JP5039549B2 - 三次元物体のための支持構造を作成するための原料 - Google Patents

三次元物体のための支持構造を作成するための原料 Download PDF

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Publication number
JP5039549B2
JP5039549B2 JP2007523635A JP2007523635A JP5039549B2 JP 5039549 B2 JP5039549 B2 JP 5039549B2 JP 2007523635 A JP2007523635 A JP 2007523635A JP 2007523635 A JP2007523635 A JP 2007523635A JP 5039549 B2 JP5039549 B2 JP 5039549B2
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Prior art keywords
alkali
soluble
raw material
plasticizer
support
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Expired - Lifetime
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JP2007523635A
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Japanese (ja)
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JP2008507619A5 (cg-RX-API-DMAC7.html
JP2008507619A (ja
Inventor
ウイリアム アール. ジュニア プリーデマン
アンドレア エル. ブローシュ
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Stratasys Inc
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Stratasys Inc
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016Plasticisers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/02Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
    • B29C41/08Coating a former, core or other substrate by spraying or fluidisation, e.g. spraying powder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/34Component parts, details or accessories; Auxiliary operations
    • B29C41/36Feeding the material on to the mould, core or other substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/34Component parts, details or accessories; Auxiliary operations
    • B29C41/50Shaping under special conditions, e.g. vacuum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10Processes of additive manufacturing
    • B29C64/106Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10Processes of additive manufacturing
    • B29C64/106Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • B29C64/118Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/40Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2055/00Use of specific polymers obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in a single one of main groups B29K2023/00 - B29K2049/00, e.g. having a vinyl group, as moulding material
    • B29K2055/02ABS polymers, i.e. acrylonitrile-butadiene-styrene polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0005Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
    • B29K2105/0008Anti-static agents

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
JP2007523635A 2004-07-26 2005-07-15 三次元物体のための支持構造を作成するための原料 Expired - Lifetime JP5039549B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/898,814 US7754807B2 (en) 1999-04-20 2004-07-26 Soluble material and process for three-dimensional modeling
US10/898,814 2004-07-26
PCT/US2005/025507 WO2006020279A2 (en) 2004-07-26 2005-07-15 Soluble material and process for three-dimensional modeling

Publications (3)

Publication Number Publication Date
JP2008507619A JP2008507619A (ja) 2008-03-13
JP2008507619A5 JP2008507619A5 (cg-RX-API-DMAC7.html) 2008-09-04
JP5039549B2 true JP5039549B2 (ja) 2012-10-03

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JP2007523635A Expired - Lifetime JP5039549B2 (ja) 2004-07-26 2005-07-15 三次元物体のための支持構造を作成するための原料

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Country Link
US (2) US7754807B2 (cg-RX-API-DMAC7.html)
EP (1) EP1773560A2 (cg-RX-API-DMAC7.html)
JP (1) JP5039549B2 (cg-RX-API-DMAC7.html)
CN (1) CN101027170A (cg-RX-API-DMAC7.html)
WO (1) WO2006020279A2 (cg-RX-API-DMAC7.html)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10988603B2 (en) 2015-09-29 2021-04-27 Kyoraku Co., Ltd. Molded resin strand
US11141901B2 (en) 2015-03-31 2021-10-12 Kyoraku Co., Ltd. Molded resin strand, method for modeling three-dimensional object, and method for manufacturing molded resin strand
US11332627B2 (en) 2017-01-31 2022-05-17 Kyoraku Co., Ltd. Filament resin molded article

Families Citing this family (128)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7754807B2 (en) * 1999-04-20 2010-07-13 Stratasys, Inc. Soluble material and process for three-dimensional modeling
US7658603B2 (en) * 2005-03-31 2010-02-09 Board Of Regents, The University Of Texas System Methods and systems for integrating fluid dispensing technology with stereolithography
US7780897B2 (en) * 2005-04-22 2010-08-24 Board Of Regents, The University Of Texas System Hydrogel constructs using stereolithography
FR2893018B1 (fr) * 2005-11-09 2008-03-14 Commissariat Energie Atomique Procede de formation de supports presentant des motifs, tels que des masques de lithographie.
US7896209B2 (en) * 2008-04-30 2011-03-01 Stratasys, Inc. Filament drive mechanism for use in extrusion-based digital manufacturing systems
US7897074B2 (en) * 2008-04-30 2011-03-01 Stratasys, Inc. Liquefier assembly for use in extrusion-based digital manufacturing systems
US8155775B2 (en) * 2008-10-02 2012-04-10 Stratasys, Inc. Support structure packaging
US8246888B2 (en) * 2008-10-17 2012-08-21 Stratasys, Inc. Support material for digital manufacturing systems
CN102369243B (zh) 2009-03-19 2014-11-05 界面解决方案Ip有限责任公司 生物基聚合物组合物
WO2011005492A1 (en) * 2009-06-23 2011-01-13 Stratasys, Inc. Consumable materials having customized characteristics
JP2011005668A (ja) * 2009-06-23 2011-01-13 Altech Co Ltd サポート材除去装置
JP2011005666A (ja) * 2009-06-23 2011-01-13 Altech Co Ltd 循環式サポート材除去装置
JP2011005667A (ja) * 2009-06-23 2011-01-13 Altech Co Ltd サポート材除去装置
US8236227B2 (en) * 2009-09-30 2012-08-07 Stratasys, Inc. Method for building three-dimensional models in extrusion-based digital manufacturing systems using tracked filaments
EP2521625A2 (en) * 2010-01-05 2012-11-14 Stratasys, Inc. Support cleaning system
US8983643B2 (en) * 2010-01-15 2015-03-17 Stratasys, Inc. Method for generating and building support structures with deposition-based digital manufacturing systems
US8920697B2 (en) 2010-09-17 2014-12-30 Stratasys, Inc. Method for building three-dimensional objects in extrusion-based additive manufacturing systems using core-shell consumable filaments
CA2809278C (en) 2010-09-17 2015-10-20 Stratasys, Inc. Semi-crystalline consumable materials for use in extrusion-based additive manufacturing systems
CN103180125B (zh) 2010-10-27 2017-03-01 雷兹公司 用于制作三维物体的工艺和设备
ES2625878T3 (es) * 2010-10-29 2017-07-20 Bellandtechnology Ag Copolímero soluble en agua o desintegrable en agua
JP5890990B2 (ja) * 2010-11-01 2016-03-22 株式会社キーエンス インクジェット光造形法における、光造形品形成用モデル材、光造形品の光造形時の形状支持用サポート材および光造形品の製造方法
USD682490S1 (en) 2011-01-05 2013-05-14 Stratasys, Inc. Support cleaning system
US8512024B2 (en) 2011-01-20 2013-08-20 Makerbot Industries, Llc Multi-extruder
US8460755B2 (en) 2011-04-07 2013-06-11 Stratasys, Inc. Extrusion-based additive manufacturing process with part annealing
EP2514775A1 (en) 2011-04-20 2012-10-24 Evonik Röhm GmbH Maleic anhydride copolymers as soluble support material for fused deposition modelling (FDM) printer
WO2012151494A2 (en) 2011-05-05 2012-11-08 Interfacial Solutions Ip, Llc Radiation curable polymers
US8865047B2 (en) * 2011-05-31 2014-10-21 Stratasys Ltd. Solid freeform fabrication of easily removeable support constructions
US8459280B2 (en) 2011-09-23 2013-06-11 Stratasys, Inc. Support structure removal system
US8975305B2 (en) 2012-02-10 2015-03-10 Kimberly-Clark Worldwide, Inc. Rigid renewable polyester compositions having a high impact strength and tensile elongation
CA2865655C (en) 2012-02-27 2018-05-22 Red River College Method for making an article from a curable material
US9364986B1 (en) 2012-05-22 2016-06-14 Rapid Prototype and Manufacturing LLC Method for three-dimensional manufacturing and high density articles produced thereby
US9708457B2 (en) 2012-06-28 2017-07-18 Stratasys, Inc. Moisture scavenger composition
US9172829B2 (en) * 2012-07-31 2015-10-27 Makerbot Industries, Llc Three-dimensional printer with laser line scanner
US10029415B2 (en) * 2012-08-16 2018-07-24 Stratasys, Inc. Print head nozzle for use with additive manufacturing system
US9744722B2 (en) * 2012-11-21 2017-08-29 Stratasys, Inc. Additive manufacturing with polyamide consumable materials
US12064917B2 (en) 2012-11-21 2024-08-20 Stratasys, Inc. Method for printing three-dimensional parts with cyrstallization kinetics control
US10023739B2 (en) 2012-11-21 2018-07-17 Stratasys, Inc. Semi-crystalline build materials
US9925714B2 (en) 2012-11-21 2018-03-27 Stratasys, Inc. Method for printing three-dimensional items wtih semi-crystalline build materials
US9527242B2 (en) 2012-11-21 2016-12-27 Stratasys, Inc. Method for printing three-dimensional parts wtih crystallization kinetics control
US10144828B2 (en) 2012-11-21 2018-12-04 Stratasys, Inc. Semi-crystalline build materials
US9592530B2 (en) 2012-11-21 2017-03-14 Stratasys, Inc. Additive manufacturing with polyamide consumable materials
US20140232035A1 (en) 2013-02-19 2014-08-21 Hemant Bheda Reinforced fused-deposition modeling
US20140363532A1 (en) * 2013-06-10 2014-12-11 Kirk W. Wolfgram Multiple color extrusion type three dimensional printer
US9498593B2 (en) 2013-06-17 2016-11-22 MetaMason, Inc. Customized medical devices and apparel
US9523934B2 (en) 2013-07-17 2016-12-20 Stratasys, Inc. Engineering-grade consumable materials for electrophotography-based additive manufacturing
US9023566B2 (en) * 2013-07-17 2015-05-05 Stratasys, Inc. ABS part material for electrophotography-based additive manufacturing
US9745458B2 (en) 2013-07-26 2017-08-29 Hewlett-Packard Development Company, L.P. Composite support material for three-dimensional printing
US9714318B2 (en) 2013-07-26 2017-07-25 Stratasys, Inc. Polyglycolic acid support material for additive manufacturing systems
CN103395209A (zh) * 2013-08-08 2013-11-20 西安非凡士机器人科技有限公司 大型fdm原理的3d打印机
WO2015019201A1 (en) 2013-08-09 2015-02-12 Kimberly-Clark Worldwide, Inc. Anisotropic polymeric material
KR102224569B1 (ko) 2013-08-09 2021-03-08 킴벌리-클라크 월드와이드, 인크. 중합체 물질의 다공성을 선택적으로 제어하기 위한 기술
RU2634255C2 (ru) 2013-08-09 2017-10-24 Кимберли-Кларк Ворлдвайд, Инк. Система доставки для активных средств
KR102334602B1 (ko) 2013-08-09 2021-12-06 킴벌리-클라크 월드와이드, 인크. 형상 보유 특성을 구비한 연성 중합체 물질
AU2014304190B2 (en) 2013-08-09 2018-02-15 Kimberly-Clark Worldwide, Inc. Polymeric material for three-dimensional printing
EP3030609B1 (en) 2013-08-09 2020-09-02 Kimberly-Clark Worldwide, Inc. Microparticles having a multimodal pore distribution
US9669586B2 (en) 2013-10-01 2017-06-06 Autodesk, Inc. Material dispensing system
USD749157S1 (en) * 2014-01-05 2016-02-09 Makerbot Industries, Llc Three-dimensional printer extruder carriage
WO2015108770A1 (en) 2014-01-16 2015-07-23 Dow Global Technologies Llc Recovery of additive manufacturing support materials
US9102099B1 (en) 2014-02-05 2015-08-11 MetaMason, Inc. Methods for additive manufacturing processes incorporating active deposition
US20150266235A1 (en) 2014-03-19 2015-09-24 Autodesk, Inc. Systems and methods for improved 3d printing
US9895841B2 (en) 2014-05-09 2018-02-20 Autodesk, Inc. User specific design customization for 3D printing
CN106715100B (zh) 2014-05-09 2019-11-15 苏州聚复高分子材料有限公司 用于材料挤出式增材制造的高结晶聚乳酸线材
US10675853B2 (en) * 2014-05-16 2020-06-09 Stratasys, Inc. High-temperature soluble support material for additive manufacturing
US9796140B2 (en) 2014-06-19 2017-10-24 Autodesk, Inc. Automated systems for composite part fabrication
US9533449B2 (en) 2014-06-19 2017-01-03 Autodesk, Inc. Material deposition systems with four or more axes
WO2016037563A1 (en) 2014-09-09 2016-03-17 Jf Polymers (Suzhou) Co., Ltd. Polymeric composition for use as a temporary support material in extrusion based additive manufacturing
JP6491467B2 (ja) 2014-10-14 2019-03-27 花王株式会社 三次元造形用可溶性材料
JP5972335B2 (ja) 2014-10-14 2016-08-17 花王株式会社 三次元造形用可溶性材料
US10059053B2 (en) 2014-11-04 2018-08-28 Stratasys, Inc. Break-away support material for additive manufacturing
GB201420870D0 (en) 2014-11-24 2015-01-07 Ngf Europ Ltd And Pilkington Group Ltd Printed article and a feedstock
KR102248466B1 (ko) 2015-01-26 2021-05-04 케이제이 케미칼즈 가부시키가이샤 3차원 조형 서포트재용 활성 에너지선 경화성 수지 조성물, 3차원 조형용 잉크젯 잉크 조성물 및 서포트재
CN107107474B (zh) 2015-02-06 2019-11-12 科巨希化学股份公司 立体造型物的制造方法以及使用其的立体造型物
EP3254836B1 (en) * 2015-02-06 2020-06-10 Kao Corporation Three-dimensional-modeling soluble material
US10118346B2 (en) * 2015-03-10 2018-11-06 Oce-Technologies B.V. Method for printing 3D structures
KR101619696B1 (ko) * 2015-03-16 2016-05-10 엘지전자 주식회사 3d 프린터
EP3287264B1 (en) 2015-04-20 2020-07-08 MCPP Innovation LLC Shaping filament for material extrusion type three-dimensional printer, and process for producing shaped object
JP6025912B1 (ja) * 2015-05-19 2016-11-16 花王株式会社 サポート材溶解廃液からの水溶性ポリエステル樹脂の回収方法
KR101680334B1 (ko) * 2015-06-15 2016-11-29 주식회사 퓨쳐캐스트 3차원 프린팅 방식을 이용한 금형 제작방법
KR102064816B1 (ko) * 2015-06-19 2020-01-10 스트래터시스,인코포레이티드 적층 제조에 사용되는 수계 분산형 중합체
JP2017019905A (ja) * 2015-07-08 2017-01-26 富士ゼロックス株式会社 三次元造形材、三次元造形用支持材、三次元造形用組成物セット、三次元造形材カートリッジ、三次元造形用支持材カートリッジ、三次元造形用カートリッジセット、三次元造形装置、及び三次元造形物の製造方法
EP3328930B1 (en) 2015-07-27 2019-05-29 Dow Global Technologies LLC Method to additive manufacture biocompatible material and articles made by the method
WO2017029658A1 (en) * 2015-08-14 2017-02-23 Stratasys Ltd. Cleaning composition
DE102015115821A1 (de) 2015-09-18 2017-03-23 Dyemansion Gmbh Verfahren zum Herstellen und zur Oberflächenbehandlung eines Formteils
CN108348311A (zh) 2015-11-13 2018-07-31 株式会社理光 三维成型材料组、三维成型物的制造方法和三维成型物的制造装置
WO2017082007A1 (ja) * 2015-11-13 2017-05-18 株式会社リコー 立体造形材料セット、立体造形物の製造方法、及び立体造形物の製造装置
EP3385333B1 (en) * 2015-12-01 2021-02-17 Ricoh Company, Ltd. Water-disintegrable resin composition, and three-dimensional modeling material set and method for producing three-dimensional model using same
JP2019501252A (ja) * 2015-12-11 2019-01-17 サビック グローバル テクノロジーズ ベスローテン フェンノートシャップ 付加製造プロセスにおいて層間接着性を改善するための接着促進層
JP6848180B2 (ja) * 2016-02-10 2021-03-24 株式会社リコー 立体造形用材料、立体造形用材料セット、立体造形物の製造方法、及び立体造形物の製造装置
JP2019513183A (ja) * 2016-02-16 2019-05-23 アリゾナ・ボード・オブ・リージェンツ・オン・ビハーフ・オブ・アリゾナ・ステイト・ユニバーシティーArizona Board of Regents on behalf of Arizona State University 様々な材料の溶解性サポートを用いる3dプリンティングを使用する金属製またはセラミックス製部品の製作
US9815118B1 (en) 2016-04-14 2017-11-14 Desktop Metal, Inc. Fabricating multi-part assemblies
WO2017199324A1 (ja) 2016-05-17 2017-11-23 花王株式会社 三次元物体前駆体処理剤組成物
JP6399165B1 (ja) 2016-07-22 2018-10-03 株式会社リコー 立体造形用樹脂粉末、立体造形物の製造装置、及び立体造形物の製造方法
ES2937741T3 (es) 2016-08-05 2023-03-30 Kao Corp Composición para tratar un precursor de objeto tridimensional
WO2018130668A2 (en) * 2017-01-12 2018-07-19 Sabic Global Technologies B.V. Build sheet for additive manufacturing
WO2018139537A1 (ja) 2017-01-30 2018-08-02 花王株式会社 三次元造形用可溶性材料
JP6359793B1 (ja) 2017-01-30 2018-07-18 花王株式会社 三次元造形用可溶性材料
JP6930176B2 (ja) * 2017-03-29 2021-09-01 株式会社リコー 立体造形用組成物のセット、立体造形物の製造方法、及び立体造形装置
EP3415563A1 (en) 2017-06-13 2018-12-19 Ricoh Company, Limited Resin powder for solid freeform fabrication, device for fabricating solid freeform fabrication object, and resin powder
WO2019013317A1 (ja) 2017-07-14 2019-01-17 花王株式会社 熱可塑性樹脂組成物の製造方法
JP7295093B2 (ja) * 2017-09-01 2023-06-20 ポリ-メド インコーポレイテッド 付加製造用重合体
US10603890B2 (en) 2017-09-15 2020-03-31 The Boeing Company Systems and methods for creating feedstock lines for additive manufacturing of an object
US10525635B2 (en) 2017-09-15 2020-01-07 The Boeing Company Systems and methods for creating feedstock lines for additive manufacturing of an object
US10105893B1 (en) * 2017-09-15 2018-10-23 The Boeing Company Feedstock lines for additive manufacturing of an object, and systems and methods for creating feedstock lines
US10611081B2 (en) 2017-09-15 2020-04-07 The Boeing Company Systems and methods for creating feedstock lines for additive manufacturing of an object
US10543645B2 (en) 2017-09-15 2020-01-28 The Boeing Company Feedstock lines for additive manufacturing of an object
US10618222B2 (en) 2017-09-15 2020-04-14 The Boeing Company Systems and methods for additively manufacturing an object
US10189237B1 (en) 2017-09-15 2019-01-29 The Boeing Company Feedstock lines for additive manufacturing of an object
WO2019075107A1 (en) 2017-10-10 2019-04-18 Stratasys, Inc. WATER-DISPERSIBLE THERMOPLASTIC MATERIAL COMPRISING A SULFINATED COPOLYMER FOR USE IN ADDITIVE MANUFACTURE
US10359764B1 (en) * 2017-12-29 2019-07-23 Palo Alto Research Center Incorporated System and method for planning support removal in hybrid manufacturing with the aid of a digital computer
CN111630144B (zh) 2018-02-22 2021-12-31 宝洁公司 用于制备单位剂量制品的方法
CN109228072B (zh) * 2018-07-10 2020-12-04 临沂文衡信息技术有限公司 一种塑料桶形成装置
US11203156B2 (en) 2018-08-20 2021-12-21 NEXA3D Inc. Methods and systems for photo-curing photo-sensitive material for printing and other applications
EP3864093A1 (en) * 2018-10-10 2021-08-18 Stratasys, Inc. Water dispersible sulfonated thermoplastic copolymer for use in additive manufacturing
CN113242787B (zh) 2018-11-09 2023-02-10 耐克森三维有限公司 三维打印系统
JP7101598B2 (ja) 2018-11-26 2022-07-15 花王株式会社 三次元物体前駆体処理剤組成物
EP3941714B1 (en) 2019-03-18 2023-03-08 Nexa3D Inc. Method and system for additive manufacturing
US10967573B2 (en) 2019-04-02 2021-04-06 NEXA3D Inc. Tank assembly and components thereof for a 3D printing system
KR20220065759A (ko) * 2019-07-23 2022-05-20 어댑티브 3디 테크놀로지스 엘엘씨 3d 프린팅을 위한 티올-아크릴레이트 엘라스토머
JP2023507985A (ja) 2019-12-17 2023-02-28 ティコナ・エルエルシー サーモトロピック液晶ポリマーを利用する三次元印刷システム
US12234364B2 (en) 2019-12-17 2025-02-25 Ticona Llc Three-dimensional printing system employing a thermally conductive polymer composition
EP3865302B1 (en) * 2020-02-14 2024-08-14 iSQUARED AG Copolymer for use in a digital manufacturing process
US12157800B2 (en) 2021-04-12 2024-12-03 Stratasys, Inc. Method for underwater processing of water-dispersible materials
WO2022225815A1 (en) 2021-04-19 2022-10-27 Jabil Inc. Improved additive manufacturing break away support material
US20250010542A1 (en) 2021-11-12 2025-01-09 Polyfos 3D Ltd Vat polymerization process
CN118679061A (zh) 2021-12-31 2024-09-20 埃肯有机硅(上海)有限公司 用于增材制造的双组份有机硅组合物
US20240009934A1 (en) * 2022-07-07 2024-01-11 Xerox Corporation Fracturable support structure and method of forming the structure
WO2024076464A1 (en) 2022-10-03 2024-04-11 Jabil Inc. Additive manufactured article comprising a grafted aliphatic polyketone, filament and powder
JP2025003106A (ja) * 2023-06-23 2025-01-09 セイコーエプソン株式会社 サポート材除去装置及びサポート材除去方法

Family Cites Families (108)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE553136A (cg-RX-API-DMAC7.html) 1955-12-08
US3016451A (en) * 1957-06-04 1962-01-09 Auto Arc Weld Mfg Co Electrode feed roll means
BE632939A (cg-RX-API-DMAC7.html) * 1962-08-08
US3381812A (en) * 1966-08-04 1968-05-07 Anaconda Wire & Cable Co Weathertight reel for pipe-type cable
GB1418901A (en) * 1972-03-30 1975-12-24 Simon W H Outlet bodies for reel housings
US3917090A (en) * 1973-11-02 1975-11-04 Pitney Bowes Inc Postage meter tape recepticle system
US4152367A (en) * 1977-08-04 1979-05-01 Bayer Aktiengesellschaft Branched polyaryl-sulphone/polycarbonate mixtures and their use for the production of extruded films
DE3000516A1 (de) 1980-01-09 1981-07-16 Roland Dipl.-Kfm. 7022 Leinfelden-Echterdingen Belz Verbundfolie, insbesondere toilettensitzauflage, sowie verfahren und vorrichtung zu ihrer herstellung
DE3126979A1 (de) 1980-01-09 1982-09-30 Roland Dipl.-Kfm. 7022 Leinfelden-Echterdingen Belz Verbundfolie
US4397986A (en) 1982-03-03 1983-08-09 Ethyl Corporation Thermoplastic polyester blends
DE3335954A1 (de) 1983-10-04 1985-04-04 Roland Dipl.-Kaufm. 7022 Leinfelden-Echterdingen Belz Verfahren zur durchfuehrung von chemischen reaktionen, insbesondere zur herstellung von kunststoffen mit hilfe von extrudern und anlage hierzu
US4665492A (en) * 1984-07-02 1987-05-12 Masters William E Computer automated manufacturing process and system
US4749347A (en) * 1985-08-29 1988-06-07 Viljo Valavaara Topology fabrication apparatus
ES2063737T3 (es) * 1986-06-03 1995-01-16 Cubital Ltd Aparato y metodo para modelizacion tridimensional.
US4886856A (en) 1986-08-21 1989-12-12 The Dow Chemical Company Functionalized elastomers blended with polar copolymers of styrene and acrylic acid methacrylic acid or maleic anhydride
US5322878A (en) 1987-10-28 1994-06-21 Belland Ag Carboxylated molding copolymers
US4844373A (en) * 1987-12-18 1989-07-04 Fike Sr Richard A Line storage and dispensing device
US4928897A (en) * 1988-01-18 1990-05-29 Fuji Photo Film Co., Ltd. Feeder for feeding photosensitive material
US5169548A (en) * 1988-04-13 1992-12-08 Ausimont S.R.L. Antirust additives for lubricants or greases based on perfluoropolyethers
US5141680A (en) * 1988-04-18 1992-08-25 3D Systems, Inc. Thermal stereolighography
US4898314A (en) * 1988-10-20 1990-02-06 International Business Machines Corporation Method and apparatus for stitcher wire loading
GB2229702B (en) * 1989-02-04 1992-09-30 Draftex Ind Ltd Strip handling apparatus
US5830087A (en) * 1995-06-26 1998-11-03 Lisco, Inc. Multi-layer golf ball
GB2233928B (en) * 1989-05-23 1992-12-23 Brother Ind Ltd Apparatus and method for forming three-dimensional article
JP2738017B2 (ja) * 1989-05-23 1998-04-08 ブラザー工業株式会社 三次元成形装置
US5216616A (en) * 1989-06-26 1993-06-01 Masters William E System and method for computer automated manufacture with reduced object shape distortion
US5134569A (en) * 1989-06-26 1992-07-28 Masters William E System and method for computer automated manufacturing using fluent material
JPH0336019A (ja) * 1989-07-03 1991-02-15 Brother Ind Ltd 三次元成形方法およびその装置
US5121329A (en) 1989-10-30 1992-06-09 Stratasys, Inc. Apparatus and method for creating three-dimensional objects
US5136515A (en) * 1989-11-07 1992-08-04 Richard Helinski Method and means for constructing three-dimensional articles by particle deposition
US5204055A (en) * 1989-12-08 1993-04-20 Massachusetts Institute Of Technology Three-dimensional printing techniques
US5257657A (en) * 1990-07-11 1993-11-02 Incre, Inc. Method for producing a free-form solid-phase object from a material in the liquid phase
DE4023910A1 (de) 1990-07-27 1992-01-30 Belland Ag Verfahren zur wiedergewinnung von in waessrig alkalischem oder saurem milieu aufloesbaren polymeren
JP2597778B2 (ja) * 1991-01-03 1997-04-09 ストラタシイス,インコーポレイテッド 三次元対象物組み立てシステム及び組み立て方法
US5594652A (en) * 1991-01-31 1997-01-14 Texas Instruments Incorporated Method and apparatus for the computer-controlled manufacture of three-dimensional objects from computer data
US6175422B1 (en) * 1991-01-31 2001-01-16 Texas Instruments Incorporated Method and apparatus for the computer-controlled manufacture of three-dimensional objects from computer data
US5474719A (en) * 1991-02-14 1995-12-12 E. I. Du Pont De Nemours And Company Method for forming solid objects utilizing viscosity reducible compositions
US5217795A (en) 1991-08-13 1993-06-08 Kimberly-Clark Corporation Polymeric web compositions having improved alkaline solubility for use as fibers
DE4202248A1 (de) 1992-01-28 1993-07-29 Belland Ag Verfahren zur wiedergewinnung von in waessrig alkalischem oder saurem milieu geloesten polymeren
US5263585A (en) * 1992-05-07 1993-11-23 Myriadlase, Inc. Package for an elongated flexible fiber
US5293996A (en) * 1992-05-14 1994-03-15 Motorola, Inc. Container having an observation window
US5304433A (en) * 1992-09-28 1994-04-19 Gnb Battery Technologies Inc. Capacity indicator for lead-acid batteries
JP2558431B2 (ja) * 1993-01-15 1996-11-27 ストラタシイス,インコーポレイテッド 3次元構造体を製造するシステムを作動する方法及び3次元構造体製造装置
US5312224A (en) * 1993-03-12 1994-05-17 International Business Machines Corporation Conical logarithmic spiral viscosity pump
DE4310884A1 (de) * 1993-04-02 1994-10-06 Huels Chemische Werke Ag Mehrschichtiges Kunststoffrohr
US5765740A (en) * 1993-12-30 1998-06-16 Ferguson; Patrick J. Suture-material-dispenser system for suture material
JPH07256764A (ja) * 1994-03-25 1995-10-09 Sekisui Chem Co Ltd 紫外線硬化型画像形成シ−トの製造方法
US5503785A (en) * 1994-06-02 1996-04-02 Stratasys, Inc. Process of support removal for fused deposition modeling
JPH0827305A (ja) * 1994-07-13 1996-01-30 Fuji Photo Film Co Ltd 写真感光材料の包装材料用着色マスターバッチ樹脂組成物及びその製造方法並びに写真感光材料用包装材料及びその製造方法
US5622216A (en) * 1994-11-22 1997-04-22 Brown; Stuart B. Method and apparatus for metal solid freeform fabrication utilizing partially solidified metal slurry
EP0742585A1 (en) 1995-05-08 1996-11-13 E.I. Du Pont De Nemours And Company Method and compositions for diffusion patterning tape on substrate
US5653925A (en) 1995-09-26 1997-08-05 Stratasys, Inc. Method for controlled porosity three-dimensional modeling
US5943235A (en) * 1995-09-27 1999-08-24 3D Systems, Inc. Rapid prototyping system and method with support region data processing
US6133355A (en) * 1995-09-27 2000-10-17 3D Systems, Inc. Selective deposition modeling materials and method
US6270335B2 (en) 1995-09-27 2001-08-07 3D Systems, Inc. Selective deposition modeling method and apparatus for forming three-dimensional objects and supports
US5764521A (en) * 1995-11-13 1998-06-09 Stratasys Inc. Method and apparatus for solid prototyping
US5738817A (en) * 1996-02-08 1998-04-14 Rutgers, The State University Solid freeform fabrication methods
US6085957A (en) * 1996-04-08 2000-07-11 Stratasys, Inc. Volumetric feed control for flexible filament
DE19639347A1 (de) 1996-09-25 1998-03-26 Belland Ag Zweiphasige, in wäßrigem Alkali auflösbare Polymerkombination und Verfahren zu ihrer Herstellung
DE19644176A1 (de) 1996-10-24 1998-04-30 Belland Ag Packung, enthaltend einen trockenen alkalischen Feststoff
US6070107A (en) * 1997-04-02 2000-05-30 Stratasys, Inc. Water soluble rapid prototyping support and mold material
US6067480A (en) * 1997-04-02 2000-05-23 Stratasys, Inc. Method and apparatus for in-situ formation of three-dimensional solid objects by extrusion of polymeric materials
US6228923B1 (en) 1997-04-02 2001-05-08 Stratasys, Inc. Water soluble rapid prototyping support and mold material
JPH10307402A (ja) * 1997-05-09 1998-11-17 Fuji Photo Film Co Ltd ネガ型感光材料
US5866058A (en) * 1997-05-29 1999-02-02 Stratasys Inc. Method for rapid prototyping of solid models
US6119567A (en) * 1997-07-10 2000-09-19 Ktm Industries, Inc. Method and apparatus for producing a shaped article
US5932055A (en) * 1997-11-11 1999-08-03 Rockwell Science Center Llc Direct metal fabrication (DMF) using a carbon precursor to bind the "green form" part and catalyze a eutectic reducing element in a supersolidus liquid phase sintering (SLPS) process
US5939008A (en) * 1998-01-26 1999-08-17 Stratasys, Inc. Rapid prototyping apparatus
US6004124A (en) * 1998-01-26 1999-12-21 Stratasys, Inc. Thin-wall tube liquifier
US5968561A (en) * 1998-01-26 1999-10-19 Stratasys, Inc. High performance rapid prototyping system
US6022207A (en) * 1998-01-26 2000-02-08 Stratasys, Inc. Rapid prototyping system with filament supply spool monitoring
US6027068A (en) * 1998-03-19 2000-02-22 New Millennium Products, Inc. Dispenser for solder and other ductile strand materials
TW500765B (en) * 1998-05-13 2002-09-01 Sumitomo Chemical Co Thermoplastic resin composition and heat-resistant tray for IC
US6095323A (en) * 1998-06-12 2000-08-01 Ferguson; Patrick J. Suture-material-dispenser system for suture material
US6322728B1 (en) * 1998-07-10 2001-11-27 Jeneric/Pentron, Inc. Mass production of dental restorations by solid free-form fabrication methods
US6129872A (en) * 1998-08-29 2000-10-10 Jang; Justin Process and apparatus for creating a colorful three-dimensional object
US6161077A (en) * 1999-01-05 2000-12-12 Hubbell Incorporated Partial discharge site location system for determining the position of faults in a high voltage cable
US6054077A (en) * 1999-01-11 2000-04-25 Stratasys, Inc. Velocity profiling in an extrusion apparatus
US6261077B1 (en) 1999-02-08 2001-07-17 3D Systems, Inc. Rapid prototyping apparatus with enhanced thermal and/or vibrational stability for production of three dimensional objects
US6162378A (en) * 1999-02-25 2000-12-19 3D Systems, Inc. Method and apparatus for variably controlling the temperature in a selective deposition modeling environment
US7314591B2 (en) 2001-05-11 2008-01-01 Stratasys, Inc. Method for three-dimensional modeling
US6645412B2 (en) * 1999-04-20 2003-11-11 Stratasys, Inc. Process of making a three-dimensional object
US7754807B2 (en) 1999-04-20 2010-07-13 Stratasys, Inc. Soluble material and process for three-dimensional modeling
US6776602B2 (en) 1999-04-20 2004-08-17 Stratasys, Inc. Filament cassette and loading system
US6790403B1 (en) * 1999-04-20 2004-09-14 Stratasys, Inc. Soluble material and process for three-dimensional modeling
US6165406A (en) * 1999-05-27 2000-12-26 Nanotek Instruments, Inc. 3-D color model making apparatus and process
DE60042117D1 (de) 1999-06-23 2009-06-10 Stratasys Inc Hochtemperatur rapid prototyping vorrichtung
US6722872B1 (en) * 1999-06-23 2004-04-20 Stratasys, Inc. High temperature modeling apparatus
US6257517B1 (en) * 1999-08-10 2001-07-10 Sandvik Steel Co. Method and apparatus for feeding welding wire
US6214279B1 (en) 1999-10-02 2001-04-10 Nanotek Instruments, Inc. Apparatus and process for freeform fabrication of composite reinforcement preforms
JP4296691B2 (ja) * 2000-06-01 2009-07-15 コニカミノルタホールディングス株式会社 画像形成方法
US6730252B1 (en) * 2000-09-20 2004-05-04 Swee Hin Teoh Methods for fabricating a filament for use in tissue engineering
US6572807B1 (en) 2000-10-26 2003-06-03 3D Systems, Inc. Method of improving surfaces in selective deposition modeling
US7568445B2 (en) 2000-11-17 2009-08-04 Lockheed Martin Corporation System and method for the holographic deposition of material
US6866807B2 (en) 2001-09-21 2005-03-15 Stratasys, Inc. High-precision modeling filament
US6814907B1 (en) 2001-12-18 2004-11-09 Stratasys, Inc. Liquifier pump control in an extrusion apparatus
US7255821B2 (en) * 2002-04-17 2007-08-14 Stratasys, Inc. Layered deposition bridge tooling
WO2003089218A1 (en) 2002-04-17 2003-10-30 Stratasys, Inc. Smoothing method for layered deposition modeling
US6907307B2 (en) 2002-07-02 2005-06-14 3D Systems, Inc. Support volume calculation for a CAD model
US6869559B2 (en) 2003-05-05 2005-03-22 Stratasys, Inc. Material and method for three-dimensional modeling
DE10348222A1 (de) 2003-10-10 2005-05-04 Belland Ag Biberist Klebstoff und seine Verwendung
US7546841B2 (en) 2003-11-19 2009-06-16 David Jonathan Tafoya Apparatus and method of removing water soluble support material from a rapid prototype part
KR100626955B1 (ko) 2004-08-27 2006-09-20 주식회사 엘지화학 저광택성과 내충격성이 우수한 스티렌계 열가소성 수지조성물
US7384255B2 (en) 2005-07-01 2008-06-10 Stratasys, Inc. Rapid prototyping system with controlled material feedstock
US7604470B2 (en) 2006-04-03 2009-10-20 Stratasys, Inc. Single-motor extrusion head having multiple extrusion lines
JP5039795B2 (ja) 2007-02-12 2012-10-03 ストラタシス,インコーポレイテッド 押出型堆積システムのための粘性ポンプ
US7625200B2 (en) 2007-07-31 2009-12-01 Stratasys, Inc. Extrusion head for use in extrusion-based layered deposition modeling
US8246888B2 (en) 2008-10-17 2012-08-21 Stratasys, Inc. Support material for digital manufacturing systems

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11141901B2 (en) 2015-03-31 2021-10-12 Kyoraku Co., Ltd. Molded resin strand, method for modeling three-dimensional object, and method for manufacturing molded resin strand
US10988603B2 (en) 2015-09-29 2021-04-27 Kyoraku Co., Ltd. Molded resin strand
US11332627B2 (en) 2017-01-31 2022-05-17 Kyoraku Co., Ltd. Filament resin molded article

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