JP2009516770A5 - - Google Patents
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- Publication number
- JP2009516770A5 JP2009516770A5 JP2008542295A JP2008542295A JP2009516770A5 JP 2009516770 A5 JP2009516770 A5 JP 2009516770A5 JP 2008542295 A JP2008542295 A JP 2008542295A JP 2008542295 A JP2008542295 A JP 2008542295A JP 2009516770 A5 JP2009516770 A5 JP 2009516770A5
- Authority
- JP
- Japan
- Prior art keywords
- glycol
- tetramethylene
- poly
- daltons
- unit derived
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 72
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 36
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 24
- 229920002334 Spandex Polymers 0.000 claims description 18
- 239000004759 spandex Substances 0.000 claims description 18
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 16
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 16
- 125000005442 diisocyanate group Chemical group 0.000 claims description 10
- 239000007795 chemical reaction product Substances 0.000 claims description 9
- 229920003226 polyurethane urea Polymers 0.000 claims description 9
- 239000004970 Chain extender Substances 0.000 claims description 8
- 239000005977 Ethylene Substances 0.000 claims description 8
- 239000000047 product Substances 0.000 claims description 8
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 8
- 239000004814 polyurethane Substances 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 6
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 4
- 239000004606 Fillers/Extenders Substances 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 150000002009 diols Chemical group 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- 229920001971 elastomer Polymers 0.000 claims description 4
- 239000000806 elastomer Substances 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 4
- 239000010408 film Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 claims description 4
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 claims description 4
- 238000009987 spinning Methods 0.000 claims description 3
- PZVANPGBOPAOIK-UHFFFAOYSA-N (1,3,3-trimethylcyclohexyl)methanamine Chemical compound CC1(C)CCCC(C)(CN)C1 PZVANPGBOPAOIK-UHFFFAOYSA-N 0.000 claims description 2
- KMKROLUYWRLWCT-UHFFFAOYSA-N 2,2-dimethylbutane-1,3-diamine Chemical compound CC(N)C(C)(C)CN KMKROLUYWRLWCT-UHFFFAOYSA-N 0.000 claims description 2
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- RGTXVXDNHPWPHH-UHFFFAOYSA-N butane-1,3-diamine Chemical compound CC(N)CCN RGTXVXDNHPWPHH-UHFFFAOYSA-N 0.000 claims description 2
- ZUIWIAKRBMBOBR-UHFFFAOYSA-N cyclohexane-1,3-diamine 4-methylcyclohexane-1,3-diamine Chemical compound NC1CCCC(N)C1.CC1CCC(N)CC1N ZUIWIAKRBMBOBR-UHFFFAOYSA-N 0.000 claims description 2
- VKIRRGRTJUUZHS-UHFFFAOYSA-N cyclohexane-1,4-diamine Chemical compound NC1CCC(N)CC1 VKIRRGRTJUUZHS-UHFFFAOYSA-N 0.000 claims description 2
- 125000004427 diamine group Chemical group 0.000 claims description 2
- 150000004985 diamines Chemical class 0.000 claims description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 2
- 150000002429 hydrazines Chemical class 0.000 claims description 2
- WTSXICLFTPPDTL-UHFFFAOYSA-N pentane-1,3-diamine Chemical compound CCC(N)CCN WTSXICLFTPPDTL-UHFFFAOYSA-N 0.000 claims description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 2
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000004753 textile Substances 0.000 claims 1
- 238000000034 method Methods 0.000 description 2
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US73868405P | 2005-11-22 | 2005-11-22 | |
| US73890105P | 2005-11-22 | 2005-11-22 | |
| US60/738,684 | 2005-11-22 | ||
| US60/738,901 | 2005-11-22 | ||
| PCT/US2006/017724 WO2007061446A1 (en) | 2005-11-22 | 2006-05-08 | Spandex from high molecular weight poly (tetramethylene-co-ethyleneether) glycols |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009516770A JP2009516770A (ja) | 2009-04-23 |
| JP2009516770A5 true JP2009516770A5 (enExample) | 2009-06-25 |
| JP5271085B2 JP5271085B2 (ja) | 2013-08-21 |
Family
ID=36763162
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008542295A Expired - Fee Related JP5271085B2 (ja) | 2005-11-22 | 2006-05-08 | 高分子量ポリ(テトラメチレン−コ−エチレンエーテル)グリコールからのスパンデックス |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9441314B2 (enExample) |
| EP (1) | EP1951782A1 (enExample) |
| JP (1) | JP5271085B2 (enExample) |
| KR (1) | KR101328876B1 (enExample) |
| CN (1) | CN104387545A (enExample) |
| BR (1) | BRPI0620534A2 (enExample) |
| HK (1) | HK1207873A1 (enExample) |
| WO (1) | WO2007061446A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8574394B2 (en) * | 2007-12-21 | 2013-11-05 | Henkel Ag & Co. Kgaa | Method for preparing a moisture curable hot melt adhesive |
| KR20120017040A (ko) * | 2009-04-15 | 2012-02-27 | 인비스타 테크놀러지스 에스.에이.알.엘. | 코폴리에테르 글리콜 제조 방법 |
| CN102695738B (zh) * | 2009-12-11 | 2014-12-10 | 因温斯特技术公司 | 改良的弹性体组合物 |
| EP2614103B1 (en) * | 2010-09-10 | 2015-04-15 | Invista Technologies S.a r.l. | Polyetheramines, compositions including polyetheramines, and methods of making |
| US20180305842A1 (en) * | 2015-06-30 | 2018-10-25 | Invista North America S.A R.L. | Polyurethane fiber including copolymer polyol |
| KR101782726B1 (ko) | 2016-04-11 | 2017-09-29 | 한양대학교 산학협력단 | 산화그래핀 방사 용액의 제조 방법, 및 이를 이용한 그래핀 섬유의 제조 방법 |
| KR101782725B1 (ko) * | 2016-04-11 | 2017-09-29 | 한양대학교 산학협력단 | 그래핀 섬유 및 그 제조 방법 |
| CN109072484B (zh) * | 2016-04-11 | 2021-06-04 | 汉阳大学校产学协力团 | 石墨烯纤维及其的制备方法 |
| WO2017179900A1 (ko) * | 2016-04-11 | 2017-10-19 | 한양대학교 산학협력단 | 그래핀 섬유 및 그 제조 방법 |
| US11649566B2 (en) | 2016-04-11 | 2023-05-16 | Iucf-Hyu (Industry-University Cooperation Foundation Hanyang University) | Graphene fiber and method of manufacturing the same |
| KR102660907B1 (ko) * | 2016-08-19 | 2024-04-26 | 한양대학교 산학협력단 | 그래핀 섬유 복합체 및 그 제조 방법 |
| MX2024011005A (es) | 2022-03-10 | 2024-09-17 | Basf Se | Poliuretano urea y su metodo de preparacion. |
Family Cites Families (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3425999A (en) * | 1966-07-11 | 1969-02-04 | Wyandotte Chemicals Corp | Tetrahydrofuran-ethylene oxide polyether urethane-urea polymers |
| US4163115A (en) | 1976-03-31 | 1979-07-31 | E. I. Du Pont De Nemours And Company | Preparation of esters of poly-(tetramethylene ether) glycol |
| US4139567A (en) | 1977-03-30 | 1979-02-13 | E. I. Du Pont De Nemours And Company | Method for preparing copolyether glycols |
| US4153786A (en) | 1977-03-30 | 1979-05-08 | E. I. Du Pont De Nemours And Company | Method for preparing ester end-capped copolyether glycols |
| US4120850A (en) * | 1977-09-06 | 1978-10-17 | E. I. Du Pont De Nemours And Company | Polyether urethane polymers prepared from a copolymer of tetrahydrofuran and ethylene oxide |
| US4224432A (en) | 1978-12-11 | 1980-09-23 | E. I. Du Pont De Nemours And Company | Polyurethanes prepared with tetrahydrofuran-alkylene oxide polymerizates having low oligomeric cyclic ether content |
| DE2964245D1 (en) * | 1978-03-16 | 1983-01-20 | Du Pont | Polyurethanes prepared with tetrahydrofuran-alkylene oxide polymerizates having low oligomeric cyclic ether content, processes for preparing the same, and articles and fibers of the polyurethanes |
| US4383100A (en) * | 1980-09-19 | 1983-05-10 | E. I. Du Pont De Nemours And Company | Polyurethanes from oligomeric formal diols of THF copolymer glycols |
| CA1216597A (en) | 1983-05-23 | 1987-01-13 | Atsushi Aoshima | Process for producing polyetherglycol |
| EP0158229B1 (en) | 1984-03-28 | 1988-06-22 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for producing polyether polyol, the produced polyether polyol and polyurethane |
| JPS61155417A (ja) * | 1984-12-27 | 1986-07-15 | Sanyo Chem Ind Ltd | ポリウレタンの製造法 |
| JPH06104116B2 (ja) * | 1988-11-29 | 1994-12-21 | 三菱化成株式会社 | 創傷被覆材 |
| DE4104199A1 (de) | 1991-02-12 | 1992-08-13 | Basf Ag | Verfahren zur herstellung von polyurethan-elastomeren und hierfuer geeignete mischungen aus polyoxybutylen-polyoxyalkylen-glykolen und glycidylverbindungen |
| US5340902A (en) | 1993-06-04 | 1994-08-23 | Olin Corporation | Spandex fibers made using low unsaturation polyols |
| KR100239204B1 (ko) | 1995-06-23 | 2000-01-15 | 야마모토 카즈모토 | 폴리우레탄 탄성 섬유 및 그의 제조 방법 |
| DE19625987A1 (de) | 1996-06-28 | 1998-01-02 | Bayer Ag | Verfahren zur kontinuierlichen Herstellung von thermoplastisch verarbeitbaren Polyurethanen mit verbessertem Verarbeitungsverhalten |
| US5998574A (en) | 1996-07-10 | 1999-12-07 | Basf Corporation | Compositions of polytetramethylene ether glycols and polyoxy alkylene polyether polyols having a low degree of unsaturation |
| US6050451A (en) * | 1998-11-19 | 2000-04-18 | Aptargroup, Inc. | Dispensing structure incorporating a valve-containing fitment for mounting to a container and a package with a dispensing structure |
| TW507028B (en) | 1999-02-12 | 2002-10-21 | Asahi Chemical Ind | A moisture-absorbable synthetic fiber with an improved moisture-release property |
| JP2001098423A (ja) | 1999-09-29 | 2001-04-10 | Asahi Kasei Corp | 高速吸湿性ポリウレタン系弾性繊維 |
| KR100709049B1 (ko) | 1999-09-30 | 2007-04-18 | 세키스이가가쿠 고교가부시키가이샤 | 열가소성 엘라스토머, 그 용도 및 제조 방법 |
| US6063892A (en) * | 1999-10-05 | 2000-05-16 | E. I. Du Pont De Nemours And Company | Spandex prepared with hindered diisocyanates |
| US6639041B2 (en) * | 1999-12-03 | 2003-10-28 | Dupont-Toray Co. Ltd. | Spandex having low set at low temperatures |
| JP4362803B2 (ja) * | 1999-12-03 | 2009-11-11 | オペロンテックス株式会社 | ポリウレタン弾性繊維およびその製造方法 |
| JP4487112B2 (ja) * | 1999-12-03 | 2010-06-23 | 東レ・オペロンテックス株式会社 | ポリウレタン弾性繊維およびその製造方法 |
| US6989432B2 (en) | 2002-01-10 | 2006-01-24 | Invista North America S.A.R.L. | Copolymers of tetrahydrofuran, ethylene oxide and an additional cyclic ether |
| JP4449011B2 (ja) | 2002-06-04 | 2010-04-14 | 東レ・オペロンテックス株式会社 | サニタリー用品 |
| US6984708B2 (en) * | 2002-10-04 | 2006-01-10 | Invista North America S.A.R.L. | Spandex of a particular composition and process for making same |
| JP2004131861A (ja) * | 2002-10-09 | 2004-04-30 | Du Pont Toray Co Ltd | ポリウレタン弾性繊維の製造方法 |
| EP1567572A1 (en) | 2002-11-04 | 2005-08-31 | INVISTA Technologies S.à.r.l. | Aqueous dispersions of poly(urea/urethanes) |
| AU2003301886A1 (en) | 2002-11-04 | 2004-06-07 | Invista Technologies S.A.R.L. | Articles treated with aqueous dispersions of poly(urea/urethanes) |
| CN100344663C (zh) | 2002-11-04 | 2007-10-24 | 因维斯塔技术有限公司 | 使用聚酯二醇的聚(脲-氨酯)水分散体 |
| WO2004041892A1 (en) | 2002-11-04 | 2004-05-21 | Invista Technologies S.À.R.L. | Articles comprising aqueous dispersions using poly(urea/urethanes) |
| JP2004215686A (ja) | 2003-01-09 | 2004-08-05 | Du Pont Toray Co Ltd | 伸縮性薄膜用品 |
| JP2004218096A (ja) | 2003-01-09 | 2004-08-05 | Du Pont Toray Co Ltd | 伸縮性薄膜用品 |
| EP1592727B1 (en) | 2003-02-14 | 2011-11-16 | Dow Global Technologies LLC | Hydrophilic polyurethane polymers derived from a mdi-based isocyanate-terminated prepolymer |
| KR101137663B1 (ko) | 2003-02-20 | 2012-04-20 | 인비스타 테크놀러지스 에스.에이.알.엘 | 폴리(우레아/우레탄)의 수성 분산액을 포함하는 물품 |
| US6916896B2 (en) * | 2003-05-05 | 2005-07-12 | Invista North America S.A.R.L. | High productivity spandex fiber process and product |
| JP2008540765A (ja) * | 2005-05-09 | 2008-11-20 | インヴィスタ テクノロジー エスアエルエル | 高エチレンエーテル含有率を有するポリ(テトラメチレン−コ−エチレンエーテル)グリコールからのスパンデックス |
| KR101322054B1 (ko) * | 2005-05-09 | 2013-10-25 | 인비스타 테크놀러지스 에스.에이.알.엘. | 고속 방사용 스판덱스 조성물 |
| US20070117949A1 (en) * | 2005-11-22 | 2007-05-24 | Palmer Charles F Jr | Spandex from poly(tetramethylene-co-ethyleneether) glycols having low ethyleneether content |
-
2006
- 2006-05-08 US US11/429,850 patent/US9441314B2/en not_active Expired - Fee Related
- 2006-05-08 BR BRPI0620534-8A patent/BRPI0620534A2/pt not_active IP Right Cessation
- 2006-05-08 JP JP2008542295A patent/JP5271085B2/ja not_active Expired - Fee Related
- 2006-05-08 EP EP06752395A patent/EP1951782A1/en not_active Withdrawn
- 2006-05-08 KR KR1020087012110A patent/KR101328876B1/ko not_active Expired - Fee Related
- 2006-05-08 CN CN201410575598.7A patent/CN104387545A/zh active Pending
- 2006-05-08 WO PCT/US2006/017724 patent/WO2007061446A1/en not_active Ceased
-
2015
- 2015-09-01 HK HK15108518.9A patent/HK1207873A1/xx unknown
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