JP3618099B2 - アルドール化−脱水法 - Google Patents

アルドール化−脱水法 Download PDF

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Publication number
JP3618099B2
JP3618099B2 JP51727493A JP51727493A JP3618099B2 JP 3618099 B2 JP3618099 B2 JP 3618099B2 JP 51727493 A JP51727493 A JP 51727493A JP 51727493 A JP51727493 A JP 51727493A JP 3618099 B2 JP3618099 B2 JP 3618099B2
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aldolization
aldehyde
catalyst
distillation
aldehydes
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Expired - Lifetime
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JP51727493A
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Japanese (ja)
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JPH07505390A (ja
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ハリソン、ジョージ・エドウィン
リーズン、アーサー・ジェイムズ
デニス、アラン・ジェイムズ
シャリフ、モハメッド
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ダーヴィー・プロセス・テクノロジー・リミテッド
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • C07C45/66Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups by dehydration
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/74Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78Separation; Purification; Stabilisation; Use of additives
    • C07C45/81Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78Separation; Purification; Stabilisation; Use of additives
    • C07C45/81Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Glass Compositions (AREA)
  • Iron Core Of Rotating Electric Machines (AREA)
JP51727493A 1992-04-07 1993-04-07 アルドール化−脱水法 Expired - Lifetime JP3618099B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB9207756.9 1992-04-07
GB929207756A GB9207756D0 (en) 1992-04-07 1992-04-07 Process
PCT/GB1993/000729 WO1993020034A1 (en) 1992-04-07 1993-04-07 Aldolisation-dehydration process

Publications (2)

Publication Number Publication Date
JPH07505390A JPH07505390A (ja) 1995-06-15
JP3618099B2 true JP3618099B2 (ja) 2005-02-09

Family

ID=10713712

Family Applications (1)

Application Number Title Priority Date Filing Date
JP51727493A Expired - Lifetime JP3618099B2 (ja) 1992-04-07 1993-04-07 アルドール化−脱水法

Country Status (24)

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US (1) US5434313A (enExample)
EP (2) EP0751109A1 (enExample)
JP (1) JP3618099B2 (enExample)
KR (1) KR100278134B1 (enExample)
CN (1) CN1058697C (enExample)
AT (1) ATE162169T1 (enExample)
AU (1) AU659554B2 (enExample)
BR (1) BR9306208A (enExample)
CA (1) CA2133764A1 (enExample)
DE (1) DE69316349T2 (enExample)
ES (1) ES2114045T3 (enExample)
FI (1) FI944619A7 (enExample)
GB (1) GB9207756D0 (enExample)
HU (1) HUT69744A (enExample)
IN (1) IN181962B (enExample)
MX (1) MX9302044A (enExample)
NO (1) NO943694L (enExample)
RO (1) RO117969B1 (enExample)
RU (1) RU2113429C1 (enExample)
SA (1) SA93130546B1 (enExample)
SG (1) SG49573A1 (enExample)
TW (1) TW241254B (enExample)
WO (1) WO1993020034A1 (enExample)
ZA (1) ZA932451B (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013177365A (ja) * 2011-12-28 2013-09-09 Dow Global Technologies Llc 分岐不飽和アルデヒドを製造するための触媒および方法

Families Citing this family (71)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5667644A (en) * 1995-02-13 1997-09-16 Mitsubishi Chemical Corporation Method for producing a dimerized aldehyde
GB9519975D0 (en) * 1995-09-28 1995-11-29 Davy Process Techn Ltd Process
EP0838435A1 (en) 1996-10-25 1998-04-29 Kvaerner Process Technology Limited Process and plant for treating an aqueous waste stream containing alkali metal carboxylates
DE19956410A1 (de) * 1999-11-24 2001-05-31 Oxeno Olefinchemie Gmbh Verfahren zur Durchführung von Aldolkondensationen
CA2483310C (en) 2002-04-26 2011-09-13 Basf Aktiengesellschaft C10-alkanol alkoxylates and their use
CA2483470C (en) 2002-04-26 2010-11-09 Basf Aktiengesellschaft Alkoxylate mixtures and detergents comprising these
BR0309487A (pt) * 2002-04-26 2005-02-09 Basf Ag Misturas de alcoxilato, processo para a preparação e uso das mesmas, e, agente de lavagem, limpeza, umedecimento, revestimento, adesão, desengraxamento de couro, retenção de umidade ou de tratamento de têxtil ou formulações cosméticas, farmacêuticas ou para a proteção de plantas
DE10243366A1 (de) 2002-09-18 2004-04-01 Basf Ag Herstellung von Alkoxylaten bei optimierten Reaktionsdrücken
DE10249912A1 (de) 2002-10-26 2004-05-06 Oxeno Olefinchemie Gmbh Benzoesäureisodecyclestergemische, Herstellung und deren Verwendung
US6960694B2 (en) * 2003-07-01 2005-11-01 Eastman Chemical Company Processes for preparing β-hydroxy-ketones and α,β-unsaturated ketones
DE10348420A1 (de) * 2003-10-14 2005-05-25 Basf Ag C10-Alkanolalkoxylat-Gemische und ihre Verwendung - Neue schaumarme Netzer
US7071361B2 (en) * 2004-06-25 2006-07-04 Fastman Chemical Company Processes for the preparation of high molecular weight saturated ketones
RU2375477C2 (ru) * 2004-12-24 2009-12-10 Басф Акциенгезельшафт Водная цианидсодержащая композиция для выщелачивания металлов из содержащих их материалов
US7291748B2 (en) * 2005-07-28 2007-11-06 Basf Corporation C10/C7 ester mixtures based on 2-propylheptanol
BRPI0719724A2 (pt) * 2006-12-07 2014-02-18 Basf Se Composição, uso da composição, kit, uso de um kit, uso de composto, e, método para proteger uma planta contra fungos nocivos
WO2008092809A1 (de) * 2007-01-29 2008-08-07 Basf Se Verzweigte decylnitrate und ihre verwendung als verbrennungsverbesserer und/oder cetanzahlverbesserer in kraftstoffen
TW201031743A (en) 2008-12-18 2010-09-01 Basf Se Surfactant mixture comprising branched short-chain and branched long-chain components
DE102009001594A1 (de) * 2009-03-17 2010-09-30 Evonik Oxeno Gmbh Verfahren zur Herstellung von alpha, beta-ungesättigten C10-Aldehyden
DE102009028976A1 (de) 2009-08-28 2011-03-03 Evonik Oxeno Gmbh Ester der 2,5-Furandicarbonsäure mit isomeren Decanolen und ihre Verwendung
DE102009045139A1 (de) * 2009-09-30 2011-03-31 Evonik Oxeno Gmbh Herstellung von alpha,beta-ungesättigten Aldehyden mittels einer Reaktionsmischpumpe
KR20120099247A (ko) 2009-11-05 2012-09-07 바스프 에스이 2-프로필헵탄올 기재의 에스테르를 포함하는 접착제 및 실란트
RU2542974C2 (ru) 2010-08-03 2015-02-27 Басф Се Жидкости-носители для абразивов
EP2655511B1 (de) 2010-12-23 2016-04-06 INEOS Styrolution Europe GmbH Thermoplastische elastomer-zusammensetzung und verfahren zu deren herstellung
DE102011121087A1 (de) 2011-12-14 2013-06-20 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren zur katalytischen Kondensation oder Kopplung
WO2013113859A1 (de) 2012-02-01 2013-08-08 Basf Se Kühl- und/oder schmierflüssigkeiten zur waferherstellung
WO2014083138A1 (de) 2012-11-30 2014-06-05 Basf Se Verfahren zur katalytischen aldolkondensation von aldehyden
US9006495B2 (en) 2012-11-30 2015-04-14 Basf Se Process for the catalytic aldol condensation of aldehydes
TWI654177B (zh) 2013-10-31 2019-03-21 德商巴斯夫歐洲公司 製備羧酸酯的方法及其作爲塑化劑的用途
TR201808387T4 (tr) 2013-12-06 2018-07-23 Basf Se Tetra hidrofuran türevleri ve 1,2- siklo heksan dikarboksilik asit esteri içeren yumuşatıcı bileşimi.
KR20160106657A (ko) 2014-01-09 2016-09-12 바스프 에스이 푸란 유도체 및 1,2-시클로헥산디카르복실산 에스테르를 함유하는 가소제 조성물
KR20160148611A (ko) 2014-04-22 2016-12-26 바스프 에스이 이온성 액체 및 산성 에스테르화 촉매의 존재 하의 카르복실산 에스테르의 제조 방법 및 가소제로서의 그 용도
DE102015207291A1 (de) 2014-04-24 2016-03-10 Basf Se Weichmacher-Zusammensetzung, die Furanderivate und 1,2-Cyclohexandicarbonsäureester enthält
FR3021314B1 (fr) * 2014-05-26 2016-05-13 Rhodia Operations Procede de preparation de composes p-hydroxymandeliques en reacteurs agites
TW201605945A (zh) 2014-07-08 2016-02-16 巴斯夫歐洲公司 包含二羧酸的酯及1,2-環己烷二羧酸的酯之模製化合物
TW201609628A (zh) 2014-07-08 2016-03-16 巴斯夫歐洲公司 包含脂族二羧酸二酯及對苯二甲酸二烷基酯之塑化劑組成物
TWI706979B (zh) 2014-08-19 2020-10-11 德商巴斯夫歐洲公司 包含聚合二羧酸酯的塑化劑組成物
TWI686444B (zh) 2014-09-04 2020-03-01 德商巴斯夫歐洲公司 包含聚合二羧酸酯的塑化劑組成物
DE202014007140U1 (de) 2014-09-08 2014-10-22 Basf Se Öl-basierte Bohrflüssigkeiten mit Copolymeren aus Styrol, (Meth)acrylaten von C10-Alkoholgemischen und (Meth)acrylsäure
DE202014007136U1 (de) 2014-09-08 2014-10-16 Basf Se Härtbare Zusammensetzung, hergestellt mit einem aus (Meth)acrylaten von C10-Alkoholgemischen aufgebauten Copolymer
TW201619120A (zh) 2014-10-09 2016-06-01 巴斯夫歐洲公司 包含飽和二羧酸之環烷基酯及對苯二甲酯之塑化劑組成物
TW201619119A (zh) 2014-10-09 2016-06-01 巴斯夫歐洲公司 包含飽和二羧酸之環烷基酯及1,2-環己烷二羧酸酯的塑化劑組成物
CA2965228A1 (en) 2014-11-10 2016-05-19 Basf Se Ethylene-propylheptyl(meth-)acrylate copolymers
US10287417B2 (en) 2015-01-30 2019-05-14 Basf Se Plasticizer composition containing polymeric dicarboxylic acid esters and terephthalic acid dialkyl esters
ES2744073T3 (es) 2015-09-30 2020-02-21 Basf Se Composición de plastificante que contiene ésteres de ácido dicarboxílico poliméricos y dialquilésteres de ácido tereftálico
US20180282510A1 (en) 2015-09-30 2018-10-04 Basf Se Plasticizer composition containing polymeric dicarboxylic acid esters and dicarboxylic acid diesters
WO2017055429A1 (de) 2015-09-30 2017-04-06 Basf Se Weichmacher-zusammensetzung, die polymere dicarbonsäureester und 1,2-cyclohexandicarbonsäureester enthält
WO2017125458A1 (de) 2016-01-20 2017-07-27 Basf Se Weichmacher-zusammensetzung, die aliphatische dicarbonsäureester und diester, die unter 1,2-cyclohexandicarbonsäureestern und terephthalsäureestern ausgewählt sind, enthält
PL3433309T3 (pl) 2016-03-23 2020-11-16 Basf Se Kompozycja polimerowa, zawierająca diester cykloalkilowo-alkilowy kwasu dikarboksylowego jako plastyfikator
CN109563306A (zh) 2016-08-01 2019-04-02 巴斯夫欧洲公司 增塑剂组合物
WO2018024597A1 (de) 2016-08-01 2018-02-08 Basf Se Weichmacher-zusammensetzung
WO2018024591A1 (de) 2016-08-01 2018-02-08 Basf Se Weichmacher-zusammensetzung
EP3301084B1 (de) 2016-09-30 2018-12-12 OXEA GmbH Kontinuierliches herstellungsverfahren für 2-methylenalkanale
GB201617463D0 (en) 2016-10-14 2016-11-30 Johnson Matthey Davy Technologies Limited Process
EP3630712B1 (en) * 2017-05-25 2021-04-07 Rohm and Haas Company Process for preparing methacrolein
US11214533B2 (en) 2017-06-28 2022-01-04 Dow Global Technologies Llc Readily biodegradable alkoxylate mixtures
WO2019185409A1 (de) 2018-03-29 2019-10-03 Basf Se Pvc-zusammensetzung, enthaltend wenigstens einen weichmacher der wenigstens eine carbonsäureestergruppe aufweist und wenigstens eine carbodiimidverbindung
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EP3747860B1 (de) 2019-06-04 2023-07-26 Basf Se Neue weichmacher auf cyclohexanon-basis
EP3786146A1 (de) * 2019-08-30 2021-03-03 Röhm GmbH Verfahren zur herstellung von methacrolein aus formaldehyd und propionaldehyd sowie herstellanlage hierfür
EP3786147A1 (de) * 2019-08-30 2021-03-03 Röhm GmbH Verfahren zur herstellung von methacrolein aus formaldehyd und propionaldehyd sowie herstellanlage hierfür
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JP2023142625A (ja) * 2022-03-25 2023-10-05 株式会社ダイセル クロトンアルデヒドの製造方法
GB202213997D0 (en) 2022-09-26 2022-11-09 Johnson Matthey Davy Technologies Ltd Parallel zone hydroformylation reaction
EP4638409A1 (de) 2022-12-21 2025-10-29 Basf Se Weichmacher-verbindung
WO2024133359A1 (de) 2022-12-21 2024-06-27 Basf Se Weichmacher
WO2024153687A1 (de) 2023-01-19 2024-07-25 Basf Se Verfahren zur herstellung von 1,2-cyclohexandicarbonsäuredialkylestern
GB202303617D0 (en) 2023-03-13 2023-04-26 Johnson Matthey Davy Technologies Ltd Method and apparatus for producing aldehyde
WO2024228768A1 (en) 2023-05-04 2024-11-07 Dow Technology Investments Llc Hydroformylation process
WO2024256670A1 (de) 2023-06-15 2024-12-19 Basf Se Weichmacher-zusammensetzung
CN117229132B (zh) * 2023-11-10 2024-02-20 济南悟通生物科技有限公司 一种反式-2,4-壬二烯醛的合成方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB549006A (en) * 1940-02-12 1942-11-03 Shell Dev Condensation of carbonylic compounds
GB714883A (en) * 1951-04-25 1954-09-01 Melle Usines Sa Improvements relating to the production of unsaturated aliphatic aldehydes
FR1036156A (fr) * 1951-04-25 1953-09-04 Melle Usines Sa Procédé de préparation d'aldéhydes aliphatiques non saturées
US3248428A (en) * 1961-12-22 1966-04-26 Exxon Research Engineering Co Aldolization process
GB1010695A (en) * 1961-12-22 1965-11-24 Exxon Research Engineering Co Process for the production of alpha, beta unsaturated carbonyl compounds
DE3106557A1 (de) * 1981-02-21 1982-09-16 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von (alpha)-alkylacroleinen
DE3740293A1 (de) * 1987-11-27 1989-06-01 Hoechst Ag Verfahren zur herstellung von alpha-alkylacroleinen
CA2068489A1 (en) * 1991-05-16 1992-11-17 Masaru Ishino Aldol condensation dehydration catalyst, a process for preparing the same and a process for preparing an aldol condensation dehydrate using the process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013177365A (ja) * 2011-12-28 2013-09-09 Dow Global Technologies Llc 分岐不飽和アルデヒドを製造するための触媒および方法

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Publication number Publication date
TW241254B (enExample) 1995-02-21
FI944619A0 (fi) 1994-10-04
CA2133764A1 (en) 1993-10-14
GB9207756D0 (en) 1992-05-27
RO117969B1 (ro) 2002-11-29
ATE162169T1 (de) 1998-01-15
EP0634994B1 (en) 1998-01-14
HUT69744A (en) 1995-09-28
RU2113429C1 (ru) 1998-06-20
MX9302044A (es) 1994-07-29
FI944619A7 (fi) 1994-10-04
EP0751109A1 (en) 1997-01-02
AU659554B2 (en) 1995-05-18
CN1105012A (zh) 1995-07-12
NO943694D0 (no) 1994-10-04
SA93130546B1 (ar) 2004-08-29
DE69316349T2 (de) 1998-07-23
CN1058697C (zh) 2000-11-22
DE69316349D1 (de) 1998-02-19
NO943694L (no) 1994-12-06
US5434313A (en) 1995-07-18
IN181962B (enExample) 1998-11-21
AU3958793A (en) 1993-11-08
KR100278134B1 (ko) 2001-02-01
SG49573A1 (en) 1998-06-15
BR9306208A (pt) 1998-06-23
JPH07505390A (ja) 1995-06-15
KR950700869A (ko) 1995-02-20
WO1993020034A1 (en) 1993-10-14
ES2114045T3 (es) 1998-05-16
EP0634994A1 (en) 1995-01-25
ZA932451B (en) 1993-10-20
RU94045865A (ru) 1996-08-10

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