JPS5673041A - Preparation of acrylic acid - Google Patents

Preparation of acrylic acid

Info

Publication number
JPS5673041A
JPS5673041A JP14987179A JP14987179A JPS5673041A JP S5673041 A JPS5673041 A JP S5673041A JP 14987179 A JP14987179 A JP 14987179A JP 14987179 A JP14987179 A JP 14987179A JP S5673041 A JPS5673041 A JP S5673041A
Authority
JP
Japan
Prior art keywords
propylene
steam
molecular oxygen
acrylic acid
molar ratio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP14987179A
Other languages
English (en)
Other versions
JPS6217579B2 (ja
Inventor
Yukishige Kadowaki
Kohei Sarumaru
Takeshi Shibano
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Petrochemical Co Ltd
Original Assignee
Mitsubishi Petrochemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Petrochemical Co Ltd filed Critical Mitsubishi Petrochemical Co Ltd
Priority to JP14987179A priority Critical patent/JPS5673041A/ja
Priority to YU2814/80A priority patent/YU42990B/xx
Priority to DE19803042468 priority patent/DE3042468A1/de
Priority to CS807791A priority patent/CS223888B2/cs
Priority to GB8036853A priority patent/GB2063861B/en
Priority to FR8024536A priority patent/FR2470107B1/fr
Publication of JPS5673041A publication Critical patent/JPS5673041A/ja
Priority to US06/426,273 priority patent/US4873368A/en
Publication of JPS6217579B2 publication Critical patent/JPS6217579B2/ja
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/023—Details
    • B01J2208/024—Particulate material
    • B01J2208/025—Two or more types of catalyst
JP14987179A 1979-11-19 1979-11-19 Preparation of acrylic acid Granted JPS5673041A (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP14987179A JPS5673041A (en) 1979-11-19 1979-11-19 Preparation of acrylic acid
YU2814/80A YU42990B (en) 1979-11-19 1980-11-04 Improved process for producing acrylic acid
DE19803042468 DE3042468A1 (de) 1979-11-19 1980-11-11 Verfahren zur herstellung von acrylsaeure
CS807791A CS223888B2 (en) 1979-11-19 1980-11-17 Method of making the acryl acid
GB8036853A GB2063861B (en) 1979-11-19 1980-11-17 Process for producing acrylic acid
FR8024536A FR2470107B1 (fr) 1979-11-19 1980-11-19 Procede de preparation d'acide acrylique
US06/426,273 US4873368A (en) 1979-11-19 1982-09-29 Process for producing acrylic acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14987179A JPS5673041A (en) 1979-11-19 1979-11-19 Preparation of acrylic acid

Publications (2)

Publication Number Publication Date
JPS5673041A true JPS5673041A (en) 1981-06-17
JPS6217579B2 JPS6217579B2 (ja) 1987-04-18

Family

ID=15484466

Family Applications (1)

Application Number Title Priority Date Filing Date
JP14987179A Granted JPS5673041A (en) 1979-11-19 1979-11-19 Preparation of acrylic acid

Country Status (7)

Country Link
US (1) US4873368A (ja)
JP (1) JPS5673041A (ja)
CS (1) CS223888B2 (ja)
DE (1) DE3042468A1 (ja)
FR (1) FR2470107B1 (ja)
GB (1) GB2063861B (ja)
YU (1) YU42990B (ja)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59163340A (ja) * 1983-02-22 1984-09-14 ザ・ハルコン・エス・デイ−・グル−プ・インコ−ポレ−テツト プロパンからアクリル酸を製造する方法
JPS63146841A (ja) * 1986-12-11 1988-06-18 Mitsubishi Petrochem Co Ltd アクリル酸の製造法
JP2001064227A (ja) * 1999-07-23 2001-03-13 Rohm & Haas Co 改良された能力を有する、プロピレンからアクリル酸を製造し、精製する方法
JP2001253846A (ja) * 2000-03-10 2001-09-18 Mitsubishi Rayon Co Ltd メタクリル酸の製造方法
JP2008024644A (ja) * 2006-07-20 2008-02-07 Nippon Shokubai Co Ltd 固定床反応装置およびその使用方法
JP2008532943A (ja) * 2005-03-01 2008-08-21 ビーエーエスエフ ソシエタス・ヨーロピア 不均一系触媒作用気相−部分酸化によって少なくとも１種の有機目標化合物を製造する方法
JP2008222598A (ja) * 2007-03-09 2008-09-25 Nippon Shokubai Co Ltd 固定床反応装置およびその使用方法
JP2015535826A (ja) * 2012-09-24 2015-12-17 アーケマ・インコーポレイテッド 改良された耐ファウリング性を有するシェルアンドチューブ酸化反応器
WO2016017722A1 (ja) * 2014-08-01 2016-02-04 株式会社日本触媒 不活性物質の回収方法及び当該方法により回収された不活性物質を用いたアクリル酸の製造方法

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59190983A (ja) * 1983-04-12 1984-10-29 Mitsubishi Petrochem Co Ltd エチレンオキシド製造用反応器に使用する充填材
JPH0813778B2 (ja) * 1988-07-11 1996-02-14 住友化学工業株式会社 メタクリル酸の製造方法
ES2092557T3 (es) * 1989-12-06 1996-12-01 Nippon Catalytic Chem Ind Procedimiento para producir metalocreina y acido metacrilico.
JPH0784400B2 (ja) * 1990-04-03 1995-09-13 株式会社日本触媒 不飽和アルデヒドおよび不飽和酸の製造方法
US5081314A (en) * 1990-12-07 1992-01-14 Kissel Charles L Process for producing acrolein
DE4132684A1 (de) * 1991-10-01 1993-04-08 Basf Ag Verfahren zur katalytischen gasphasenoxidation von methacrolein zu methacrylsaeure
DE4431949A1 (de) * 1994-09-08 1995-03-16 Basf Ag Verfahren zur katalytischen Gasphasenoxidation von Acrolein zu Acrylsäure
DE4431957A1 (de) * 1994-09-08 1995-03-16 Basf Ag Verfahren zur katalytischen Gasphasenoxidation von Propen zu Acrolein
JP3775872B2 (ja) * 1996-12-03 2006-05-17 日本化薬株式会社 アクロレイン及びアクリル酸の製造方法
JP3948798B2 (ja) * 1997-10-27 2007-07-25 株式会社日本触媒 アクリル酸の製造方法
DE19833644C2 (de) * 1998-07-25 2002-06-13 Xcellsis Gmbh Reaktoreinheit in einem System zur Erzeugung eines wasserstoffreichen Gases aus einem flüssigen Rohkraftstoff
JP3948837B2 (ja) * 1998-08-10 2007-07-25 株式会社日本触媒 アクリル酸の製造方法
US6384274B1 (en) * 1998-09-27 2002-05-07 Rohm And Haas Company Single reactor process for preparing acrylic acid from propylene having improved capacity
DE19926608B4 (de) * 1999-06-11 2004-10-14 Ballard Power Systems Ag Chemischer Reaktor für ein Brennstoffzellensystem
DE60000708T2 (de) 1999-06-28 2003-07-24 Rohm & Haas Verfahren zur Herstellung von (Meth)acrylsäure
US6620968B1 (en) 1999-11-23 2003-09-16 Rohm And Haas Company High hydrocarbon space velocity process for preparing unsaturated aldehydes and acids
KR20010104053A (ko) * 2000-05-12 2001-11-24 성재갑 프로필렌의 기상 산화 반응에 의한 아크롤레인의 제조 방법
JP4426069B2 (ja) * 2000-06-12 2010-03-03 株式会社日本触媒 アクリル酸の製造方法
DE10127374A1 (de) * 2001-06-06 2002-12-12 Basf Ag Reaktor zum Testen von Katalysatorsystemen
ATE391116T1 (de) 2001-12-14 2008-04-15 Stockhausen Chem Fab Gmbh Verfahren zur herstellung von acrylsäure
JP4325146B2 (ja) * 2002-03-11 2009-09-02 三菱化学株式会社 （メタ）アクリル酸類の製造方法
US7115776B2 (en) 2002-07-18 2006-10-03 Basf Aktiengesellschaft Heterogeneously catalyzed gas-phase partial oxidation of at least one organic compound
JP3908118B2 (ja) 2002-08-08 2007-04-25 株式会社日本触媒 アクリル酸の製造方法
JP4465144B2 (ja) * 2002-08-08 2010-05-19 株式会社日本触媒 アクリル酸の製造方法
BRPI0408629B1 (pt) 2003-03-25 2013-06-25 processo para a oxidaÇço parcial de propeno a Ácido acrÍlico em fase gasosa
DE10313213A1 (de) * 2003-03-25 2004-10-07 Basf Ag Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrylsäure
JP3999160B2 (ja) * 2003-05-14 2007-10-31 株式会社日本触媒 易重合性物質の製造方法
JP2007521242A (ja) * 2003-09-24 2007-08-02 ダウ グローバル テクノロジーズ インコーポレイティド エチレン性不飽和モノマーの重合を抑制する金属表面
US7161044B2 (en) * 2003-10-22 2007-01-09 Nippon Shokubai Co., Ltd. Catalytic gas phase oxidation reaction
DE102004005863A1 (de) * 2004-02-05 2005-09-08 Stockhausen Gmbh Reaktor mit einem einen Einsatz aufweisenden Wärmetauscherbereich
DE102004008573A1 (de) * 2004-02-19 2005-09-08 Stockhausen Gmbh Ein Verfahren zur Entfernung kohlenstoffhaltiger Rückstände in einem Reaktor
JP4572573B2 (ja) * 2004-05-13 2010-11-04 三菱化学株式会社 （メタ）アクロレイン又は（メタ）アクリル酸の製造方法
DE102005030414A1 (de) * 2005-06-30 2007-01-18 Stockhausen Gmbh Reaktor und Verfahren zur katalytischen Gasphasenreaktion sowie Verfahren zur Applikation eines Katalysators in einem Reaktor
US7884235B2 (en) * 2006-07-20 2011-02-08 Nippon Shokubai Co., Ltd. Method for gas-phase catalytic oxidation using a fixed bed reactor
EP2177500A1 (en) * 2007-07-27 2010-04-21 Nippon Shokubai Co., Ltd. Process for producing acrylic acid by two-stage catalytic vapor-phase oxidation
DE102011011895A1 (de) 2011-02-21 2012-08-23 Lurgi Gmbh Rohrreaktor
CA2781246A1 (en) 2011-07-14 2013-01-14 Rohm And Haas Company Method for removal of organic compounds from waste water streams in a process for production of (meth)acrylic acid
DE102013217386A1 (de) 2013-09-02 2015-03-05 Evonik Industries Ag Verfahren zur Herstellung von Acrylsäure
KR20170081198A (ko) 2014-11-03 2017-07-11 알케마 인코포레이티드 중합체 플레이크 및 분말의 밀도 증가 방법
EP3892367A1 (en) 2020-04-09 2021-10-13 Röhm GmbH A tube bundle reactor and method for the production of methacrylic acid through the partial oxidation of methacrolein

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3147084A (en) * 1962-03-08 1964-09-01 Shell Oil Co Tubular catalytic reactor with cooler
GB1112638A (en) * 1965-12-13 1968-05-08 Grace W R & Co Process for the production of ª‡,ª‰- unsaturated monocarboxylic acids
JPS5025521A (ja) * 1973-07-07 1975-03-18
JPS5136415A (en) * 1974-07-31 1976-03-27 Basf Ag Akurirusannoseiho

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB939713A (en) * 1960-07-18 1963-10-16 Shell Int Research A process for preparing unsaturated monocarboxylic acids from olefins
NL293571A (ja) * 1962-06-04
DE1568925C3 (de) * 1966-08-09 1975-10-09 Hoechst Ag, 6000 Frankfurt Verfahren zur Abtrennung von Acrylsäure aus den Reaktionsgasen der Propylen- oder Acrolein-Oxydation
DE2056614C3 (de) * 1970-11-18 1981-04-16 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Acrylsäure aus Propylen
DE2238851B2 (de) * 1972-08-07 1979-08-30 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung von Acrolein und/oder Acrylsäure unter Vermeidung von Nachreaktionen bei der katalytischen Oxidation von Propylen und/oder Acrolein
IT971370B (it) * 1972-11-30 1974-04-30 Sir Soc Italiana Resine Spa Procedimento perfezionato per la produzione di acroleina ed acido acrilico
DE2513405C2 (de) * 1975-03-26 1982-10-21 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Acrylsäure durch Oxidation von Propylen mit Sauerstoff enthaltenden Gasen in zwei getrennten Katalysatorstufen, die in einem Röhrenreaktor hintereinander angeordnet sind
JPS52108917A (en) * 1976-03-11 1977-09-12 Nippon Shokubai Kagaku Kogyo Co Ltd Preparation of acrylic acid by vapor-phase catalytic oxidation of prop ylene
JPS6032615B2 (ja) * 1976-07-29 1985-07-29 株式会社日本触媒 プロピレンの接触気相酸化によるアクリル酸の製造方法
JPS5330688A (en) * 1976-09-03 1978-03-23 Agency Of Ind Science & Technol Polymers having metal collecting ability

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3147084A (en) * 1962-03-08 1964-09-01 Shell Oil Co Tubular catalytic reactor with cooler
GB1112638A (en) * 1965-12-13 1968-05-08 Grace W R & Co Process for the production of ª‡,ª‰- unsaturated monocarboxylic acids
JPS5025521A (ja) * 1973-07-07 1975-03-18
JPS5136415A (en) * 1974-07-31 1976-03-27 Basf Ag Akurirusannoseiho

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59163340A (ja) * 1983-02-22 1984-09-14 ザ・ハルコン・エス・デイ−・グル−プ・インコ−ポレ−テツト プロパンからアクリル酸を製造する方法
JPS63146841A (ja) * 1986-12-11 1988-06-18 Mitsubishi Petrochem Co Ltd アクリル酸の製造法
JP2001064227A (ja) * 1999-07-23 2001-03-13 Rohm & Haas Co 改良された能力を有する、プロピレンからアクリル酸を製造し、精製する方法
JP2001253846A (ja) * 2000-03-10 2001-09-18 Mitsubishi Rayon Co Ltd メタクリル酸の製造方法
JP2008532943A (ja) * 2005-03-01 2008-08-21 ビーエーエスエフ ソシエタス・ヨーロピア 不均一系触媒作用気相−部分酸化によって少なくとも１種の有機目標化合物を製造する方法
JP2008024644A (ja) * 2006-07-20 2008-02-07 Nippon Shokubai Co Ltd 固定床反応装置およびその使用方法
JP2008222598A (ja) * 2007-03-09 2008-09-25 Nippon Shokubai Co Ltd 固定床反応装置およびその使用方法
JP2015535826A (ja) * 2012-09-24 2015-12-17 アーケマ・インコーポレイテッド 改良された耐ファウリング性を有するシェルアンドチューブ酸化反応器
JP2018111696A (ja) * 2012-09-24 2018-07-19 アーケマ・インコーポレイテッド 改良された耐ファウリング性を有するシェルアンドチューブ酸化反応器
WO2016017722A1 (ja) * 2014-08-01 2016-02-04 株式会社日本触媒 不活性物質の回収方法及び当該方法により回収された不活性物質を用いたアクリル酸の製造方法
JPWO2016017722A1 (ja) * 2014-08-01 2017-04-27 株式会社日本触媒 不活性物質の回収方法及び当該方法により回収された不活性物質を用いたアクリル酸の製造方法
US10035747B2 (en) 2014-08-01 2018-07-31 Nippon Shokubai Co., Ltd. Method for recovering inert material and method for producing acrylic acid using inert material recovered by said method

Also Published As

Publication number Publication date
DE3042468A1 (de) 1981-06-11
US4873368A (en) 1989-10-10
GB2063861A (en) 1981-06-10
YU281480A (en) 1983-10-31
GB2063861B (en) 1983-10-05
DE3042468C2 (ja) 1990-06-07
FR2470107A1 (fr) 1981-05-29
YU42990B (en) 1989-02-28
JPS6217579B2 (ja) 1987-04-18
CS223888B2 (en) 1983-11-25
FR2470107B1 (fr) 1985-07-19

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