TW200909549A - Antistatic optically clear pressure sensitive adhesive - Google Patents
Antistatic optically clear pressure sensitive adhesive Download PDFInfo
- Publication number
- TW200909549A TW200909549A TW097113407A TW97113407A TW200909549A TW 200909549 A TW200909549 A TW 200909549A TW 097113407 A TW097113407 A TW 097113407A TW 97113407 A TW97113407 A TW 97113407A TW 200909549 A TW200909549 A TW 200909549A
- Authority
- TW
- Taiwan
- Prior art keywords
- adhesive
- acrylate
- salt
- meth
- group
- Prior art date
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- 239000004820 Pressure-sensitive adhesive Substances 0.000 title claims abstract description 50
- 239000000853 adhesive Substances 0.000 claims abstract description 129
- 230000001070 adhesive effect Effects 0.000 claims abstract description 124
- 150000003839 salts Chemical class 0.000 claims abstract description 47
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000004014 plasticizer Substances 0.000 claims abstract description 32
- 238000000034 method Methods 0.000 claims abstract description 12
- -1 2-ethyl Chemical group 0.000 claims description 45
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 24
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 21
- 239000000178 monomer Substances 0.000 claims description 19
- 239000011521 glass Substances 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 239000004973 liquid crystal related substance Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 16
- 230000003068 static effect Effects 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 12
- 239000003431 cross linking reagent Substances 0.000 claims description 12
- 230000003287 optical effect Effects 0.000 claims description 12
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- 210000002858 crystal cell Anatomy 0.000 claims description 10
- 230000005611 electricity Effects 0.000 claims description 10
- 150000002891 organic anions Chemical class 0.000 claims description 10
- 150000001450 anions Chemical class 0.000 claims description 9
- 150000001768 cations Chemical class 0.000 claims description 9
- 238000012360 testing method Methods 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000000052 vinegar Substances 0.000 claims description 8
- 235000021419 vinegar Nutrition 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 230000010287 polarization Effects 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 6
- 150000004060 quinone imines Chemical class 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- 239000012711 adhesive precursor Substances 0.000 claims description 5
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 claims description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 2
- 230000000694 effects Effects 0.000 claims description 2
- 150000002433 hydrophilic molecules Chemical class 0.000 claims description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 150000002892 organic cations Chemical class 0.000 claims description 2
- 239000002689 soil Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims 3
- 230000001737 promoting effect Effects 0.000 claims 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims 2
- 239000007795 chemical reaction product Substances 0.000 claims 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 2
- 125000005207 tetraalkylammonium group Chemical group 0.000 claims 2
- 125000006176 2-ethylbutyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])*)C([H])([H])C([H])([H])[H] 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 1
- 239000003522 acrylic cement Substances 0.000 claims 1
- 239000001361 adipic acid Substances 0.000 claims 1
- 235000011037 adipic acid Nutrition 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- JHRWWRDRBPCWTF-OLQVQODUSA-N captafol Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)C(Cl)Cl)C(=O)[C@H]21 JHRWWRDRBPCWTF-OLQVQODUSA-N 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 229910001410 inorganic ion Inorganic materials 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052712 strontium Inorganic materials 0.000 claims 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims 1
- 229910021653 sulphate ion Inorganic materials 0.000 claims 1
- 239000001117 sulphuric acid Substances 0.000 claims 1
- 235000011149 sulphuric acid Nutrition 0.000 claims 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- 239000010410 layer Substances 0.000 description 18
- 239000002216 antistatic agent Substances 0.000 description 17
- 239000000463 material Substances 0.000 description 16
- CGSLYBDCEGBZCG-UHFFFAOYSA-N Octicizer Chemical compound C=1C=CC=CC=1OP(=O)(OCC(CC)CCCC)OC1=CC=CC=C1 CGSLYBDCEGBZCG-UHFFFAOYSA-N 0.000 description 15
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 14
- 125000003118 aryl group Chemical group 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 11
- 229910052757 nitrogen Inorganic materials 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- 230000005540 biological transmission Effects 0.000 description 9
- 239000000758 substrate Substances 0.000 description 9
- 239000002002 slurry Substances 0.000 description 8
- 101100456566 Caenorhabditis elegans dpy-22 gene Proteins 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 7
- 239000002585 base Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000010494 dissociation reaction Methods 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 description 5
- 239000002738 chelating agent Substances 0.000 description 5
- 230000006378 damage Effects 0.000 description 5
- 230000005593 dissociations Effects 0.000 description 5
- 230000003993 interaction Effects 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
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- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 4
- 101000617550 Dictyostelium discoideum Presenilin-A Proteins 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 101100137869 Trypanosoma brucei brucei PSA4 gene Proteins 0.000 description 4
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- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 4
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- 238000002360 preparation method Methods 0.000 description 4
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- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
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- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
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- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
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- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
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- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
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- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 2
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- C—CHEMISTRY; METALLURGY
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| US91180007P | 2007-04-13 | 2007-04-13 |
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| TW200909549A true TW200909549A (en) | 2009-03-01 |
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| TW097113407A TW200909549A (en) | 2007-04-13 | 2008-04-11 | Antistatic optically clear pressure sensitive adhesive |
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| US (1) | US20100136265A1 (enExample) |
| EP (1) | EP2139971A4 (enExample) |
| JP (1) | JP2010523806A (enExample) |
| KR (1) | KR20100016163A (enExample) |
| CN (1) | CN101657522B (enExample) |
| TW (1) | TW200909549A (enExample) |
| WO (1) | WO2008128073A2 (enExample) |
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| KR100694445B1 (ko) * | 2004-08-24 | 2007-03-12 | 주식회사 엘지화학 | 대전 방지 성능을 갖는 아크릴계 점착제 조성물 |
| CN1973014B (zh) * | 2004-10-21 | 2010-07-07 | Lg化学株式会社 | 具有优良抗静电性能的丙烯酸压敏粘合剂 |
| KR100838973B1 (ko) * | 2005-06-08 | 2008-06-17 | 주식회사 엘지화학 | 아크릴계 점착제 조성물 |
| KR100784991B1 (ko) * | 2005-06-10 | 2007-12-11 | 주식회사 엘지화학 | 아크릴계 점착제 조성물 |
| JP2007002111A (ja) * | 2005-06-24 | 2007-01-11 | Toyo Ink Mfg Co Ltd | 帯電防止アクリル粘着剤 |
| DE112005003598A5 (de) * | 2005-07-21 | 2008-07-24 | Tesa Ag | Doppelseitige Haftklebebänder zur Herstellung von LC-Displays mit lichtreflektirenden und absorbierenden Eigenschaften |
-
2008
- 2008-04-11 TW TW097113407A patent/TW200909549A/zh unknown
- 2008-04-11 KR KR1020097022947A patent/KR20100016163A/ko not_active Ceased
- 2008-04-11 JP JP2010503242A patent/JP2010523806A/ja active Pending
- 2008-04-11 CN CN200880011906.6A patent/CN101657522B/zh not_active Expired - Fee Related
- 2008-04-11 EP EP08745637A patent/EP2139971A4/en not_active Withdrawn
- 2008-04-11 US US12/595,280 patent/US20100136265A1/en not_active Abandoned
- 2008-04-11 WO PCT/US2008/060075 patent/WO2008128073A2/en not_active Ceased
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI466971B (zh) * | 2008-03-07 | 2015-01-01 | 3M Innovative Properties Co | 抗靜電之嵌段共聚物壓敏性黏著劑及物件 |
| TWI566006B (zh) * | 2009-12-17 | 2017-01-11 | ３Ｍ新設資產公司 | 顯示面板組件及光學結合之方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101657522A (zh) | 2010-02-24 |
| EP2139971A4 (en) | 2011-09-21 |
| EP2139971A2 (en) | 2010-01-06 |
| WO2008128073A3 (en) | 2009-01-08 |
| US20100136265A1 (en) | 2010-06-03 |
| KR20100016163A (ko) | 2010-02-12 |
| JP2010523806A (ja) | 2010-07-15 |
| CN101657522B (zh) | 2014-05-07 |
| WO2008128073A2 (en) | 2008-10-23 |
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