JP5608668B2 - 金属層の後処理方法 - Google Patents
金属層の後処理方法 Download PDFInfo
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- JP5608668B2 JP5608668B2 JP2011536518A JP2011536518A JP5608668B2 JP 5608668 B2 JP5608668 B2 JP 5608668B2 JP 2011536518 A JP2011536518 A JP 2011536518A JP 2011536518 A JP2011536518 A JP 2011536518A JP 5608668 B2 JP5608668 B2 JP 5608668B2
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- metal
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- 229910052751 metal Inorganic materials 0.000 title claims description 134
- 239000002184 metal Substances 0.000 title claims description 134
- 238000000034 method Methods 0.000 title claims description 54
- 239000000758 substrate Substances 0.000 claims description 52
- 238000005260 corrosion Methods 0.000 claims description 50
- 230000007797 corrosion Effects 0.000 claims description 50
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 35
- 150000001450 anions Chemical class 0.000 claims description 33
- 239000008151 electrolyte solution Substances 0.000 claims description 30
- 229910052804 chromium Inorganic materials 0.000 claims description 23
- 239000011651 chromium Substances 0.000 claims description 23
- 239000000470 constituent Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 21
- 239000003792 electrolyte Substances 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 18
- 229910052802 copper Inorganic materials 0.000 claims description 16
- 229910052759 nickel Inorganic materials 0.000 claims description 16
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 15
- 238000000576 coating method Methods 0.000 claims description 12
- 229910052709 silver Inorganic materials 0.000 claims description 12
- 229910045601 alloy Inorganic materials 0.000 claims description 11
- 239000000956 alloy Substances 0.000 claims description 11
- 150000007942 carboxylates Chemical class 0.000 claims description 11
- 229920000642 polymer Polymers 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 10
- 125000000524 functional group Chemical group 0.000 claims description 10
- 229910052737 gold Inorganic materials 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 229910019142 PO4 Inorganic materials 0.000 claims description 9
- 150000002739 metals Chemical class 0.000 claims description 9
- 239000002052 molecular layer Substances 0.000 claims description 9
- 125000000129 anionic group Chemical group 0.000 claims description 8
- 230000002209 hydrophobic effect Effects 0.000 claims description 8
- 239000010452 phosphate Substances 0.000 claims description 8
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims description 8
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 8
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 7
- -1 phosphinates Chemical class 0.000 claims description 6
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910002651 NO3 Inorganic materials 0.000 claims description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 4
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims description 4
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 claims description 4
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 claims description 4
- 150000001642 boronic acid derivatives Chemical class 0.000 claims description 2
- MQIGTIFMSSGUBS-UHFFFAOYSA-N ethenylphosphinic acid Chemical compound OP(=O)C=C MQIGTIFMSSGUBS-UHFFFAOYSA-N 0.000 claims description 2
- 150000002823 nitrates Chemical class 0.000 claims description 2
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 238000004381 surface treatment Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 150000003891 oxalate salts Chemical class 0.000 claims 1
- 239000010410 layer Substances 0.000 description 99
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 30
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 25
- 239000002253 acid Substances 0.000 description 19
- 229920002125 Sokalan® Polymers 0.000 description 16
- 239000004584 polyacrylic acid Substances 0.000 description 16
- 239000000243 solution Substances 0.000 description 16
- 239000007864 aqueous solution Substances 0.000 description 15
- 229910052742 iron Inorganic materials 0.000 description 15
- 150000003839 salts Chemical class 0.000 description 15
- 239000010949 copper Substances 0.000 description 14
- 229910000510 noble metal Inorganic materials 0.000 description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 12
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 12
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 12
- 239000010935 stainless steel Substances 0.000 description 12
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- 150000001491 aromatic compounds Chemical class 0.000 description 11
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 10
- 230000006872 improvement Effects 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 239000011133 lead Substances 0.000 description 9
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 8
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 8
- 239000010931 gold Substances 0.000 description 8
- 238000007747 plating Methods 0.000 description 8
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- 229910052718 tin Inorganic materials 0.000 description 8
- 230000001965 increasing effect Effects 0.000 description 7
- 239000002966 varnish Substances 0.000 description 7
- 229910052725 zinc Inorganic materials 0.000 description 7
- 239000011701 zinc Substances 0.000 description 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 6
- 239000004922 lacquer Substances 0.000 description 6
- 229910052750 molybdenum Inorganic materials 0.000 description 6
- 239000011733 molybdenum Substances 0.000 description 6
- 229910052763 palladium Inorganic materials 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- 229910052697 platinum Inorganic materials 0.000 description 6
- 229910052703 rhodium Inorganic materials 0.000 description 6
- 239000010948 rhodium Substances 0.000 description 6
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 6
- 229910001369 Brass Inorganic materials 0.000 description 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000001110 calcium chloride Substances 0.000 description 5
- 229910001628 calcium chloride Inorganic materials 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 238000001336 glow discharge atomic emission spectroscopy Methods 0.000 description 5
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- 239000007921 spray Substances 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000010951 brass Substances 0.000 description 4
- 230000002708 enhancing effect Effects 0.000 description 4
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical compound COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 4
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- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
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- 150000004679 hydroxides Chemical class 0.000 description 3
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- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 3
- 235000019795 sodium metasilicate Nutrition 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
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- 238000012546 transfer Methods 0.000 description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- XQDNFAMOIPNVES-UHFFFAOYSA-N 3,5-Dimethoxyphenol Chemical compound COC1=CC(O)=CC(OC)=C1 XQDNFAMOIPNVES-UHFFFAOYSA-N 0.000 description 2
- IJFXRHURBJZNAO-UHFFFAOYSA-N 3-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC(O)=C1 IJFXRHURBJZNAO-UHFFFAOYSA-N 0.000 description 2
- VGMJYYDKPUPTID-UHFFFAOYSA-N 4-ethylbenzene-1,3-diol Chemical compound CCC1=CC=C(O)C=C1O VGMJYYDKPUPTID-UHFFFAOYSA-N 0.000 description 2
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- 239000000126 substance Substances 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- NCPXQVVMIXIKTN-UHFFFAOYSA-N trisodium;phosphite Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])[O-] NCPXQVVMIXIKTN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D9/00—Electrolytic coating other than with metals
- C25D9/04—Electrolytic coating other than with metals with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4407—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained by polymerisation reactions involving only carbon-to-carbon unsaturated bonds
- C09D5/4411—Homopolymers or copolymers of acrylates or methacrylates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4484—Anodic paints
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/26—Anodisation of refractory metals or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/34—Anodisation of metals or alloys not provided for in groups C25D11/04 - C25D11/32
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/36—Phosphatising
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/38—Chromatising
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/48—After-treatment of electroplated surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Chemical Treatment Of Metals (AREA)
- Electroplating Methods And Accessories (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08019899.7 | 2008-11-14 | ||
| EP08019899A EP2186928A1 (en) | 2008-11-14 | 2008-11-14 | Method for the post-treatment of metal layers |
| EP09002335.9 | 2009-02-19 | ||
| EP09002335A EP2189553A1 (en) | 2008-11-14 | 2009-02-19 | Method for the post-treatment of metal layers |
| PCT/US2009/064394 WO2010057001A2 (en) | 2008-11-14 | 2009-11-13 | Method for the post-treatment of metal layers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012508821A JP2012508821A (ja) | 2012-04-12 |
| JP2012508821A5 JP2012508821A5 (enExample) | 2013-01-10 |
| JP5608668B2 true JP5608668B2 (ja) | 2014-10-15 |
Family
ID=40481736
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011536518A Active JP5608668B2 (ja) | 2008-11-14 | 2009-11-13 | 金属層の後処理方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9222189B2 (enExample) |
| EP (3) | EP2186928A1 (enExample) |
| JP (1) | JP5608668B2 (enExample) |
| KR (1) | KR101639830B1 (enExample) |
| CN (1) | CN102282296B (enExample) |
| WO (2) | WO2010056386A1 (enExample) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4728437B1 (ja) * | 2010-03-10 | 2011-07-20 | 日本特殊陶業株式会社 | スパークプラグ、スパークプラグ用の主体金具、及び、スパークプラグの製造方法 |
| DE102011002837A1 (de) | 2011-01-18 | 2012-07-19 | Henkel Ag & Co. Kgaa | Mehrstufige Vorbehandlung von Weißblech vor einer Lackierung |
| DE102011002836A1 (de) | 2011-01-18 | 2012-07-19 | Henkel Ag & Co. Kgaa | Vorbehandlung von Weißblech vor einer Lackierung |
| JP5828448B2 (ja) * | 2011-03-28 | 2015-12-09 | 公立大学法人首都大学東京 | 金コロイドの製造方法 |
| CN102181911B (zh) * | 2011-04-21 | 2012-10-10 | 河北联合大学 | ZnO纳米带阵列的制备方法 |
| AT514229B1 (de) | 2013-04-29 | 2015-02-15 | Voestalpine Stahl Gmbh | Verfahren zur Oberflächenbehandlung eines metallischen Substrats |
| TR201815433T4 (tr) | 2013-05-24 | 2018-11-21 | Macdermid Enthone Inc | Metal yüzeylerdeki polimerik yüzey sızdırmazlık maddelerinin giderilmesi için sulu sıyırma bileşimi. |
| EP2826890A1 (en) * | 2013-07-19 | 2015-01-21 | ATOTECH Deutschland GmbH | Method for cathodic corrosion protection of chromium surfaces |
| CN104425654B (zh) * | 2013-08-28 | 2017-08-25 | 上海晶玺电子科技有限公司 | 蚀刻方法 |
| AT514818B1 (de) | 2013-09-18 | 2015-10-15 | W Garhöfer Ges M B H Ing | Abscheidung von Cu, Sn, Zn-Beschichtungen auf metallischen Substraten |
| CN104099650B (zh) * | 2014-08-01 | 2018-03-20 | 广东富行洗涤剂科技有限公司 | 一种脱水剂 |
| SG10201913611QA (en) | 2014-08-08 | 2020-03-30 | Alector Llc | Anti-trem2 antibodies and methods of use thereof |
| ES2623764T3 (es) * | 2015-01-13 | 2017-07-12 | Atotech Deutschland Gmbh | Método para aumentar la adherencia entre una superficie de cromo y un barniz |
| EP3299497A1 (en) | 2016-09-27 | 2018-03-28 | ATOTECH Deutschland GmbH | Method for treatment of a chromium surface |
| EP3382062A1 (en) | 2017-03-31 | 2018-10-03 | COVENTYA S.p.A. | Method for increasing the corrosion resistance of a chrome-plated substrate |
| WO2019023273A1 (en) * | 2017-07-26 | 2019-01-31 | Arconic Inc. | ROLL-COATING PREPARATION METHODS FOR ALUMINUM ALLOY-ADHESION BONDING, AND PRODUCTS RELATED THERETO |
| TWI868807B (zh) | 2017-08-03 | 2025-01-01 | 美商阿列克特有限責任公司 | 抗trem2抗體及其使用方法 |
| CN107522811A (zh) * | 2017-08-31 | 2017-12-29 | 陕西科技大学 | 阴离子型反应型聚电解质及其制备方法及应用 |
| CN107675209A (zh) * | 2017-10-18 | 2018-02-09 | 江西理工大学 | 一种绿色环保锡电解精炼电解液 |
| JP6808180B2 (ja) * | 2018-09-27 | 2021-01-06 | Toto株式会社 | 衛生設備部材 |
| WO2020067510A1 (ja) * | 2018-09-27 | 2020-04-02 | Toto株式会社 | 水栓金具 |
| DE102019109188B4 (de) * | 2019-04-08 | 2022-08-11 | Umicore Galvanotechnik Gmbh | Verwendung eines Elektrolyten zur Abscheidung von anthrazit/schwarzen Rhodium/Ruthenium Legierungsschichten |
| JP7358886B2 (ja) * | 2019-09-27 | 2023-10-11 | Toto株式会社 | 衛生設備部材 |
| US11328877B2 (en) | 2019-10-21 | 2022-05-10 | Imam Abdulrahman Bin Faisal University | Redox-mediated poly(vinylphosphonic acid) useful in capacitors |
| KR102380019B1 (ko) * | 2020-08-02 | 2022-03-28 | 김석진 | 양극산화를 이용한 순금 및 순은제품 표면 처리방법 |
| WO2022046996A1 (en) * | 2020-08-28 | 2022-03-03 | Coatings For Industry, Inc. | Corrosion-resistant coatings |
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| US2377792A (en) * | 1941-02-28 | 1945-06-05 | Solvay Process Co | Preventing corrosion of ferrous metals by solutions of electrolytes |
| US3350285A (en) * | 1963-07-20 | 1967-10-31 | Ngk Insulators Ltd | Method of forming rust-proofing and corrosion-resisting coating on metal surfaces |
| GB1116385A (en) * | 1964-08-31 | 1968-06-06 | Kansai Paint Co Ltd | Anticorrosion treatment of zinc surfaces |
| US3382165A (en) * | 1965-06-28 | 1968-05-07 | Ford Motor Co | Electrodeposition with organic acid resins having mineral acid groups attached thereto |
| GB1135406A (en) * | 1965-11-20 | 1968-12-04 | Ford Motor Co | Bath composition for electrodeposition |
| FR1592078A (enExample) * | 1968-01-29 | 1970-05-11 | ||
| US4383897A (en) * | 1980-09-26 | 1983-05-17 | American Hoechst Corporation | Electrochemically treated metal plates |
| IT1161593B (it) * | 1983-03-03 | 1987-03-18 | Lavezzari Impianti Spa | Procedimento per la protezione di laminati piani di acciaio zincato mediante rivestimento elettrolitico multistrato |
| US6004448A (en) * | 1995-06-06 | 1999-12-21 | Atotech Usa, Inc. | Deposition of chromium oxides from a trivalent chromium solution containing a complexing agent for a buffer |
| EP1369502A1 (en) * | 1997-01-31 | 2003-12-10 | Elisha Holding LLC | Electrodeposition medium |
| US6149794A (en) | 1997-01-31 | 2000-11-21 | Elisha Technologies Co Llc | Method for cathodically treating an electrically conductive zinc surface |
| CA2233339A1 (en) | 1997-03-26 | 1998-09-26 | Rong Yue | Coated subtrate and process for production thereof |
| US6030710A (en) | 1997-06-30 | 2000-02-29 | Alcoa Inc. | Copolymer primer for aluminum alloy food and beverage containers |
| KR200169658Y1 (ko) * | 1997-12-30 | 2000-04-01 | 김덕중 | 4-바아 링크 로봇의 링크길이 조절장치 |
| US6328874B1 (en) * | 1998-01-05 | 2001-12-11 | Mcdonnell Douglas Corporation | Anodically formed intrinsically conductive polymer-aluminum oxide composite as a coating on aluminum |
| US6020030A (en) | 1998-05-07 | 2000-02-01 | Aluminum Company Of America | Coating an aluminum alloy substrate |
| EP1074640A4 (en) * | 1998-12-17 | 2006-06-21 | Denso Corp | ELECTROLYTIC PHOSPHATING PROCESS AND COMPOSITE COATINGS APPLIED TO A STEEL SURFACE |
| JP4072304B2 (ja) | 2000-05-12 | 2008-04-09 | 新日本製鐵株式会社 | 環境適合性に優れた自動車用燃料容器材料および自動車用燃料容器 |
| US6696106B1 (en) | 2002-09-11 | 2004-02-24 | Alcoa Inc. | Primer for radiation curable coating compositions |
| JP4205939B2 (ja) * | 2002-12-13 | 2009-01-07 | 日本パーカライジング株式会社 | 金属の表面処理方法 |
| CN1312214C (zh) * | 2003-02-24 | 2007-04-25 | 巴斯福股份公司 | 用于处理金属表面的含羧基聚合物 |
| ATE338090T1 (de) | 2003-02-24 | 2006-09-15 | Basf Ag | Carboxylat-haltige polymere für die metalloberflächenbehandlung |
| EP1618229A2 (en) * | 2003-04-25 | 2006-01-25 | Elisha Holding LLC | Method for preparing and using silicate systems to treat electrically conductive surfaces and products obtained therefrom |
| KR100489640B1 (ko) * | 2003-05-01 | 2005-05-17 | 한국과학기술연구원 | 양극산화처리용 전해질 용액 및 이를 이용하는 마그네슘합금의 내부식 코팅 방법 |
| JP4141393B2 (ja) * | 2004-02-18 | 2008-08-27 | トヨタ自動車株式会社 | 外装意匠部品および製造方法、検査方法 |
| US20080057336A1 (en) * | 2004-06-22 | 2008-03-06 | Toyo Seikan Kaisha, Ltd | Surface-Treated Metal Materials, Method of Treating the Surfaces Thereof, Resin-Coated Metal Materials, Cans and Can Lids |
| US7101469B2 (en) * | 2004-11-10 | 2006-09-05 | Atotech Deutschland Gmbh | Metal pieces and articles having improved corrosion resistance |
| JP4242827B2 (ja) * | 2004-12-08 | 2009-03-25 | 日本パーカライジング株式会社 | 金属の表面処理用組成物、表面処理用処理液、表面処理方法、及び表面処理金属材料 |
| FR2884458B1 (fr) | 2005-04-13 | 2010-09-24 | Heuliez | Toit mobile et vehicule ainsi equipe |
| EP1712300A1 (en) * | 2005-04-13 | 2006-10-18 | Enthone Inc. | Method for coating metal surfaces with corrosion inhibiting polymer layers |
| DE102005020767A1 (de) * | 2005-05-02 | 2006-11-09 | Eckart Gmbh & Co. Kg | Anodischer Elektrotauchlack, dessen Herstellung und Verwendung, Verwendung von plättchenförmigem Metallpigment und beschichteter Gegenstand |
| JP5186763B2 (ja) * | 2006-12-11 | 2013-04-24 | 新日鐵住金株式会社 | 摺動性および耐食性に優れたＮｉメッキ鋼板およびその製造方法 |
-
2008
- 2008-11-14 EP EP08019899A patent/EP2186928A1/en not_active Withdrawn
-
2009
- 2009-02-19 EP EP09002335A patent/EP2189553A1/en not_active Withdrawn
- 2009-03-26 WO PCT/US2009/038348 patent/WO2010056386A1/en not_active Ceased
- 2009-11-13 EP EP09760050.6A patent/EP2366041B1/en active Active
- 2009-11-13 US US13/129,300 patent/US9222189B2/en active Active
- 2009-11-13 CN CN200980154659.XA patent/CN102282296B/zh active Active
- 2009-11-13 KR KR1020117013372A patent/KR101639830B1/ko active Active
- 2009-11-13 JP JP2011536518A patent/JP5608668B2/ja active Active
- 2009-11-13 WO PCT/US2009/064394 patent/WO2010057001A2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| WO2010057001A2 (en) | 2010-05-20 |
| CN102282296A (zh) | 2011-12-14 |
| KR20110084529A (ko) | 2011-07-25 |
| EP2366041A2 (en) | 2011-09-21 |
| EP2366041B1 (en) | 2016-02-10 |
| WO2010056386A1 (en) | 2010-05-20 |
| KR101639830B1 (ko) | 2016-07-14 |
| US20110272284A1 (en) | 2011-11-10 |
| JP2012508821A (ja) | 2012-04-12 |
| CN102282296B (zh) | 2014-10-15 |
| EP2186928A1 (en) | 2010-05-19 |
| US9222189B2 (en) | 2015-12-29 |
| WO2010057001A3 (en) | 2010-08-19 |
| EP2189553A1 (en) | 2010-05-26 |
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