JP2014512451A5 - - Google Patents
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- Publication number
- JP2014512451A5 JP2014512451A5 JP2014508121A JP2014508121A JP2014512451A5 JP 2014512451 A5 JP2014512451 A5 JP 2014512451A5 JP 2014508121 A JP2014508121 A JP 2014508121A JP 2014508121 A JP2014508121 A JP 2014508121A JP 2014512451 A5 JP2014512451 A5 JP 2014512451A5
- Authority
- JP
- Japan
- Prior art keywords
- mixture
- organic solvent
- temperature
- catalyst component
- magnesium compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 claims 4
- 239000003960 organic solvent Substances 0.000 claims 3
- 229910052719 titanium Inorganic materials 0.000 claims 3
- 239000010936 titanium Substances 0.000 claims 3
- -1 alkyl epoxide Chemical class 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 150000002681 magnesium compounds Chemical class 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 2
- 239000002841 Lewis acid Substances 0.000 claims 1
- 150000007517 lewis acids Chemical class 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
Claims (1)
- ポリオレフィン製造用の固体チタン触媒成分を製造する方法であって、
非還元性マグネシウム化合物、アルキルエポキシド、ルイス酸、及び有機溶媒を接触させて混合物を得る工程(ただし、有機溶媒は、得られる混合物が二以上の相:ハロアルコキシドマグネシウム化合物を含むマグネシウム相及び有機溶媒を含む溶媒相を生成するように選択される)と、
第1温度で混合物にハロゲン化チタンを添加する工程と、
第1温度より高い第2温度で混合物に界面活性剤を添加する工程と、
実質的に球形状で所定のサイズを有する固体チタン触媒成分を混合物から分離する工程と、
を有することを特徴とする製造方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/097,210 | 2011-04-29 | ||
US13/097,210 US8685879B2 (en) | 2011-04-29 | 2011-04-29 | Emulsion process for improved large spherical polypropylene catalysts |
PCT/US2012/035507 WO2012149360A1 (en) | 2011-04-29 | 2012-04-27 | Emulsion process for improved large spherical polypropylene catalysts |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2014512451A JP2014512451A (ja) | 2014-05-22 |
JP2014512451A5 true JP2014512451A5 (ja) | 2015-06-18 |
JP6152091B2 JP6152091B2 (ja) | 2017-06-21 |
Family
ID=47068335
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014508121A Active JP6152091B2 (ja) | 2011-04-29 | 2012-04-27 | 改良された大球形のポリプロピレン触媒用の乳化方法 |
Country Status (8)
Country | Link |
---|---|
US (1) | US8685879B2 (ja) |
EP (1) | EP2701843B1 (ja) |
JP (1) | JP6152091B2 (ja) |
KR (1) | KR101944562B1 (ja) |
CN (1) | CN103619475B (ja) |
BR (1) | BR112013027847B1 (ja) |
ES (1) | ES2661105T3 (ja) |
WO (1) | WO2012149360A1 (ja) |
Families Citing this family (19)
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JP6623323B2 (ja) * | 2012-12-12 | 2019-12-25 | ブラスケム アメリカ インコーポレイテッドBraskem America,Inc. | オレフィン重合触媒用の内部電子供与体、その作製および使用方法 |
WO2014102813A1 (en) * | 2012-12-31 | 2014-07-03 | Reliance Industries Limited | Heterogeneous ziegler-natta catalyst system and a process for olefin polymerization using the same |
WO2015054758A1 (pt) * | 2013-10-17 | 2015-04-23 | Petróleo Brasileiro S.A. - Petrobras | Método de preparo de catalisadores ziegler-natta bissuportados |
TWI650335B (zh) * | 2013-10-18 | 2019-02-11 | 中國石油化工科技開發有限公司 | 用於烯烴聚合催化劑的球形載體、催化劑組分、催化劑及它們的製備方法 |
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MX2016008105A (es) * | 2013-12-18 | 2016-10-03 | Braskem Sa | Soporte de catalizador y procesos relacionados. |
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US9738736B2 (en) * | 2014-08-12 | 2017-08-22 | W. R. Grace & Co.-Conn | Combined internal donor system for Ziegler-Natta polyolefin catalysts and methods of making and using same |
US9714302B2 (en) * | 2014-10-10 | 2017-07-25 | W. R. Grace & Co.—Conn. | Process for preparing spherical polymerization catalyst components for use in olefin polymerizations |
CN108117618A (zh) * | 2016-11-28 | 2018-06-05 | 任丘市利和科技发展有限公司 | 一种气相聚合法制备聚烯烃的方法 |
CN108117617B (zh) * | 2016-11-28 | 2021-05-04 | 任丘市利和科技发展有限公司 | 一种用于烯烃聚合的固体催化剂组分和催化剂 |
US11279777B2 (en) * | 2017-10-24 | 2022-03-22 | Borealis Ag | Catalysts |
WO2019094216A1 (en) * | 2017-11-13 | 2019-05-16 | W.R. Grace & Co.-Conn. | Catalyst components for propylene polymerization |
US11753486B2 (en) | 2017-12-28 | 2023-09-12 | Borealis Ag | Catalyst and preparation thereof |
CN108219038B (zh) * | 2018-01-09 | 2021-01-26 | 为信(深圳)材料科技有限公司 | 烷氧基镁颗粒的组份及制备方法 |
CN110283261B (zh) * | 2019-06-28 | 2021-08-03 | 上海化工研究院有限公司 | 一种烯烃聚合催化剂的主体组分及其制备方法 |
TW202231673A (zh) | 2020-10-15 | 2022-08-16 | 大陸商中國石油化工科技開發有限公司 | 具有多峰孔分佈的鎂基固體物和催化劑組分以及它們的製備方法 |
CN116622012A (zh) * | 2023-06-21 | 2023-08-22 | 金发科技股份有限公司 | 一种丙烯聚合用球型载体及其制备方法以及其制成的丙烯聚合催化剂 |
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-
2011
- 2011-04-29 US US13/097,210 patent/US8685879B2/en active Active
-
2012
- 2012-04-27 CN CN201280032149.7A patent/CN103619475B/zh active Active
- 2012-04-27 ES ES12776274.8T patent/ES2661105T3/es active Active
- 2012-04-27 EP EP12776274.8A patent/EP2701843B1/en active Active
- 2012-04-27 WO PCT/US2012/035507 patent/WO2012149360A1/en active Application Filing
- 2012-04-27 KR KR1020137031287A patent/KR101944562B1/ko active IP Right Grant
- 2012-04-27 JP JP2014508121A patent/JP6152091B2/ja active Active
- 2012-04-27 BR BR112013027847-1A patent/BR112013027847B1/pt active IP Right Grant
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