NO319040B1 - Soyleformede leirekatalysatorer til katalytisk pyrolyseprosess for tungolje og fremgangsmate til fremstilling og anvendelse derav - Google Patents
Soyleformede leirekatalysatorer til katalytisk pyrolyseprosess for tungolje og fremgangsmate til fremstilling og anvendelse derav Download PDFInfo
- Publication number
- NO319040B1 NO319040B1 NO19986119A NO986119A NO319040B1 NO 319040 B1 NO319040 B1 NO 319040B1 NO 19986119 A NO19986119 A NO 19986119A NO 986119 A NO986119 A NO 986119A NO 319040 B1 NO319040 B1 NO 319040B1
- Authority
- NO
- Norway
- Prior art keywords
- catalysts
- zeolites
- catalyst
- mixtures
- sol
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims description 235
- 238000000034 method Methods 0.000 title claims description 88
- 239000004927 clay Substances 0.000 title claims description 38
- 230000008569 process Effects 0.000 title claims description 36
- 239000000295 fuel oil Substances 0.000 title claims description 28
- 238000007233 catalytic pyrolysis Methods 0.000 title claims description 24
- 238000002360 preparation method Methods 0.000 title description 3
- 239000010457 zeolite Substances 0.000 claims description 74
- 238000006243 chemical reaction Methods 0.000 claims description 50
- 229910052782 aluminium Inorganic materials 0.000 claims description 38
- 239000000203 mixture Substances 0.000 claims description 35
- 239000000047 product Substances 0.000 claims description 33
- 239000011230 binding agent Substances 0.000 claims description 32
- 238000005336 cracking Methods 0.000 claims description 30
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 29
- 229910052698 phosphorus Inorganic materials 0.000 claims description 29
- 238000012986 modification Methods 0.000 claims description 28
- 230000004048 modification Effects 0.000 claims description 28
- 150000001875 compounds Chemical class 0.000 claims description 27
- 239000002202 Polyethylene glycol Substances 0.000 claims description 24
- 229920001223 polyethylene glycol Polymers 0.000 claims description 24
- 238000004519 manufacturing process Methods 0.000 claims description 22
- 239000003921 oil Substances 0.000 claims description 22
- 239000000126 substance Substances 0.000 claims description 20
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 19
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- 239000011574 phosphorus Substances 0.000 claims description 19
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 16
- 150000001336 alkenes Chemical class 0.000 claims description 16
- -1 aluminum chlorohydroxide Chemical compound 0.000 claims description 16
- 238000001694 spray drying Methods 0.000 claims description 15
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 claims description 14
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 14
- 239000011265 semifinished product Substances 0.000 claims description 14
- 229910052749 magnesium Inorganic materials 0.000 claims description 13
- 239000002243 precursor Substances 0.000 claims description 13
- 229910052718 tin Inorganic materials 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 12
- 238000001354 calcination Methods 0.000 claims description 11
- 239000011159 matrix material Substances 0.000 claims description 11
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 11
- 229910052710 silicon Inorganic materials 0.000 claims description 11
- 239000002002 slurry Substances 0.000 claims description 11
- 239000010703 silicon Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- 229910052700 potassium Inorganic materials 0.000 claims description 9
- 230000032683 aging Effects 0.000 claims description 8
- 229910052809 inorganic oxide Inorganic materials 0.000 claims description 8
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical group CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 claims description 7
- 239000005995 Aluminium silicate Substances 0.000 claims description 7
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims description 7
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 7
- 229910052622 kaolinite Inorganic materials 0.000 claims description 7
- 239000003502 gasoline Substances 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 238000007796 conventional method Methods 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 238000011068 loading method Methods 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 239000003463 adsorbent Substances 0.000 claims description 4
- 239000000969 carrier Substances 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 239000011541 reaction mixture Substances 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000007858 starting material Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 238000004231 fluid catalytic cracking Methods 0.000 claims description 2
- 239000000499 gel Substances 0.000 claims 6
- 239000008279 sol Substances 0.000 claims 2
- 238000007865 diluting Methods 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 238000011156 evaluation Methods 0.000 description 24
- 102100028099 Thyroid receptor-interacting protein 6 Human genes 0.000 description 18
- 101710084345 Thyroid receptor-interacting protein 6 Proteins 0.000 description 18
- 230000003197 catalytic effect Effects 0.000 description 17
- 230000000694 effects Effects 0.000 description 16
- 239000000243 solution Substances 0.000 description 15
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 14
- 239000005977 Ethylene Substances 0.000 description 14
- 239000011777 magnesium Substances 0.000 description 13
- 239000002994 raw material Substances 0.000 description 13
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 10
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 10
- 230000009849 deactivation Effects 0.000 description 9
- 229910001868 water Inorganic materials 0.000 description 8
- 206010042674 Swelling Diseases 0.000 description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 7
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- 239000011229 interlayer Substances 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- 235000010755 mineral Nutrition 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 230000008961 swelling Effects 0.000 description 7
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 7
- 229910021536 Zeolite Inorganic materials 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- 238000004523 catalytic cracking Methods 0.000 description 6
- 102100032756 Cysteine-rich protein 1 Human genes 0.000 description 5
- 101710202818 Cysteine-rich protein 1 Proteins 0.000 description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 238000004227 thermal cracking Methods 0.000 description 5
- 241000839426 Chlamydia virus Chp1 Species 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 238000005755 formation reaction Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 4
- 239000012188 paraffin wax Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052593 corundum Inorganic materials 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 239000009671 shengli Substances 0.000 description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229910019440 Mg(OH) Inorganic materials 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 235000012254 magnesium hydroxide Nutrition 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000011268 mixed slurry Substances 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 102220043690 rs1049562 Human genes 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/12—Naturally occurring clays or bleaching earth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/005—Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/049—Pillared clays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Analytical Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97122089A CN1069682C (zh) | 1997-12-23 | 1997-12-23 | 重油催化热裂解层柱粘土催化剂及其制备 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO986119D0 NO986119D0 (no) | 1998-12-23 |
| NO986119L NO986119L (no) | 1999-06-24 |
| NO319040B1 true NO319040B1 (no) | 2005-06-06 |
Family
ID=5176677
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO19986119A NO319040B1 (no) | 1997-12-23 | 1998-12-23 | Soyleformede leirekatalysatorer til katalytisk pyrolyseprosess for tungolje og fremgangsmate til fremstilling og anvendelse derav |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6342153B1 (ja) |
| EP (1) | EP0925831B1 (ja) |
| JP (1) | JP4068246B2 (ja) |
| CN (1) | CN1069682C (ja) |
| DE (1) | DE69841771D1 (ja) |
| NO (1) | NO319040B1 (ja) |
Families Citing this family (52)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6458738B1 (en) * | 2000-09-22 | 2002-10-01 | Union Carbide Chemicals & Plastics Technology Corporation | Spray-drying compositions and methods of spray-drying |
| WO2003004444A1 (en) | 2001-07-02 | 2003-01-16 | Exxonmobil Chemical Patents Inc. | Inhibiting catalyst coke formation in the manufacture of an olefin |
| US6908544B2 (en) * | 2001-12-25 | 2005-06-21 | China Petroleum & Chemical Corporation | Cracking catalyst comprising layered clays and a process for cracking hydrocarbon oils using the same |
| US6872680B2 (en) | 2002-03-20 | 2005-03-29 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst composition, its making and use in conversion processes |
| US7271123B2 (en) | 2002-03-20 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst composition, its making and use in conversion process |
| JP4112943B2 (ja) | 2002-10-28 | 2008-07-02 | 出光興産株式会社 | 炭化水素の接触分解によるオレフィンの製造方法 |
| US7084318B2 (en) * | 2003-08-01 | 2006-08-01 | Saudi Basic Industries Corporation | Toluene methylation process |
| US7060864B2 (en) * | 2003-09-30 | 2006-06-13 | Saudi Basic Industries Corporation | Toluene methylation process |
| EP1677908B1 (en) * | 2003-10-10 | 2007-08-29 | Dow Gloval Technologies Inc. | Composite of exfoliated clay in soot and the preparation thereof |
| US7060644B2 (en) * | 2004-01-08 | 2006-06-13 | Saudi Basic Industries Corporation | Aromatic alkylation catalyst and method |
| US6943131B1 (en) * | 2004-03-02 | 2005-09-13 | Saudi Basic Industries Corporation | Selective zeolite catalyst modification |
| US7399727B2 (en) * | 2004-04-23 | 2008-07-15 | Saudi Basic Industries Corporation | Zeolite catalyst and method |
| US7285511B2 (en) * | 2004-04-23 | 2007-10-23 | Saudi Basic Industries Corporation | Method of modifying zeolite catalyst |
| WO2005123251A1 (en) * | 2004-06-09 | 2005-12-29 | Saudi Basic Industries Corporation | Fluoride-modified zeolite catalyst and method |
| KR100632563B1 (ko) * | 2004-09-10 | 2006-10-09 | 에스케이 주식회사 | 접촉 분해용 고체산 촉매 및 이를 이용하여 전범위납사로부터 경질 올레핀을 선택적으로 제조하는 공정 |
| CN100497530C (zh) * | 2004-12-28 | 2009-06-10 | 中国石油化工股份有限公司 | 一种烃油裂化方法 |
| US7304194B2 (en) * | 2005-05-05 | 2007-12-04 | Saudi Basic Industries Corporation | Hydrothermal treatment of phosphorus-modified zeolite catalysts |
| KR100598988B1 (ko) * | 2005-05-18 | 2006-07-12 | 주식회사 하이닉스반도체 | 오버레이 버니어 및 이를 이용한 반도체소자의 제조방법 |
| US7368410B2 (en) * | 2005-08-03 | 2008-05-06 | Saudi Basic Industries Corporation | Zeolite catalyst and method of preparing and use of zeolite catalyst |
| KR100632571B1 (ko) * | 2005-10-07 | 2006-10-09 | 에스케이 주식회사 | 탄화수소 원료 혼합물로부터 접촉분해공정을 통해서 경질올레핀계 탄화수소 화합물을 증산하는 방법 |
| KR100651329B1 (ko) * | 2005-10-07 | 2006-11-30 | 에스케이 주식회사 | 탄화수소 원료로부터 경질 올레핀을 제조하는 공정 |
| CA2617585C (en) * | 2005-10-07 | 2014-02-04 | Sk Energy Co., Ltd. | Process for production of light olefins from hydrocarbon feedstock |
| CA2539231C (en) | 2006-03-10 | 2013-08-13 | Baojian Shen | Catalyst composition for treating heavy feedstocks |
| KR100651418B1 (ko) * | 2006-03-17 | 2006-11-30 | 에스케이 주식회사 | 고속유동층을 이용하여 탄화수소 원료로부터 경질 올레핀을제조하는 접촉분해 공정 |
| CN101134913B (zh) | 2006-08-31 | 2011-05-18 | 中国石油化工股份有限公司 | 一种烃类催化转化方法 |
| CN101134172B (zh) | 2006-08-31 | 2010-10-27 | 中国石油化工股份有限公司 | 一种烃类转化催化剂 |
| EP2086675B1 (en) * | 2006-11-13 | 2010-11-03 | Albemarle Netherlands B.V. | Process for the preparation of an fcc catalyst |
| JP4818157B2 (ja) * | 2007-02-19 | 2011-11-16 | 一般財団法人石油エネルギー技術センター | 炭化水素油の接触分解触媒及び該触媒を用いる炭化水素油の接触分解方法 |
| JP4818156B2 (ja) * | 2007-02-19 | 2011-11-16 | 一般財団法人石油エネルギー技術センター | 炭化水素油の接触分解触媒及び該触媒を用いる炭化水素油の接触分解方法 |
| CN101332433B (zh) * | 2007-06-27 | 2011-07-20 | 中国石油化工股份有限公司 | 一种催化裂化催化剂及其制备和应用方法 |
| CN101722036B (zh) * | 2008-10-10 | 2011-08-10 | 中国石油化工股份有限公司 | 一种催化裂解催化剂及其制备方法 |
| US8846559B2 (en) * | 2008-11-03 | 2014-09-30 | Saudi Basic Industries Corporation | Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing |
| CN101898146B (zh) * | 2009-05-27 | 2013-01-09 | 中国石油化工股份有限公司 | 一种催化热裂解催化剂及其制备方法 |
| WO2011009074A2 (en) * | 2009-07-16 | 2011-01-20 | Champagne Gary E | Vacuum pyrolytic gasification and liquefaction to produce liquid and gaseous fuels from biomass |
| US8062987B2 (en) * | 2009-10-05 | 2011-11-22 | Saudi Basic Industries Corporation | Phosphorus-containing zeolite catalysts and their method of preparation |
| CN102211039B (zh) * | 2010-04-08 | 2013-09-04 | 中国石油化工股份有限公司 | 一种催化裂解催化剂及其制备方法 |
| CN102211038B (zh) * | 2010-04-08 | 2013-03-06 | 中国石油化工股份有限公司 | 一种催化裂解催化剂及其制备方法 |
| CN101892067A (zh) * | 2010-07-22 | 2010-11-24 | 中国石油天然气股份有限公司 | 一种促进重油催化裂解提高丙烯收率和选择性的方法 |
| US9181146B2 (en) | 2010-12-10 | 2015-11-10 | Exxonmobil Chemical Patents Inc. | Process for the production of xylenes and light olefins |
| US8921633B2 (en) | 2012-05-07 | 2014-12-30 | Exxonmobil Chemical Patents Inc. | Process for the production of xylenes and light olefins |
| US8937205B2 (en) | 2012-05-07 | 2015-01-20 | Exxonmobil Chemical Patents Inc. | Process for the production of xylenes |
| US9181147B2 (en) | 2012-05-07 | 2015-11-10 | Exxonmobil Chemical Patents Inc. | Process for the production of xylenes and light olefins |
| SG11201407659XA (en) | 2012-05-25 | 2014-12-30 | Saudi Arabian Oil Co | Catalyst for enhanced propylene in fluidized catalytic cracking |
| US9278342B2 (en) | 2012-07-02 | 2016-03-08 | Saudi Basic Industries Corporation | Method of modifying a phosphorus-containing zeolite catalyst |
| CN102963907A (zh) * | 2012-12-03 | 2013-03-13 | 华东师范大学 | 一种pentasil型沸石分子筛合成方法 |
| WO2017020848A1 (zh) * | 2015-08-05 | 2017-02-09 | 中国石油天然气股份有限公司 | 分子筛的改性方法及含分子筛的催化裂化催化剂 |
| JP6803729B2 (ja) * | 2016-11-16 | 2020-12-23 | Ｅｎｅｏｓ株式会社 | ｐ−キシレンの製造方法 |
| CN109304209B (zh) * | 2017-07-28 | 2021-07-30 | 中国石油天然气股份有限公司 | 一种多产汽油催化裂化催化剂及其制备方法 |
| CN110038511A (zh) * | 2018-01-17 | 2019-07-23 | 华中科技大学 | 一种载镧改性膨润土除磷材料的制备方法及其应用 |
| CN109569501B (zh) * | 2019-01-19 | 2020-01-10 | 长沙达树环保工程有限公司 | 一种含氟废水处理专用捕吸剂的制备方法 |
| CN111718753B (zh) * | 2019-03-22 | 2021-10-08 | 中国石油化工股份有限公司 | 一种多产丙烯的催化转化方法和系统 |
| CN115041223B (zh) * | 2022-07-18 | 2023-12-12 | 青岛惠城环保科技集团股份有限公司 | 一种直接催化裂解原油制低碳烯烃催化剂的制备方法 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3758403A (en) | 1970-10-06 | 1973-09-11 | Mobil Oil | Olites catalytic cracking of hydrocarbons with mixture of zsm-5 and other ze |
| US4176090A (en) | 1975-11-18 | 1979-11-27 | W. R. Grace & Co. | Pillared interlayered clay materials useful as catalysts and sorbents |
| US4757040A (en) * | 1985-04-01 | 1988-07-12 | Research Institute Of Petroleum Processing Sinopec | Class of pillared interlayered clay molecular sieve products with regularly interstratified mineral structure |
| JPS62101990A (ja) | 1985-10-25 | 1987-05-12 | 住友電気工業株式会社 | 複合パイプの端末部 |
| US4968652A (en) * | 1985-11-12 | 1990-11-06 | Mobil Oil Corporation | Pillared layered silicate compositions containing pillars of silica and metal oxide and their preparation |
| CN86101990B (zh) | 1986-03-27 | 1988-06-01 | 中国石油化工总公司石油化工科学研究院 | 一种粘土类层柱分子筛的制备方法 |
| US4742033A (en) * | 1987-01-29 | 1988-05-03 | Phillips Petroleum Company | Cracking catalysts comprising pillared clays |
| US5202295A (en) * | 1987-03-05 | 1993-04-13 | Uop | Intercalated clay having large interlayer spacing |
| JPH0635104B2 (ja) * | 1987-07-03 | 1994-05-11 | 株式会社日進製作所 | ロッカ−ア−ムのスリッパ−面のア−ル加工方法およびその装置 |
| CN1007879B (zh) * | 1987-07-13 | 1990-05-09 | 中国石化总公司石油化工科学研究院 | 层柱粘土分子筛裂化催化剂 |
| JPS6434114A (en) | 1987-07-30 | 1989-02-03 | Kansai Electric Power Co | Advancing tube in pneumatic feed type conduit device |
| CN1005613B (zh) * | 1987-08-22 | 1989-11-01 | 中国石油化工总公司石油化工科学研究院 | 含层柱粘土分子筛的催化剂的制备 |
| JPS6456860A (en) | 1987-08-28 | 1989-03-03 | Riken Kk | Sliding member |
| JPH0197751A (ja) | 1987-10-12 | 1989-04-17 | Hideo Yugawa | 板材を軽量鉄骨に固定する方法 |
| US4845066A (en) * | 1988-08-25 | 1989-07-04 | Phillips Petroleum Company | Preparation of pillared clay |
| JP2853859B2 (ja) | 1988-10-14 | 1999-02-03 | 旭化成工業株式会社 | 未延伸ポリアミド捲縮糸 |
| CN1043520A (zh) | 1988-12-21 | 1990-07-04 | 中国石油化工总公司石油化工科学研究院 | 一种生产低碳烯烃的裂解催化剂 |
| US5183559A (en) * | 1989-08-22 | 1993-02-02 | Mobil Oil Corp. | Rare earth exchanged layered silicate catalysts |
| JPH0458382A (ja) | 1990-06-27 | 1992-02-25 | Ricoh Co Ltd | 文字認識装置 |
| US5308812A (en) * | 1993-04-01 | 1994-05-03 | Bp America, Inc. | Treated pillared clays and alkylation process using same |
| JPH07107080A (ja) | 1993-09-30 | 1995-04-21 | Nippon Denki Idou Tsushin Kk | フレームパターン高速照合方法 |
| CN1048427C (zh) * | 1994-02-18 | 2000-01-19 | 中国石油化工总公司 | 多产烯烃的层柱分子筛催化剂 |
-
1997
- 1997-12-23 CN CN97122089A patent/CN1069682C/zh not_active Expired - Lifetime
-
1998
- 1998-12-23 DE DE69841771T patent/DE69841771D1/de not_active Expired - Lifetime
- 1998-12-23 US US09/219,119 patent/US6342153B1/en not_active Expired - Lifetime
- 1998-12-23 EP EP98124463A patent/EP0925831B1/en not_active Expired - Lifetime
- 1998-12-23 NO NO19986119A patent/NO319040B1/no not_active IP Right Cessation
- 1998-12-24 JP JP36824298A patent/JP4068246B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69841771D1 (de) | 2010-09-02 |
| NO986119D0 (no) | 1998-12-23 |
| EP0925831B1 (en) | 2010-07-21 |
| CN1221015A (zh) | 1999-06-30 |
| JPH11253808A (ja) | 1999-09-21 |
| EP0925831A3 (en) | 1999-12-22 |
| NO986119L (no) | 1999-06-24 |
| JP4068246B2 (ja) | 2008-03-26 |
| EP0925831A2 (en) | 1999-06-30 |
| CN1069682C (zh) | 2001-08-15 |
| US6342153B1 (en) | 2002-01-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| NO319040B1 (no) | Soyleformede leirekatalysatorer til katalytisk pyrolyseprosess for tungolje og fremgangsmate til fremstilling og anvendelse derav | |
| US4584091A (en) | Cracking with co-matrixed zeolite and p/alumina | |
| US6022471A (en) | Mesoporous FCC catalyst formulated with gibbsite and rare earth oxide | |
| Busca | Acid catalysts in industrial hydrocarbon chemistry | |
| US4567152A (en) | Co-matrixed zeolite and p/alumina | |
| CA2662077C (en) | A hydrocarbon conversion catalyst | |
| KR101122208B1 (ko) | 희토류 ｙ-제올라이트 함유 탄화수소 크래킹용 촉매 및 그의 제조 방법 | |
| CA1269087A (en) | Cracking catalyst | |
| US5051385A (en) | Monodispersed mesoporous catalyst matrices and FCC catalysts thereof | |
| US9943836B2 (en) | Metal modified Y zeolite, its preparation and use | |
| GB2521515A (en) | A metal modified Y zeolite, its preparation and use | |
| CA2017027C (en) | Cracking catalyst and process | |
| US5961817A (en) | Mesoporous FCC catalyst formulated with gibbsite | |
| US4764269A (en) | Cracking catalyst | |
| CA2662082A1 (en) | A process for the catalytic conversion of hydrocarbons | |
| JPH0214102B2 (ja) | ||
| JP4282059B2 (ja) | 希土類ゼオライトｙの調製方法 | |
| CA1135242A (en) | Hydrocarbon cracking catalyst and process utilizing the same | |
| EP2773459A1 (en) | Phosphorus modified cracking catalysts with enhanced activity and hydrothermal stability | |
| US5583082A (en) | Stable supergallery pillared clay compositions | |
| AU2014253496B2 (en) | A metal modified Y zeolite, its preparation and use | |
| EP0550270B1 (en) | Catalyst and process for cracking hydrocarbons with highly attrition resistant mesoporous catalytic cracking catalysts | |
| NO327131B1 (no) | Zeolitt basert katalysator med ultrahoy kinetisk konverteringsaktivitet | |
| KR100944728B1 (ko) | 다층 점토를 포함하는 열분해용 촉매 및 이를 이용한탄화수소유의 열분해방법 | |
| JP3138459B2 (ja) | 接触分解 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK1K | Patent expired |