JP5801528B2 - 抗菌接着フィルム - Google Patents
抗菌接着フィルム Download PDFInfo
- Publication number
- JP5801528B2 JP5801528B2 JP2008545821A JP2008545821A JP5801528B2 JP 5801528 B2 JP5801528 B2 JP 5801528B2 JP 2008545821 A JP2008545821 A JP 2008545821A JP 2008545821 A JP2008545821 A JP 2008545821A JP 5801528 B2 JP5801528 B2 JP 5801528B2
- Authority
- JP
- Japan
- Prior art keywords
- examples
- antibacterial agent
- layer
- multilayer film
- antibacterial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- LRULOSWUOKGECR-UHFFFAOYSA-N CC(C(OCC[N](C)(C)C)=[U])=C Chemical compound CC(C(OCC[N](C)(C)C)=[U])=C LRULOSWUOKGECR-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/06—Interconnection of layers permitting easy separation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/10—Inorganic particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/10—Inorganic particles
- B32B2264/105—Metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
- B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/75—Printability
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2405/00—Adhesive articles, e.g. adhesive tapes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2479/00—Furniture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2357/00—Characterised by the use of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Manufacturing & Machinery (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Toxicology (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Laminated Bodies (AREA)
- Adhesive Tapes (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Mycology (AREA)
Description
本明細書に全体的に参照して公開される、2005年12月14日出願の、米国特許仮出願番号第60/743036号の先行権を主張する。
本発明は抗菌剤フィルムに関する。詳細には、本発明は、望ましくない微生物による汚染の危険を減ずるため、表面上で用いる抗菌接着フィルムに関する。
メタクリル酸ジメチルヘキサデシルアンモニウムエチルブロミド(DMAEMA−C16Br)は、四級アミンの官能性を持たせたエチレン性不飽和モノマーであり、以下の手順に従って合成した。500ミリリットルの丸底フラスコに、42.2部のジメチルアミノエチルメタクリレート塩、154.7部のアセトン、93.2部の1−ブロムヘキサデカン、及び0.34部のBHT酸化防止剤を充填した。当該混合物を約16時間、35℃で撹拌した後、室温まで冷却した。派生した白色固形物沈殿を、濾過によって分離して、冷えた酢酸エチルで洗浄した後、真空下で40℃で乾燥させた。当該固体生成物をNMR分析した結果、構造が純粋なDMAEMA−C16Brであって、以下の化学式構造を有することが明らかになった。
以下の実施例6及び28で用いる酸化銀溶液の調製を、5部のアンモニウム・カーボネート塩を95部の水と組み合わせること及び塩が溶解するまで混合することによって、行なった。この溶液に1部の酸化銀を添加した。当該混合物の撹拌を、酸化銀が溶解するまで、60℃で1時間行なった。
以下の実施例及び比較例では、どのフィルムに対しても、接着層は、コア層の対向するサイド上には積層しなかった。後述する以下の試験において、抗菌活性及び磨耗耐性を測定したが、両方とも、主として当該抗菌剤ハードコート層を含む。従来の接着剤から形成される接着層を用いた場合、抗菌活性又は磨耗耐性には影響しないこと、及びこのような接着層を含む後述の実施例及び比較例の多層フィルムの場合でも、同様の結果を生じることが考えられる。
実施例1〜11並びに比較例A及びBの多層フィルムは、それぞれ以下の手順に従って調製した。ハードコート混合物が、最初、100部の3M906ハードコートを12部のトルエン及び12部のメチルエチルケトンと組み合わせて、調製された。当該ハードコート混合物は、良くブレンドされるまで静かに振った。次に当該抗菌剤をハードコート混合物に添加した後、当該混合物全体を手で振った。表1に、実施例1〜11並びに比較例A及びBに対する、ハードコート混合物中で用いられる抗菌剤のタイプ及び濃度を列挙する。
実施例12の多層フィルムを、以下の手順に従って調製した。分散物を、95重量部の3MSG組成物を5部のAgイオンと組み合わせることによって調製して、ハードコート混合物を得た。ハードコート混合物を、振って均一の分散物を作った後、PETフィルム上にメイヤー・ロッド#6を用いてコーティングした。次にハードコート混合物は、フュージョン・システムズUVプロセッサ(前述した)を用いて、ベルト速度は14メートル/分(45フィート/分)において、2回通して、硬化させたが、その結果、全体の放射線投与量として250ミリジュール/センチメートル2が得られた。この結果、抗菌剤ハードコート層がPETコア層上に積層された2層フィルムが得られたが、そこでは、当該抗菌層は、3MSG組成物のAgイオン抗菌剤及び架橋母材が含まれていた。
実施例13の多層フィルムは、2つの抗菌剤が含まれており、このフィルムを以下の手順に従って調製した。ハードコート混合物を、5部の銀ガラス、10部のDMAEMA−C16Br、及び85部の3M906ハードコートを組み合わせることによって調製した。ハードコート混合物を次に、PETフィルム上にコーティングして硬化させることを、実施例1〜11に対して前述した手順に従って行なった。
実施例14〜16並びに比較例C及びDの多層フィルムをそれぞれ、以下の手順に従って調製した。ハードコート混合物は、ハードコート混合物を形成するために(イソプロパノール中で40固体重量%)、DMAEMA−C16Br、イルガキュア819、及び3M906ハードコートをイソプロパノール中で組み合わせて、調製した。ハードコート混合物は、振って、固形物を溶解させ、十分に混合した。表3に、実施例14〜16並びに比較例C及びDのフィルムに対するハードコート混合物の成分濃度を示す。
実施例17〜21及び比較例E〜Jの多層フィルムは、それぞれ以下の手順に従って調製した。比較例Eのフィルムに対しては、ハードコート混合は、イルガキュア819及び3M906ハードコートをイソプロパノール中で組み合わせて調製した。比較例Eに対しては、派生したハードコート混合物は、相対重量濃度として、1%のイルガキュア819及び99%の3M906ハードコートを有していた。実施例17〜19並びに比較例F及びGのフィルムのそれぞれに対して、ハードコート混合物は、DMAEMA誘導体抗菌剤、イルガキュア819、及び3M906ハードコートをイソプロパノール中で組み合わせて調製された。ハードコート混合物は、振って、固形物を溶解し十分に混合した。派生したハードコート混合物は、相対重量濃度5%のDMAEMA塩、1%のイルガキュア819、及び94%の3M906ハードコート、を有した。
実施例22の多層フィルムは、以下の手順に従って調製した。ハードコート混合物が、5.0グラムのDMAEMA−C16Br、及び197.9グラムの3M906ハードコート溶液(イソプロパノール中で47.5%の固形物、固形物の1%はイルガキュア819であった)、並びに47.1グラムのイソプロパノールを組み合わて、調製された。当該ハードコート混合物は、振って、当該固形物を溶解し十分に混合した。派生したハードコート混合物は、DMAEMA−C16Br対3M906ハードコートの比率5:95を有した。
実施例23〜25の多層フィルムをそれぞれ、以下の手順に従って調製した。各フィルムに対して、当該抗菌剤は、トルエン/メチルエチルケトン溶媒の50/50ブレンドに添加され、又超音波処理されて均一の分散物を得た。3M906ハードコートは次に、分散物とともに混合して、ハードコート混合物を形成した。表12に、実施例23〜25のフィルムに対するハードコート混合物の成分リスティングを示す。
実施例32〜35の多層フィルムは、それぞれ以下の手順に従って調製した。各フィルムに対して、当該抗菌剤は、3MUV製剤とブレンドした。ブレンドされた組成物は、超音波処理して、均一の分散物を得た。表15は、実施例32〜35のフィルムに対するブレンドされた組成物の成分リスティングを示す。
アクリル酸ジメチルヘキサデシルアンモニウムエチルブロミド(DMAEA−C16Br)の合成物は、以下の手順に従って調製した。三つ口丸底反応フラスコには、機械的撹拌機、温度プローブ、及び凝縮器を取り付けた。当該反応フラスコは、234部のアクリル酸ジメチルアミノエチル、617部のアセトン、500部の1−ブロムヘキサデカン、及び0.5部のBHT酸化防止剤を充填した。当該混合物は、24時間、35℃で攪拌した。当該反応混合物は、次に室温まで冷却して、わずかに黄色の透明な溶液が得られた。当該溶液は、丸底フラスコへ移し、又アセトンは、真空下40℃で回転蒸発させ、取り除いた。派生する固形物は、冷えた酢酸エチルを用いて洗浄後、真空下40℃で乾燥させた。当該固体生成物のNMR分析は、構造が純粋なDMAEA−C16Brであることを明らかにした。当該DMAEA−C16Brは、本発明の多層フィルム中で用いたときに、DMAEA−C16Brと同様の抗菌活性をもたらす考えられた。DMAEA−C16Brによりもたらされる、そのメタクリレート系バージョン(DMAEMA−C16Br)に対する優位性は、放射線硬化が速いことである。これは、エチレン性不飽和ボンド(すなわち、モノマーの反応性部位)の付近にメチル基が無いことに起因する。
20.0%ラウリシディン、10.0%サリチル酸、及びイソプロパノール中で10.0%DOSS界面活性剤の流体溶液は、当該ラウリシディンが溶解するまで当該混合物を攪拌して調製された。当該流体溶液20%が、実施例1〜11に記載のハードコート混合物(すなわち、100部の3M906ハードコートと12部のトルエン及び12部のメチルエチルケトンとの混合物)80%、と組み合わされた。当該の組み合わせた溶液は、コーティングされて、実施例1〜11に記載したように、硬化された。派生した多層フィルムは、澄んで透明であった。派生した多層フィルムは次に、実施例1〜11で前述したように、微生物負荷低減について試験し、それにより、グラム陽性病原体に対して100%の微生物負荷低減が、又グラム陰性病原体に対して99.4%の微生物負荷低減もたらした。
Claims (3)
- 表面上の微生物汚染を低減するための多層フィルムであって、
第1の表面、及び前記第1の表面の反対側の第2の表面を有する熱可塑性コア層、
前記コア層の前記第1の表面に隣接して配置される接着層、及び
前記第2の表面に隣接して配置される抗菌ハードコート層であって、架橋母材に重合によって化学的に結合された抗菌剤、及び無機酸化物粒子を含む前記抗菌ハードコート層、
を含み、前記架橋母材が、重合性モノマー、分子量が1000以下の重合性ポリマー、及びそれらの混合物からなる群から選択される材料、5〜50重量%の反応性抗菌剤、及び無機酸化物粒子を含む重合性前駆体から得られ、前記反応性抗菌剤がアクリル酸ジメチルアルキルアンモニウムエチルハライド及びメタクリル酸ジメチルアルキルアンモニウムエチルハライドの少なくとも一方を含み、ここで前記アルキルが14〜16個の炭素を有する、多層フィルム。 - 前記架橋母材に化学的に結合された抗菌剤が第一の抗菌剤であり、前記架橋した母材内に分散した第二の抗菌剤をさらに含む、請求項1記載の多層フィルム。
- 表面上の微生物汚染を低減するための多層フィルムを製造する方法であって、前記方法は、
コア層の第1の表面に隣接して接着層を積層すること、
前記コア層の第2の表面に隣接して抗菌層をコーティングすることであって、前記第2の表面は前記第1の表面の反対側にあり、そこでは、前記抗菌層は、5〜50重量%の反応性抗菌剤、無機酸化物粒子、並びに重合性モノマー、分子量が1000以下の重合性ポリマー、及びそれらの混合物を包含する群から選択される材料を含む重合性前駆体とを含み、ここで前記反応性抗菌剤がアクリル酸ジメチルアルキルアンモニウムエチルハライド及びメタクリル酸ジメチルアルキルアンモニウムエチルハライドの少なくとも一方を含み、ここで前記アルキルが14〜16個の炭素を有し、及び、
前記重合性前駆体、反応性抗菌剤及び無機酸化物粒子を重合して、架橋母材を含む抗菌ハードコート層を形成すること、ここで前記抗菌剤は架橋母材に化学的に結合している、を含む方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US74303605P | 2005-12-14 | 2005-12-14 | |
US60/743,036 | 2005-12-14 | ||
PCT/US2006/047780 WO2007070650A2 (en) | 2005-12-14 | 2006-12-14 | Antimicrobial adhesive films |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2009520076A JP2009520076A (ja) | 2009-05-21 |
JP2009520076A5 JP2009520076A5 (ja) | 2010-02-12 |
JP5801528B2 true JP5801528B2 (ja) | 2015-10-28 |
Family
ID=37946148
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008545821A Expired - Fee Related JP5801528B2 (ja) | 2005-12-14 | 2006-12-14 | 抗菌接着フィルム |
Country Status (3)
Country | Link |
---|---|
US (1) | US9247736B2 (ja) |
JP (1) | JP5801528B2 (ja) |
WO (1) | WO2007070650A2 (ja) |
Families Citing this family (74)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9247736B2 (en) | 2005-12-14 | 2016-02-02 | 3M Innovative Properties Company | Antimicrobial adhesive films |
WO2008021500A2 (en) | 2006-08-17 | 2008-02-21 | University Of Pittsburgh-Of The Commonwealth System Of Higher Education | Modification of surfaces with polymers |
US20100034858A1 (en) * | 2006-11-10 | 2010-02-11 | Basf Se | Biocidal coatings |
FR2912417A1 (fr) * | 2007-02-08 | 2008-08-15 | Hexis Sa | Methode de protection antimicrobienne d'une surface d'un objet a l'aide d'un film plastique auto adhesif antimicorbien |
JP2008308645A (ja) * | 2007-06-18 | 2008-12-25 | Sumitomo Electric Ind Ltd | 抗菌性塗料とそれを用いて形成される抗菌性物品、抗菌性フィルムおよび抗菌性テープ |
BRPI0820705A2 (pt) | 2007-12-12 | 2014-10-07 | 3M Innovative Properties Co | Filme antimicrobiano microestruturado |
WO2009082644A1 (en) | 2007-12-21 | 2009-07-02 | 3M Innovative Properties Company | Retroreflective articles and retroreflective elements comprising a spherical core and two concentric optical interference layers |
FR2925912B1 (fr) * | 2007-12-26 | 2010-01-22 | Toray Plastics Europ | Film polyester enroulable comprenant sur au moins l'une de ses faces, un revetement reticule resistant aux rayures, procede d'obtention de ce film polyester |
US9139355B2 (en) | 2008-04-18 | 2015-09-22 | Medline Industries, Inc. | Glove packaging having antimicrobial barrier |
WO2009140334A2 (en) * | 2008-05-16 | 2009-11-19 | 3M Innovative Properties Company | Foamable compositions for dental coatings and methods |
EP2358317A1 (en) * | 2008-11-24 | 2011-08-24 | Kimberly-Clark Worldwide, Inc. | Antimicrobial laminate constructs |
US20100148395A1 (en) * | 2008-12-17 | 2010-06-17 | Lux Products Corporation | Bacteria-resistant grab bar |
DE102009050425A1 (de) * | 2009-10-22 | 2011-05-26 | BLüCHER GMBH | Überzug für Gegenstände, insbesondere in öffentlichen Einrichtungen und/oder Verkehrsmitteln, zur Verhinderung einer Infektionsübertragung |
EP2552314A1 (en) * | 2010-03-31 | 2013-02-06 | Nellcor Puritan Bennett LLC | Films for touchscreen displays of medical device monitors |
TWI515276B (zh) * | 2010-05-25 | 2016-01-01 | 3M新設資產公司 | 抗微生物塗料 |
CN102947237B (zh) * | 2010-05-25 | 2016-01-20 | 3M创新有限公司 | 抗微生物剂涂覆的医学制品 |
US20130195949A1 (en) * | 2010-06-29 | 2013-08-01 | Waters Technologies Corporation | Antimicrobial Layer For Chromatographic Containers |
US20120081853A1 (en) * | 2010-10-05 | 2012-04-05 | Wen-Liang Huang | Medical antibacterial full-flat touch screen |
US11058793B2 (en) | 2011-05-16 | 2021-07-13 | Avery Dennison Corporation | Adhesive containing microparticles |
FI125519B (fi) * | 2011-08-29 | 2015-11-13 | Bewi Styrochem Oy | Paisutettavat polymeerihelmet ja niiden valmistus |
US20160107415A1 (en) * | 2011-09-19 | 2016-04-21 | John Joseph Scheible | Colored biocidal multi-layer structure |
US8840978B2 (en) | 2011-10-24 | 2014-09-23 | Precision Dynamics Corporation | Identification device having antimicrobial properties |
US20130196146A1 (en) * | 2012-01-31 | 2013-08-01 | Prestige Film Technologies | Clear protective covering for permanent installation on countertops |
GB2508675A (en) * | 2012-12-06 | 2014-06-11 | Emlyn William Pagden | Multi-ply anti-microbial laminate |
US10422158B2 (en) | 2012-12-20 | 2019-09-24 | SafeHandles, LLC | Replaceable antimicrobial system |
US20140199358A1 (en) * | 2013-01-14 | 2014-07-17 | Dmr International, Inc. | Antimicrobial polymer systems using multifunctional organometallic additives for thermoset hosts |
EP2954019B1 (en) | 2013-02-07 | 2018-08-15 | Avery Dennison Corporation | Antimicrobial adhesives having improved properties |
CA2949915C (en) * | 2013-03-08 | 2020-01-28 | Medline Industries, Inc. | Glove packaging having antimicrobial barrier |
WO2014151355A1 (en) | 2013-03-15 | 2014-09-25 | Avery Dennison Corporation | Transparent cover dressing application system and inclusion of label strip |
US10455831B2 (en) | 2013-03-15 | 2019-10-29 | Dmr International, Inc. | Liquid material systems with multifunctional organometallic additives |
US10682830B2 (en) * | 2013-06-06 | 2020-06-16 | 3M Innovative Properties Company | Successively peelable coextruded polymer film with embedded antimicrobial layer(s) |
WO2015041619A1 (en) * | 2013-09-23 | 2015-03-26 | Er Lincoln | Apparatus for the displaying advertising and publicity information on moving conveyor belts of conveyor devices with antibacterial-featured foil |
EP2868722A1 (en) | 2013-11-04 | 2015-05-06 | Axinnove SAS | UV curable coating composition for antimicrobial coating |
CN105916951A (zh) * | 2013-12-20 | 2016-08-31 | 3M创新有限公司 | 抗菌压敏粘合剂体系 |
US10154935B1 (en) * | 2014-05-27 | 2018-12-18 | Bryan L. Ales | Pressure bearing auricular hematoma appliance |
WO2015187632A1 (en) * | 2014-06-02 | 2015-12-10 | Avery Dennison Corporation | Polymeric films comprising antimicrobial agents |
EP3151813B1 (en) | 2014-06-05 | 2020-12-09 | Avery Dennison Corporation | Articles with active agent concentrated at the substrate contacting surface and related methods |
US10138038B2 (en) | 2014-06-05 | 2018-11-27 | Thomas & Betts International, Llc | Antimicrobial detectable cable tie |
US10518950B2 (en) * | 2014-11-06 | 2019-12-31 | Thomas & Betts International Llc | Antimicrobial cable tie |
US9939295B2 (en) * | 2014-12-16 | 2018-04-10 | Carestream Health, Inc. | Impact protection for wireless digital detector glass panel |
GB201506034D0 (en) * | 2015-04-09 | 2015-05-27 | Dycem Ltd | Contamination control sheet |
JP6473378B2 (ja) * | 2015-04-30 | 2019-02-20 | マクセルホールディングス株式会社 | 粘着テープ |
WO2016203957A1 (ja) | 2015-06-17 | 2016-12-22 | 株式会社ダイセル | 硬化性組成物、及び成形体 |
JP6619955B2 (ja) | 2015-06-17 | 2019-12-11 | 株式会社ダイセル | 傷回復フィルム |
JP6619954B2 (ja) * | 2015-06-17 | 2019-12-11 | 株式会社ダイセル | 成形体 |
WO2017027560A1 (en) * | 2015-08-11 | 2017-02-16 | Dow Global Technologies Llc | Material for packaging comprising antimicrobial composition |
US10278390B2 (en) | 2016-06-09 | 2019-05-07 | Thomas Agnew ROLFE | Antimicrobial transparent plastic in the form of film or extruded shape |
US10093811B2 (en) | 2016-07-11 | 2018-10-09 | Spartan Chemical Company, Inc. | Antimicrobial sacrificial floor coating systems |
US10759949B2 (en) | 2016-07-11 | 2020-09-01 | Spartan Chemical Company, Inc. | Antimicrobial sacrificial floor coating systems |
US11285709B1 (en) * | 2016-09-23 | 2022-03-29 | James Hardie Technology Limited | Packaging for prefinished articles |
JP7418211B2 (ja) | 2016-12-14 | 2024-01-19 | エコラブ ユーエスエイ インク | 四級カチオン性ポリマー |
WO2018212351A1 (en) | 2017-05-19 | 2018-11-22 | Daikin America, Inc. | Composition and method for producing composition |
CN107596368B (zh) * | 2017-10-11 | 2020-02-14 | 华南师范大学 | 一种细菌靶向纳米粒子的制备及其抑杀细菌的应用 |
US20200337302A1 (en) * | 2017-11-20 | 2020-10-29 | Korea Institute Of Industrial Technology | Method for manufacturing antimicrobial adhesive film |
US11427964B2 (en) | 2018-06-12 | 2022-08-30 | Ecolab Usa Inc. | Quaternary cationic surfactants and polymers for use as release and coating modifying agents in creping and tissue papers |
CN109135603B (zh) * | 2018-08-02 | 2023-01-17 | 江苏双星彩塑新材料股份有限公司 | 一种抑菌防爆窗膜 |
JP7084846B2 (ja) * | 2018-10-25 | 2022-06-15 | 株式会社Uacj | 抗菌シート及びその製造方法 |
KR102236216B1 (ko) * | 2018-11-23 | 2021-04-05 | 한국생산기술연구원 | 천연 항균 점착필름의 제조방법 |
WO2020231955A1 (en) * | 2019-05-10 | 2020-11-19 | Silver Defender, Corp | Antimicrobial adhesives |
CN114096624B (zh) * | 2019-06-26 | 2023-09-26 | 3M创新有限公司 | 水基离型涂料以及由其制得的制品 |
US11291203B2 (en) * | 2019-08-20 | 2022-04-05 | Lawrence Livermore National Security, Llc | Soluble metallogels including antimicrobial silver metallogels |
US11215546B2 (en) * | 2019-10-07 | 2022-01-04 | Particle Measuring Systems, Inc. | Antimicrobial particle detectors |
FR3107428B1 (fr) * | 2020-02-24 | 2023-03-31 | Atlantic Led | Borne de commande munie d’un film antimicrobien |
WO2021195374A1 (en) * | 2020-03-26 | 2021-09-30 | Nanotouch Materials, Llc | Covers with bioactive surface coatings for use on door knobs, latches and handles |
JP7474395B2 (ja) * | 2020-04-09 | 2024-04-25 | 株式会社Uacj | 抗菌シート及びその製造方法 |
US20230192299A1 (en) * | 2020-05-18 | 2023-06-22 | Safran Seats Usa Llc | Antimicrobial adhesive films for aircraft fixtures |
US11812744B2 (en) | 2020-08-20 | 2023-11-14 | Magic 8 Box LLC | Antimicrobial laminates and coatings indicating efficacy |
WO2022036467A1 (es) * | 2020-08-20 | 2022-02-24 | Guerrero Caro Jose Luis | Película y lámina autoadhesiva que en una de sus caras posee una capa antibacteriana y antiviral |
FR3115181B1 (fr) | 2020-10-21 | 2024-03-15 | Encapsulix | Film multicouche auto-desinfectant comprenant une couche d'oxyde semi-conducteur polycristallin photocatalytique |
US20240114905A1 (en) | 2021-01-28 | 2024-04-11 | 3M Innovative Properties Company | Antimicrobial compositions and articles and related methods |
KR102258923B1 (ko) * | 2021-02-08 | 2021-05-31 | 박진희 | 중금속 무함유의 항균 및 항바이러스 조성물 및 이를 포함하는 필름 |
KR102368575B1 (ko) * | 2021-08-17 | 2022-02-28 | 주식회사 퀀텀바이오닉스 | 항 마이코플라즈마 기능을 제공하는 배양용기 및 그 제조방법 |
US20230133694A1 (en) * | 2021-10-28 | 2023-05-04 | Kismet Technologies Llc | Electronic device with self-disinfecting touch screen and method of manufacture |
US11840646B2 (en) | 2021-11-09 | 2023-12-12 | Xerox Corporation | Printed surfaces with antimicrobial properties |
Family Cites Families (214)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2502881A (en) * | 1945-10-17 | 1950-04-04 | Parker Elizabeth Weston | Household cleaning composition |
US2537124A (en) * | 1946-01-23 | 1951-01-09 | Union Bay State Co Inc | Latex adhesive containing phenolphthalein and method of using the same |
US2449274A (en) | 1946-05-27 | 1948-09-14 | Fuld Bros Inc | Self-indicating quaternary ammonium bacteriocidal composition |
GB1073462A (en) | 1963-05-23 | 1967-06-28 | Nippon Comb Chemicals Mfg Co L | A new cleaning solution |
FR2043995A5 (en) | 1969-05-12 | 1971-02-19 | Protex Manuf | Aqueous stable emulsions, polyvinyl ace- - tate |
US7291570B1 (en) | 2000-06-02 | 2007-11-06 | Milliken & Company | Yarns and fabrics having a wash-durable non-electrically conductive topically applied metal-based finish |
US3926830A (en) | 1970-11-25 | 1975-12-16 | Dainichiswika Color & Chemical | Detergent composition having polymer bonded indicator |
US3832459A (en) | 1971-03-18 | 1974-08-27 | Hysan Corp | Spray disinfectant-deodorant |
AU4904672A (en) | 1971-12-02 | 1974-05-23 | Duralex Paints Pty Ltd | Surface coating composition |
US4070194A (en) * | 1976-02-13 | 1978-01-24 | Kinki Aerosol Industrial Co., Ltd. | Ink for marking |
FR2342074A1 (fr) | 1976-02-26 | 1977-09-23 | Salkin Nicolas | Produits de desinfection a remanence d'action |
US4070510A (en) * | 1976-03-12 | 1978-01-24 | Acme Chemical Company | Aqueous polish composition |
US4071645A (en) * | 1976-03-12 | 1978-01-31 | Acme Chemical Company | Aqueous coating composition |
JPS54131428A (en) * | 1978-04-03 | 1979-10-12 | Adger Kogyo Co Ltd | Ink |
US4308625A (en) * | 1978-06-12 | 1982-01-05 | The Procter & Gamble Company | Article for sanitizing toilets |
US4231370A (en) | 1979-06-18 | 1980-11-04 | The Procter & Gamble Company | Disposable diaper type garment having wetness indicator |
US4384869A (en) * | 1980-11-05 | 1983-05-24 | The Procter & Gamble Company | Activation of hypochlorite bleaching of dyes |
US4420412A (en) | 1980-11-05 | 1983-12-13 | The Procter & Gamble Company | Activation of hypochlorite bleaching of dyes |
US4353866A (en) | 1980-11-05 | 1982-10-12 | The Procter & Gamble Company | Activation of hypochlorite bleaching of dyes |
US4499001A (en) * | 1981-04-03 | 1985-02-12 | Warner-Lambert Company | Controlled fade effervescing cleanser |
EP0075934B1 (en) | 1981-09-30 | 1986-04-23 | Kiyoharu Kawashima | Clay capable of changing colour and method for its production |
JPS59501776A (ja) | 1982-09-13 | 1984-10-25 | ハイドロマ インコ−ポレイテツド | 抗細菌性の医療材料及び器具 |
US4699885A (en) | 1983-05-02 | 1987-10-13 | Melpolder Frank W | Composition and probe for detection of water |
US4578357A (en) * | 1983-06-27 | 1986-03-25 | Atlantic Richfield Company | Stabilized water indicating paste composition |
US4717671A (en) * | 1983-06-27 | 1988-01-05 | Pony Industries, Inc. | Stabilized water indicating paste composition |
DE3343479C1 (de) | 1983-12-01 | 1984-08-23 | Fried. Krupp Gmbh, 4300 Essen | Verfahren zum Oszillieren einer in sich starren Horizontal-Stranggiesskokille fuer Metalle,insbesondere Stahl |
JPS60170674U (ja) | 1984-04-20 | 1985-11-12 | 株式会社ノーリツ | 浴槽加熱用蒸気供給兼給湯回路の安全装置 |
US4584192A (en) * | 1984-06-04 | 1986-04-22 | Minnesota Mining & Manufacturing Company | Film-forming composition containing an antimicrobial agent and methods of use |
US4502605A (en) * | 1984-06-29 | 1985-03-05 | Denerik Creativity, Inc. | Container closure integrity system |
KR940010078B1 (ko) | 1985-03-13 | 1994-10-21 | 안토니 그룩 브루노 | 소독액과 그의 도포구 |
US5110492A (en) * | 1985-05-24 | 1992-05-05 | Irene Casey | Cleaner and disinfectant with dye |
US4965063A (en) | 1985-05-24 | 1990-10-23 | Irene Casey | Cleaner and disinfectant with dye |
US5057303A (en) | 1985-05-24 | 1991-10-15 | Irene Casey | Cleaner and disinfectant with dye |
US5064635A (en) | 1985-05-24 | 1991-11-12 | Irene Casey | Cleaner and disinfectant with dye |
US4793988A (en) | 1985-05-24 | 1988-12-27 | Irene Casey | Germicide and dye composition |
US5288486A (en) * | 1985-10-28 | 1994-02-22 | Calgon Corporation | Alcohol-based antimicrobial compositions |
GB8629640D0 (en) | 1986-12-11 | 1987-01-21 | Beecham Group Plc | Composition & method |
US4783340A (en) | 1987-04-29 | 1988-11-08 | Ecolab Inc. | Two-package co-sprayable film-forming sanitizer |
US5196243A (en) * | 1987-08-10 | 1993-03-23 | Kiyoharu Kawashima | Printed matter |
US5656286A (en) * | 1988-03-04 | 1997-08-12 | Noven Pharmaceuticals, Inc. | Solubility parameter based drug delivery system and method for altering drug saturation concentration |
US5470585A (en) | 1989-01-27 | 1995-11-28 | Giltech Limited | Medicinal substance for topical application |
US4954544A (en) | 1989-03-23 | 1990-09-04 | Conros Corporation | Modified adhesive composition which undergoes color changes upon application |
JPH0639368B2 (ja) * | 1990-02-28 | 1994-05-25 | 株式会社萩原技研 | シリカゲルを母体とした抗菌性組生物 |
US5234974A (en) | 1990-07-26 | 1993-08-10 | S. C. Johnson & Son, Inc. | Alkali-soluble hydrophilic polymer coatings |
US5223245A (en) * | 1990-09-11 | 1993-06-29 | Beecham Inc. | Color change mouthrinse |
US5154917A (en) | 1990-09-11 | 1992-10-13 | Beecham Inc. | Color change mouthrinse |
DE69132661T9 (de) | 1990-11-05 | 2005-06-09 | Fina Research S.A. | Verwendung von Säure-Base-Indikatoren zur Verbesserung der Nassdeckkraft von Emulsionsfarben |
GB2250817A (en) | 1990-12-12 | 1992-06-17 | Naresh Gathani | Dental caries diagnostic floss. |
CA2033107C (en) | 1990-12-24 | 2001-06-12 | Robert Edward Burrell | Actively sterile surfaces |
US5125956A (en) * | 1991-02-25 | 1992-06-30 | Monsanto Company | Substituted pyridine compounds |
ES2266683T3 (es) * | 1991-08-09 | 2007-03-01 | 3M Company | Barra de cola reposicionable. |
BR9206408A (pt) | 1991-08-23 | 1994-11-22 | Gillette Canada | Escova oral, matriz de liberação prolongada, processo para liberar um agente antimicrobiano de uma escova oral e para liberação de um agente antimicrobiano na boca de um animal e escova oral indicadora de desgaste |
JP3085478B2 (ja) * | 1991-08-30 | 2000-09-11 | 日本化学工業株式会社 | 抗菌性樹脂材料およびその製造方法 |
EP0537774B1 (en) * | 1991-10-18 | 1998-01-07 | Kuraray Co., Ltd. | Antimicrobial polymerizable composition, the polymer and article obtained from the same |
EP0549145A1 (en) | 1991-12-20 | 1993-06-30 | Rohm And Haas Company | Method for increasing the hiding power of paint |
US5421898A (en) * | 1992-02-21 | 1995-06-06 | Reckitt & Colman Inc. | Method and element for controlling release of a disinfectant from a substrate |
EP0639068A1 (en) * | 1992-05-05 | 1995-02-22 | The Procter & Gamble Company | Acne treating composition |
US5681575A (en) * | 1992-05-19 | 1997-10-28 | Westaim Technologies Inc. | Anti-microbial coating for medical devices |
GEP20002074B (en) * | 1992-05-19 | 2000-05-10 | Westaim Tech Inc Ca | Modified Material and Method for its Production |
JP3178557B2 (ja) * | 1992-08-04 | 2001-06-18 | 大塚化学株式会社 | 単独重合体及びその製造方法 |
WO1994001474A1 (en) | 1992-07-06 | 1994-01-20 | Otsuka Kagaku Kabushiki Kaisha | Polymerizable monomer, polymer thereof, and process for producing the same |
US5478382A (en) | 1992-07-31 | 1995-12-26 | Binney & Smith Inc. | Color changing compositions for use on non-porous surfaces |
US5489331A (en) * | 1992-07-31 | 1996-02-06 | Binney & Smith Inc. | Color changing compositions using acids |
US5492558A (en) * | 1992-07-31 | 1996-02-20 | Binney & Smith Inc. | Color changing compositions for highlighters |
US5766615A (en) * | 1992-11-13 | 1998-06-16 | Isp Investments Inc. | Compositions of insoluble film-forming polymers and uses therefor |
US5532029A (en) * | 1993-05-13 | 1996-07-02 | Fuerst; Ronnie S. | Materials and methods utilizing a temporary visual indicator |
US5418013A (en) * | 1993-06-21 | 1995-05-23 | Rohm And Haas Company | Method for decreasing drying time |
US5547662A (en) | 1993-08-27 | 1996-08-20 | Becton, Dickinson And Company | Preparation of a skin surface for a surgical procedure |
GB9318170D0 (en) * | 1993-09-02 | 1993-10-20 | Kodak Ltd | Antimicrobial polymers and compositions containing them |
CA2169559C (en) | 1993-09-14 | 2004-11-30 | Jeffrey F. Andrews | Disinfectant composition |
DE69317564T2 (de) * | 1993-09-25 | 1998-11-12 | Symalit Ag | Faserverstärkte, thermoplastische Platte |
EP0875146B1 (en) | 1993-11-18 | 2002-07-31 | Westaim Biomedical Corp. | Anti-microbial materials |
US5454886A (en) | 1993-11-18 | 1995-10-03 | Westaim Technologies Inc. | Process of activating anti-microbial materials |
US5817325A (en) | 1996-10-28 | 1998-10-06 | Biopolymerix, Inc. | Contact-killing antimicrobial devices |
US5849311A (en) | 1996-10-28 | 1998-12-15 | Biopolymerix, Inc. | Contact-killing non-leaching antimicrobial materials |
US5548010A (en) | 1993-12-29 | 1996-08-20 | Franer Victor R | Color dissipatable paint |
US5420197A (en) * | 1994-01-13 | 1995-05-30 | Hydromer, Inc. | Gels formed by the interaction of polyvinylpyrrolidone with chitosan derivatives |
JPH0880597A (ja) | 1994-07-14 | 1996-03-26 | Kyodo Printing Co Ltd | 抗菌性積層体、これを用いた袋体、容器および成形カップ |
US5460802A (en) | 1994-07-18 | 1995-10-24 | Minnesota Mining And Manufacturing Company | Oral disinfectant for companion animals |
US5482654A (en) * | 1994-11-09 | 1996-01-09 | Warnaway Corporation | Safety indicator system |
US5567420A (en) | 1994-11-16 | 1996-10-22 | Mceleney; John | Lotion which is temporarily colored upon application |
US6239048B1 (en) * | 1994-12-28 | 2001-05-29 | Fibermark, Inc. | Light-activated antimicrobial and antiviral materials |
US5567753A (en) | 1995-01-27 | 1996-10-22 | Avery Dennison Corporation | Adhesive composition which changes from colored to colorless upon application to a substrate |
US5569461A (en) | 1995-02-07 | 1996-10-29 | Minnesota Mining And Manufacturing Company | Topical antimicrobial composition and method |
US5460647A (en) | 1995-02-10 | 1995-10-24 | Binney & Smith Inc. | Color-changing marking composition system |
US5464470A (en) | 1995-02-10 | 1995-11-07 | Binney & Smith Inc. | Color-changing marking composition system |
US5667303A (en) | 1995-03-10 | 1997-09-16 | Minnesota Mining And Manufacturing Company | Time-temperature integrating indicator device |
US6730294B1 (en) * | 1995-04-24 | 2004-05-04 | Novapharm Research (Australia) Pty Limited | Method of forming a water soluble biocidal film on a solid surface |
AUPN262595A0 (en) | 1995-04-24 | 1995-05-18 | Novapharm Research (Australia) Pty Limited | Biocidal surface films |
US5586643A (en) | 1995-05-19 | 1996-12-24 | Globe International Inc. | Modular belting having antimicrobial characteristics and method of manufacture |
US5585407A (en) | 1995-07-13 | 1996-12-17 | Minnesota Mining And Manufacturing Company | Water-based coatable compositions comprising reaction products of acrylic emulsion polymers with organoalkoxysilanes |
JP3812757B2 (ja) * | 1996-03-28 | 2006-08-23 | 大日本印刷株式会社 | 抗菌性透明フィルム |
JP3628809B2 (ja) | 1996-06-10 | 2005-03-16 | アルケア株式会社 | 薬剤徐放性医療用配合物及びその製造方法 |
ATE380226T1 (de) * | 1996-11-01 | 2007-12-15 | Choisy Ltee Lab | Beschichtungs oder versiegelungszusammensetzung |
US5747011A (en) * | 1996-11-25 | 1998-05-05 | Schering-Plough Healthcare Products, Inc. | Sunscreen with disappering color indicator |
US6261541B1 (en) | 1996-11-25 | 2001-07-17 | Schering-Plough Healthcare Products, Inc. | Sunless tanning emulsions with disappearing color indicator |
US6290936B1 (en) | 1996-11-25 | 2001-09-18 | Schering-Plough Healthcare Products, Inc. | Sunscreen with disappearing color indicator |
US6197397B1 (en) * | 1996-12-31 | 2001-03-06 | 3M Innovative Properties Company | Adhesives having a microreplicated topography and methods of making and using same |
JP3711412B2 (ja) | 1997-01-14 | 2005-11-02 | 独立行政法人農業生物資源研究所 | 抗菌性付与剤並びに抗菌性繊維及びその製造方法 |
US6667082B2 (en) | 1997-01-21 | 2003-12-23 | Cryovac, Inc. | Additive transfer film suitable for cook-in end use |
US6333093B1 (en) | 1997-03-17 | 2001-12-25 | Westaim Biomedical Corp. | Anti-microbial coatings having indicator properties and wound dressings |
US5746814A (en) * | 1997-05-07 | 1998-05-05 | Xerox Corporation | Decurling compositions |
JPH1134240A (ja) * | 1997-07-15 | 1999-02-09 | Dainippon Printing Co Ltd | 抗菌性能を有する化粧シート |
JPH1157603A (ja) * | 1997-08-27 | 1999-03-02 | Lintec Corp | ハードコートシート |
US5929160A (en) * | 1997-09-25 | 1999-07-27 | Minnesota Mining And Manufacturing Company | Method for reducing water uptake in silyl terminated sulfopoly(ester-urethanes) |
US6102205A (en) | 1997-10-08 | 2000-08-15 | Medlogic Global Corporation | Prepolymer compositions comprising an antimicrobial agent |
JP5000037B2 (ja) * | 1997-10-10 | 2012-08-15 | ピュア バイオサイエンス | 殺菌剤 |
JPH11269448A (ja) * | 1997-12-22 | 1999-10-05 | Sanyo Chem Ind Ltd | 抗菌性を有する感圧接着剤 |
US6677287B1 (en) * | 1998-05-18 | 2004-01-13 | The Procter & Gamble Company | Implement containing cleaning composition and disappearing dye |
EP0966883A1 (en) | 1998-06-26 | 1999-12-29 | The Procter & Gamble Company | The use of an anti-microbial compound for disinfection |
US6007797A (en) | 1998-08-06 | 1999-12-28 | Ipa, Llc | Disappearing color sunscreen compositions |
GB9817457D0 (en) | 1998-08-12 | 1998-10-07 | Reckitt & Colman Inc | Improvements in or related to organic compositions |
US6504583B2 (en) * | 1998-10-02 | 2003-01-07 | 3M Innovative Properties Company | Anti-microbial touch panel and method of making same using homeotropic liquid crystal silanes |
US6296863B1 (en) | 1998-11-23 | 2001-10-02 | Agion Technologies, Llc | Antimicrobial fabric and medical graft of the fabric |
US6365130B1 (en) * | 1998-11-23 | 2002-04-02 | Agion Technologies L.L.C. | Antimicrobial chewing gum |
DE19858554A1 (de) | 1998-12-18 | 2000-06-21 | Sueddeutsche Kalkstickstoff | Selbstvernetzende Polyurethan-Polymer-Hybrid-Dispersion |
US6170564B1 (en) * | 1998-12-30 | 2001-01-09 | Unted Technologies Corporation | Room temperature cure antimicrobial coating that demonstrates a balance of properties includes low dissolution and good cohesion and adhesion |
US6653522B1 (en) | 1999-04-09 | 2003-11-25 | National Starch And Chemical Investment Holding Corporation | Hot melt adhesives based on sulfonated polyesters comprising wetness indicator |
US6482423B1 (en) | 1999-04-13 | 2002-11-19 | The Procter & Gamble Company | Antimicrobial wipes which provide improved residual benefit versus gram positive bacteria |
US6582715B1 (en) * | 1999-04-27 | 2003-06-24 | Agion Technologies, Inc. | Antimicrobial orthopedic implants |
JP4833414B2 (ja) | 1999-05-21 | 2011-12-07 | スリーエム イノベイティブ プロパティズ カンパニー | 抗微生物性物品 |
US6299799B1 (en) | 1999-05-27 | 2001-10-09 | 3M Innovative Properties Company | Ceramer compositions and antistatic abrasion resistant ceramers made therefrom |
JP2001019730A (ja) | 1999-07-07 | 2001-01-23 | Toua Planning:Kk | 抗微生物性防曇性樹脂組成物およびその硬化物 |
DE19932603A1 (de) * | 1999-07-13 | 2001-01-25 | Gruenenthal Gmbh | Wirkstoffhaltiger Mehrschichtfilm aus in situ vernetzten hydrophilen Polymeren |
US6559116B1 (en) * | 1999-09-27 | 2003-05-06 | The Procter & Gamble Company | Antimicrobial compositions for hard surfaces |
WO2001043549A2 (en) | 1999-11-24 | 2001-06-21 | 3M Innovative Properties Company | Fruit, vegetable, and seed disinfectants |
US6267590B1 (en) | 1999-11-24 | 2001-07-31 | Agion Technologies, Llc | Antimicrobial dental products |
US6340663B1 (en) * | 1999-11-24 | 2002-01-22 | The Clorox Company | Cleaning wipes |
WO2001046900A1 (en) | 1999-12-22 | 2001-06-28 | Agion Technologies, Llc | Touch screen with antimicrobial properties |
AU775841B2 (en) | 1999-12-28 | 2004-08-19 | Kimberly-Clark Worldwide, Inc. | A wiper containing a controlled-release anti-microbial agent |
US6306419B1 (en) | 2000-02-23 | 2001-10-23 | Aegis Biosciences, Llc | Medical uses of styrene sulfonate polymers |
AUPQ656300A0 (en) | 2000-03-29 | 2000-04-20 | Novapharm Research (Australia) Pty Ltd | Biostatic filter |
US6267976B1 (en) | 2000-04-14 | 2001-07-31 | Gojo Industries, Inc. | Skin cleanser with photosensitive dye |
US6719987B2 (en) | 2000-04-17 | 2004-04-13 | Nucryst Pharmaceuticals Corp. | Antimicrobial bioabsorbable materials |
US6741523B1 (en) * | 2000-05-15 | 2004-05-25 | 3M Innovative Properties Company | Microstructured time dependent indicators |
US6461386B1 (en) | 2000-05-17 | 2002-10-08 | Milliken & Company | Antimicrobial transfer substrates and methods of use therewith |
US7279452B2 (en) | 2000-06-12 | 2007-10-09 | Commun-I-Tec, Ltd. | Sanitizing applicator having a positively charged fabric cover |
US7459167B1 (en) | 2000-07-27 | 2008-12-02 | 3M Innovative Properties Company | Biocidal polyurethane compositions and methods of use |
US6544621B1 (en) * | 2000-09-01 | 2003-04-08 | Milliken & Company | Floor covering articles comprising antimicrobial adhesive latex components |
US6342212B1 (en) * | 2000-09-01 | 2002-01-29 | Milliken & Company | Antimicrobial adhesive latexes and methods of making thereof |
US20020183233A1 (en) * | 2000-12-14 | 2002-12-05 | The Clorox Company, Delaware Corporation | Bactericidal cleaning wipe |
HUP0600689A3 (en) | 2000-12-21 | 2012-10-29 | Unilever Nv | Antimicrobial wipe |
US6467897B1 (en) | 2001-01-08 | 2002-10-22 | 3M Innovative Properties Company | Energy curable inks and other compositions incorporating surface modified, nanometer-sized particles |
JP2002241418A (ja) | 2001-02-21 | 2002-08-28 | Nippon Kayaku Co Ltd | 放射線硬化型樹脂組成物 |
GB0105811D0 (en) | 2001-03-09 | 2001-04-25 | Hilltout Alexander M | Cleaning cloth |
US20020146385A1 (en) | 2001-04-10 | 2002-10-10 | Lin Tung Liang | Ionic antimicrobial coating |
JP2002327005A (ja) | 2001-05-02 | 2002-11-15 | Mitsubishi Rayon Co Ltd | 光硬化性樹脂組成物及びその樹脂積層体 |
DE10123831A1 (de) * | 2001-05-16 | 2002-11-28 | Creavis Tech & Innovation Gmbh | Mikrobizide Folienstacksysteme |
US6554156B1 (en) * | 2001-05-17 | 2003-04-29 | The Clorox Company | Dispenser for cleaning wipes |
DE10133399A1 (de) | 2001-07-13 | 2003-01-23 | Cognis Deutschland Gmbh | Zusammensetzung auf Wachsbasis |
EP1275371A1 (en) * | 2001-07-13 | 2003-01-15 | Johnson and Johnson GmbH | Dry products comprising a sheet and two phases |
JP4388244B2 (ja) | 2001-08-16 | 2009-12-24 | 独立行政法人海洋研究開発機構 | 抗菌性高分子物質および抗菌性高分子ゲル |
CA2482306C (en) | 2001-08-24 | 2011-10-18 | The Clorox Company | Improved cleaning composition |
ATE497979T1 (de) * | 2001-10-10 | 2011-02-15 | Microban Products | Antimikrobielle strahlungshärtbare beschichtung |
US6772708B2 (en) | 2001-10-30 | 2004-08-10 | The Procter And Gamble Company | Wetness indicator having improved colorant retention |
US20030118733A1 (en) * | 2001-12-21 | 2003-06-26 | Delwin Jackson | Low-temperature method of producing an antimicrobial, durable coating for hard surface substrates |
US6838078B2 (en) * | 2002-01-16 | 2005-01-04 | 3M Innovative Properties Company | Film-forming compositions and methods |
US20030175438A1 (en) | 2002-01-17 | 2003-09-18 | Reeve John A. | Treatments of solid substrates to enhance durability of treatments placed thereon |
US6726584B2 (en) * | 2002-01-22 | 2004-04-27 | Jerry Iggulden | Method and apparatus for temporarily marking a point of contact |
US20030157147A1 (en) | 2002-02-15 | 2003-08-21 | William Hoge | Anti-microbial utility and kitchen wipe utilizing metallic silver as an oligodynamic agent |
US7053029B2 (en) * | 2002-03-27 | 2006-05-30 | Kimberly-Clark Worldwide, Inc. | Use indicating soap |
DE10216945A1 (de) * | 2002-04-17 | 2003-11-06 | Bayer Ag | Selbstvernetzende PUR-Dispersionen |
US6905711B1 (en) * | 2002-05-02 | 2005-06-14 | Smart Anti-Microbial Solutions, Llc | Antimicrobial agents, products incorporating said agents and methods of making products incorporating antimicrobial agents |
US6733766B2 (en) * | 2002-05-06 | 2004-05-11 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Personal care composition with color change indicator |
US6926745B2 (en) | 2002-05-17 | 2005-08-09 | The Clorox Company | Hydroscopic polymer gel films for easier cleaning |
US7829478B2 (en) | 2002-06-11 | 2010-11-09 | 3M Innovative Properties Company | Consumer scrubbing wipe article and method of making same |
US6894095B2 (en) * | 2002-07-17 | 2005-05-17 | The Dial Corporation | Color-changing wallpaper adhesive primer/activator |
US6884741B2 (en) * | 2002-07-23 | 2005-04-26 | H.B. Fuller Licensing & Financing, Inc. | Antimicrobial sheeting article |
GB0219780D0 (en) | 2002-08-23 | 2002-10-02 | Bramley Christopher S | Colour changing paint |
US7183455B2 (en) * | 2002-08-27 | 2007-02-27 | Drdc Limited | Adhesive dressing |
GB0305222D0 (en) | 2002-10-03 | 2003-04-09 | Unilever Plc | Indicator kit |
GB2393911A (en) | 2002-10-12 | 2004-04-14 | Reckitt Benckiser Inc | Antimicrobial hard surface cleaner |
US6641829B1 (en) | 2002-10-22 | 2003-11-04 | Milliken & Company | Topical application of solid antimicrobials to carpet pile fibers during carpet manufacture |
JP2004143374A (ja) | 2002-10-28 | 2004-05-20 | Mitsubishi Rayon Co Ltd | 光硬化性樹脂組成物及びその硬化樹脂積層体 |
WO2004041312A2 (en) | 2002-10-31 | 2004-05-21 | Polymer Group Inc. | Anti-microbial nonwoven wipe |
FR2846970B1 (fr) * | 2002-11-08 | 2006-08-11 | Desarrollo Del Grafting S L | Procede de traitement de surface par photopolymerisation pour obtenir des proprietes biocides |
US20060127425A1 (en) * | 2002-12-10 | 2006-06-15 | Venture Management Alliance, Llc | Encapsulated material released to generate perceivable sensorial indicia of discrete event occurrence |
EP1443099A3 (de) | 2003-01-17 | 2004-08-11 | VIP Domotec S.A.R.L. | Reinigungstuch mit selbstreinigender Wirkung und dessen Anwendung |
JP2004269836A (ja) * | 2003-03-07 | 2004-09-30 | Sutetsupu Moa:Kk | 透明性を有する鮮度保持シール |
DE502004004117D1 (de) | 2003-03-08 | 2007-08-02 | Brillux Gmbh & Co Kg | Beschichtungsmittel mit Farbumschlag |
US20040180093A1 (en) * | 2003-03-12 | 2004-09-16 | 3M Innovative Properties Company | Polymer compositions with bioactive agent, medical articles, and methods |
WO2004100664A1 (en) | 2003-05-15 | 2004-11-25 | Arch Uk Biocides Limited | Composition comprising an acidic copolymer and an antimicrobial agent and use thereof |
AU2003902552A0 (en) | 2003-05-21 | 2003-06-12 | Novapharm Research (Australia) Pty Ltd | Biofilm growth prevention |
US20050000642A1 (en) * | 2003-07-03 | 2005-01-06 | 3M Innovative Properties Company | Cling articles |
US7491753B2 (en) * | 2003-07-03 | 2009-02-17 | Mallard Creek Polymers, Inc. | Antimicrobial and antistatic polymers and methods of using such polymers on various substrates |
US7070737B2 (en) * | 2003-08-01 | 2006-07-04 | The Clorox Company | Disinfecting article with extended efficacy |
US7008600B2 (en) * | 2003-08-01 | 2006-03-07 | The Clorox Company | Disinfecting article and cleaning composition with extended stability |
ZA200602543B (en) * | 2003-08-28 | 2008-03-26 | Pure Bioscience | Silver dihydrogen citrate compositions a second antimicrobial agent |
US20050058673A1 (en) * | 2003-09-09 | 2005-03-17 | 3M Innovative Properties Company | Antimicrobial compositions and methods |
US20050101511A1 (en) * | 2003-11-06 | 2005-05-12 | Colgate-Palmolive Company | Antimicrobial cleaning composition |
US20050129937A1 (en) * | 2003-12-16 | 2005-06-16 | Eastman Kodak Company | Antimicrobial web for application to a surface |
US20050129742A1 (en) * | 2003-12-16 | 2005-06-16 | Eastman Kodak Company | Antimicrobial article with diffusion control layer |
US7306777B2 (en) * | 2003-12-16 | 2007-12-11 | Eastman Kodak Company | Antimicrobial composition |
US20050137540A1 (en) * | 2003-12-23 | 2005-06-23 | Kimberly-Clark Worldwide, Inc. | Bacteria removing wipe |
US20050191326A1 (en) | 2004-02-27 | 2005-09-01 | Melker Richard J. | Materials and methods for creating customized compositions having a temporary visual indicator |
US7320956B2 (en) | 2004-04-01 | 2008-01-22 | 3M Innovative Properties Company | Aqueous cleaning/treatment composition for fibrous substrates |
US20080063693A1 (en) | 2004-04-29 | 2008-03-13 | Bacterin Inc. | Antimicrobial coating for inhibition of bacterial adhesion and biofilm formation |
JP2005319240A (ja) | 2004-05-06 | 2005-11-17 | Kahinomoto Technologies:Kk | カラーシャボン玉液 |
US20050249791A1 (en) | 2004-05-07 | 2005-11-10 | 3M Innovative Properties Company | Antimicrobial articles |
US20060008912A1 (en) * | 2004-07-09 | 2006-01-12 | Simon Patrick L | Temporary visual indicators for paint and other compositions |
US20060030512A1 (en) * | 2004-08-06 | 2006-02-09 | Hart Eric R | Cleaner leaving an anti-microbial film |
US20060040835A1 (en) * | 2004-08-19 | 2006-02-23 | Newkirk R S | Cleansing system and method |
ATE415460T1 (de) * | 2004-10-12 | 2008-12-15 | 3M Innovative Properties Co | Einen schützenden film ausbildender klebstoff |
JP2006111815A (ja) | 2004-10-18 | 2006-04-27 | Mitsubishi Pencil Co Ltd | 下書き用インキ組成物及び筆記具 |
US20060134163A1 (en) * | 2004-12-16 | 2006-06-22 | Bagwell Alison S | Immobilizing anti-microbial compounds on elastomeric articles |
JP2006299214A (ja) | 2005-04-20 | 2006-11-02 | Satoshi Nagura | 保護シート |
US20060293205A1 (en) | 2005-06-27 | 2006-12-28 | Jessica Chung | Cleaning substrate with a visual cue |
US20070048356A1 (en) * | 2005-08-31 | 2007-03-01 | Schorr Phillip A | Antimicrobial treatment of nonwoven materials for infection control |
US8137735B2 (en) | 2005-11-10 | 2012-03-20 | Allegiance Corporation | Elastomeric article with antimicrobial coating |
WO2007070649A2 (en) | 2005-12-14 | 2007-06-21 | 3M Innovative Properties Company | Antimicrobial coating system |
US9247736B2 (en) | 2005-12-14 | 2016-02-02 | 3M Innovative Properties Company | Antimicrobial adhesive films |
US9668476B2 (en) | 2006-02-23 | 2017-06-06 | Lanxess Corporation | Removable antimicrobial coating compositions and methods of use |
US20080075951A1 (en) * | 2006-09-27 | 2008-03-27 | 3M Innovative Properties Company | Fluoroacrylates and hardcoat compositions including the same |
US20100240799A1 (en) | 2007-06-13 | 2010-09-23 | 3M Innovative Properties Company | Antimicrobial film-forming composition, antimicrobial film, and method of verifying the presence of an antimicrobial film |
-
2006
- 2006-12-14 US US12/094,758 patent/US9247736B2/en not_active Expired - Fee Related
- 2006-12-14 JP JP2008545821A patent/JP5801528B2/ja not_active Expired - Fee Related
- 2006-12-14 WO PCT/US2006/047780 patent/WO2007070650A2/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
WO2007070650A2 (en) | 2007-06-21 |
WO2007070650A3 (en) | 2008-07-03 |
US9247736B2 (en) | 2016-02-02 |
JP2009520076A (ja) | 2009-05-21 |
US20090130157A1 (en) | 2009-05-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5801528B2 (ja) | 抗菌接着フィルム | |
Divya et al. | Biogenic synthesis and effect of silver nanoparticles (AgNPs) to combat catheter-related urinary tract infections | |
AU2009204189B2 (en) | Disinfectant alcohol-soluble quaternary ammonium polymers | |
US8343523B2 (en) | Disinfectant with durable activity based on alcohol-soluble quaternary ammonium polymers and copolymers | |
US5753699A (en) | Methods for treating non-suturable, superficial wounds by use of cyanoacrylate ester compositions comprising an antimicrobial agent | |
EP2227228B1 (en) | Microstructured antimicrobial film | |
Sivakumar et al. | Incorporation of antimicrobial macromolecules in acrylic denture base resins: a research composition and update | |
CA2620175C (en) | Disinfectant with quaternary ammonium polymers and copolymers | |
Liu et al. | Antimicrobial property of halogenated catechols | |
CN112521880B (zh) | 一种抗菌防爆膜及其制备方法 | |
CN110862680B (zh) | 一种含氟聚丙烯酸类共聚物抗菌复合材料的制备方法及所得产品和应用 | |
JP6843079B2 (ja) | 抗菌性物品及びその使用方法 | |
AU2014373706B2 (en) | Method for cleaning hard surfaces | |
JPWO2018016207A1 (ja) | 抗菌組成物、抗菌膜、抗菌膜付き基材、抗菌膜の製造方法、及び、抗菌膜付き基材の製造方法 | |
Alvarez-Paino et al. | Antimicrobial films obtained from latex particles functionalized with quaternized block copolymers | |
Chen et al. | Cooperative enhancement of fungal repelling performance by surface photografting of stereochemical bi-molecules | |
CN1361796A (zh) | 制备固有杀微生物聚合物表面的方法 | |
JP4916200B2 (ja) | 皮膚貼着材およびその製造方法 | |
JP5942339B2 (ja) | 人工爪装着キット、及び人工爪の装着方法 | |
CN1360602A (zh) | 生产固有杀微生物聚合物表面的方法 | |
JP2003129028A (ja) | 抗菌剤を含有した接着剤、および抗菌剤を含有した抗菌組成物およびそれらを用いた抗菌方法 | |
CN116323719A (zh) | 抗菌聚合物和包含其的抗菌聚合物膜 | |
JP6977550B2 (ja) | 微生物付着抑制剤 | |
EP0855191A2 (en) | Methods for treating non-suturable, superficial wounds by use of cyanoacrylate ester compositions comprising an antimicrobial agent | |
US20040072944A1 (en) | Reactive formulations comprising anitmicrobial polymers |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20091214 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20091214 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20120516 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120717 |
|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20121015 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130806 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20131112 |
|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140203 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20141028 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20150127 |
|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150422 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150526 |
|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150626 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20150728 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20150827 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5801528 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |