KR101863154B1 - 혼합된 염 아세틸아세토네이트 촉매를 이용한 에스터교환 방법 - Google Patents

혼합된 염 아세틸아세토네이트 촉매를 이용한 에스터교환 방법 Download PDF

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KR101863154B1
KR101863154B1 KR1020137000243A KR20137000243A KR101863154B1 KR 101863154 B1 KR101863154 B1 KR 101863154B1 KR 1020137000243 A KR1020137000243 A KR 1020137000243A KR 20137000243 A KR20137000243 A KR 20137000243A KR 101863154 B1 KR101863154 B1 KR 101863154B1
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alkyl
catalyst
group
alcohol
phenyl
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KR20140002591A (ko
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토마스 피터 안느 구센스
프릭 애니 카미엘 브리에린크
노엘 가브리엘 코넬리우스 호스텐
코엔 잔느 알폰스 반 아켄
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에코신스 비브이비에이
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00—Preparation of esters of carbonic or haloformic acids
    • C07C68/06—Preparation of esters of carbonic or haloformic acids from organic carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/49—Esterification or transesterification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
KR1020137000243A 2010-06-15 2011-06-10 혼합된 염 아세틸아세토네이트 촉매를 이용한 에스터교환 방법 Expired - Fee Related KR101863154B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB201009969A GB201009969D0 (en) 2010-06-15 2010-06-15 Transesterification process using mixed salt acetylacetonates catalysts
GB1009969.5 2010-06-15
PCT/EP2011/059672 WO2011157645A2 (en) 2010-06-15 2011-06-10 Transesterification process using mixed salt acetylacetonates catalysts

Publications (2)

Publication Number Publication Date
KR20140002591A KR20140002591A (ko) 2014-01-08
KR101863154B1 true KR101863154B1 (ko) 2018-07-04

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KR1020137000243A Expired - Fee Related KR101863154B1 (ko) 2010-06-15 2011-06-10 혼합된 염 아세틸아세토네이트 촉매를 이용한 에스터교환 방법

Country Status (10)

Country Link
US (1) US8865931B2 (cg-RX-API-DMAC10.html)
EP (1) EP2582453B1 (cg-RX-API-DMAC10.html)
JP (1) JP5916722B2 (cg-RX-API-DMAC10.html)
KR (1) KR101863154B1 (cg-RX-API-DMAC10.html)
CN (1) CN103140287B (cg-RX-API-DMAC10.html)
BR (1) BR112012031918B1 (cg-RX-API-DMAC10.html)
GB (1) GB201009969D0 (cg-RX-API-DMAC10.html)
MX (1) MX341537B (cg-RX-API-DMAC10.html)
RS (1) RS55808B1 (cg-RX-API-DMAC10.html)
WO (1) WO2011157645A2 (cg-RX-API-DMAC10.html)

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EP3072879A1 (en) 2015-03-26 2016-09-28 Nitto Europe N.V Method for prevention of premature polymerization
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TWI796324B (zh) * 2017-03-09 2023-03-21 日商東亞合成股份有限公司 (甲基)丙烯酸酯的製造方法
JP6991236B2 (ja) * 2017-10-24 2022-02-10 信越化学工業株式会社 ラジカル重合性オルガノポリシロキサンの製造方法、放射線硬化性オルガノポリシロキサン組成物、及び剥離シート
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CN109748826B (zh) * 2018-12-28 2021-09-21 京博农化科技有限公司 一种茚虫威中间体肼基甲酸苄酯的合成方法
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JP7512289B2 (ja) 2018-12-31 2024-07-08 ダウ シリコーンズ コーポレーション 分岐状有機ケイ素化合物、その調製方法、及びそれを含む組成物
WO2020142442A1 (en) 2018-12-31 2020-07-09 Dow Silicones Corporation Branched organosilicon compound, method of preparing same, and compositions comprising same
CN113330055A (zh) 2018-12-31 2021-08-31 美国陶氏有机硅公司 丙烯酸酯官能支链有机硅化合物、其制备方法以及用其形成的共聚物
WO2020142388A1 (en) 2018-12-31 2020-07-09 Dow Silicones Corporation Composition, method of preparing copolymer, and methods and end uses thereof
CN113330054B (zh) 2018-12-31 2023-02-21 美国陶氏有机硅公司 支链有机硅化合物、其制备方法以及用其形成的共聚物
US12215117B2 (en) 2018-12-31 2025-02-04 Dow Silicones Corporation Method of preparing acryloxy-functional organosilicon compounds
WO2020208951A1 (ja) * 2019-04-11 2020-10-15 株式会社クラレ 重合体、それを用いた酸素吸収剤、及び硬化性組成物
CN110252396B (zh) * 2019-06-27 2022-03-11 山东第一医科大学(山东省医学科学院) 一种用于间苯二甲酸二甲酯-5-磺酸钠合成过程中的催化剂、制备方法及应用
EP4299556B1 (en) * 2021-04-12 2026-06-17 Korea Research Institute of Chemical Technology Method for producing terephthalate derivative by transesterification of dimethyl terephthalate
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Also Published As

Publication number Publication date
US8865931B2 (en) 2014-10-21
GB201009969D0 (en) 2010-07-21
US20130090492A1 (en) 2013-04-11
MX341537B (es) 2016-08-24
JP2013533861A (ja) 2013-08-29
KR20140002591A (ko) 2014-01-08
CN103140287A (zh) 2013-06-05
WO2011157645A3 (en) 2012-10-18
CN103140287B (zh) 2016-08-03
JP5916722B2 (ja) 2016-05-11
EP2582453A2 (en) 2013-04-24
BR112012031918A2 (pt) 2016-11-08
MX2012014722A (es) 2013-04-11
WO2011157645A2 (en) 2011-12-22
BR112012031918B1 (pt) 2019-07-02
RS55808B1 (sr) 2017-08-31
EP2582453B1 (en) 2016-12-28

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