KR20120061831A - 광화이버 및 그 제조 방법 - Google Patents
광화이버 및 그 제조 방법 Download PDFInfo
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- KR20120061831A KR20120061831A KR1020127003520A KR20127003520A KR20120061831A KR 20120061831 A KR20120061831 A KR 20120061831A KR 1020127003520 A KR1020127003520 A KR 1020127003520A KR 20127003520 A KR20127003520 A KR 20127003520A KR 20120061831 A KR20120061831 A KR 20120061831A
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- South Korea
- Prior art keywords
- optical fiber
- polymer
- weight
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- core
- Prior art date
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- 239000002019 doping agent Substances 0.000 claims description 49
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 claims description 33
- JYNDMWZEMQAWTD-UHFFFAOYSA-N 2,2,2-trichloroethyl prop-2-enoate Chemical compound ClC(Cl)(Cl)COC(=O)C=C JYNDMWZEMQAWTD-UHFFFAOYSA-N 0.000 claims description 31
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 claims description 31
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- 239000000113 methacrylic resin Substances 0.000 description 1
- ZQMHJBXHRFJKOT-UHFFFAOYSA-N methyl 2-[(1-methoxy-2-methyl-1-oxopropan-2-yl)diazenyl]-2-methylpropanoate Chemical compound COC(=O)C(C)(C)N=NC(C)(C)C(=O)OC ZQMHJBXHRFJKOT-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SEEYREPSKCQBBF-UHFFFAOYSA-N n-methylmaleimide Chemical compound CN1C(=O)C=CC1=O SEEYREPSKCQBBF-UHFFFAOYSA-N 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
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- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
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- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229940070710 valerate Drugs 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
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Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/045—Light guides
- G02B1/046—Light guides characterised by the core material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/12—Esters of monohydric alcohols or phenols
- C08F20/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/22—Esters containing halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
- C08L33/16—Homopolymers or copolymers of esters containing halogen atoms
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/045—Light guides
- G02B1/048—Light guides characterised by the cladding material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1806—C6-(meth)acrylate, e.g. (cyclo)hexyl (meth)acrylate or phenyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1811—C10or C11-(Meth)acrylate, e.g. isodecyl (meth)acrylate, isobornyl (meth)acrylate or 2-naphthyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/22—Esters containing halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/36—Amides or imides
- C08F222/40—Imides, e.g. cyclic imides
- C08F222/402—Alkyl substituted imides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
- G02B6/02033—Core or cladding made from organic material, e.g. polymeric material
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JPJP-P-2009-163317 | 2009-07-10 | ||
| JP2009163317 | 2009-07-10 | ||
| JPJP-P-2009-293955 | 2009-12-25 | ||
| JP2009293955 | 2009-12-25 | ||
| JP2010087570 | 2010-04-06 | ||
| JPJP-P-2010-087570 | 2010-04-06 | ||
| PCT/JP2010/061378 WO2011004785A1 (ja) | 2009-07-10 | 2010-07-05 | 光ファイバー及びその製造方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20120061831A true KR20120061831A (ko) | 2012-06-13 |
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| KR1020127003520A Ceased KR20120061831A (ko) | 2009-07-10 | 2010-07-05 | 광화이버 및 그 제조 방법 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8611714B2 (enExample) |
| EP (1) | EP2453270B1 (enExample) |
| JP (1) | JP5419815B2 (enExample) |
| KR (1) | KR20120061831A (enExample) |
| CN (1) | CN102472861B (enExample) |
| CA (1) | CA2767727A1 (enExample) |
| IN (1) | IN2012DN01200A (enExample) |
| TW (1) | TWI471619B (enExample) |
| WO (1) | WO2011004785A1 (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102132185B (zh) * | 2008-06-23 | 2013-03-06 | 三菱丽阳株式会社 | 塑料光纤缆及信号传输方法 |
| CN102326106B (zh) * | 2009-02-20 | 2013-07-31 | 积水化学工业株式会社 | Gi型光纤及其制造方法 |
| JP5419815B2 (ja) * | 2009-07-10 | 2014-02-19 | 積水化学工業株式会社 | 光ファイバー及びその製造方法 |
| JP2012140559A (ja) * | 2011-01-06 | 2012-07-26 | Sekisui Chem Co Ltd | 樹脂組成物、成形体及び光ファイバー |
| PL3064970T3 (pl) * | 2013-11-01 | 2020-06-01 | Toray Industries, Inc. | Światłowód oświetlający z tworzywa sztucznego i sposób jego wytwarzania |
| CN105849610A (zh) * | 2013-12-11 | 2016-08-10 | 英派尔科技开发有限公司 | 光波导的制备和使用 |
| US10093787B2 (en) * | 2016-08-18 | 2018-10-09 | The Hong Kong Polytechnic University | Polymeric waveguide with single dopant |
| DK3764131T3 (da) * | 2018-03-05 | 2023-09-25 | Toray Industries | Optisk plastfiber og optisk plastfiberledning |
| TWI843720B (zh) | 2018-03-13 | 2024-06-01 | 小池康 | 一體成型多重光傳送片、一體成型多重光傳送片連接器及其製造方法 |
| EP3862800B1 (en) * | 2018-11-01 | 2023-11-22 | Kuraray Co., Ltd. | Light-emitting fiber |
| JP2020173390A (ja) * | 2019-04-12 | 2020-10-22 | 日東電工株式会社 | プラスチック光ファイバー及びその製造方法 |
| CN110670169B (zh) * | 2019-09-04 | 2022-03-15 | 苏州大学 | 一种聚合物光纤的制备方法 |
| EP4150385A1 (en) * | 2020-05-13 | 2023-03-22 | Haute Ecole Arc | Optical waveguide and method of fabrication thereof |
| US20240195503A1 (en) | 2021-04-07 | 2024-06-13 | Yasuhiro Koike | Optical transmission system, optical transmission path, and photoelectric composite cable |
| US12298553B2 (en) * | 2022-03-31 | 2025-05-13 | Microsoft Technology Licensing, Llc | Graded-index polymer optical fibre and the fabrication thereof |
| US20230314695A1 (en) * | 2022-03-31 | 2023-10-05 | Microsoft Technology Licensing, Llc | Multi-core optical fibre and fabrication thereof |
| US11931977B2 (en) | 2022-03-31 | 2024-03-19 | Microsoft Technology Licensing, Llc | Multi-core polymer optical fibre and the fabrication thereof |
| CN115840297A (zh) * | 2022-11-30 | 2023-03-24 | 安徽大学 | 基于聚合物光纤产生涡旋光的方法 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62156105A (ja) * | 1985-06-20 | 1987-07-11 | Mitsubishi Rayon Co Ltd | メタクリルイミド含有重合体 |
| JPH0644085B2 (ja) | 1985-12-20 | 1994-06-08 | 住友電気工業株式会社 | プラスチツク光フアイバおよびその製法 |
| GB2196148B (en) * | 1986-09-09 | 1990-03-28 | Central Glass Co Ltd | Optical fiber using vinylidene fluoride base ternary copolymer as cladding material |
| JPH0814646B2 (ja) * | 1986-12-15 | 1996-02-14 | 旭化成工業株式会社 | 耐熱性プラスチツク光フアイバ− |
| JPH04243203A (ja) * | 1991-01-17 | 1992-08-31 | Showa Denko Kk | プラスチック光ファイバー |
| KR0170358B1 (ko) | 1991-10-22 | 1999-05-01 | . | 굴절률 분포형 광학 수지 재료와 그 제조 방법 및 광전송체 |
| JPH11337781A (ja) * | 1998-05-29 | 1999-12-10 | Asahi Glass Co Ltd | 被覆プラスチック光ファイバおよびその製造方法 |
| FR2795997B1 (fr) * | 1999-07-05 | 2001-10-19 | Cit Alcatel | Procede de fabrication d'une fibre optique plastique a gradient d'indice |
| JP2001116967A (ja) * | 1999-08-06 | 2001-04-27 | Shin Etsu Chem Co Ltd | 光ファイバテープ及びその製造方法 |
| GB0013767D0 (en) * | 2000-06-07 | 2000-07-26 | Univ Heriot Watt | Photo-polymers and use thereof |
| JP2003139972A (ja) * | 2001-11-02 | 2003-05-14 | Mitsubishi Rayon Co Ltd | プラスチック光ファイバ、プラスチック光ファイバケーブル及びプラグ付きプラスチック光ファイバケーブル |
| JP2003226558A (ja) * | 2002-02-05 | 2003-08-12 | Shin Etsu Chem Co Ltd | 光ファイバ被覆用電子線硬化型樹脂組成物及び光ファイバ心線 |
| KR20040088402A (ko) * | 2003-04-01 | 2004-10-16 | 후지 샤신 필름 가부시기가이샤 | 플라스틱 광섬유 제조 방법 및 장치 |
| JP2005035284A (ja) * | 2003-06-30 | 2005-02-10 | Sekisui Chem Co Ltd | 屈折率分布型光学材料の製造方法 |
| JP4243203B2 (ja) | 2004-01-21 | 2009-03-25 | 積水ハウス株式会社 | 階段の接続構造 |
| JP2006010775A (ja) * | 2004-06-22 | 2006-01-12 | Fuji Photo Film Co Ltd | プラスチック光ファイバプリフォームの製造方法 |
| JP2006208551A (ja) * | 2005-01-26 | 2006-08-10 | Fuji Photo Film Co Ltd | プラスチック光ファイバ素線の製造方法およびその製造設備 |
| KR101016082B1 (ko) * | 2005-05-09 | 2011-02-17 | 미츠비시 레이온 가부시키가이샤 | 플라스틱 광섬유 케이블 |
| JP2006317844A (ja) * | 2005-05-16 | 2006-11-24 | Three M Innovative Properties Co | 側面発光型光ファイバー及び発光装置 |
| JP2007163910A (ja) * | 2005-12-15 | 2007-06-28 | Fujifilm Corp | プラスチック光ファイバ素線およびその製造方法 |
| JP2008250112A (ja) * | 2007-03-30 | 2008-10-16 | Sekisui Chem Co Ltd | プラスチック製光伝送体及びポリ塩化ビニル系樹脂製光伝送体の製造方法 |
| CN102132185B (zh) * | 2008-06-23 | 2013-03-06 | 三菱丽阳株式会社 | 塑料光纤缆及信号传输方法 |
| CN102326106B (zh) * | 2009-02-20 | 2013-07-31 | 积水化学工业株式会社 | Gi型光纤及其制造方法 |
| JP5419815B2 (ja) * | 2009-07-10 | 2014-02-19 | 積水化学工業株式会社 | 光ファイバー及びその製造方法 |
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2010
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- 2010-07-05 KR KR1020127003520A patent/KR20120061831A/ko not_active Ceased
- 2010-07-05 CN CN2010800309547A patent/CN102472861B/zh active Active
- 2010-07-05 WO PCT/JP2010/061378 patent/WO2011004785A1/ja not_active Ceased
- 2010-07-05 EP EP10797096.4A patent/EP2453270B1/en not_active Not-in-force
- 2010-07-05 CA CA2767727A patent/CA2767727A1/en not_active Abandoned
- 2010-07-05 US US13/383,041 patent/US8611714B2/en not_active Expired - Fee Related
- 2010-07-09 TW TW99122624A patent/TWI471619B/zh active
- 2010-07-10 IN IN1200DEN2012 patent/IN2012DN01200A/en unknown
Also Published As
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| EP2453270A4 (en) | 2015-05-13 |
| CN102472861B (zh) | 2013-06-26 |
| WO2011004785A1 (ja) | 2011-01-13 |
| EP2453270A1 (en) | 2012-05-16 |
| US20120114291A1 (en) | 2012-05-10 |
| US8611714B2 (en) | 2013-12-17 |
| IN2012DN01200A (enExample) | 2015-04-10 |
| TWI471619B (zh) | 2015-02-01 |
| CA2767727A1 (en) | 2011-01-13 |
| TW201106031A (en) | 2011-02-16 |
| EP2453270B1 (en) | 2016-06-22 |
| JP5419815B2 (ja) | 2014-02-19 |
| JP2011232726A (ja) | 2011-11-17 |
| CN102472861A (zh) | 2012-05-23 |
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