JP6094797B2 - リチウム二次電池用正極活物質、その製造方法、リチウム二次電池用電極、リチウム二次電池 - Google Patents

リチウム二次電池用正極活物質、その製造方法、リチウム二次電池用電極、リチウム二次電池 Download PDF

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JP6094797B2
JP6094797B2 JP2012282964A JP2012282964A JP6094797B2 JP 6094797 B2 JP6094797 B2 JP 6094797B2 JP 2012282964 A JP2012282964 A JP 2012282964A JP 2012282964 A JP2012282964 A JP 2012282964A JP 6094797 B2 JP6094797 B2 JP 6094797B2
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secondary battery
positive electrode
lithium
active material
lithium secondary
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JP2014044928A (ja
JP2014044928A5 (enExample
Inventor
遠藤 大輔
大輔 遠藤
元信 村上
元信 村上
弘将 村松
弘将 村松
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GS Yuasa International Ltd
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GS Yuasa International Ltd
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Priority to JP2012282964A priority Critical patent/JP6094797B2/ja
Priority to US13/792,372 priority patent/US20140038053A1/en
Priority to EP13158728.9A priority patent/EP2692693B1/en
Priority to KR1020130030217A priority patent/KR101998644B1/ko
Priority to CN201310147636.4A priority patent/CN103579606B/zh
Publication of JP2014044928A publication Critical patent/JP2014044928A/ja
Publication of JP2014044928A5 publication Critical patent/JP2014044928A5/ja
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00Compounds of manganese
    • C01G45/12Complex oxides containing manganese and at least one other metal element
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • C01G53/42Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • C01G53/42Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0471Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/11Powder tap density
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/12Surface area
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/14Pore volume
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/16Pore diameter
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
JP2012282964A 2012-08-03 2012-12-26 リチウム二次電池用正極活物質、その製造方法、リチウム二次電池用電極、リチウム二次電池 Active JP6094797B2 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2012282964A JP6094797B2 (ja) 2012-08-03 2012-12-26 リチウム二次電池用正極活物質、その製造方法、リチウム二次電池用電極、リチウム二次電池
US13/792,372 US20140038053A1 (en) 2012-08-03 2013-03-11 Positive active material for lithium secondary battery, manufacturing method thereof, lithium secondary battery electrode, and lithium secondary battery
EP13158728.9A EP2692693B1 (en) 2012-08-03 2013-03-12 Positive active material for lithium secondary battery, manufacturing method thereof, lithium secondary battery electrode, and lithium secondary battery
KR1020130030217A KR101998644B1 (ko) 2012-08-03 2013-03-21 리튬 2차 전지용 양극 활물질, 그 제조 방법, 리튬 2차 전지용 전극, 및 리튬 2차 전지
CN201310147636.4A CN103579606B (zh) 2012-08-03 2013-04-25 锂二次电池用正极活性物质、其制造方法、锂二次电池用电极及锂二次电池

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2012172535 2012-08-03
JP2012172535 2012-08-03
JP2012282964A JP6094797B2 (ja) 2012-08-03 2012-12-26 リチウム二次電池用正極活物質、その製造方法、リチウム二次電池用電極、リチウム二次電池

Publications (3)

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JP2014044928A JP2014044928A (ja) 2014-03-13
JP2014044928A5 JP2014044928A5 (enExample) 2014-08-14
JP6094797B2 true JP6094797B2 (ja) 2017-03-15

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US (1) US20140038053A1 (enExample)
EP (1) EP2692693B1 (enExample)
JP (1) JP6094797B2 (enExample)
KR (1) KR101998644B1 (enExample)
CN (1) CN103579606B (enExample)

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WO2021153936A1 (ko) * 2020-01-29 2021-08-05 주식회사 엘지에너지솔루션 이차전지용 양극 활물질 및 이를 포함하는 리튬 이차전지

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CN103765639B (zh) * 2011-12-09 2016-03-02 株式会社杰士汤浅国际 非水电解质二次电池用活性物质、非水电解质二次电池用活性物质的制造方法、非水电解质二次电池用电极、及非水电解质二次电池
JP6090661B2 (ja) 2012-06-20 2017-03-08 株式会社Gsユアサ リチウム二次電池用正極活物質、その正極活物質の前駆体、リチウム二次電池用電極、リチウム二次電池
JP6090662B2 (ja) * 2012-06-29 2017-03-08 株式会社Gsユアサ リチウム二次電池用正極活物質、その製造方法、リチウム二次電池用電極、リチウム二次電池
JP6131760B2 (ja) * 2012-08-03 2017-05-24 株式会社Gsユアサ リチウム二次電池用正極活物質、その製造方法、リチウム二次電池用電極、リチウム二次電池
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WO2015083330A1 (ja) 2013-12-02 2015-06-11 株式会社Gsユアサ リチウム二次電池用正極活物質、リチウム二次電池用電極及びリチウム二次電池
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US10693183B2 (en) * 2015-04-09 2020-06-23 Battelle Memorial Institute Ether-based electrolyte for Na-ion battery anode
JP6583662B2 (ja) * 2015-05-21 2019-10-02 株式会社Gsユアサ 非水電解質二次電池用正極活物質及び非水電解質二次電池
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JP6692632B2 (ja) * 2015-11-30 2020-05-13 住友化学株式会社 正極活物質の製造方法
JP6737586B2 (ja) * 2015-11-30 2020-08-12 トヨタ自動車株式会社 正極活物質とそれを用いたリチウムイオン二次電池
EP3392936B1 (en) 2015-12-15 2021-09-29 GS Yuasa International Ltd. Positive electrode active material for lithium secondary batteries, method for manufacturing positive electrode active material, positive electrode for lithium secondary batteries, and lithium secondary battery
US10693136B2 (en) * 2016-07-11 2020-06-23 Ecopro Bm Co., Ltd. Lithium complex oxide for lithium secondary battery positive active material and method of preparing the same
KR102165664B1 (ko) * 2016-07-13 2020-10-14 가부시키가이샤 지에스 유아사 리튬 2차전지용 양극 활물질, 그 제조 방법 및 리튬 2차전지
EP3486219A4 (en) 2016-07-14 2020-01-22 GS Yuasa International Ltd. LITHIUM TRANSITION METAL COMPOSITE OXIDE, TRANSITION METAL HYDROXIDE PRECURSOR, PROCESS FOR PRODUCING TRANSITION METAL HYDROXIDE PRECURSOR, PROCESS FOR MANUFACTURE OF TRANSITION METAL COMPOSITE METAL OXIDE, TRANSITION METAL ACTIVE AGENT NON-AQUEOUS ELECTROLYTE POSITIVE ELECTRODE FOR NONAQUEOUS ELECTROLYTE SECONDARY CELL, NONAQUEOUS ELECTROLYTE SECONDARY ELECTRODE, NONAQUEOUS ELECTROLYTE SECONDARY CELL AND ENERGY STORAGE DEVICE
US10903490B2 (en) 2016-08-02 2021-01-26 Ecopro Bm Co., Ltd. Lithium complex oxide for lithium secondary battery positive active material and method of preparing the same
EP3497738A4 (en) * 2016-08-12 2020-05-06 Viking Power Systems Pte. Ltd. ELECTROLYTE CONTAINING ADDITIVE FOR HIGH-ENERGY RECHARGEABLE METAL ANODE BATTERIES
US11005090B2 (en) * 2016-12-08 2021-05-11 Panasonic Intellectual Property Management Co., Ltd. Negative electrode for non-aqueous electrolyte secondary batteries, and non-aqueous electrolyte secondary battery
US11545662B2 (en) 2017-12-15 2023-01-03 Gs Yuasa International Ltd. Positive active material for nonaqueous electrolyte secondary battery, method of producing positive active material for nonaqueous electrolyte secondary battery, positive electrode for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery
BE1025799B1 (nl) * 2017-12-18 2019-07-19 Soleras Advanced Coatings Bvba Gespoten lithiumcobaltoxide-targets
EP3757065A4 (en) * 2018-02-22 2021-11-17 Sumitomo Metal Mining Co., Ltd. METAL COMPOSITE HYDROXIDE PARTICLES AND METHOD FOR MANUFACTURING THEREOF, POSITIVE ELECTRODE ACTIVE SUBSTANCE FOR SECONDARY BATTERIES WITH ANHYDROUS ELECTROLYTE, METHOD FOR MANUFACTURING THEREOF AND SECONDARY ELECTROLYTE WITH WATER
JP6523508B1 (ja) 2018-03-30 2019-06-05 住友化学株式会社 リチウム複合金属化合物、リチウム二次電池用正極活物質、リチウム二次電池用正極、リチウム二次電池、及びリチウム複合金属化合物の製造方法
KR102123274B1 (ko) * 2018-04-25 2020-06-17 주식회사 에코프로비엠 리튬 복합 산화물
JP7147478B2 (ja) 2018-06-21 2022-10-05 株式会社Gsユアサ 非水電解質二次電池、及び非水電解質二次電池の製造方法
CN111525120B (zh) * 2019-02-02 2021-11-16 中国科学院物理研究所 一种含有Mg、Cu、Mn的氧化物材料及其制备方法和应用
KR20210107851A (ko) 2019-03-15 2021-09-01 가부시키가이샤 지에스 유아사 비수전해질 이차전지용 양극 활물질, 비수전해질 이차전지용 양극, 및 비수전해질 이차전지
JP6630864B1 (ja) * 2019-04-12 2020-01-15 住友化学株式会社 リチウム金属複合酸化物粉末、リチウム二次電池用正極活物質、及びリチウム金属複合酸化物粉末の製造方法
KR102844879B1 (ko) 2020-01-30 2025-08-11 주식회사 엘지에너지솔루션 리튬 이차전지용 양극 활물질의 제조 방법 및 상기 방법에 의해 제조된 리튬 이차전지용 양극 활물질
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WO2021153936A1 (ko) * 2020-01-29 2021-08-05 주식회사 엘지에너지솔루션 이차전지용 양극 활물질 및 이를 포함하는 리튬 이차전지
CN115004414A (zh) * 2020-01-29 2022-09-02 株式会社Lg新能源 二次电池用正极活性材料及包含其的锂二次电池

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CN103579606B (zh) 2017-05-03
KR20140018092A (ko) 2014-02-12
EP2692693A1 (en) 2014-02-05
US20140038053A1 (en) 2014-02-06
CN103579606A (zh) 2014-02-12
JP2014044928A (ja) 2014-03-13
EP2692693B1 (en) 2018-07-04
KR101998644B1 (ko) 2019-07-10

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