SK282160B6 - 3-(2-acyloxyetoxyfenyl)benzofuran-2-óny, spôsob ich prípravy, kompozície s ich obsahom a ich použitie ako stabilizátorov - Google Patents

Info

Publication number

SK282160B6

SK282160B6 SK1017-93A SK101793A SK282160B6 SK 282160 B6 SK282160 B6 SK 282160B6 SK 101793 A SK101793 A SK 101793A SK 282160 B6 SK282160 B6 SK 282160B6

Authority

SK

Slovakia

Prior art keywords

carbon atoms

group

alkyl

hydrogen

interrupted

Prior art date

1992-09-23

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• 239000003381 stabilizer Substances 0.000 title claims abstract description 15
• 239000000203 mixture Substances 0.000 title claims description 52
• 238000000034 method Methods 0.000 title claims description 22
• 238000002360 preparation method Methods 0.000 title claims description 21
• 150000001875 compounds Chemical class 0.000 claims abstract description 124
• 239000000126 substance Substances 0.000 claims abstract description 20
• 230000015556 catabolic process Effects 0.000 claims abstract description 10
• 238000006731 degradation reaction Methods 0.000 claims abstract description 10
• 230000001590 oxidative effect Effects 0.000 claims abstract description 10
• 125000004432 carbon atom Chemical group C* 0.000 claims description 241
• -1 mercury metal cation Chemical class 0.000 claims description 216
• 125000000217 alkyl group Chemical group 0.000 claims description 91
• 229910052739 hydrogen Inorganic materials 0.000 claims description 57
• 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 57
• 125000002947 alkylene group Chemical group 0.000 claims description 55
• 239000001257 hydrogen Substances 0.000 claims description 49
• 229910052717 sulfur Inorganic materials 0.000 claims description 47
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 45
• 229910052760 oxygen Inorganic materials 0.000 claims description 31
• 150000002431 hydrogen Chemical class 0.000 claims description 27
• 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 24
• 125000004434 sulfur atom Chemical group 0.000 claims description 24
• 229910052799 carbon Inorganic materials 0.000 claims description 23
• 125000004430 oxygen atom Chemical group O* 0.000 claims description 23
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 21
• 125000003884 phenylalkyl group Chemical group 0.000 claims description 21
• 239000001301 oxygen Substances 0.000 claims description 19
• 125000002993 cycloalkylene group Chemical group 0.000 claims description 18
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 16
• ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical compound C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 claims description 15
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 14
• 125000002252 acyl group Chemical group 0.000 claims description 14
• 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 14
• 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 14
• 239000011593 sulfur Substances 0.000 claims description 14
• SVSARCCKBMZNMR-UHFFFAOYSA-N [1-[2-[methyl-[2-[4-(oxoazaniumylmethylidene)pyridin-1-yl]ethyl]amino]ethyl]pyridin-4-ylidene]methyl-oxoazanium;dichloride Chemical compound [Cl-].[Cl-].C1=CC(=C[NH+]=O)C=CN1CCN(C)CCN1C=CC(=C[NH+]=O)C=C1 SVSARCCKBMZNMR-UHFFFAOYSA-N 0.000 claims description 12
• 125000003545 alkoxy group Chemical group 0.000 claims description 11
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 10
• ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 9
• 125000004423 acyloxy group Chemical group 0.000 claims description 9
• 150000001721 carbon Chemical group 0.000 claims description 9
• 229910052751 metal Inorganic materials 0.000 claims description 9
• 239000002184 metal Substances 0.000 claims description 9
• NAWXUBYGYWOOIX-SFHVURJKSA-N (2s)-2-[[4-[2-(2,4-diaminoquinazolin-6-yl)ethyl]benzoyl]amino]-4-methylidenepentanedioic acid Chemical compound C1=CC2=NC(N)=NC(N)=C2C=C1CCC1=CC=C(C(=O)N[C@@H](CC(=C)C(O)=O)C(O)=O)C=C1 NAWXUBYGYWOOIX-SFHVURJKSA-N 0.000 claims description 8
• 125000001231 benzoyloxy group Chemical group C(C1=CC=CC=C1)(=O)O* 0.000 claims description 8
• 125000001589 carboacyl group Chemical group 0.000 claims description 7
• 229910052801 chlorine Inorganic materials 0.000 claims description 7
• 125000004956 cyclohexylene group Chemical group 0.000 claims description 7
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
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• 230000000087 stabilizing effect Effects 0.000 claims description 7
• YHXHKYRQLYQUIH-UHFFFAOYSA-N 4-hydroxymandelic acid Chemical compound OC(=O)C(O)C1=CC=C(O)C=C1 YHXHKYRQLYQUIH-UHFFFAOYSA-N 0.000 claims description 6
• IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 6
• 239000000460 chlorine Substances 0.000 claims description 6
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 6
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
• 125000004450 alkenylene group Chemical group 0.000 claims description 5
• 125000001118 alkylidene group Chemical group 0.000 claims description 5
• 125000006254 cycloalkyl carbonyl group Chemical group 0.000 claims description 5
• 125000000753 cycloalkyl group Chemical group 0.000 claims description 5
• 125000004414 alkyl thio group Chemical group 0.000 claims description 4
• 125000006639 cyclohexyl carbonyl group Chemical group 0.000 claims description 4
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
• 125000005201 cycloalkylcarbonyloxy group Chemical group 0.000 claims description 3
• 125000004663 dialkyl amino group Chemical group 0.000 claims description 3
• 125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims description 2
• MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
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• 125000001309 chloro group Chemical group Cl* 0.000 claims 2
• 239000000543 intermediate Substances 0.000 claims 2
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• 239000004927 clay Substances 0.000 claims 1
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• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 17
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• HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 8
• XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 8
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