JP4274939B2 - カラー印刷した積層構造体、それを包含する吸収性物品、及びその製造方法 - Google Patents
カラー印刷した積層構造体、それを包含する吸収性物品、及びその製造方法 Download PDFInfo
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- JP4274939B2 JP4274939B2 JP2003528387A JP2003528387A JP4274939B2 JP 4274939 B2 JP4274939 B2 JP 4274939B2 JP 2003528387 A JP2003528387 A JP 2003528387A JP 2003528387 A JP2003528387 A JP 2003528387A JP 4274939 B2 JP4274939 B2 JP 4274939B2
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- Health & Medical Sciences (AREA)
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Description
当該技術分野における代表的なものには、次の参照が挙げられる。
米国特許第5,458,590号明細書は、一対の対向する表面を含む不織布繊維質ウェブを含む、インキ印刷した不織布繊維質ウェブを開示し、絵柄が前記表面の一表面上にインキで印刷され、前記不織布繊維質ウェブが、少なくとも約4以上の平均湿潤色落ち堅牢値を有する。米国特許第5,458,590号明細書はまた、トップシート、バックシート、及び吸収性複合物を備える使い捨て吸収性物品を開示し、バックシートはそのようなインキ印刷した不織布繊維質ウェブを含む。
本明細書で使用する用語「吸収性物品」は、体の排泄物を吸収及び封じ込める物品を包含する。より詳細には、この用語は、ユーザの体から排泄される種々の排泄物を吸収及び封じ込めるためにユーザの体に密着または近接して配置される物品に関する。用語「吸収性物品」は、乳幼児用おむつ、生理用ナプキン、パンティーライナー、失禁者用製品を含むことを意図している。しかし、汗吸収腋窩パッド、授乳パッド、襟挿入物、吸収性傷包帯、及び体液または排泄物を吸収するために使用されるあらゆる他の物品も、本発明から便益を得ることができる。
本発明は、流体、典型的には体液を獲得、拡散、及び吸収することを主に意図するカラー印刷した液体透過性(繊維質)積層構造体に関する。この構造体は、少なくとも2層、すなわちその表面の少なくとも一表面上でカラー印刷されている第1層と、第2層、いわゆる繊維質ウェブとを含む。本明細書の好ましい実施形態では、カラー印刷した繊維質積層構造体は、本明細書で説明されるような第1層と第2層のみから成る。
第1層は、体液(例:経血及び/または尿)が第1層の厚みを迅速に通過する液体透過性(換言すれば、液体浸透性)である。
第1層の材料の本来の色彩が、カラー印刷、特に明るい淡い色彩のカラー印刷に影響を及ぼすこともある。カラー印刷は、ソフト(黄色っぽい)ホワイトに対してより明瞭である一方、プロセスカラーは無色のホワイトの材料上で最も正確に再現されることが評価される。カラー印刷のコントラストまたは明るさを調節するために、第1層素材の明度を変えることも可能である。ほとんどの人工的な光沢剤は、色彩が無色ではなく、青の反射率が過剰なため、人工的な光沢剤(例:蛍光性添加剤)が第1層素材に組み込まれる場合、色彩を再現すると、その影響を受けることがある。第1層自体が彩色されることもあるが(すなわち、ホワイト以外のもう一つの色を有してもよい)、本明細書で次に説明されるようにカラー印刷される前には、第1層自体は彩色されていない、すなわちホワイトであることが非常に望ましい。
吸収性物品におけるカラー印刷した絵柄の例が、図5と図6に示されている。
カラー印刷した積層構造体の第2層は繊維質ウェブである。
本明細書で使用するための繊維質ウェブには、スパンレースの、湿式ウェブ及び乾式繊維質ウェブが挙げられる。乾式繊維質ウェブが本明細書では好ましく、本明細書において次に更に詳細に説明する。
本発明による積層構造体は、結合手段によって安定化される。
本明細書に用いるのに好適な結合手段は、積層構造体の繊維を結合することのできるいずれかの手段であり、それによって本発明による積層構造体を安定化させる。本明細書に用いるのに好適な結合手段には、にかわ、接着剤、ラテックス結合剤、熱可塑性ポリマー材料などの熱シール材料などが含まれるが、それらに制限されない当業者に既知のあらゆる従来の結合剤が挙げられる。
例えば、ラテックス結合剤は、水性エマルションまたは分散剤として適用され、典型的に約2%〜20%の固体、好ましくは2%〜10%の固体を含有し、またこのような材料は、数人の製造者から容易に入手可能である。ラテックスエマルションは、水混和性であるので、所望する場合、積層構造体の少なくとも一層、好ましくは外側層に適用される前に、更に希釈することもできる。同様に、これらのラテックス組成物は、熱硬化性であり、架橋を行うために、N−メチロールアクリルアミドなど、この目的に周知の化学剤である少量の好適な架橋剤を含有する。ユーザにとって不愉快になることがあるので、特に硬化後に、好ましくは認識可能なにおいを発生しないという条件で、(繊維質)積層構造体を安定化するために好適である、当該技術分野で既知のラテックス結合剤のあらゆるタイプを本明細書で使用し得る。入手可能なラテックスは、化学族によって分類され、特に有用なものには、ビニルアセテート及びアクリルエステルコポリマー、エチレンビニルアセテートコポリマー、スチレンブタジエンカルボキシレートコポリマー、及びポリアクリロニトリルが挙げられ、例えば、エアプロダクツ社(Air Products,Inc.)のエアボンド(Airbond)、エアフレックス(Airflex)、及びビナック(Vinac)と、グッドリッチケミカル社(Goodrich Chemical Co.)のハイカー(Hycar)及びジオン(Geon)と、H.B.フラー社(H.B.Fuller Company)のフラテックス(Fulatex)、との商品名で販売されている。使用されるラテックス結合剤の量は、繊維の流体取り扱い特性を実質的に害してしまう程、または構造体に硬さを付与して非実用的にしてしまう程、多くてはならない。典型的に、ラテックス結合剤は、積層構造体の約2重量%〜30重量%、好ましくは約4重量%〜8重量%の範囲であることも可能である。
第1層と、繊維質ウェブ、好ましくは乾式繊維質ウェブである第2層の二つの層を備える、カラー印刷した積層構造体を製造するのに好適な方法は、少なくとも次の:
(a)−前記第1層を提供し、その表面の少なくとも一表面上でカラー印刷する工程と、
(b)−次に、繊維を前記第1層上に提供して、前記第2層を形成する工程と、
(c)−次に、結合手段、好ましくはラテックス結合剤を前記第2層の外側表面上に適用して硬化させる工程と、及び/または、
(d)−結合手段、好ましくはラテックス結合剤を前記第1層の外側表面上に適用して硬化させる工程、
とを備える。
フレキソ印刷に比べて、スクリーン印刷の装置は相対的に費用がかかると共に、フレキソ印刷装置ほど早く稼動され得ない。
図1は、本発明の乾式繊維質積層構造体を製造するための好ましい実施形態を単純化した模式図である。この実施形態によれば、数字100によってほぼ示されるエア形成システムは、連続する形成スクリーンの上で横向きに配置された分配器ユニット101、ローラー103の上に搭載され、好適なモータ(図示せず)によって駆動されるカラー印刷した第1層(例えば、カラー印刷した不織布)102、及びスクリーンの下に配置されている真空手段または吸引ボックス104を備える。分配器ユニット101の上流には、ハンマーミルまたはランドフィーダなどのデフィブレータ(繊維化装置)またはフィーダ(供給装置)105があり、そこで梱、ラップなど(例えば、ロール106によって供給される木材パルプ)が繊維に分けられる。主として、使用される繊維のタイプ、使用される繊維の混合、及び要求される最終製品次第で、必要なまたは所望される場合、繊維は、洗浄及び/または混合することも可能である。例えば、木材パルプ繊維が合成繊維と混合されて、単一の分配器によって混合物として適用されてもよく、または異なる繊維が各々、異なる分配器によって第1層まで運搬されて、別個のプライまたは層を形成し得る。
本発明は、本明細書において次の生理用ナプキン及びパンティーライナーに関連して説明される一方、成人失禁保護または乳幼児保護など、女性保護以外の保護のために、本明細書で上述されたように適用可能でもある。
本明細書で次に主要トップシートとも呼ばれる、本発明で使用するトップシートは、少なくとも一つの主なトップ層から形成される。本明細書の好ましい実施形態では、主要トップシートは、本明細書で補助トップシートとも呼ばれる下部層と対面する関係にある。
或いは、主要トップシートの材料は、従来の(白い)材料から作製されて、透明になるように処理されることも可能である。そのような処理は一般に、不連続な熱結合、音波結合、または圧力によるエンボス加工によって熱エネルギーを適用することから成る。
主要トップシートは典型的には、吸収性構造体全体を横切って、吸収性構造体と同一の広がりを持つ区域の外側へ伸びる。
第1トップシートが言及される場合には、多重層孔あき構造体または単層孔あき構造体が各々考察される。
本発明における使用に好適な吸収性コアは、当該技術分野で既知の吸収性コアまたはコアシステムのいずれかから選択することも可能である。本明細書で使用する用語「吸収性コア」は、その主要な機能が流体を吸収、貯蔵、及び分布することである、いかなる物質または多数の物質の層を指す。本明細書の一実施形態では、本発明のカラー印刷した積層構造体は、吸収性コアの一部分として、または吸収性コア全体としても使用することも可能である。
バックシートは主として、吸収性構造体に吸収及び封じ込められた排泄物が、ズボン下、ズボン、パジャマ、及び下着など、吸収性のある製品に接触している衣類を濡らすのを防ぐ。バックシートは好ましくは、流体(例:経血及び/または尿)に不浸透性であり、好ましくは薄い可塑性フィルムから製造されるが、他の可撓性液体不浸透性材料も使用され得る。
図5は、着用者に面する表面から見た生理用ナプキン20の上部平面図を説明し、前記ナプキン20は、一つの主要トップ層21と、主要トップシート層21を通して見える補助トップシート層23とを含む。補助トップシート層23は、主要トップシート層21を通して見えるカラー印刷した絵柄24を備えている。主要トップ層21は、不規則に形成した五角形の孔22の巨視的に拡張された3次元パターンを表す3次元成形フィルムである。図示されないもう一つの実施形態では、そのような生理用ナプキンはエンボス加工され得、エンボス加工する箇所は、米国特許第4,397,644号明細書またはPCT国際公開特許WO98/27904号明細書に説明されているようにして得られる。
− 主要トップシート21として、0.889平方ミリメートルの孔、25g/m2の坪量、及び80%の開口区域を有する白色孔あきポリエチレン成形フィルム(インディアナ州テレホーテ(Terrehaute-Indiana)のトレデガー社(TREDEGAR)から市販されている、コードネームX25602のホワイトCPM)
− 補助トップシート23として、BBAリノテック社(Linotec)から得られる、製品番号No.1WH05−01−17B(または’P−9’)と呼ばれ、17g/m2の坪量を有し、その内側表面上をカラー印刷したスパンボンドポリプロピレン不織布材を22重量%と、全積層構造体の坪量の68重量%のセルロース及び25重量%のポリエチレン粉末から作製されたマルチボンドエアレイド不織布材と、両側面に適用された、全積層構造体の重量の4%のラテックス(2.5%をマルチボンドエアレイド上に、また1.5%をスパンボンドポリプロピレン不織布上に)、とから作製されたカラー印刷した積層構造体(77g/m2)。(図3参照)
− 接着剤の螺旋層(アトフィンドレー社(Ato Findley)から入手可能なH2545(登録商標))(図4に示さず)、
− 超吸収性繊維を17%と、ポリプロピレン及びポリエチレン二成分繊維と、セルロースとを有する白色吸収性ティッシュコア25(ドイツ、ファルケンハーゲン(Falkenhagen)のコンサート(Concert)GmbH社から市販されている、坪量150gsmのコードGH.150.1006)、
− 接着剤の螺旋層(アトフィンドレー社(Ato Findley)から入手可能なH2545(登録商標))(図4に示さず)、
− バックシートとして、トレデガー社(Tredegar)からコードXBF 616Wで市販されているポリエチレンマイクロエンボス加工フィルム26
− パンティー締着接着剤のストリップ(サバレ社(Savare)から入手可能なLA203/TF1(登録商標))(図4に示さず)と剥離ペーパー(図示せず)
生理用ナプキン(図4に説明)においてトップシート23(図3に説明)として本明細書で上述した、カラー印刷した積層構造体は、都合よく、(アルカリ溶液及び酸性溶液の両方について)ISO 105−E01に従って測定される時、水に対して4の染色堅牢度と、ISO 105−X12に従って測定される時、擦れに対して乾燥状態で4、湿潤状態で3の染色堅牢度と、ISO 105−E04に従って測定される時、発汗に対して4の染色堅牢度とを有する。
Claims (13)
- 第1液体透過性層と、繊維質ウェブである第2液体透過性層とを少なくとも備えるカラー印刷した液体透過性積層構造体であって、前記第1層を前記第2層に積層し、前記積層構造体を結合手段で安定化する前に、第1層を、少なくとも、その、前記第2層に直接隣接する表面上でカラー印刷することを特徴とする、カラー印刷した液体透過性積層構造体。
- 前記第1層が不織布である請求項1に記載の積層構造体。
- 前記カラー印刷が前記第1層の対向する表面において前記第1層を通して見えることを特徴とする、請求項1または2に記載の積層構造体。
- 前記第2層が、セルロース繊維を含む、乾式繊維質ウェブである、請求項1〜3のいずれか一項に記載の積層構造体。
- 前記乾式繊維質ウェブがエアレイドウェブである請求項4に記載の積層構造体。
- 前記構造体を安定化する前記結合手段が、前記積層構造体の総重量の2重量%〜30重量%のレベルで、ビニルアセテート及びアクリルエステルコポリマー、エチレンビニルアセテートコポリマー、スチレンブタジエンカルボキシレートコポリマー、並びにポリアクリロニトリルから成る群より選択されるラテックス結合剤を含む、請求項1〜5のいずれか一項に記載の積層構造体。
- 前記結合手段が、前記繊維質層の繊維を結合するために、前記第2の繊維質層内に分布された微粒子形状の熱可塑性ポリマー材料を含む、請求項1〜6のいずれか一項に記載の積層構造体。
- 前記第1層をカラー印刷するための色彩が、イエローからブルーまで(440〜580ナノメーター)の色彩範囲より選択される、請求項1〜7のいずれか一項に記載の積層構造体。
- 前記第1層が、水系インキでカラー印刷されている、請求項1〜8のいずれか一項に記載の積層構造体。
- トップシートと、バックシートと、前記トップシートを通して見えるように、前記トップシートに直接隣接する下部層として、請求項1〜9のいずれか一項に記載のカラー印刷した積層構造体、とを備える使い捨て吸収性物品。
- 請求項1〜9のいずれか1項に記載の積層構造体を製造する方法であって、該方法が:
(a)−前記第1層を提供し、次に、その少なくとも前記表面上でカラー印刷する工程と、
(b)−次に、繊維を前記第1層上に提供して、前記第2層を形成する工程と、
(c)−次に、結合手段を前記第2層の外側表面上に適用して硬化させる工程と、及び/または、
(d)−結合手段を前記第1層の外側表面上に適用して硬化させる工程、
とを備え、工程(c)と(d)の両方が行われる時、工程(c)と(d)は、最初に(c)次に(d)、最初に(d)次に(c)、または(c)と(d)の同時、を含むいかなる順序で行うことも可能な方法。 - 前記第1層のカラー印刷がフレキソ印刷によって行われる請求項11に記載の方法。
- 前記結合手段が、ラテックス結合剤である請求項11に記載の方法。
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PCT/US2002/029558 WO2003024706A1 (en) | 2001-09-19 | 2002-09-18 | A color printed laminated structure, absorbent article comprising the same and process or manufacturing the same |
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2001
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- 2001-09-19 DE DE60118737T patent/DE60118737T2/de not_active Expired - Lifetime
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- 2002-09-18 CN CNB028171799A patent/CN1301852C/zh not_active Expired - Fee Related
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WO2003024706A1 (en) | 2003-03-27 |
US20170312140A1 (en) | 2017-11-02 |
US20150245953A1 (en) | 2015-09-03 |
ATE322975T1 (de) | 2006-04-15 |
US20040170813A1 (en) | 2004-09-02 |
EP1295711A1 (en) | 2003-03-26 |
US20130281950A1 (en) | 2013-10-24 |
CA2459135A1 (en) | 2003-03-27 |
JP2005502509A (ja) | 2005-01-27 |
EP1295711B1 (en) | 2006-04-12 |
US9707133B2 (en) | 2017-07-18 |
US10596043B2 (en) | 2020-03-24 |
CN1549770A (zh) | 2004-11-24 |
BR0212674A (pt) | 2004-08-24 |
DE60118737T2 (de) | 2006-10-19 |
MXPA04002296A (es) | 2004-06-29 |
US9050220B2 (en) | 2015-06-09 |
CA2459135C (en) | 2009-07-14 |
CN1301852C (zh) | 2007-02-28 |
DE60118737D1 (de) | 2006-05-24 |
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