KR910700289A - 안정화 폴리페닐렌 에테르 수지 및 그의 제조방법 - Google Patents

안정화 폴리페닐렌 에테르 수지 및 그의 제조방법

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Publication number
KR910700289A
KR910700289A KR1019890701476A KR890701476A KR910700289A KR 910700289 A KR910700289 A KR 910700289A KR 1019890701476 A KR1019890701476 A KR 1019890701476A KR 890701476 A KR890701476 A KR 890701476A KR 910700289 A KR910700289 A KR 910700289A
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South Korea
Prior art keywords
group
polyphenylene ether
carboxylic acid
hydrogen atom
independently
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KR1019890701476A
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English (en)
Other versions
KR920010148B1 (ko
Inventor
아끼히로 가나야마
스미오 우에다
사다오 이베
Original Assignee
에리 마사요시
아사히가세이고오교 가부시끼가이샤
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Publication of KR910700289A publication Critical patent/KR910700289A/ko
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Publication of KR920010148B1 publication Critical patent/KR920010148B1/ko

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C08G65/48Polymers modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C08G65/48Polymers modified by chemical after-treatment
    • C08G65/485Polyphenylene oxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12Polyphenylene oxides
    • C08L71/126Polyphenylene oxides modified by chemical after-treatment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/905Polyphenylene oxide

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyethers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

내용 없음.

Description

안정화 폴리페닐렌 에테르 수지 및 그의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 각각 반복 폴리페닐렌 에테르 유니트를 함유하는 다수의 폴리페닐렌 에테르 쇄를 포함하는 폴리페닐렌 에테르 수지로서, 상기 다수의 폴리페닐렌 에테르 쇄가 전체적으로 하기 일반식(a)의 6-크로만 말단기를 수지중 페닐렌 에테르 유니트 100개당 6-크로만 말단기의 수로 환산하여 적어도 0.01개 함유하고, 수지의 수평균 분자량이 1,000 내지 100,000의 범위내인 폴리페닐렌 에테르 수지.
    식중, R1~R5각각은 독립적으로 수소원자, 알킬기, 치환 알킬기, 할로겐원자, 아릴기 또는 치환 아릴기이며, R6~R9각각은 독립적으로 수소원자, 알킬기, 치환알킬기, 알케닐기, 치환 알케닐기, 할로겐원자, 아릴기, 치환 아릴기, 알콕시기, N-락탐기, 카르복실산, 아미드기, 카르복실산기, 카르복실산 무수물기, 카르복실산 에스테르기, 니트릴기, 아실기 또는 아실옥시기이고, 단, R6, R7, R8및 R9각각은 독립적으로 유리 말단을 갖거나, R6과 R7, 및 R8과 R9는 독립적으로 결합하여 환을 형성한다.
  2. 제1항에 있어서, 6-크로만 말단기 (a)의 수가 페닐렌 에테르 유니트 100개당 평균 0.15개 이상인 폴리페닐렌 에테르 수지.
  3. 제2항에 있어서, 6-크로만 말단기의 수가 페닐렌 에테르 유니트 100개 당 평균 0.2개 이상인 폴리페닐렌 에테르 수지.
  4. 제1항에 있어서, R6~R9치환체 중 2 또는 3개의 치환체 각각이 수소원자인 폴리페닐렌 에테르 수지.
  5. 제1항에 있어서, R6~R9치환체 중 2 또는 3개의 치환체 각각이 수소원자이고, 나머지 치환체 각각이 독립적으로 아릴기, 치환 아릴기, 카르복실산기, 카르복실산 무수물기, 카르복실산 에스테르기, 카르복실산 아미노기, 니트릴기 및 N-락탐기로부터 선택되는 폴리페닐렌 에테르 수지.
  6. 제5항에 있어서, R6~R9치환체중 3개의 치환체 각각이 수소원자이고, 나머지 치환체가 페닐기, 알킬-치환 페닐기, 할로게노페닐기, 피리딜기, 트리아질기, 카르복실산 에스테르가 또는 카르복실산 아미드기인 폴리페닐렌 에테르 수지.
  7. 제1항에 있어서, 페닐렌 에테르 유니트의 90~100%가 하기 일반식 (b)의 페닐렌 에테르 유니트인 폴리페닐렌 에테르 수지.
    식중, R1은 메틸기이고, R2~R5각각은 수소원자이다.
  8. 하기 일반식 (c)의 말단기를 갖는 페닐렌 에테르 중합체와 하기 일반식 (d)의 탄소-탄소 이중결합을 갖는 화합물을 라디칼 중합 개시제의 부재중에서 페닐렌 에테르 중합체의 유리전이 온도이상의 온도에서 가열함을 특징으로 하는, 제1항에 따른 폴리페닐렌 에테르 수지의 제조방법.
    식중, R1~R5각각은 독립적으로 수소원자, 알킬기, 치환알킬기, 할로겐 원자, 아릴기 또는 치환 아릴기이며, R10및 R11각각은 독립적으로 수소원자, 알킬기 또는 치환 알킬기이고, 단 R10및 R11은 동시에 수소원자이지 않으며, R6~R9각각은 독립적으로 수소원자, 알킬기, 치환 알킬기, 알케닐기, 치환 알케닐기, 할로겐원자, 아릴기, 치환 아릴기, 알콕시기, N-락탐기, 카르복실산 아미드기, 카르복실산기, 카르복실산 무수물기, 카르복실산 에스테르기, 니트릴기, 아실기 또는 아실옥시기이다.
  9. 제1항에 따른 폴리페닐렌 에테르 수지 1 내지 99중량% 및 폴리스티렌 수지 1 내지 99중량%를 함유하는 수지 조성물.
  10. 제1항에 있어서, 필름인 폴리페닐렌 에테로 수지.
  11. 제9항에 있어서, 필름인 수지 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890701476A 1989-01-27 1989-08-07 안정화 폴리페닐렌 에테르 수지 및 그의 제조방법 KR920010148B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP1-16300 1989-01-27
JP1630089 1989-01-27
JP16300 1989-01-27
PCT/JP1989/000538 WO1990008794A1 (en) 1989-01-27 1989-05-30 Stabilized polyphenylene ether resin

Publications (2)

Publication Number Publication Date
KR910700289A true KR910700289A (ko) 1991-03-14
KR920010148B1 KR920010148B1 (ko) 1992-11-16

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Country Status (8)

Country Link
US (2) US5159027A (ko)
EP (1) EP0407584B1 (ko)
JP (2) JP3052256B2 (ko)
KR (1) KR920010148B1 (ko)
CN (1) CN1029000C (ko)
CA (1) CA1338545C (ko)
DE (1) DE68925581T2 (ko)
WO (1) WO1990008794A1 (ko)

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EP0407584A4 (en) 1992-08-05
JP3052256B2 (ja) 2000-06-12
EP0407584A1 (en) 1991-01-16
USRE35695E (en) 1997-12-16
DE68925581D1 (de) 1996-03-14
DE68925581T2 (de) 1996-10-02
US5159027A (en) 1992-10-27
JPH02276823A (ja) 1990-11-13
EP0407584B1 (en) 1996-01-31
JP3109735B2 (ja) 2000-11-20
KR920010148B1 (ko) 1992-11-16
CN1029000C (zh) 1995-06-21
JP2000191770A (ja) 2000-07-11
CA1338545C (en) 1996-08-20
WO1990008794A1 (en) 1990-08-09
CN1044471A (zh) 1990-08-08

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