KR100658383B1 - 에틸렌과 아세트산의 비닐 아세테이트로의 기상 산화용 촉매 및 이의 제조방법 - Google Patents
에틸렌과 아세트산의 비닐 아세테이트로의 기상 산화용 촉매 및 이의 제조방법 Download PDFInfo
- Publication number
- KR100658383B1 KR100658383B1 KR1020017012298A KR20017012298A KR100658383B1 KR 100658383 B1 KR100658383 B1 KR 100658383B1 KR 1020017012298 A KR1020017012298 A KR 1020017012298A KR 20017012298 A KR20017012298 A KR 20017012298A KR 100658383 B1 KR100658383 B1 KR 100658383B1
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst
- reduction
- delete delete
- compounds
- reducing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/135—Halogens; Compounds thereof with titanium, zirconium, hafnium, germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19914066A DE19914066A1 (de) | 1999-03-27 | 1999-03-27 | Katalysatoren für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE19914066.9 | 1999-03-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20010105396A KR20010105396A (ko) | 2001-11-28 |
| KR100658383B1 true KR100658383B1 (ko) | 2006-12-21 |
Family
ID=7902722
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020017012298A Expired - Fee Related KR100658383B1 (ko) | 1999-03-27 | 2000-03-21 | 에틸렌과 아세트산의 비닐 아세테이트로의 기상 산화용 촉매 및 이의 제조방법 |
Country Status (25)
| Country | Link |
|---|---|
| US (1) | US6849243B1 (enExample) |
| EP (1) | EP1189694B1 (enExample) |
| JP (1) | JP4750283B2 (enExample) |
| KR (1) | KR100658383B1 (enExample) |
| CN (1) | CN1125677C (enExample) |
| AR (1) | AR023146A1 (enExample) |
| AT (1) | ATE513617T1 (enExample) |
| AU (1) | AU764236B2 (enExample) |
| BR (1) | BR0009356B1 (enExample) |
| CA (1) | CA2366465C (enExample) |
| CZ (1) | CZ300040B6 (enExample) |
| DE (1) | DE19914066A1 (enExample) |
| ES (1) | ES2368483T3 (enExample) |
| ID (1) | ID30304A (enExample) |
| MX (1) | MXPA01009724A (enExample) |
| MY (1) | MY122744A (enExample) |
| NO (1) | NO20014678D0 (enExample) |
| NZ (1) | NZ514433A (enExample) |
| PL (1) | PL203044B1 (enExample) |
| RU (1) | RU2261142C2 (enExample) |
| TR (1) | TR200102803T2 (enExample) |
| TW (1) | TW548134B (enExample) |
| UA (1) | UA77384C2 (enExample) |
| WO (1) | WO2000058008A1 (enExample) |
| ZA (1) | ZA200107080B (enExample) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002078843A1 (en) | 2001-03-30 | 2002-10-10 | Shell Internationale Research Maatschappij B.V. | Process for preparing a group viii-metal containing catalyst, use thereof for preparing an alkenyl carboxylate |
| GB0201378D0 (en) * | 2002-01-22 | 2002-03-13 | Bp Chem Int Ltd | Process |
| JP4421201B2 (ja) | 2002-03-27 | 2010-02-24 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒を調製する方法、触媒、および触媒の使用 |
| TW200539941A (en) | 2003-12-19 | 2005-12-16 | Celanese Int Corp | Methods of making alkenyl alkanoates |
| NZ547073A (en) * | 2003-12-19 | 2010-05-28 | Celanese Int Corp | Layered support material for catalysts |
| JP4551109B2 (ja) * | 2004-04-14 | 2010-09-22 | エヌ・イーケムキャット株式会社 | 触媒の製造方法 |
| DE102004050585A1 (de) * | 2004-10-15 | 2006-04-20 | Degussa Ag | Mikroreaktor und Verfahren zur Synthese von Vinylacetat-Monomer (VAM) in der Gasphase |
| CA2586584C (en) | 2004-12-20 | 2011-01-18 | Celanese International Corporation | Modified support materials for catalysts |
| US8227369B2 (en) | 2005-05-25 | 2012-07-24 | Celanese International Corp. | Layered composition and processes for preparing and using the composition |
| US8168562B2 (en) * | 2006-02-02 | 2012-05-01 | Lyondell Chemical Technology, L.P. | Preparation of palladium-gold catalysts |
| US7825204B2 (en) * | 2006-12-19 | 2010-11-02 | Lyondell Chemical Technology, L.P. | Inorganic oxide extrudates |
| US7811968B2 (en) * | 2007-05-11 | 2010-10-12 | Lyondell Chemical Technology, L.P. | Preparation of palladium-gold catalysts |
| DE102007025358A1 (de) * | 2007-05-31 | 2009-01-08 | Süd-Chemie AG | Verfahren zur Herstellung eines mit Pd und/oder Au beladenen Schalenkatalysators |
| DE102007025356A1 (de) * | 2007-05-31 | 2009-01-08 | Süd-Chemie AG | Verfahren zur Herstellung eines Schalenkatalysators und Schalenkatalysator |
| DE102007025223A1 (de) | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102007025362A1 (de) | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102007025443A1 (de) | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102007025315A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung |
| DE102007025444A1 (de) | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102007025442B4 (de) | 2007-05-31 | 2023-03-02 | Clariant International Ltd. | Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator |
| DE102007043446B4 (de) | 2007-09-12 | 2013-08-22 | Süd-Chemie Ip Gmbh & Co. Kg | Katalysatorträger mit erhöhter Wärmeleitfähigkeit |
| DE102007043447B4 (de) | 2007-09-12 | 2014-02-13 | Süd-Chemie Ip Gmbh & Co. Kg | Katalysatorträger mit erhöhter thermischer Leitfähigkeit |
| JP5237616B2 (ja) * | 2007-11-27 | 2013-07-17 | 石福金属興業株式会社 | 白金族金属又は白金族金属とそれ以外の他の金属との合金を担持してなる酸化チタン担体の製造方法 |
| US20100121100A1 (en) * | 2008-11-12 | 2010-05-13 | Daniel Travis Shay | Supported palladium-gold catalysts and preparation of vinyl acetate therewith |
| US7855303B2 (en) * | 2008-11-14 | 2010-12-21 | Celanese International Corporation | Integrated process for the production of vinyl acetate from acetic acid via ethylene |
| DE102008059340A1 (de) | 2008-11-30 | 2010-06-10 | Süd-Chemie AG | Katalysatorträger, Verfahren zu seiner Herstellung sowie dessen Verwendung |
| DE102008059341A1 (de) | 2008-11-30 | 2010-06-10 | Süd-Chemie AG | Katalysatorträger, Verfahren zu seiner Herstellung sowie Verwendung |
| DE102008059342A1 (de) | 2008-11-30 | 2010-06-10 | Süd-Chemie AG | Schalenkatalysator, Verfahren zu seiner Herstellung sowie Verwendung |
| DE102009001021A1 (de) * | 2009-02-19 | 2010-08-26 | Wacker Chemie Ag | Verfahren und Vorrichtung zur Herstellung von Vinylacetat |
| US8329611B2 (en) | 2009-12-16 | 2012-12-11 | Lyondell Chemical Technology, L,P. | Titania-containing extrudate |
| US8507720B2 (en) * | 2010-01-29 | 2013-08-13 | Lyondell Chemical Technology, L.P. | Titania-alumina supported palladium catalyst |
| US8273682B2 (en) | 2009-12-16 | 2012-09-25 | Lyondell Chemical Technology, L.P. | Preparation of palladium-gold catalyst |
| DE102010056428B4 (de) | 2009-12-28 | 2013-01-31 | Süd-Chemie Ip Gmbh & Co. Kg | Geträgerte Übergangsmetallkatalysatoren |
| DE102010026462A1 (de) * | 2010-07-08 | 2012-01-12 | Süd-Chemie AG | Verfahren zur Herstellung eines Schalenkatalysators und Schalenkatalysator |
| FR2975777B1 (fr) * | 2011-05-26 | 2014-03-14 | Arkema France | Procede de caracterisation d'un copolymere d'ethylene et d'acetate de vinyle |
| CN102381966A (zh) * | 2011-11-11 | 2012-03-21 | 天津大学 | 一种醋酸乙烯生产方法 |
| CN119657128B (zh) * | 2024-12-23 | 2025-09-23 | 西安交通大学 | 一种基于金属载体强相互作用的高稳定贵金属基催化剂和制备方法及其在二氧化碳催化加氢制甲醇中的应用 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0839793A1 (en) * | 1996-11-04 | 1998-05-06 | BP Chemicals Limited | Process for the production of vinyl acetate |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1252662B (enExample) * | 1965-06-25 | |||
| JPS514118A (en) * | 1974-06-27 | 1976-01-14 | Kuraray Co | Sakusanbiniruno seizohoho |
| US4048096A (en) * | 1976-04-12 | 1977-09-13 | E. I. Du Pont De Nemours And Company | Surface impregnated catalyst |
| US4188490A (en) * | 1977-05-27 | 1980-02-12 | National Distillers And Chemical Corporation | Catalytic oxidation of ethylene to mixtures of acetic acid and vinyl acetate |
| US5179056A (en) * | 1991-05-06 | 1993-01-12 | Union Carbide Chemicals & Plastics Technology Corporation | Production of alkenyl alkanoate catalysts |
| US5179057A (en) * | 1991-05-06 | 1993-01-12 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts for alkenyl alkanoate production |
| US5185308A (en) * | 1991-05-06 | 1993-02-09 | Bp Chemicals Limited | Catalysts and processes for the manufacture of vinyl acetate |
| US5189004A (en) * | 1991-11-18 | 1993-02-23 | Union Carbide Chemicals & Plastics Technology Corporation | Alkenyl alkanoate catalyst process |
| US5194417A (en) * | 1991-12-05 | 1993-03-16 | Quantum Chemical Corporation | Pretreatment of palladium-gold catalysts useful in vinyl acetate synthesis |
| RU2061544C1 (ru) * | 1992-01-31 | 1996-06-10 | Бп Кемикалз Лимитед | Катализатор для получения винилацетата |
| TW330160B (en) * | 1992-04-08 | 1998-04-21 | Hoechst Ag | Supported catalyst, process for its preparation and its use for the preparation of vinyl acetate |
| US5314858A (en) * | 1992-10-14 | 1994-05-24 | Hoechst Celanese Corporation | Vinyl acetate catalyst preparation method |
| DE4323978C1 (de) * | 1993-07-16 | 1995-02-16 | Hoechst Ag | Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat |
| SG47363A1 (en) | 1994-02-22 | 1998-04-17 | Standard Oil Co Ohio | Process for the preparation of fluid bed vinyl acetate catalyst |
| US6395676B2 (en) * | 1994-02-22 | 2002-05-28 | The Standard Oil Company | Process for the preparation of fluid bed vinyl acetate catalyst |
| US5466652A (en) * | 1994-02-22 | 1995-11-14 | The Standard Oil Co. | Process for the preparation of vinyl acetate catalyst |
| DE19501891C1 (de) * | 1995-01-23 | 1996-09-26 | Degussa | Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat |
| US6022823A (en) * | 1995-11-07 | 2000-02-08 | Millennium Petrochemicals, Inc. | Process for the production of supported palladium-gold catalysts |
| DE19613791C2 (de) * | 1996-04-04 | 2002-01-31 | Celanese Chem Europe Gmbh | Katalysator, Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Vinylacetat |
| SA97180048B1 (ar) * | 1996-05-24 | 2005-12-21 | هوكست سيلانس كوربوريشن | محفز بلاديوم - ذهب palladium gold ثنائي المعدن متغاير الخواص heterogeneous bimetallic vinyl acetate لإنتاج أسيتات فينيل |
| US5693586A (en) * | 1996-06-28 | 1997-12-02 | Hoechst Celanese Corporation | Palladium-gold catalyst for vinyl acetate production |
| US6407283B2 (en) * | 1996-11-04 | 2002-06-18 | Bp Chemicals Limited | Process for the production of vinyl acetate |
| US5731457A (en) * | 1997-06-03 | 1998-03-24 | Hoechst Celanese Corporation | Vinyl acetate process utilizing a palladium-gold-copper catalyst |
| DE19734974A1 (de) * | 1997-08-13 | 1999-02-25 | Hoechst Ag | Verfahren zur Herstellung von porös geträgerten Metall-Nanopartikel-haltigen Katalysatoren, insbesondere für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat |
| DE19755022C2 (de) * | 1997-12-11 | 2000-03-09 | Celanese Chem Europe Gmbh | Katalysator und Verfahren zur Herstellung von Vinylacetat |
| DE19815608A1 (de) * | 1998-04-07 | 1999-10-14 | Emitec Emissionstechnologie | Katalytisch wirksame Struktur |
| GB9817363D0 (en) * | 1998-08-11 | 1998-10-07 | Bp Chem Int Ltd | Process for the production of vinyl acetate |
| US6358882B1 (en) * | 1998-12-08 | 2002-03-19 | The Standard Oil Company | Fluid bed vinyl acetate catalyst |
| US6303537B1 (en) * | 1999-11-17 | 2001-10-16 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication |
| US6534438B1 (en) * | 2000-07-26 | 2003-03-18 | Bp Chemicals Limited | Catalyst composition |
-
1999
- 1999-03-27 DE DE19914066A patent/DE19914066A1/de not_active Withdrawn
-
2000
- 2000-03-21 KR KR1020017012298A patent/KR100658383B1/ko not_active Expired - Fee Related
- 2000-03-21 CN CN00805582A patent/CN1125677C/zh not_active Expired - Fee Related
- 2000-03-21 ES ES00910867T patent/ES2368483T3/es not_active Expired - Lifetime
- 2000-03-21 US US09/937,524 patent/US6849243B1/en not_active Expired - Fee Related
- 2000-03-21 EP EP00910867A patent/EP1189694B1/de not_active Expired - Lifetime
- 2000-03-21 BR BRPI0009356-4A patent/BR0009356B1/pt not_active IP Right Cessation
- 2000-03-21 WO PCT/EP2000/002455 patent/WO2000058008A1/de not_active Ceased
- 2000-03-21 CZ CZ20013473A patent/CZ300040B6/cs not_active IP Right Cessation
- 2000-03-21 TR TR2001/02803T patent/TR200102803T2/xx unknown
- 2000-03-21 UA UA2001107324A patent/UA77384C2/uk unknown
- 2000-03-21 MX MXPA01009724A patent/MXPA01009724A/es active IP Right Grant
- 2000-03-21 AU AU32918/00A patent/AU764236B2/en not_active Ceased
- 2000-03-21 ID IDW00200102053A patent/ID30304A/id unknown
- 2000-03-21 PL PL351795A patent/PL203044B1/pl unknown
- 2000-03-21 JP JP2000607753A patent/JP4750283B2/ja not_active Expired - Fee Related
- 2000-03-21 CA CA002366465A patent/CA2366465C/en not_active Expired - Fee Related
- 2000-03-21 NZ NZ514433A patent/NZ514433A/xx not_active IP Right Cessation
- 2000-03-21 AT AT00910867T patent/ATE513617T1/de active
- 2000-03-21 RU RU2001129158/04A patent/RU2261142C2/ru not_active IP Right Cessation
- 2000-03-23 AR ARP000101309A patent/AR023146A1/es unknown
- 2000-03-24 TW TW089105402A patent/TW548134B/zh not_active IP Right Cessation
- 2000-03-27 MY MYPI20001223A patent/MY122744A/en unknown
-
2001
- 2001-08-27 ZA ZA200107080A patent/ZA200107080B/xx unknown
- 2001-09-26 NO NO20014678A patent/NO20014678D0/no unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0839793A1 (en) * | 1996-11-04 | 1998-05-06 | BP Chemicals Limited | Process for the production of vinyl acetate |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4750283B2 (ja) | 2011-08-17 |
| JP2002539934A (ja) | 2002-11-26 |
| KR20010105396A (ko) | 2001-11-28 |
| BR0009356A (pt) | 2002-02-19 |
| ZA200107080B (en) | 2003-02-26 |
| NO20014678L (no) | 2001-09-26 |
| ID30304A (id) | 2001-11-22 |
| PL351795A1 (en) | 2003-06-16 |
| MY122744A (en) | 2006-05-31 |
| ES2368483T3 (es) | 2011-11-17 |
| PL203044B1 (pl) | 2009-08-31 |
| MXPA01009724A (es) | 2002-03-14 |
| AR023146A1 (es) | 2002-09-04 |
| CA2366465A1 (en) | 2000-10-05 |
| CA2366465C (en) | 2009-09-29 |
| BR0009356B1 (pt) | 2010-12-28 |
| CZ300040B6 (cs) | 2009-01-14 |
| EP1189694B1 (de) | 2011-06-22 |
| EP1189694A1 (de) | 2002-03-27 |
| TW548134B (en) | 2003-08-21 |
| CN1345256A (zh) | 2002-04-17 |
| ATE513617T1 (de) | 2011-07-15 |
| WO2000058008A1 (de) | 2000-10-05 |
| CN1125677C (zh) | 2003-10-29 |
| UA77384C2 (en) | 2006-12-15 |
| DE19914066A1 (de) | 2000-10-05 |
| NO20014678D0 (no) | 2001-09-26 |
| CZ20013473A3 (cs) | 2002-02-13 |
| NZ514433A (en) | 2004-01-30 |
| US6849243B1 (en) | 2005-02-01 |
| TR200102803T2 (tr) | 2002-04-22 |
| AU764236B2 (en) | 2003-08-14 |
| AU3291800A (en) | 2000-10-16 |
| RU2261142C2 (ru) | 2005-09-27 |
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