JP7110110B2 - 酸素吸収剤 - Google Patents
酸素吸収剤 Download PDFInfo
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- JP7110110B2 JP7110110B2 JP2018550123A JP2018550123A JP7110110B2 JP 7110110 B2 JP7110110 B2 JP 7110110B2 JP 2018550123 A JP2018550123 A JP 2018550123A JP 2018550123 A JP2018550123 A JP 2018550123A JP 7110110 B2 JP7110110 B2 JP 7110110B2
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- transition metal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1515—Three-membered rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/012—Additives improving oxygen scavenging properties
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Gas Separation By Absorption (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
[2] 前記化合物(A)に対して前記遷移金属塩(B)を0.001~10mol%含む、[1]の酸素吸収剤。
[3] 前記一般式(I)において、Xが酸素原子である、[1]または[2]の酸素吸収剤。
[4] 前記一般式(I)において、R3が水素原子である、[1]~[3]のいずれかの酸素吸収剤。
[5] 前記一般式(I)において、R4が水素原子またはメチル基である、[1]~[4]のいずれかの酸素吸収剤。
[6] 前記一般式(I)において、R5が下記一般式(II)、(III)および(IV)のいずれかで示される重合性基
[7] 前記一般式(I)において、R5が一般式(II)で示される重合性基である、[6]の酸素吸収剤。
[8] 下記一般式(I)で示される化合物(A)
測定することができる。
実施例または比較例で得た酸素吸収剤から100mgを精秤し、内容量20mLのサンプル瓶に入れた。その後、係るサンプル瓶内の湿度調整のため、0.5mLのイオン交換水が入った小瓶を該サンプル瓶に入れ、該サンプル瓶の開口部をポリテトラフルオロエチレン樹脂でシールされたゴムキャップおよびアルミシールで塞いだ。係るサンプル瓶を20℃の恒温槽に静置し、1日間、5日間、および15日間経過後の該サンプル瓶内の残存酸素量を、残存酸素計(飯島電子工業株式会社製;パックマスターRO-103)を使用して測定した。酸素吸収剤を入れなかったこと以外は同様に調製し、同条件で静置したサンプル瓶内の残存酸素量を同様に測定し、これらの残存酸素量の差を酸素吸収剤の酸素吸収量(20℃)[mL/g]とした。同じ試験を3度行い、その平均値を採用した。
酸素吸収量(20℃)の測定において、恒温槽の温度を20℃から60℃に変更した以外は同様にして、酸素吸収剤の酸素吸収量(60℃)[mL/g]とした。
ガラス製サンプル瓶中に、1-(3-メチル-2-ブテノキシ)-2,3-エポキシプロパン10g(70mmol)とステアリン酸コバルト(II)(和光純薬工業社製;純度90%)56mg(0.08mmol;1-(3-メチル-2-ブテノキシ)-2,3-エポキシプロパンに対して0.11mol%)を加えよく撹拌し、酸素吸収剤を得た。評価結果を表1に示す。
実施例1において、1-(3-メチル-2-ブテノキシ)-2,3-エポキシプロパンを下記式(VII)に示すアリルグリシジルエーテル(和光純薬工業社製;純度98%;85.9mmol)に変更し、ステアリン酸コバルト(II)の量を56mgから70mg(0.10mmol;アリルグリシジルエーテルに対して0.11mol%)に変更したこと以外は実施例1と同様の手法で調製し、酸素吸収剤を得た。評価結果を表1に示す。
実施例1において、1-(3-メチル-2-ブテノキシ)-2,3-エポキシプロパンを製造例2で得た1-(2-ブテノキシ)-2,3-エポキシプロパンに変更し、ステアリン酸コバルト(II)の量を56mgから63mg(0.09mmol;1-(2-ブテノキシ)-2,3-エポキシプロパンに対して0.11mol%)に変更したこと以外は実施例1と同様の手法で調製し、酸素吸収剤を得た。評価結果を表1に示す。
Claims (8)
- 前記一般式(I)において、R1、R2はそれぞれ、炭素数1~6のアルキル基である、請求項1に記載の酸素吸収剤。
- 前記化合物(A)に対して前記遷移金属塩(B)を0.001~10mol%含む、請求項1または2に記載の酸素吸収剤。
- 前記一般式(I)において、Xが酸素原子である、請求項1~3のいずれかに記載の酸素吸収剤。
- 前記一般式(I)において、R3が水素原子である、請求項1~4のいずれかに記載の酸素吸収剤。
- 前記一般式(I)において、R4が水素原子またはメチル基である、請求項1~5のいずれかに記載の酸素吸収剤。
- 前記一般式(I)において、R1、R2はそれぞれ、炭素数1~6のアルキル基である、請求項7に記載の樹脂組成物。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2016218853 | 2016-11-09 | ||
JP2016218853 | 2016-11-09 | ||
PCT/JP2017/038445 WO2018088206A1 (ja) | 2016-11-09 | 2017-10-25 | 酸素吸収剤 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPWO2018088206A1 JPWO2018088206A1 (ja) | 2019-09-26 |
JP7110110B2 true JP7110110B2 (ja) | 2022-08-01 |
Family
ID=62109683
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2018550123A Active JP7110110B2 (ja) | 2016-11-09 | 2017-10-25 | 酸素吸収剤 |
Country Status (7)
Country | Link |
---|---|
US (1) | US11174368B2 (ja) |
EP (1) | EP3539640B1 (ja) |
JP (1) | JP7110110B2 (ja) |
KR (1) | KR102413731B1 (ja) |
CN (1) | CN109890483B (ja) |
TW (1) | TWI742189B (ja) |
WO (1) | WO2018088206A1 (ja) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3782975B1 (en) | 2018-04-19 | 2023-07-05 | Kuraray Co., Ltd. | Compound containing unsaturated double bond, oxygen absorbent using same and resin composition |
JP6690850B1 (ja) * | 2018-11-01 | 2020-04-28 | 希久子 岩井 | 絵画の画面保護構造 |
US20220152582A1 (en) * | 2019-04-11 | 2022-05-19 | Kuraray Co., Ltd. | Polymer, oxygen absorber using same, and curable composition |
JP7341827B2 (ja) * | 2019-09-30 | 2023-09-11 | 株式会社クラレ | 長期耐候性に優れる熱可塑性樹脂組成物、その成形体及び積層体 |
US20230060171A1 (en) * | 2020-07-20 | 2023-03-02 | Kuraray Co., Ltd. | Metal particle composition, method for producing metal particle composition, and paste |
CN113388309A (zh) * | 2021-05-24 | 2021-09-14 | 青岛川青院新材料科技有限公司 | 一种具有吸氧功能的用于金属包装的涂料 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005230756A (ja) | 2004-02-23 | 2005-09-02 | Kuraray Co Ltd | 酸素吸収剤ならびにそれを用いた酸素吸収性組成物および包装材 |
WO2007040060A1 (ja) | 2005-09-30 | 2007-04-12 | Kuraray Co., Ltd. | 酸素吸収性組成物およびそれを用いた容器 |
Family Cites Families (15)
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US3644568A (en) * | 1968-10-31 | 1972-02-22 | Anchor Chemical Co Ltd The | Polyester compositions |
JPS51122690A (en) * | 1975-03-18 | 1976-10-26 | Hitachi Ltd | Method of separating and condensing oxygen |
JPS61101518A (ja) * | 1984-10-23 | 1986-05-20 | Showa Highpolymer Co Ltd | 空気乾燥性を有するビニルエステル樹脂の製造方法 |
JPH0623222B2 (ja) | 1986-11-20 | 1994-03-30 | 日立化成工業株式会社 | 空乾性不飽和ポリエステル樹脂組成物 |
JP3146551B2 (ja) | 1991-09-20 | 2001-03-19 | 日立化成工業株式会社 | 不飽和ポリエステル樹脂組成物およびパテ塗料 |
US5608110A (en) * | 1993-06-15 | 1997-03-04 | Bracco International B.V. | Heteroatom-bearing ligands and metal complexes thereof |
JPH09188645A (ja) * | 1996-01-05 | 1997-07-22 | Kuraray Co Ltd | シトラールの製造方法 |
JPH09235321A (ja) * | 1996-02-29 | 1997-09-09 | Nippon Zeon Co Ltd | 新規なエステルおよびその利用 |
WO2004018556A1 (ja) | 2002-08-23 | 2004-03-04 | Toyo Seikan Kaisha,Ltd. | 酸素吸収性樹脂組成物及び積層体 |
US20100187137A1 (en) | 2006-02-16 | 2010-07-29 | Zeon Corporation | Oxygen-Absorbable Resin Composition, Oxygen-Absorbable Barrier Resin Composition, Oxygen-Absorbable Molded Article, Packaging Material Comprising the Molded Article, and Packaging Container |
JP5464436B2 (ja) * | 2009-09-30 | 2014-04-09 | 共同印刷株式会社 | 酸素吸収剤及び酸素吸収性樹脂組成物ならびに酸素吸収性フィルム |
GB201009969D0 (en) * | 2010-06-15 | 2010-07-21 | Ecosynth Bvba | Transesterification process using mixed salt acetylacetonates catalysts |
WO2013099921A1 (ja) * | 2011-12-26 | 2013-07-04 | 東洋製罐グループホールディングス株式会社 | 酸素吸収性樹脂組成物 |
JP6410214B2 (ja) * | 2013-03-06 | 2018-10-24 | 三菱瓦斯化学株式会社 | 酸素吸収剤組成物並びにそれを用いた成形体及び包装体 |
JP2016174731A (ja) * | 2015-03-20 | 2016-10-06 | 三菱瓦斯化学株式会社 | 多層採血管 |
-
2017
- 2017-10-25 JP JP2018550123A patent/JP7110110B2/ja active Active
- 2017-10-25 US US16/343,802 patent/US11174368B2/en active Active
- 2017-10-25 CN CN201780068073.6A patent/CN109890483B/zh active Active
- 2017-10-25 EP EP17870354.2A patent/EP3539640B1/en active Active
- 2017-10-25 KR KR1020197010925A patent/KR102413731B1/ko active IP Right Grant
- 2017-10-25 WO PCT/JP2017/038445 patent/WO2018088206A1/ja unknown
- 2017-11-02 TW TW106137861A patent/TWI742189B/zh active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005230756A (ja) | 2004-02-23 | 2005-09-02 | Kuraray Co Ltd | 酸素吸収剤ならびにそれを用いた酸素吸収性組成物および包装材 |
WO2007040060A1 (ja) | 2005-09-30 | 2007-04-12 | Kuraray Co., Ltd. | 酸素吸収性組成物およびそれを用いた容器 |
Also Published As
Publication number | Publication date |
---|---|
EP3539640A4 (en) | 2020-06-17 |
US20190270864A1 (en) | 2019-09-05 |
US11174368B2 (en) | 2021-11-16 |
CN109890483B (zh) | 2022-03-01 |
EP3539640B1 (en) | 2021-06-16 |
TW201829580A (zh) | 2018-08-16 |
CN109890483A (zh) | 2019-06-14 |
WO2018088206A1 (ja) | 2018-05-17 |
JPWO2018088206A1 (ja) | 2019-09-26 |
KR102413731B1 (ko) | 2022-06-27 |
TWI742189B (zh) | 2021-10-11 |
EP3539640A1 (en) | 2019-09-18 |
KR20190079614A (ko) | 2019-07-05 |
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