-yl)phosphane Chemical compound CCCCCCCP(C(C)C)CCCCCCC DNJWGDRCDNRDIL-UHFFFAOYSA-N 0.000 description 1
• RXLRDQWFWTWSAH-UHFFFAOYSA-N diheptyl(propyl)phosphane Chemical compound CCCCCCCP(CCC)CCCCCCC RXLRDQWFWTWSAH-UHFFFAOYSA-N 0.000 description 1
• TWYAWLYZDNVYPT-UHFFFAOYSA-N dihexan-2-yl hydrogen phosphate Chemical compound CCCCC(C)OP(O)(=O)OC(C)CCCC TWYAWLYZDNVYPT-UHFFFAOYSA-N 0.000 description 1
• MYHCUFHNVQONIR-UHFFFAOYSA-N dihexan-2-yl phenyl phosphate Chemical compound CCCCC(C)OP(=O)(OC(C)CCCC)OC1=CC=CC=C1 MYHCUFHNVQONIR-UHFFFAOYSA-N 0.000 description 1
• JLJBVTLOSXPYDG-UHFFFAOYSA-N dihexan-3-yl phenyl phosphate Chemical compound CCCC(CC)OP(=O)(OC(CC)CCC)OC1=CC=CC=C1 JLJBVTLOSXPYDG-UHFFFAOYSA-N 0.000 description 1
• DQLJOCWRWFJZMD-UHFFFAOYSA-N dihexyl phenyl phosphate Chemical compound CCCCCCOP(=O)(OCCCCCC)OC1=CC=CC=C1 DQLJOCWRWFJZMD-UHFFFAOYSA-N 0.000 description 1
• GJZKQIFATBQWBJ-UHFFFAOYSA-N dihexyl(methyl)phosphane Chemical compound CCCCCCP(C)CCCCCC GJZKQIFATBQWBJ-UHFFFAOYSA-N 0.000 description 1
• ICGRXOJPKLUZID-UHFFFAOYSA-N dihexyl(propan-2-yl)phosphane Chemical compound CCCCCCP(C(C)C)CCCCCC ICGRXOJPKLUZID-UHFFFAOYSA-N 0.000 description 1
• GXIMEGMEYWTKRN-UHFFFAOYSA-N dihexyl(propyl)phosphane Chemical compound CCCCCCP(CCC)CCCCCC GXIMEGMEYWTKRN-UHFFFAOYSA-N 0.000 description 1
• WZPMZMCZAGFKOC-UHFFFAOYSA-N diisopropyl hydrogen phosphate Chemical compound CC(C)OP(O)(=O)OC(C)C WZPMZMCZAGFKOC-UHFFFAOYSA-N 0.000 description 1
• MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 1
• AXDCOWAMLFDLEP-UHFFFAOYSA-N dimethoxyphosphoryl dimethyl phosphate Chemical compound COP(=O)(OC)OP(=O)(OC)OC AXDCOWAMLFDLEP-UHFFFAOYSA-N 0.000 description 1
• 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
• OGUWNVAAFURAQD-UHFFFAOYSA-N dimethyl pentyl phosphate Chemical compound CCCCCOP(=O)(OC)OC OGUWNVAAFURAQD-UHFFFAOYSA-N 0.000 description 1
• RIEWSWCAHAVEKK-UHFFFAOYSA-N dioctan-2-yl phenyl phosphate Chemical compound CCCCCCC(C)OP(=O)(OC(C)CCCCCC)OC1=CC=CC=C1 RIEWSWCAHAVEKK-UHFFFAOYSA-N 0.000 description 1
• BLTQUMGSCQHJAM-UHFFFAOYSA-N dioctan-3-yl hydrogen phosphate Chemical compound CCCCCC(CC)OP(O)(=O)OC(CC)CCCCC BLTQUMGSCQHJAM-UHFFFAOYSA-N 0.000 description 1
• WUKJTCYTWJATLP-UHFFFAOYSA-N dioctan-3-yl phenyl phosphate Chemical compound CCCCCC(CC)OP(=O)(OC(CC)CCCCC)OC1=CC=CC=C1 WUKJTCYTWJATLP-UHFFFAOYSA-N 0.000 description 1
• BPWXJCCABQQWQA-UHFFFAOYSA-N dioctan-4-yl hydrogen phosphate Chemical compound CCCCC(CCC)OP(O)(=O)OC(CCC)CCCC BPWXJCCABQQWQA-UHFFFAOYSA-N 0.000 description 1
• DMEGVGQMHNHVMU-UHFFFAOYSA-N dioctan-4-yl phenyl phosphate Chemical compound CCCCC(CCC)OP(=O)(OC(CCC)CCCC)OC1=CC=CC=C1 DMEGVGQMHNHVMU-UHFFFAOYSA-N 0.000 description 1
• HTDKEJXHILZNPP-UHFFFAOYSA-N dioctyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OCCCCCCCC HTDKEJXHILZNPP-UHFFFAOYSA-N 0.000 description 1
• QHGRPTNUHWYCEN-UHFFFAOYSA-N dioctyl phenyl phosphate Chemical compound CCCCCCCCOP(=O)(OCCCCCCCC)OC1=CC=CC=C1 QHGRPTNUHWYCEN-UHFFFAOYSA-N 0.000 description 1
• AZKYRJFAQUTGPQ-UHFFFAOYSA-N dioctyl(propan-2-yl)phosphane Chemical compound CCCCCCCCP(C(C)C)CCCCCCCC AZKYRJFAQUTGPQ-UHFFFAOYSA-N 0.000 description 1
• PRBYIGPVGVDJLI-UHFFFAOYSA-N dioctyl(propyl)phosphane Chemical compound CCCCCCCCP(CCC)CCCCCCCC PRBYIGPVGVDJLI-UHFFFAOYSA-N 0.000 description 1
• AKQLEQJPAXULST-UHFFFAOYSA-N dipentan-2-yl hydrogen phosphate Chemical compound CCCC(C)OP(O)(=O)OC(C)CCC AKQLEQJPAXULST-UHFFFAOYSA-N 0.000 description 1
• LRDNYVHXOLIAAL-UHFFFAOYSA-N dipentan-2-yl phenyl phosphate Chemical compound CCCC(C)OP(=O)(OC(C)CCC)OC1=CC=CC=C1 LRDNYVHXOLIAAL-UHFFFAOYSA-N 0.000 description 1
• NWEIRQMBFHIYBF-UHFFFAOYSA-N dipentan-3-yl phenyl phosphate Chemical compound CCC(CC)OP(=O)(OC(CC)CC)OC1=CC=CC=C1 NWEIRQMBFHIYBF-UHFFFAOYSA-N 0.000 description 1
• WJZUIWBZDGBLKK-UHFFFAOYSA-N dipentyl hydrogen phosphate Chemical compound CCCCCOP(O)(=O)OCCCCC WJZUIWBZDGBLKK-UHFFFAOYSA-N 0.000 description 1
• WJZUIWBZDGBLKK-UHFFFAOYSA-M dipentyl phosphate Chemical compound CCCCCOP([O-])(=O)OCCCCC WJZUIWBZDGBLKK-UHFFFAOYSA-M 0.000 description 1
• 238000007598 dipping method Methods 0.000 description 1
• QVKQJEWZVQFGIY-UHFFFAOYSA-N dipropyl hydrogen phosphate Chemical compound CCCOP(O)(=O)OCCC QVKQJEWZVQFGIY-UHFFFAOYSA-N 0.000 description 1
• 239000000428 dust Substances 0.000 description 1
• 229920001971 elastomer Polymers 0.000 description 1
• 238000005516 engineering process Methods 0.000 description 1
• OCATXDXVSFLBRW-UHFFFAOYSA-N ethene;phosphoric acid Chemical compound C=C.OP(O)(O)=O.OP(O)(O)=O OCATXDXVSFLBRW-UHFFFAOYSA-N 0.000 description 1
• 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
• HCDLTAHUJKIXJE-UHFFFAOYSA-N ethoxy(heptyl)phosphinic acid Chemical compound CCCCCCCP(O)(=O)OCC HCDLTAHUJKIXJE-UHFFFAOYSA-N 0.000 description 1
• IMCARZNNWXRLAN-UHFFFAOYSA-N ethoxy(octyl)phosphinic acid Chemical compound CCCCCCCCP(O)(=O)OCC IMCARZNNWXRLAN-UHFFFAOYSA-N 0.000 description 1
• UMBYQXLEVYPMHV-UHFFFAOYSA-N ethoxy(pentyl)phosphinic acid Chemical compound CCCCCP(O)(=O)OCC UMBYQXLEVYPMHV-UHFFFAOYSA-N 0.000 description 1
• XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 1
• SMHZBABQDPBZSJ-UHFFFAOYSA-N ethyl diheptan-2-yl phosphate Chemical compound CCCCCC(C)OP(=O)(OCC)OC(C)CCCCC SMHZBABQDPBZSJ-UHFFFAOYSA-N 0.000 description 1
• WWCCAGFVZQUJPI-UHFFFAOYSA-N ethyl diheptan-3-yl phosphate Chemical compound CCCCC(CC)OP(=O)(OCC)OC(CC)CCCC WWCCAGFVZQUJPI-UHFFFAOYSA-N 0.000 description 1
• VWUSXGSZDZHRSL-UHFFFAOYSA-N ethyl diheptyl phosphate Chemical compound CCCCCCCOP(=O)(OCC)OCCCCCCC VWUSXGSZDZHRSL-UHFFFAOYSA-N 0.000 description 1
• ZVEVEWIDWZDHKE-UHFFFAOYSA-N ethyl dihexan-2-yl phosphate Chemical compound CCCCC(C)OP(=O)(OCC)OC(C)CCCC ZVEVEWIDWZDHKE-UHFFFAOYSA-N 0.000 description 1
• XMHITHWDFUKKNT-UHFFFAOYSA-N ethyl dihexan-3-yl phosphate Chemical compound CCCC(CC)OP(=O)(OCC)OC(CC)CCC XMHITHWDFUKKNT-UHFFFAOYSA-N 0.000 description 1
• PJUWDWLIKQZRKX-UHFFFAOYSA-N ethyl dihexyl phosphate Chemical class CCCCCCOP(=O)(OCC)OCCCCCC PJUWDWLIKQZRKX-UHFFFAOYSA-N 0.000 description 1
• ZJXZSIYSNXKHEA-UHFFFAOYSA-N ethyl dihydrogen phosphate Chemical compound CCOP(O)(O)=O ZJXZSIYSNXKHEA-UHFFFAOYSA-N 0.000 description 1
• LNIQAUJVHAMHIQ-UHFFFAOYSA-N ethyl dipentan-2-yl phosphate Chemical compound CCCC(C)OP(=O)(OCC)OC(C)CCC LNIQAUJVHAMHIQ-UHFFFAOYSA-N 0.000 description 1
• KABLEHWCLUCHAT-UHFFFAOYSA-N ethyl dipentan-3-yl phosphate Chemical compound CCC(CC)OP(=O)(OCC)OC(CC)CC KABLEHWCLUCHAT-UHFFFAOYSA-N 0.000 description 1
• KRKNUAGEKOBLSU-UHFFFAOYSA-N ethyl dipentyl phosphate Chemical compound CCCCCOP(=O)(OCC)OCCCCC KRKNUAGEKOBLSU-UHFFFAOYSA-N 0.000 description 1
• JSPBAVGTJNAVBJ-UHFFFAOYSA-N ethyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCC)OC1=CC=CC=C1 JSPBAVGTJNAVBJ-UHFFFAOYSA-N 0.000 description 1
• YYJCIPQEOSOUSV-UHFFFAOYSA-N ethyl dipropan-2-yl phosphate Chemical compound CCOP(=O)(OC(C)C)OC(C)C YYJCIPQEOSOUSV-UHFFFAOYSA-N 0.000 description 1
• ANPYQJSSFZGXFE-UHFFFAOYSA-N ethyl dipropyl phosphate Chemical compound CCCOP(=O)(OCC)OCCC ANPYQJSSFZGXFE-UHFFFAOYSA-N 0.000 description 1
• YARXZVMNXKHGHL-UHFFFAOYSA-N ethyl heptyl methyl phosphate Chemical compound CCCCCCCOP(=O)(OC)OCC YARXZVMNXKHGHL-UHFFFAOYSA-N 0.000 description 1
• HCIQUGMKXQZZMG-UHFFFAOYSA-N ethyl hexyl hydrogen phosphate Chemical compound CCCCCCOP(O)(=O)OCC HCIQUGMKXQZZMG-UHFFFAOYSA-N 0.000 description 1
• KKLSTYKNFSNFAF-UHFFFAOYSA-N ethyl hexyl methyl phosphate Chemical compound CCCCCCOP(=O)(OC)OCC KKLSTYKNFSNFAF-UHFFFAOYSA-N 0.000 description 1
• MSNSKDGQLPLKKR-UHFFFAOYSA-N ethyl hexyl octyl phosphate Chemical compound CCCCCCCCOP(=O)(OCC)OCCCCCC MSNSKDGQLPLKKR-UHFFFAOYSA-N 0.000 description 1
• WLPVPLKXNMSLLC-UHFFFAOYSA-N ethyl methyl pentyl phosphate Chemical compound CCCCCOP(=O)(OC)OCC WLPVPLKXNMSLLC-UHFFFAOYSA-N 0.000 description 1
• QOSZFDSHQYCCHU-UHFFFAOYSA-N ethyl methyl propyl phosphate Chemical compound CCCOP(=O)(OC)OCC QOSZFDSHQYCCHU-UHFFFAOYSA-N 0.000 description 1
• MNKNAPFEXFDRAP-UHFFFAOYSA-M ethyl propyl phosphate Chemical compound CCCOP([O-])(=O)OCC MNKNAPFEXFDRAP-UHFFFAOYSA-M 0.000 description 1
• VRROQFXKEVCQBZ-UHFFFAOYSA-N ethyl(dioctyl)phosphane Chemical compound CCCCCCCCP(CC)CCCCCCCC VRROQFXKEVCQBZ-UHFFFAOYSA-N 0.000 description 1
• ZNOXPPRACNEBIA-UHFFFAOYSA-N ethyl(phenyl)phosphane Chemical compound CCPC1=CC=CC=C1 ZNOXPPRACNEBIA-UHFFFAOYSA-N 0.000 description 1
• JHKPXKJDHILFHA-UHFFFAOYSA-N ethyl-di(heptan-4-yl)phosphane Chemical compound CCCC(CCC)P(CC)C(CCC)CCC JHKPXKJDHILFHA-UHFFFAOYSA-N 0.000 description 1
• UGWGXKVPGFKBNI-UHFFFAOYSA-N ethyl-di(octan-2-yl)phosphane Chemical compound CCCCCCC(C)P(CC)C(C)CCCCCC UGWGXKVPGFKBNI-UHFFFAOYSA-N 0.000 description 1
• JDHCFWIXEGQJJS-UHFFFAOYSA-N ethyl-di(octan-3-yl)phosphane Chemical compound CCCCCC(CC)P(CC)C(CC)CCCCC JDHCFWIXEGQJJS-UHFFFAOYSA-N 0.000 description 1
• RTEDZLVDNZVVHW-UHFFFAOYSA-N ethyl-di(octan-4-yl)phosphane Chemical compound CCCCC(CCC)P(CC)C(CCC)CCCC RTEDZLVDNZVVHW-UHFFFAOYSA-N 0.000 description 1
• NPABQWSZGGHWCK-UHFFFAOYSA-N ethyl-heptyl-hexylphosphane Chemical compound CCCCCCCP(CC)CCCCCC NPABQWSZGGHWCK-UHFFFAOYSA-N 0.000 description 1
• DJRSBZANDOPWJE-UHFFFAOYSA-N ethyl-heptyl-pentylphosphane Chemical compound CCCCCCCP(CC)CCCCC DJRSBZANDOPWJE-UHFFFAOYSA-N 0.000 description 1
• LIPNXZVCUOAVLA-UHFFFAOYSA-N ethyl-heptyl-propylphosphane Chemical compound CCCCCCCP(CC)CCC LIPNXZVCUOAVLA-UHFFFAOYSA-N 0.000 description 1
• OEWQLTOHXFMHMS-UHFFFAOYSA-N ethyl-hexyl-pentylphosphane Chemical compound CCCCCCP(CC)CCCCC OEWQLTOHXFMHMS-UHFFFAOYSA-N 0.000 description 1
• HYKBXPOGFCPEIX-UHFFFAOYSA-N ethyl-hexyl-propylphosphane Chemical compound CCCCCCP(CC)CCC HYKBXPOGFCPEIX-UHFFFAOYSA-N 0.000 description 1
• RRTXPTNZWBIAKG-UHFFFAOYSA-N ethyl-hexyl-trihydroxy-$l^{5}-phosphane Chemical compound CCCCCCP(O)(O)(O)CC RRTXPTNZWBIAKG-UHFFFAOYSA-N 0.000 description 1
• QCFKMMLFAJBTBJ-UHFFFAOYSA-N ethyl-octyl-pentylphosphane Chemical compound CCCCCCCCP(CC)CCCCC QCFKMMLFAJBTBJ-UHFFFAOYSA-N 0.000 description 1
• FRAVTKWAXSXKCB-UHFFFAOYSA-N ethyl-octyl-propylphosphane Chemical compound CCCCCCCCP(CC)CCC FRAVTKWAXSXKCB-UHFFFAOYSA-N 0.000 description 1
• QCRLZVFXLXXPMR-UHFFFAOYSA-N ethyl-pentyl-propylphosphane Chemical compound CCCCCP(CC)CCC QCRLZVFXLXXPMR-UHFFFAOYSA-N 0.000 description 1
• ZIOQQMCUVFIHJZ-UHFFFAOYSA-N ethyl-trihydroxy-octyl-$l^{5}-phosphane Chemical compound CCCCCCCCP(O)(O)(O)CC ZIOQQMCUVFIHJZ-UHFFFAOYSA-N 0.000 description 1
• 238000002474 experimental method Methods 0.000 description 1
• 239000012527 feed solution Substances 0.000 description 1
• 238000001917 fluorescence detection Methods 0.000 description 1
• 229910052733 gallium Inorganic materials 0.000 description 1
• PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
• 229910052737 gold Inorganic materials 0.000 description 1
• 239000010931 gold Substances 0.000 description 1
• 229910052735 hafnium Inorganic materials 0.000 description 1
• VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
• 150000008282 halocarbons Chemical class 0.000 description 1
• 239000000383 hazardous chemical Substances 0.000 description 1
• GGKJPMAIXBETTD-UHFFFAOYSA-N heptyl dihydrogen phosphate Chemical compound CCCCCCCOP(O)(O)=O GGKJPMAIXBETTD-UHFFFAOYSA-N 0.000 description 1
• UGXUPAKCTYOISO-UHFFFAOYSA-N heptyl hexyl hydrogen phosphate Chemical compound CCCCCCCOP(O)(=O)OCCCCCC UGXUPAKCTYOISO-UHFFFAOYSA-N 0.000 description 1
• YMRHNWOPOBYBPY-UHFFFAOYSA-N heptyl methyl hydrogen phosphate Chemical compound CCCCCCCOP(O)(=O)OC YMRHNWOPOBYBPY-UHFFFAOYSA-N 0.000 description 1
• GGKJPMAIXBETTD-UHFFFAOYSA-L heptyl phosphate Chemical compound CCCCCCCOP([O-])([O-])=O GGKJPMAIXBETTD-UHFFFAOYSA-L 0.000 description 1
• FEKFIHUXXGOQDC-UHFFFAOYSA-N heptyl-hexyl-methylphosphane Chemical compound CCCCCCCP(C)CCCCCC FEKFIHUXXGOQDC-UHFFFAOYSA-N 0.000 description 1
• VAJFLSRDMGNZJY-UHFFFAOYSA-N heptylphosphonic acid Chemical compound CCCCCCCP(O)(O)=O VAJFLSRDMGNZJY-UHFFFAOYSA-N 0.000 description 1
• DEKKNVOOBDLURO-UHFFFAOYSA-N hexan-2-ylphosphonic acid Chemical compound CCCCC(C)P(O)(O)=O DEKKNVOOBDLURO-UHFFFAOYSA-N 0.000 description 1
• LYEBVZZLFOFERJ-UHFFFAOYSA-N hexan-3-ylphosphinic acid Chemical compound C(C)C(CCC)P(O)=O LYEBVZZLFOFERJ-UHFFFAOYSA-N 0.000 description 1
• NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 1
• MUEVYRUGFRAAIB-UHFFFAOYSA-N hexyl methyl hydrogen phosphate Chemical compound CCCCCCOP(O)(=O)OC MUEVYRUGFRAAIB-UHFFFAOYSA-N 0.000 description 1
• XWKFRUCQRXQQIF-UHFFFAOYSA-N hexyl pentyl hydrogen phosphate Chemical compound CCCCCCOP(O)(=O)OCCCCC XWKFRUCQRXQQIF-UHFFFAOYSA-N 0.000 description 1
• PHNWGDTYCJFUGZ-UHFFFAOYSA-L hexyl phosphate Chemical compound CCCCCCOP([O-])([O-])=O PHNWGDTYCJFUGZ-UHFFFAOYSA-L 0.000 description 1
• JAXRBLAJXQMBAK-UHFFFAOYSA-N hexyl-methyl-octylphosphane Chemical compound CCCCCCCCP(C)CCCCCC JAXRBLAJXQMBAK-UHFFFAOYSA-N 0.000 description 1
• GJWAEWLHSDGBGG-UHFFFAOYSA-N hexylphosphonic acid Chemical compound CCCCCCP(O)(O)=O GJWAEWLHSDGBGG-UHFFFAOYSA-N 0.000 description 1
• 239000012510 hollow fiber Substances 0.000 description 1
• 238000006703 hydration reaction Methods 0.000 description 1
• 125000005597 hydrazone group Chemical group 0.000 description 1
• 230000003301 hydrolyzing effect Effects 0.000 description 1
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
• 230000006872 improvement Effects 0.000 description 1
• 229910052738 indium Inorganic materials 0.000 description 1
• APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
• 229910052500 inorganic mineral Inorganic materials 0.000 description 1
• 238000007689 inspection Methods 0.000 description 1
• 230000002427 irreversible effect Effects 0.000 description 1
• 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
• 239000012948 isocyanate Substances 0.000 description 1
• 150000002513 isocyanates Chemical class 0.000 description 1
• 150000002576 ketones Chemical class 0.000 description 1
• 238000009940 knitting Methods 0.000 description 1
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• OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
• 235000020778 linoleic acid Nutrition 0.000 description 1
• 239000007788 liquid Substances 0.000 description 1
• 230000001050 lubricating effect Effects 0.000 description 1
• 229910052749 magnesium Inorganic materials 0.000 description 1
• 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
• 235000019341 magnesium sulphate Nutrition 0.000 description 1
• 230000014759 maintenance of location Effects 0.000 description 1
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
• QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
• 229910052753 mercury Inorganic materials 0.000 description 1
• CAAULPUQFIIOTL-UHFFFAOYSA-N methyl dihydrogen phosphate Chemical compound COP(O)(O)=O CAAULPUQFIIOTL-UHFFFAOYSA-N 0.000 description 1
• MGHBWQMOJPRVKE-UHFFFAOYSA-N methyl dioctan-3-yl phosphate Chemical compound CCCCCC(CC)OP(=O)(OC)OC(CC)CCCCC MGHBWQMOJPRVKE-UHFFFAOYSA-N 0.000 description 1
• QRFTZUVEVYZZKT-UHFFFAOYSA-N methyl dioctyl phosphate Chemical compound CCCCCCCCOP(=O)(OC)OCCCCCCCC QRFTZUVEVYZZKT-UHFFFAOYSA-N 0.000 description 1
• VOWPVJACXJNHBC-UHFFFAOYSA-N methyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OC)OC1=CC=CC=C1 VOWPVJACXJNHBC-UHFFFAOYSA-N 0.000 description 1
• FKOZQALYXWKSAF-UHFFFAOYSA-N methyl dipropan-2-yl phosphate Chemical class CC(C)OP(=O)(OC)OC(C)C FKOZQALYXWKSAF-UHFFFAOYSA-N 0.000 description 1
• KCJPXMHUFVFEGM-UHFFFAOYSA-N methyl dipropyl phosphate Chemical compound CCCOP(=O)(OC)OCCC KCJPXMHUFVFEGM-UHFFFAOYSA-N 0.000 description 1
• GFOAOEDAKIXISY-UHFFFAOYSA-N methyl pentyl hydrogen phosphate Chemical compound CCCCCOP(O)(=O)OC GFOAOEDAKIXISY-UHFFFAOYSA-N 0.000 description 1
• JXWKMMCPAYWOKV-UHFFFAOYSA-M methyl propyl phosphate Chemical compound CCCOP([O-])(=O)OC JXWKMMCPAYWOKV-UHFFFAOYSA-M 0.000 description 1
• BMWOMXHGRVLKCW-UHFFFAOYSA-N methyl(dioctyl)phosphane Chemical compound CCCCCCCCP(C)CCCCCCCC BMWOMXHGRVLKCW-UHFFFAOYSA-N 0.000 description 1
• VIPDUXHNDAXVBZ-UHFFFAOYSA-N methyl-di(octan-4-yl)phosphane Chemical compound CCCCC(CCC)P(C)C(CCC)CCCC VIPDUXHNDAXVBZ-UHFFFAOYSA-N 0.000 description 1
• YACKEPLHDIMKIO-UHFFFAOYSA-N methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 description 1
• 235000010755 mineral Nutrition 0.000 description 1
• 239000011707 mineral Substances 0.000 description 1
• 150000004712 monophosphates Chemical class 0.000 description 1
• XPLOQMVUXWZLET-UHFFFAOYSA-N n-hexylphosphonate ethyl ester Chemical compound CCCCCC[P@@](O)(=O)OCC XPLOQMVUXWZLET-UHFFFAOYSA-N 0.000 description 1
• 239000002120 nanofilm Substances 0.000 description 1
• 230000007935 neutral effect Effects 0.000 description 1
• 150000002825 nitriles Chemical class 0.000 description 1
• QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
• 239000012454 non-polar solvent Substances 0.000 description 1
• 229910052755 nonmetal Inorganic materials 0.000 description 1
• IDNPKSLIPKVTPV-UHFFFAOYSA-N octyl propyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OCCC IDNPKSLIPKVTPV-UHFFFAOYSA-N 0.000 description 1
• CBFCDTFDPHXCNY-UHFFFAOYSA-N octyldodecane Natural products CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 1
• OHEMLAUGLPRNIV-UHFFFAOYSA-N octylphosphinic acid Chemical compound CCCCCCCCP(O)=O OHEMLAUGLPRNIV-UHFFFAOYSA-N 0.000 description 1
• JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
• 239000003960 organic solvent Substances 0.000 description 1
• 125000002524 organometallic group Chemical group 0.000 description 1
• 229910052762 osmium Inorganic materials 0.000 description 1
• SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
• MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
• 239000006174 pH buffer Substances 0.000 description 1
• 239000003973 paint Substances 0.000 description 1
• NIFSKIGEQZXNBS-UHFFFAOYSA-N pentan-3-yl dihydrogen phosphate Chemical compound CCC(CC)OP(O)(O)=O NIFSKIGEQZXNBS-UHFFFAOYSA-N 0.000 description 1
• NVTPMUHPCAUGCB-UHFFFAOYSA-L pentyl phosphate Chemical compound CCCCCOP([O-])([O-])=O NVTPMUHPCAUGCB-UHFFFAOYSA-L 0.000 description 1
• CKVICYBZYGZLLP-UHFFFAOYSA-N pentylphosphonic acid Chemical compound CCCCCP(O)(O)=O CKVICYBZYGZLLP-UHFFFAOYSA-N 0.000 description 1
• 230000035699 permeability Effects 0.000 description 1
• NFBAXHOPROOJAW-UHFFFAOYSA-N phenindione Chemical compound O=C1C2=CC=CC=C2C(=O)C1C1=CC=CC=C1 NFBAXHOPROOJAW-UHFFFAOYSA-N 0.000 description 1
• LCNPPGIYNLTPFC-UHFFFAOYSA-N phenylphosphanium phosphate Chemical compound P(=O)([O-])([O-])[O-].C1(=CC=CC=C1)[PH3+].C1(=CC=CC=C1)[PH3+].C1(=CC=CC=C1)[PH3+] LCNPPGIYNLTPFC-UHFFFAOYSA-N 0.000 description 1
• MLCHBQKMVKNBOV-UHFFFAOYSA-N phenylphosphinic acid Chemical compound OP(=O)C1=CC=CC=C1 MLCHBQKMVKNBOV-UHFFFAOYSA-N 0.000 description 1
• ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
• 150000003014 phosphoric acid esters Chemical class 0.000 description 1
• 150000003016 phosphoric acids Chemical class 0.000 description 1
• 125000004437 phosphorous atom Chemical group 0.000 description 1
• 150000004885 piperazines Chemical class 0.000 description 1
• 229920003023 plastic Polymers 0.000 description 1
• 239000004033 plastic Substances 0.000 description 1
• 239000003880 polar aprotic solvent Substances 0.000 description 1
• 239000003495 polar organic solvent Substances 0.000 description 1
• 229910052699 polonium Inorganic materials 0.000 description 1
• 239000004584 polyacrylic acid Substances 0.000 description 1
• 239000004417 polycarbonate Substances 0.000 description 1
• 229920000515 polycarbonate Polymers 0.000 description 1
• 238000006068 polycondensation reaction Methods 0.000 description 1
• 229920000728 polyester Polymers 0.000 description 1
• 229920000573 polyethylene Polymers 0.000 description 1
• 229920001155 polypropylene Polymers 0.000 description 1
• 229920002223 polystyrene Polymers 0.000 description 1
• 229920002451 polyvinyl alcohol Polymers 0.000 description 1
• 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
• 239000011148 porous material Substances 0.000 description 1
• 229910052700 potassium Inorganic materials 0.000 description 1
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
• 150000003142 primary aromatic amines Chemical class 0.000 description 1
• 238000007639 printing Methods 0.000 description 1
• 238000012545 processing Methods 0.000 description 1
• 230000002035 prolonged effect Effects 0.000 description 1
• GGHDAUPFEBTORZ-UHFFFAOYSA-N propane-1,1-diamine Chemical compound CCC(N)N GGHDAUPFEBTORZ-UHFFFAOYSA-N 0.000 description 1
• MHZDONKZSXBOGL-UHFFFAOYSA-N propyl dihydrogen phosphate Chemical compound CCCOP(O)(O)=O MHZDONKZSXBOGL-UHFFFAOYSA-N 0.000 description 1
• 238000004445 quantitative analysis Methods 0.000 description 1
• 150000003254 radicals Chemical class 0.000 description 1
• 229910052705 radium Inorganic materials 0.000 description 1
• HCWPIIXVSYCSAN-UHFFFAOYSA-N radium atom Chemical compound [Ra] HCWPIIXVSYCSAN-UHFFFAOYSA-N 0.000 description 1
• 239000012429 reaction media Substances 0.000 description 1
• 230000035484 reaction time Effects 0.000 description 1
• 230000009467 reduction Effects 0.000 description 1
• 230000002940 repellent Effects 0.000 description 1
• 239000005871 repellent Substances 0.000 description 1
• 238000011160 research Methods 0.000 description 1
• 230000004044 response Effects 0.000 description 1
• 229910052702 rhenium Inorganic materials 0.000 description 1
• WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
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• 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
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• 238000004611 spectroscopical analysis Methods 0.000 description 1
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• 125000001424 substituent group Chemical group 0.000 description 1
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• ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
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• OMXBGKCMXUAHQB-UHFFFAOYSA-N tert-butyl methyl hydrogen phosphate Chemical compound COP(O)(=O)OC(C)(C)C OMXBGKCMXUAHQB-UHFFFAOYSA-N 0.000 description 1
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• GQRQDDIGHMRDMG-UHFFFAOYSA-N tri(heptan-3-yl)phosphane Chemical compound CCCCC(CC)P(C(CC)CCCC)C(CC)CCCC GQRQDDIGHMRDMG-UHFFFAOYSA-N 0.000 description 1
• UXYMZAXLUPHEKH-UHFFFAOYSA-N tri(heptan-4-yl)phosphane Chemical compound CCCC(CCC)P(C(CCC)CCC)C(CCC)CCC UXYMZAXLUPHEKH-UHFFFAOYSA-N 0.000 description 1
• MBFBOWOPHAIFBS-UHFFFAOYSA-N tri(hexan-2-yl)phosphane Chemical compound CCCCC(C)P(C(C)CCCC)C(C)CCCC MBFBOWOPHAIFBS-UHFFFAOYSA-N 0.000 description 1
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• IFXORIIYQORRMJ-UHFFFAOYSA-N tribenzylphosphane Chemical compound C=1C=CC=CC=1CP(CC=1C=CC=CC=1)CC1=CC=CC=C1 IFXORIIYQORRMJ-UHFFFAOYSA-N 0.000 description 1
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• MHOHPNGCKKJHSD-UHFFFAOYSA-N triheptan-3-yl phosphate Chemical compound CCCCC(CC)OP(=O)(OC(CC)CCCC)OC(CC)CCCC MHOHPNGCKKJHSD-UHFFFAOYSA-N 0.000 description 1
• XGBSCBAEKRHTMZ-UHFFFAOYSA-N trihexan-2-yl phosphate Chemical compound CCCCC(C)OP(=O)(OC(C)CCCC)OC(C)CCCC XGBSCBAEKRHTMZ-UHFFFAOYSA-N 0.000 description 1
• CDYVQSZPXAFIFA-UHFFFAOYSA-N trihydroxy(dipentyl)-lambda5-phosphane Chemical compound CCCCCP(O)(O)(O)CCCCC CDYVQSZPXAFIFA-UHFFFAOYSA-N 0.000 description 1
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• YIZBZLXFYAOFDQ-UHFFFAOYSA-N trinonan-4-yl phosphate Chemical compound CCCCCC(CCC)OP(=O)(OC(CCC)CCCCC)OC(CCC)CCCCC YIZBZLXFYAOFDQ-UHFFFAOYSA-N 0.000 description 1
• JFDIYJKFEQXGLQ-UHFFFAOYSA-N trioctan-4-yl phosphate Chemical compound CCCCC(CCC)OP(=O)(OC(CCC)CCCC)OC(CCC)CCCC JFDIYJKFEQXGLQ-UHFFFAOYSA-N 0.000 description 1
• LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
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• BCIFMBSWFCXFAS-UHFFFAOYSA-N tripentan-2-yl phosphate Chemical compound CCCC(C)OP(=O)(OC(C)CCC)OC(C)CCC BCIFMBSWFCXFAS-UHFFFAOYSA-N 0.000 description 1
• ALCLDNINWGASPT-UHFFFAOYSA-N tripentan-3-yl phosphate Chemical compound CCC(CC)OP(=O)(OC(CC)CC)OC(CC)CC ALCLDNINWGASPT-UHFFFAOYSA-N 0.000 description 1
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• RIOQSEWOXXDEQQ-UHFFFAOYSA-O triphenylphosphanium Chemical compound C1=CC=CC=C1[PH+](C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-O 0.000 description 1
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• DTOOHWOPSUKNJL-UHFFFAOYSA-N tris(2-ethylphenyl) phosphate Chemical compound CCC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)CC)OC1=CC=CC=C1CC DTOOHWOPSUKNJL-UHFFFAOYSA-N 0.000 description 1
• RLRSSUBSVSBAJD-UHFFFAOYSA-N tris(2-ethylphenyl)phosphane Chemical compound CCC1=CC=CC=C1P(C=1C(=CC=CC=1)CC)C1=CC=CC=C1CC RLRSSUBSVSBAJD-UHFFFAOYSA-N 0.000 description 1
• XWJWJLGDEPPVJH-UHFFFAOYSA-N tris(2-methylnonan-2-yl) phosphate Chemical compound CCCCCCCC(C)(C)OP(=O)(OC(C)(C)CCCCCCC)OC(C)(C)CCCCCCC XWJWJLGDEPPVJH-UHFFFAOYSA-N 0.000 description 1
• COIOYMYWGDAQPM-UHFFFAOYSA-N tris(2-methylphenyl)phosphane Chemical compound CC1=CC=CC=C1P(C=1C(=CC=CC=1)C)C1=CC=CC=C1C COIOYMYWGDAQPM-UHFFFAOYSA-N 0.000 description 1
• NCXYBZTUGKHJFB-UHFFFAOYSA-N tris(3-ethylnonan-3-yl) phosphate Chemical compound CCCCCCC(CC)(CC)OP(=O)(OC(CC)(CC)CCCCCC)OC(CC)(CC)CCCCCC NCXYBZTUGKHJFB-UHFFFAOYSA-N 0.000 description 1
• QZWWNNQRBSJVLL-UHFFFAOYSA-N tris(3-ethylphenyl) phosphate Chemical compound CCC1=CC=CC(OP(=O)(OC=2C=C(CC)C=CC=2)OC=2C=C(CC)C=CC=2)=C1 QZWWNNQRBSJVLL-UHFFFAOYSA-N 0.000 description 1
• VTDQEJSEFIJDRP-UHFFFAOYSA-N tris(3-ethylphenyl)phosphane Chemical compound CCC1=CC=CC(P(C=2C=C(CC)C=CC=2)C=2C=C(CC)C=CC=2)=C1 VTDQEJSEFIJDRP-UHFFFAOYSA-N 0.000 description 1
• RMLPZKRPSQVRAB-UHFFFAOYSA-N tris(3-methylphenyl) phosphate Chemical compound CC1=CC=CC(OP(=O)(OC=2C=C(C)C=CC=2)OC=2C=C(C)C=CC=2)=C1 RMLPZKRPSQVRAB-UHFFFAOYSA-N 0.000 description 1
• BMPBPTNLNBRGOT-UHFFFAOYSA-N tris(4-ethylphenyl) phosphate Chemical compound C1=CC(CC)=CC=C1OP(=O)(OC=1C=CC(CC)=CC=1)OC1=CC=C(CC)C=C1 BMPBPTNLNBRGOT-UHFFFAOYSA-N 0.000 description 1
• PCCAGZSOGFNURV-UHFFFAOYSA-N tris(4-ethylphenyl)phosphane Chemical compound C1=CC(CC)=CC=C1P(C=1C=CC(CC)=CC=1)C1=CC=C(CC)C=C1 PCCAGZSOGFNURV-UHFFFAOYSA-N 0.000 description 1
• BOSMZFBHAYFUBJ-UHFFFAOYSA-N tris(4-methylphenyl) phosphate Chemical compound C1=CC(C)=CC=C1OP(=O)(OC=1C=CC(C)=CC=1)OC1=CC=C(C)C=C1 BOSMZFBHAYFUBJ-UHFFFAOYSA-N 0.000 description 1
• WXAZIUYTQHYBFW-UHFFFAOYSA-N tris(4-methylphenyl)phosphane Chemical compound C1=CC(C)=CC=C1P(C=1C=CC(C)=CC=1)C1=CC=C(C)C=C1 WXAZIUYTQHYBFW-UHFFFAOYSA-N 0.000 description 1
• WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
• 229910052721 tungsten Inorganic materials 0.000 description 1
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• 238000000108 ultra-filtration Methods 0.000 description 1
• 239000012808 vapor phase Substances 0.000 description 1
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• 229910052727 yttrium Inorganic materials 0.000 description 1