KR101632616B1 - 양이온성 중합용 개시제 시스템 및 그것을 이용한 중합 방법 - Google Patents

양이온성 중합용 개시제 시스템 및 그것을 이용한 중합 방법 Download PDF

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KR101632616B1
KR101632616B1 KR1020127010147A KR20127010147A KR101632616B1 KR 101632616 B1 KR101632616 B1 KR 101632616B1 KR 1020127010147 A KR1020127010147 A KR 1020127010147A KR 20127010147 A KR20127010147 A KR 20127010147A KR 101632616 B1 KR101632616 B1 KR 101632616B1
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polymerization
aryl
alkyl
group
water
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Korean (ko)
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KR20120078724A (ko
Inventor
이시안 우
치앙 황
한 저우
루팅 진
핑 헤
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차이나 페트로리움 앤드 케미컬 코포레이션
베이징 유니버시티 오브 캐미컬 테크놀로지
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Priority claimed from CN 200910092795 external-priority patent/CN102030840B/zh
Priority claimed from CN201010257364XA external-priority patent/CN102399308B/zh
Priority claimed from CN2010102573635A external-priority patent/CN102399311B/zh
Application filed by 차이나 페트로리움 앤드 케미컬 코포레이션, 베이징 유니버시티 오브 캐미컬 테크놀로지 filed Critical 차이나 페트로리움 앤드 케미컬 코포레이션
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • C08F210/12—Isobutene with conjugated diolefins, e.g. butyl rubber

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
KR1020127010147A 2009-09-25 2010-09-21 양이온성 중합용 개시제 시스템 및 그것을 이용한 중합 방법 Active KR101632616B1 (ko)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
CN200910092795.2 2009-09-25
CN 200910092795 CN102030840B (zh) 2009-09-25 2009-09-25 乙烯基单体阳离子聚合的方法
CN201010257363.5 2010-08-19
CN201010257364XA CN102399308B (zh) 2010-08-19 2010-08-19 一种阳离子聚合方法
CN2010102573635A CN102399311B (zh) 2010-08-19 2010-08-19 一种阳离子聚合的引发体系及聚合方法
CN201010257364.X 2010-08-19

Publications (2)

Publication Number Publication Date
KR20120078724A KR20120078724A (ko) 2012-07-10
KR101632616B1 true KR101632616B1 (ko) 2016-06-22

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KR1020127010091A Active KR101691127B1 (ko) 2009-09-25 2010-09-21 이소올레핀 폴리머 및 그의 제조 방법
KR1020127010147A Active KR101632616B1 (ko) 2009-09-25 2010-09-21 양이온성 중합용 개시제 시스템 및 그것을 이용한 중합 방법

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US (2) US8883943B2 (enExample)
EP (2) EP2481760B1 (enExample)
JP (2) JP5600352B2 (enExample)
KR (2) KR101691127B1 (enExample)
CN (2) CN102597011B (enExample)
BR (2) BR112012007419B1 (enExample)
CA (2) CA2775006C (enExample)
IN (2) IN2012DN02574A (enExample)
PL (2) PL2481759T3 (enExample)
RU (2) RU2499004C1 (enExample)
WO (2) WO2011035544A1 (enExample)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8883943B2 (en) 2009-09-25 2014-11-11 China Petroleum & Chemical Corporation Isoolefin polymers and process for preparing the same
CA2789843C (en) * 2010-02-17 2018-07-10 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
CN102558911A (zh) * 2011-12-15 2012-07-11 安徽省润普纳米科技股份有限公司 一种表面改性SnO纳米添加剂的制备方法
JP7022115B2 (ja) * 2017-04-10 2022-02-17 株式会社カネカ イソブチレン系重合体の製造方法
HRP20221534T1 (hr) * 2018-08-03 2023-03-17 Cebiotex, S.L. Netkana membrana sa perlama kao sustav za isporuku lijekova
CN110898999A (zh) * 2019-11-26 2020-03-24 中国矿业大学 一种煤焦油基煤泥浮选药剂及其制备方法
CN120944000A (zh) * 2020-08-05 2025-11-14 巴斯夫欧洲公司 制备高反应性异丁烯均聚物或共聚物的方法
CN113589684B (zh) * 2021-05-20 2023-11-21 北京工业大学 一种基于自调整多任务粒子群算法的污水处理过程优化控制方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000017020A (ja) 1998-06-29 2000-01-18 Bridgestone Corp イソブチレン系共重合体の製造方法
CN1277212A (zh) * 2000-07-17 2000-12-20 北京化工大学 可控碳阳离子聚合方法
JP2009007385A (ja) 2005-12-01 2009-01-15 Kaneka Corp イソブチレン系重合体の製造方法

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE604903A (enExample) * 1960-06-13
US3640983A (en) * 1966-11-09 1972-02-08 Shojiro Horiguchi Method of making coupler-bonded-polymers and chromogen-bonded-polymers nd polymers made thereby
US4154916A (en) 1977-08-25 1979-05-15 Exxon Research & Engineering Co. Process for polymerization of isoolefins and multiolefins
US4269955A (en) 1977-08-25 1981-05-26 Exxon Research & Engineering Company Catalyst composition polymerization of isoolefins and multiolefins
CN1003082B (zh) 1987-05-16 1989-01-18 中国石油化工总公司大庆石油化工总厂 一种用于生产聚异丁烯的新型三氧化铝体系催化剂及其制备方法
US5350726A (en) * 1993-09-03 1994-09-27 Exxon Chemical Patents Inc. Carbocationic catalysts and process for using said catalysts
US6008307A (en) * 1994-04-28 1999-12-28 Exxon Chemical Patents Inc Process for producing olefin polymers using cationic catalysts
DE19525035A1 (de) 1995-07-10 1997-01-16 Bayer Ag Verfahren zur Herstellung von Polyisoolefinen mittels neuer Initiatorsysteme
JPH10130315A (ja) 1996-10-28 1998-05-19 Kuraray Co Ltd 重合体の製造方法
JPH1180221A (ja) 1997-09-08 1999-03-26 Kuraray Co Ltd 重合体の製造方法
US6300444B1 (en) 1998-08-25 2001-10-09 Nippon Petrochemicals Company, Limited Process for producing butene polymer
JP2000191714A (ja) * 1998-12-25 2000-07-11 Bridgestone Corp 重合用触媒及びそれを用いたイソブチレン―スチレン共重合体の製造方法
ATE320453T1 (de) 2000-08-25 2006-04-15 Kraton Polymers Res Bv Verfahren zur herstellung von selektiv hydrierten blockcopolymeren aus vinylaromatischen kohlenwasserstoffen und konjugierten dienen
DE10061715A1 (de) 2000-12-12 2002-06-13 Basf Ag Verfahren zur Herstellung von Homo- und Copolymeren des Isobutens
CA2332203A1 (en) * 2001-01-24 2002-07-24 Bayer Inc. Process for making high molecular weight isobutylene polymers
US20040000149A1 (en) 2002-07-01 2004-01-01 Kirkconnell Carl S. High-frequency, low-temperature regenerative heat exchanger
DE10243576A1 (de) 2002-09-19 2004-04-01 Basf Ag Verfahren zur Herstellung von Polyisobuten
US7196149B2 (en) 2003-04-17 2007-03-27 The University Of Akron Polymerization of i-butane in hydrocarbon media using bis(borane) co-initiators
US7202317B2 (en) * 2003-04-17 2007-04-10 The University Of Akron Polymerization of i-butene in hydrocarbon media using bis(borane) co-initiators
US7202371B2 (en) 2004-01-20 2007-04-10 The University Of Chicago Catalytic asymmetric epoxidation
WO2007102470A1 (ja) * 2006-03-09 2007-09-13 Nippon Steel Chemical Co., Ltd. 体積位相型ホログラム記録用感光性樹脂組成物及びそれを用いた光情報記録媒体
CN101423579B (zh) 2008-12-15 2010-09-15 中国海洋石油总公司 一种lng冷能用于丁基橡胶合成的方法
US8883943B2 (en) 2009-09-25 2014-11-11 China Petroleum & Chemical Corporation Isoolefin polymers and process for preparing the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000017020A (ja) 1998-06-29 2000-01-18 Bridgestone Corp イソブチレン系共重合体の製造方法
CN1277212A (zh) * 2000-07-17 2000-12-20 北京化工大学 可控碳阳离子聚合方法
JP2009007385A (ja) 2005-12-01 2009-01-15 Kaneka Corp イソブチレン系重合体の製造方法

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BR112012007446A2 (pt) 2016-12-06
IN2012DN02575A (enExample) 2015-08-28
EP2481759A4 (en) 2014-02-26
RU2012113605A (ru) 2013-10-27
CA2775006A1 (en) 2011-03-31
EP2481759B1 (en) 2021-05-05
IN2012DN02574A (enExample) 2015-08-28
CN102597014B (zh) 2015-05-13
KR101691127B1 (ko) 2016-12-29
JP5600352B2 (ja) 2014-10-01
US8937138B2 (en) 2015-01-20
WO2011035545A8 (zh) 2012-05-10
JP2013506013A (ja) 2013-02-21
BR112012007419A2 (pt) 2016-12-06
KR20120078724A (ko) 2012-07-10
RU2012114458A (ru) 2013-10-27
US20120238715A1 (en) 2012-09-20
CA2775006C (en) 2015-06-16
CN102597014A (zh) 2012-07-18
BR112012007419B1 (pt) 2021-02-02
WO2011035545A1 (zh) 2011-03-31
RU2499004C1 (ru) 2013-11-20
KR20120088715A (ko) 2012-08-08
US20120329973A1 (en) 2012-12-27
CA2775005A1 (en) 2011-03-31
CN102597011A (zh) 2012-07-18
JP5784021B2 (ja) 2015-09-24
BR112012007446B1 (pt) 2020-11-17
PL2481759T3 (pl) 2021-09-27
JP2013506012A (ja) 2013-02-21
WO2011035544A1 (zh) 2011-03-31
CN102597011B (zh) 2014-03-05
EP2481759A1 (en) 2012-08-01
EP2481760A1 (en) 2012-08-01
PL2481760T3 (pl) 2021-11-29
RU2506277C2 (ru) 2014-02-10
CA2775005C (en) 2015-11-17
US8883943B2 (en) 2014-11-11
EP2481760A4 (en) 2014-02-26
EP2481760B1 (en) 2021-05-05

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