KR101602980B1 - 혼합된 선택성 조절제를 갖는 촉매 조성물 및 이를 사용하는 중합 방법 - Google Patents
혼합된 선택성 조절제를 갖는 촉매 조성물 및 이를 사용하는 중합 방법 Download PDFInfo
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- KR101602980B1 KR101602980B1 KR1020117006170A KR20117006170A KR101602980B1 KR 101602980 B1 KR101602980 B1 KR 101602980B1 KR 1020117006170 A KR1020117006170 A KR 1020117006170A KR 20117006170 A KR20117006170 A KR 20117006170A KR 101602980 B1 KR101602980 B1 KR 101602980B1
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- KR
- South Korea
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- sca2
- dimethoxysilane
- catalyst composition
- ala
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 125
- 239000003054 catalyst Substances 0.000 title claims abstract description 76
- 238000000034 method Methods 0.000 title claims description 64
- 239000003795 chemical substances by application Substances 0.000 title description 4
- 239000012041 precatalyst Substances 0.000 claims abstract description 14
- 239000011954 Ziegler–Natta catalyst Substances 0.000 claims abstract description 11
- 239000003607 modifier Substances 0.000 claims abstract description 5
- -1 poly (alkylene glycol) esters Chemical class 0.000 claims description 74
- 239000010936 titanium Substances 0.000 claims description 31
- 229910052719 titanium Inorganic materials 0.000 claims description 24
- 125000000217 alkyl group Chemical group 0.000 claims description 19
- 125000003118 aryl group Chemical group 0.000 claims description 19
- YQGOWXYZDLJBFL-UHFFFAOYSA-N dimethoxysilane Chemical compound CO[SiH2]OC YQGOWXYZDLJBFL-UHFFFAOYSA-N 0.000 claims description 18
- 229910052782 aluminium Inorganic materials 0.000 claims description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 13
- 239000011777 magnesium Substances 0.000 claims description 13
- 125000001931 aliphatic group Chemical group 0.000 claims description 11
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 claims description 11
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 claims description 10
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 10
- 229910052749 magnesium Inorganic materials 0.000 claims description 10
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 8
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 125000005907 alkyl ester group Chemical group 0.000 claims description 4
- CPLASELWOOUNGW-UHFFFAOYSA-N benzyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)CC1=CC=CC=C1 CPLASELWOOUNGW-UHFFFAOYSA-N 0.000 claims description 4
- ATGKAFZFOALBOF-UHFFFAOYSA-N cyclohexyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C1CCCCC1 ATGKAFZFOALBOF-UHFFFAOYSA-N 0.000 claims description 4
- LORADGICSMRHTR-UHFFFAOYSA-N cyclohexyl-diethoxy-methylsilane Chemical compound CCO[Si](C)(OCC)C1CCCCC1 LORADGICSMRHTR-UHFFFAOYSA-N 0.000 claims description 4
- YPENMAABQGWRBR-UHFFFAOYSA-N dibutyl(dimethoxy)silane Chemical compound CCCC[Si](OC)(OC)CCCC YPENMAABQGWRBR-UHFFFAOYSA-N 0.000 claims description 4
- WOZOEHNJNZTJDH-UHFFFAOYSA-N diethoxy-bis(2-methylpropyl)silane Chemical compound CCO[Si](CC(C)C)(CC(C)C)OCC WOZOEHNJNZTJDH-UHFFFAOYSA-N 0.000 claims description 4
- 125000003342 alkenyl group Chemical group 0.000 claims description 3
- ZXPDYFSTVHQQOI-UHFFFAOYSA-N diethoxysilane Chemical compound CCO[SiH2]OCC ZXPDYFSTVHQQOI-UHFFFAOYSA-N 0.000 claims description 3
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims description 3
- NKOASXOHUZFMGE-UHFFFAOYSA-N triethoxy(pent-2-enyl)silane Chemical compound CCO[Si](OCC)(OCC)CC=CCC NKOASXOHUZFMGE-UHFFFAOYSA-N 0.000 claims description 3
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 claims description 3
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 3
- GLVIMRBXUNCALJ-UHFFFAOYSA-N 1-ethoxy-2-pentoxybenzene Chemical compound CCCCCOC1=CC=CC=C1OCC GLVIMRBXUNCALJ-UHFFFAOYSA-N 0.000 claims description 2
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 claims description 2
- JJQZDUKDJDQPMQ-UHFFFAOYSA-N dimethoxy(dimethyl)silane Chemical compound CO[Si](C)(C)OC JJQZDUKDJDQPMQ-UHFFFAOYSA-N 0.000 claims description 2
- VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 claims description 2
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims description 2
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- 239000012190 activator Substances 0.000 claims 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims 1
- DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical compound CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 claims 1
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- 150000003623 transition metal compounds Chemical class 0.000 description 10
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- 238000006243 chemical reaction Methods 0.000 description 9
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- HRAQMGWTPNOILP-UHFFFAOYSA-N 4-Ethoxy ethylbenzoate Chemical compound CCOC(=O)C1=CC=C(OCC)C=C1 HRAQMGWTPNOILP-UHFFFAOYSA-N 0.000 description 7
- 230000008901 benefit Effects 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 125000001183 hydrocarbyl group Chemical group 0.000 description 7
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- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 6
- 238000012937 correction Methods 0.000 description 6
- 230000026030 halogenation Effects 0.000 description 6
- 238000005658 halogenation reaction Methods 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
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- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 5
- 229910052736 halogen Inorganic materials 0.000 description 5
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
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- 150000004703 alkoxides Chemical class 0.000 description 4
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Images
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| PCT/US2009/034875 WO2010021762A1 (en) | 2008-08-21 | 2009-02-23 | Catalyst composition with mixed selectivity control agent and polymerisation method using it |
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| BRPI0912920B1 (pt) * | 2008-08-21 | 2019-07-09 | W. R. Grace & Co. -Conn | Processo de polimerização e copolímero de impacto de propileno |
| US8507717B2 (en) * | 2008-12-31 | 2013-08-13 | Dow Global Technologies Llc | Production of substituted phenylene aromatic diesters |
| US8378045B2 (en) * | 2008-12-31 | 2013-02-19 | Dow Global Technologies Llc | Thermoformed article with high stiffness and good optics |
| CN102325808B (zh) | 2008-12-31 | 2014-03-12 | 陶氏环球技术有限责任公司 | 包含取代的1,2-亚苯基芳族二酯内给体的前催化剂组合物及方法 |
| MY156361A (en) * | 2009-12-21 | 2016-02-15 | Grace W R & Co | Gas-phase polymerization process having multiple flow regimes |
| JP5640402B2 (ja) * | 2010-03-08 | 2014-12-17 | 住友化学株式会社 | α−オレフィン重合用触媒 |
| RU2584694C2 (ru) * | 2010-09-28 | 2016-05-20 | Базелль Полиолефине Гмбх | Полиэтиленовые экструдированные изделия |
| WO2012064468A2 (en) * | 2010-11-09 | 2012-05-18 | Exxonmobil Chemical Patents Inc. | Meltblown nonwoven compositions and methods for making them |
| US9434796B2 (en) | 2010-12-21 | 2016-09-06 | W. R. Grace & Co.-Conn. | Catalyst composition with alkoxyalkyl ester internal electron donor and polymer from same |
| US8604146B2 (en) * | 2010-12-21 | 2013-12-10 | Dow Global Technologies Llc | Catalyst composition with alkoxyalkyl ester internal electron donor and polymer from same |
| KR101906621B1 (ko) * | 2010-12-21 | 2018-10-10 | 더블유.알. 그레이스 앤드 캄파니-콘. | 고 용융 유동 프로필렌-기재 중합체의 생산 공정 및 이로부터의 생산물 |
| WO2012118883A1 (en) * | 2011-03-01 | 2012-09-07 | Dow Global Technologies Llc | Process for improving bulk density with multi-contact procatalyst and product |
| ES2606052T3 (es) * | 2011-11-21 | 2017-03-17 | W.R. Grace & Co.-Conn. | Catalizador de alta actividad para la polimerización de olefinas |
| EP2607384A1 (en) * | 2011-12-21 | 2013-06-26 | Basell Poliolefine Italia S.r.l. | Catalyst system for the polymerization of olefins |
| CN103788265B (zh) * | 2012-10-30 | 2016-12-21 | 中国石油化工股份有限公司 | 一种具有高熔体强度的聚丙烯的制备方法 |
| ES2963034T3 (es) * | 2013-08-19 | 2024-03-25 | Dow Global Technologies Llc | Método para producir un polímero a base de etileno en un procedimiento de polimerización usando un agente de autolimitación |
| TWI639626B (zh) * | 2013-09-30 | 2018-11-01 | 中國石油化工科技開發有限公司 | Catalyst composition for olefin polymerization and application thereof |
| WO2015073221A1 (en) * | 2013-11-15 | 2015-05-21 | Dow Global Technologies Llc | A polyolefin composition and method of producing the same |
| RU2702633C1 (ru) * | 2013-11-15 | 2019-10-09 | У.Р. Грейс Энд Ко.-Конн | Полимер на основе пропилена с уменьшенной высокомолекулярной частью |
| EA034562B1 (ru) | 2013-12-20 | 2020-02-20 | Сауди Бейсик Индастриз Корпорейшн | Композиция катализатора для полимеризации олефинов |
| WO2015091940A1 (en) | 2013-12-20 | 2015-06-25 | Saudi Basic Industries Corporation | Catalyst system for polymerisation of an olefin |
| MX2016008041A (es) | 2013-12-20 | 2017-03-03 | Saudi Basic Ind Corp | Sistema catalizador para polimerizacion de una olefina. |
| EP3083722B1 (en) | 2013-12-20 | 2021-11-10 | Saudi Basic Industries Corporation | Catalyst system for polymerisation of an olefin |
| CN105940019B (zh) | 2013-12-20 | 2018-05-18 | 沙特基础工业公司 | 用于烯烃聚合的催化剂体系 |
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| WO2010021762A4 (en) | 2010-04-15 |
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| US10322394B2 (en) | 2019-06-18 |
| US20090203863A1 (en) | 2009-08-13 |
| US7893003B2 (en) | 2011-02-22 |
| BRPI0912917A8 (pt) | 2017-09-19 |
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