JP2008540863A5 - - Google Patents
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- Publication number
- JP2008540863A5 JP2008540863A5 JP2008511239A JP2008511239A JP2008540863A5 JP 2008540863 A5 JP2008540863 A5 JP 2008540863A5 JP 2008511239 A JP2008511239 A JP 2008511239A JP 2008511239 A JP2008511239 A JP 2008511239A JP 2008540863 A5 JP2008540863 A5 JP 2008540863A5
- Authority
- JP
- Japan
- Prior art keywords
- glycol
- poly
- tetramethylene
- spandex
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 162
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 78
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 58
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 45
- 229920002334 Spandex Polymers 0.000 claims description 41
- 239000004759 spandex Substances 0.000 claims description 41
- 239000005977 Ethylene Substances 0.000 claims description 27
- 239000004970 Chain extender Substances 0.000 claims description 26
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 26
- 125000005442 diisocyanate group Chemical group 0.000 claims description 24
- 150000004985 diamines Chemical class 0.000 claims description 14
- 239000007795 chemical reaction product Substances 0.000 claims description 12
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 12
- 125000004427 diamine group Chemical group 0.000 claims description 8
- 150000002009 diols Chemical class 0.000 claims description 6
- 238000009987 spinning Methods 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine group Chemical group NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 229940035437 1,3-propanediol Drugs 0.000 description 2
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 description 2
- LHOBKFFUEUQRQX-UHFFFAOYSA-N 2,2,4-trimethylpentane-1,5-diol Chemical compound OCC(C)CC(C)(C)CO LHOBKFFUEUQRQX-UHFFFAOYSA-N 0.000 description 2
- KMKROLUYWRLWCT-UHFFFAOYSA-N 2,2-dimethylbutane-1,3-diamine Chemical compound CC(N)C(C)(C)CN KMKROLUYWRLWCT-UHFFFAOYSA-N 0.000 description 2
- DDHUNHGZUHZNKB-UHFFFAOYSA-N 2,2-dimethylpropane-1,3-diamine Chemical compound NCC(C)(C)CN DDHUNHGZUHZNKB-UHFFFAOYSA-N 0.000 description 2
- VNAWKNVDKFZFSU-UHFFFAOYSA-N 2-ethyl-2-methylpropane-1,3-diol Chemical compound CCC(C)(CO)CO VNAWKNVDKFZFSU-UHFFFAOYSA-N 0.000 description 2
- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 description 2
- QTKDDPSHNLZGRO-UHFFFAOYSA-N 4-methylcyclohexane-1,3-diamine Chemical compound CC1CCC(N)CC1N QTKDDPSHNLZGRO-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- RGTXVXDNHPWPHH-UHFFFAOYSA-N butane-1,3-diamine Chemical compound CC(N)CCN RGTXVXDNHPWPHH-UHFFFAOYSA-N 0.000 description 2
- WTSXICLFTPPDTL-UHFFFAOYSA-N pentane-1,3-diamine Chemical compound CCC(N)CCN WTSXICLFTPPDTL-UHFFFAOYSA-N 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 2
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 2
- -1 1,3-cyclohexanediamine 1,2-diaminobutane Chemical compound 0.000 description 1
- WTPYFJNYAMXZJG-UHFFFAOYSA-N 2-[4-(2-hydroxyethoxy)phenoxy]ethanol Chemical compound OCCOC1=CC=C(OCCO)C=C1 WTPYFJNYAMXZJG-UHFFFAOYSA-N 0.000 description 1
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 description 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 description 1
- ULEAQRIQMIQDPJ-UHFFFAOYSA-N butane-1,2-diamine Chemical compound CCC(N)CN ULEAQRIQMIQDPJ-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- GEQHKFFSPGPGLN-UHFFFAOYSA-N cyclohexane-1,3-diamine Chemical compound NC1CCCC(N)C1 GEQHKFFSPGPGLN-UHFFFAOYSA-N 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
- XTBMQKZEIICCCS-UHFFFAOYSA-N hexane-1,5-diamine Chemical group CC(N)CCCCN XTBMQKZEIICCCS-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US59481105P | 2005-05-09 | 2005-05-09 | |
| US60/594,811 | 2005-05-09 | ||
| US73873405P | 2005-11-22 | 2005-11-22 | |
| US73873305P | 2005-11-22 | 2005-11-22 | |
| US60/738,734 | 2005-11-22 | ||
| US60/738,733 | 2005-11-22 | ||
| PCT/US2006/017723 WO2006122027A2 (en) | 2005-05-09 | 2006-05-08 | Spandex compositons for high speed spinning |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008540863A JP2008540863A (ja) | 2008-11-20 |
| JP2008540863A5 true JP2008540863A5 (enExample) | 2009-06-25 |
| JP5203936B2 JP5203936B2 (ja) | 2013-06-05 |
Family
ID=36940635
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008511239A Expired - Fee Related JP5203936B2 (ja) | 2005-05-09 | 2006-05-08 | 高速紡糸用のスパンデックス組成物 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US8765901B2 (enExample) |
| EP (1) | EP1880045B1 (enExample) |
| JP (1) | JP5203936B2 (enExample) |
| KR (1) | KR101322054B1 (enExample) |
| CN (1) | CN103806122A (enExample) |
| AT (1) | ATE429531T1 (enExample) |
| BR (1) | BRPI0612949B1 (enExample) |
| CA (1) | CA2606283C (enExample) |
| DE (1) | DE602006006435D1 (enExample) |
| ES (1) | ES2323547T3 (enExample) |
| HK (1) | HK1198184A1 (enExample) |
| WO (1) | WO2006122027A2 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9441314B2 (en) * | 2005-11-22 | 2016-09-13 | Invista North America S.A.R.L. | Spandex from high molecular weight poly (tetramethylene-co-ethyleneether) glycols |
| ES2403419T3 (es) * | 2005-11-22 | 2013-05-17 | Invista Technologies S.À.R.L. | Elastano obtenido a partir de poli(tetrametilén-co-etilén éter)glicoles mezclados con glicoles poliméricos |
| US9499929B2 (en) * | 2007-11-29 | 2016-11-22 | Invista North America S.A.R.L. | High-loft nonwoven including stabilizer or binder |
| BRPI0912075A2 (pt) * | 2008-08-06 | 2017-05-23 | Invista Technologies Sarl | "artigo que compreende ao menos um substrato relativamente não elástico, um material de poliuretano selecionado a partir do grupo que consiste em um filme e um ou mais filamentos, processo para fabricar uma estrutura compósita elástica e processo para fabricar uma estrutura laminada compósita multicamada elástica" |
| KR101148302B1 (ko) * | 2009-12-31 | 2012-05-25 | 주식회사 효성 | 고속방사용 폴리우레탄우레아 탄성사의 제조방법 |
| WO2012124691A1 (ja) | 2011-03-14 | 2012-09-20 | 旭化成せんい株式会社 | ポリウレタン弾性繊維 |
| WO2013103159A1 (ko) * | 2012-01-03 | 2013-07-11 | 주식회사 효성 | 우수한 파워를 가진 탄성사의 제조 방법 및 이를 이용하여 제조된 고파워 탄성사 |
| TWI751100B (zh) * | 2014-05-05 | 2022-01-01 | 盧森堡商英威達技術有限公司 | 生物衍生之聚胺基甲酸酯纖維 |
| KR101941317B1 (ko) * | 2014-11-28 | 2019-01-23 | 효성티앤씨 주식회사 | 저온 가공성 폴리우레탄우레아 탄성사 |
| CN111575817A (zh) * | 2019-02-19 | 2020-08-25 | 海宁新高纤维有限公司 | 一种热塑性聚氨酯纤维的制造方法 |
| CN111718461B (zh) * | 2019-03-22 | 2022-06-21 | 浙江华峰热塑性聚氨酯有限公司 | 热塑性聚氨酯弹性纤维及其制备方法 |
| JP2023517945A (ja) * | 2020-03-11 | 2023-04-27 | ザ ライクラ カンパニー ユーケー リミテッド | 目寄れ防止性能を有する弾性繊維、複合ヤーンおよび布地 |
| CN115867241A (zh) | 2020-03-25 | 2023-03-28 | 莱卡英国有限公司 | 弹性化非织造层合物 |
| KR102836618B1 (ko) * | 2025-02-21 | 2025-07-22 | 효성티앤씨 주식회사 | 에스터계 공중합 폴리올을 적용한 생분해성 폴리우레탄우레아 탄성사 및 이의 제조방법 |
Family Cites Families (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3425999A (en) | 1966-07-11 | 1969-02-04 | Wyandotte Chemicals Corp | Tetrahydrofuran-ethylene oxide polyether urethane-urea polymers |
| US4163115A (en) | 1976-03-31 | 1979-07-31 | E. I. Du Pont De Nemours And Company | Preparation of esters of poly-(tetramethylene ether) glycol |
| US4139567A (en) | 1977-03-30 | 1979-02-13 | E. I. Du Pont De Nemours And Company | Method for preparing copolyether glycols |
| US4153786A (en) | 1977-03-30 | 1979-05-08 | E. I. Du Pont De Nemours And Company | Method for preparing ester end-capped copolyether glycols |
| US4120850A (en) * | 1977-09-06 | 1978-10-17 | E. I. Du Pont De Nemours And Company | Polyether urethane polymers prepared from a copolymer of tetrahydrofuran and ethylene oxide |
| DE2964245D1 (en) * | 1978-03-16 | 1983-01-20 | Du Pont | Polyurethanes prepared with tetrahydrofuran-alkylene oxide polymerizates having low oligomeric cyclic ether content, processes for preparing the same, and articles and fibers of the polyurethanes |
| US4224432A (en) | 1978-12-11 | 1980-09-23 | E. I. Du Pont De Nemours And Company | Polyurethanes prepared with tetrahydrofuran-alkylene oxide polymerizates having low oligomeric cyclic ether content |
| US4383100A (en) * | 1980-09-19 | 1983-05-10 | E. I. Du Pont De Nemours And Company | Polyurethanes from oligomeric formal diols of THF copolymer glycols |
| CA1216597A (en) | 1983-05-23 | 1987-01-13 | Atsushi Aoshima | Process for producing polyetherglycol |
| EP0158229B1 (en) | 1984-03-28 | 1988-06-22 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for producing polyether polyol, the produced polyether polyol and polyurethane |
| JPH06104116B2 (ja) * | 1988-11-29 | 1994-12-21 | 三菱化成株式会社 | 創傷被覆材 |
| DE4104199A1 (de) | 1991-02-12 | 1992-08-13 | Basf Ag | Verfahren zur herstellung von polyurethan-elastomeren und hierfuer geeignete mischungen aus polyoxybutylen-polyoxyalkylen-glykolen und glycidylverbindungen |
| US5340902A (en) | 1993-06-04 | 1994-08-23 | Olin Corporation | Spandex fibers made using low unsaturation polyols |
| KR100239204B1 (ko) | 1995-06-23 | 2000-01-15 | 야마모토 카즈모토 | 폴리우레탄 탄성 섬유 및 그의 제조 방법 |
| DE19625987A1 (de) | 1996-06-28 | 1998-01-02 | Bayer Ag | Verfahren zur kontinuierlichen Herstellung von thermoplastisch verarbeitbaren Polyurethanen mit verbessertem Verarbeitungsverhalten |
| US5998574A (en) | 1996-07-10 | 1999-12-07 | Basf Corporation | Compositions of polytetramethylene ether glycols and polyoxy alkylene polyether polyols having a low degree of unsaturation |
| JPH1077323A (ja) | 1996-08-30 | 1998-03-24 | Asahi Chem Ind Co Ltd | ポリウレタンウレア重合体溶液及び該溶液から弾性成形体の製造方法。 |
| TW507028B (en) | 1999-02-12 | 2002-10-21 | Asahi Chemical Ind | A moisture-absorbable synthetic fiber with an improved moisture-release property |
| JP2001098423A (ja) | 1999-09-29 | 2001-04-10 | Asahi Kasei Corp | 高速吸湿性ポリウレタン系弾性繊維 |
| KR100709049B1 (ko) | 1999-09-30 | 2007-04-18 | 세키스이가가쿠 고교가부시키가이샤 | 열가소성 엘라스토머, 그 용도 및 제조 방법 |
| US6639041B2 (en) * | 1999-12-03 | 2003-10-28 | Dupont-Toray Co. Ltd. | Spandex having low set at low temperatures |
| JP4362803B2 (ja) * | 1999-12-03 | 2009-11-11 | オペロンテックス株式会社 | ポリウレタン弾性繊維およびその製造方法 |
| JP2002155421A (ja) | 2000-11-16 | 2002-05-31 | Toyobo Co Ltd | 乾式紡糸方法 |
| JP2002348730A (ja) * | 2001-05-28 | 2002-12-04 | Du Pont Toray Co Ltd | サニタリー用ポリウレタン弾性繊維 |
| JP2002363823A (ja) * | 2001-06-05 | 2002-12-18 | Du Pont Toray Co Ltd | 吸湿性ポリウレタン弾性繊維およびその製造方法 |
| US6989432B2 (en) | 2002-01-10 | 2006-01-24 | Invista North America S.A.R.L. | Copolymers of tetrahydrofuran, ethylene oxide and an additional cyclic ether |
| JP4449011B2 (ja) | 2002-06-04 | 2010-04-14 | 東レ・オペロンテックス株式会社 | サニタリー用品 |
| US6984708B2 (en) * | 2002-10-04 | 2006-01-10 | Invista North America S.A.R.L. | Spandex of a particular composition and process for making same |
| CN100344663C (zh) | 2002-11-04 | 2007-10-24 | 因维斯塔技术有限公司 | 使用聚酯二醇的聚(脲－氨酯)水分散体 |
| EP1567572A1 (en) | 2002-11-04 | 2005-08-31 | INVISTA Technologies S.à.r.l. | Aqueous dispersions of poly(urea/urethanes) |
| AU2003301886A1 (en) | 2002-11-04 | 2004-06-07 | Invista Technologies S.A.R.L. | Articles treated with aqueous dispersions of poly(urea/urethanes) |
| WO2004041892A1 (en) | 2002-11-04 | 2004-05-21 | Invista Technologies S.À.R.L. | Articles comprising aqueous dispersions using poly(urea/urethanes) |
| JP2004218096A (ja) | 2003-01-09 | 2004-08-05 | Du Pont Toray Co Ltd | 伸縮性薄膜用品 |
| JP2004215686A (ja) | 2003-01-09 | 2004-08-05 | Du Pont Toray Co Ltd | 伸縮性薄膜用品 |
| EP1592727B1 (en) | 2003-02-14 | 2011-11-16 | Dow Global Technologies LLC | Hydrophilic polyurethane polymers derived from a mdi-based isocyanate-terminated prepolymer |
| KR101137663B1 (ko) | 2003-02-20 | 2012-04-20 | 인비스타 테크놀러지스 에스.에이.알.엘 | 폴리(우레아/우레탄)의 수성 분산액을 포함하는 물품 |
| US6916896B2 (en) * | 2003-05-05 | 2005-07-12 | Invista North America S.A.R.L. | High productivity spandex fiber process and product |
| ES2403419T3 (es) * | 2005-11-22 | 2013-05-17 | Invista Technologies S.À.R.L. | Elastano obtenido a partir de poli(tetrametilén-co-etilén éter)glicoles mezclados con glicoles poliméricos |
-
2006
- 2006-05-08 KR KR1020077025948A patent/KR101322054B1/ko not_active Expired - Fee Related
- 2006-05-08 US US11/429,897 patent/US8765901B2/en not_active Expired - Fee Related
- 2006-05-08 CA CA2606283A patent/CA2606283C/en not_active Expired - Fee Related
- 2006-05-08 DE DE602006006435T patent/DE602006006435D1/de active Active
- 2006-05-08 JP JP2008511239A patent/JP5203936B2/ja not_active Expired - Fee Related
- 2006-05-08 ES ES06752394T patent/ES2323547T3/es active Active
- 2006-05-08 AT AT06752394T patent/ATE429531T1/de not_active IP Right Cessation
- 2006-05-08 CN CN201410054162.3A patent/CN103806122A/zh active Pending
- 2006-05-08 EP EP06752394A patent/EP1880045B1/en not_active Not-in-force
- 2006-05-08 BR BRPI0612949A patent/BRPI0612949B1/pt not_active IP Right Cessation
- 2006-05-08 WO PCT/US2006/017723 patent/WO2006122027A2/en not_active Ceased
-
2014
- 2014-11-19 HK HK14111656.6A patent/HK1198184A1/xx unknown
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