JP2015504239A5 - - Google Patents
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- JP2015504239A5 JP2015504239A5 JP2014541148A JP2014541148A JP2015504239A5 JP 2015504239 A5 JP2015504239 A5 JP 2015504239A5 JP 2014541148 A JP2014541148 A JP 2014541148A JP 2014541148 A JP2014541148 A JP 2014541148A JP 2015504239 A5 JP2015504239 A5 JP 2015504239A5
- Authority
- JP
- Japan
- Prior art keywords
- dielectric layer
- water vapor
- exposing
- substrate
- chamber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 17
- 239000000758 substrate Substances 0.000 claims 12
- 239000007789 gas Substances 0.000 claims 7
- 238000004140 cleaning Methods 0.000 claims 4
- 229910052739 hydrogen Inorganic materials 0.000 claims 4
- 239000002184 metal Substances 0.000 claims 4
- 229910052760 oxygen Inorganic materials 0.000 claims 4
- 210000002381 Plasma Anatomy 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 3
- 239000001301 oxygen Substances 0.000 claims 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 3
- 239000005368 silicate glass Substances 0.000 claims 3
- 229910052581 Si3N4 Inorganic materials 0.000 claims 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N Silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- -1 phosphorus-silicate Chemical compound 0.000 claims 2
- 229910021332 silicide Inorganic materials 0.000 claims 2
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims 2
- 238000009736 wetting Methods 0.000 claims 2
- AYHOQSGNVUZKJA-UHFFFAOYSA-N [B+3].[B+3].[B+3].[B+3].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] Chemical compound [B+3].[B+3].[B+3].[B+3].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] AYHOQSGNVUZKJA-UHFFFAOYSA-N 0.000 claims 1
- 229910052786 argon Inorganic materials 0.000 claims 1
- 239000005380 borophosphosilicate glass Substances 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 239000001307 helium Substances 0.000 claims 1
- 229910052734 helium Inorganic materials 0.000 claims 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium(0) Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims 1
- 230000005660 hydrophilic surface Effects 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
Claims (15)
- 基板の表面を洗浄する方法であって、
コンタクト構造体を有する基板を処理チャンバ内に配置することであって、前記基板が、前記基板上に配置され、前記基板上に開口を形成する誘電体層を有する、前記配置すること、
前記基板上に配置された前記誘電体層を、前記チャンバ内に供給された水蒸気にさらし、水蒸気中にプラズマを形成すること、
前記チャンバ内のプロセス圧力を約1トルから約120トルの間に維持すること、および
前記基板上に形成された前記コンタクト構造体を洗浄すること
を含む方法。 - 前記コンタクト構造体を形成するのに使用された前記誘電体層が、ドープされていないシリコンガラス(USG)、ホウ素−ケイ酸塩ガラス(BSG)、リン−ケイ酸塩ガラス(PSG)、ホウ素−リン−ケイ酸塩ガラス(BPSG)およびこれらの混合物からなるグループから選択される、請求項1に記載の方法。
- 前記誘電体層をさらすことが、
約40度未満の濡れ角を有するように前記誘電体層の表面を制御すること
をさらに含む、請求項1に記載の方法。 - 前記誘電体層をさらすことが、
前記誘電体層の表面を親水性表面に変えること
をさらに含む、請求項3に記載の方法。 - 前記誘電体層を前記水蒸気にさらすことが、
前記水蒸気と一緒に、酸素を含むガスまたは水素を含むガスを前記チャンバ内に供給すること
をさらに含む、請求項1に記載の方法。 - 前記誘電体層をさらすことが、
前記水蒸気中に前記プラズマを形成するため、約5ワットから約5000ワットの間のRF電力を加えること
をさらに含む、請求項1に記載の方法。 - 前記誘電体層をさらすことが、
前記水蒸気にさらす前に、前記誘電体層を、炭素−フッ素を含むガスにさらすこと
をさらに含む、請求項1に記載の方法。 - 前記水蒸気が、アルゴン、ヘリウムまたは窒素の存在下で生成される、請求項1に記載の方法。
- 前記誘電体層を前記水蒸気にさらすことが、
前記水蒸気を前記チャンバにパルスモードで供給すること
をさらに含む、請求項1に記載の方法。 - 前記基板上に形成された前記開口が、その下のコンタクト金属またはコンタクト金属ケイ化物層またはコンタクト窒化ケイ素層を露出させる前記誘電体層内の前記開口の中に開口を形成することをさらに含む、請求項1に記載の方法。
- 前記チャンバに供給された前記水蒸気が、前記基板上に配置された、前記コンタクト金属またはコンタクト金属ケイ化物層またはコンタクト窒化ケイ素層、および前記誘電体層を洗浄する、請求項10に記載の方法。
- 基板表面を洗浄する方法であって、
その上に配置された誘電体層を有する基板をチャンバ内に配置すること、
前記誘電体層を、前記チャンバ内に供給された水蒸気にさらし、水蒸気中にプラズマを形成すること、
約40度未満の濡れ角を有するように前記誘電体層の表面を制御すること、および
前記基板から前記誘電体層を洗浄すること
を含む方法。 - 前記誘電体層を前記水蒸気にさらすことが、
前記チャンバ内のプロセス圧力を約1トルから約120トルの間に維持すること
をさらに含む、請求項12に記載の方法。 - 前記誘電体層を前記水蒸気にさらすことが、
前記水蒸気にRF電力を加えること
をさらに含む、請求項12に記載の方法。 - 前記誘電体層を前記水蒸気にさらすことが、
前記水蒸気と一緒に、酸素を含むガスおよび/または水素を含むガスを前記チャンバに流入させることをさらに含み、前記酸素を含むガスが、O2、N2O、CO2、NOおよびNO2からなるグループから選択され、前記水素を含むガスが、H2、H2O2およびNH3からなるグループから選択される、
請求項12に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/291,286 US9653327B2 (en) | 2011-05-12 | 2011-11-08 | Methods of removing a material layer from a substrate using water vapor treatment |
US13/291,286 | 2011-11-08 | ||
PCT/US2012/063651 WO2013070570A1 (en) | 2011-11-08 | 2012-11-06 | Methods of removing a material layer from a substrate using water vapor treatment |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2015504239A JP2015504239A (ja) | 2015-02-05 |
JP2015504239A5 true JP2015504239A5 (ja) | 2015-12-24 |
JP6158199B2 JP6158199B2 (ja) | 2017-07-05 |
Family
ID=47141035
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014541148A Active JP6158199B2 (ja) | 2011-11-08 | 2012-11-06 | 水蒸気処理を使用して基板から材料層を除去する方法 |
Country Status (5)
Country | Link |
---|---|
US (1) | US9653327B2 (ja) |
JP (1) | JP6158199B2 (ja) |
KR (1) | KR102033707B1 (ja) |
TW (1) | TWI636501B (ja) |
WO (1) | WO2013070570A1 (ja) |
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